Magnetic Anisotropy of Rocks

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Anisoft5 Magnetic Anisotropy of Rocks Martin Chadima AGICO Inc., Brno, Czech Republic Institute of Geology, ASCR, v.v.i., Prague, Czech Republic

Magnetic anisotropy of rocks Literature Tarling, D.H. & Hrouda, F. 1993. The Magnetic Anisotropy of Rock. Chapman & Hall, 217 pp. Lanza, R. & Meloni, A. 2006. The Earth s Magnetism: An Introduction for Geologist. Springer, 278 pp. (Chapter 5). Hrouda, F. 2007. Magnetic Susceptibility, Anisotropy. Encyclopedia of Geomagnetism and Paleomagnetism. Springer. 546-560. Sagnotti, L. 2009. Magnetic anisotropy. Encyclopedia of Solid Earth Geophysics. Springer. 717-729. Tauxe, L. 2013. Lectures in paleomagnetism. http://magician.ucsd.edu/essentials_2/webbook2ch13.html#x15-15500013. Hrouda, F., 1982. Magnetic anisotropy of rocks and its application in geology and geophysics. Geophysical Surveys, 5, 37 82. Borradaile, G. J. & Henry, B. 1997. Tectonic applications of magnetic susceptibility and its anisotropy. Earth Science Reviews, 42, 49 93. Jackson,M.J. & Tauxe, L. 1991. Anisotropy of magnetic susceptibility and remanence: developments in the characterization of tectonic, sedimentary, and igneous fabric. Reviews of Geophysics, 29, 371 376. Rochette, P., Jackson, M. J. & Aubourg, C. 1992. Rock magnetism and the interpretation of anisotropy of magnetic susceptibility. Reviews of Geophysics, 30, 209 226.

Magnetic anisotropy of rocks Agenda 1. Definition and application in geology 2. Magnetic anisotropy of minerals 3. Magnetic fabric vs. texture of rocks 4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks 5. Magnetic fabric of igneous rocks 6. Sampling, measurement and data processing

1. Definition and application in geology Agenda 1. Definition and application in geology 2. Magnetic anisotropy of minerals 3. Magnetic fabric vs. texture of rocks 4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks 5. Magnetic fabric of igneous rocks 6. Sampling, measurement and data processing

1. Definition and application in geology Definition Magnetic anisotropy is a directional variability of a certain magnetic property, usually Anisotropy of Magnetic Susceptibility (AMS) Tool to study rock texture (Petrofabric) Compared to the other methods of fabric analysis (U-stage, X-ray texture goniometry, neutron texture goniometry, EBSD), AMS is fast, cheap, high-resolution, non-destructive. It can be applied to many samples covering whole outcrops, drill cores, or geological units. Application in structural geology and tectonics, volcanology, sedimentology, and paleomagnetism.

1. Definition and application in geology Magnetic susceptibility is the ability to acquire induced magnetization, i.e. ability to get magnetized k = M / H M H k = Mi / H M = Mi + Mr Induced magnetization Remanent magnetization Mi = k H Magnetic susceptibility

1. Definition and application in geology Diamagnetism Paramagnetism Ferromagnetism (s.l.) M M M k < 0 k > 0 k >> 0 Induced magnetization antiparallel to the external field Magnetic susceptibility relatively low and negative Induced magnetization parallel to the external field Magnetic susceptibility relatively low and positive Complex relationship between external field and induced magnetization: hysteresis curve Magnetic susceptibiliy relatively high No remanence No remanence Remanent magnetization quartz calcite aragonite pyroxene hornblende olivine micas iron magnetite hematite pyrrhotite

1. Definition and application in geology Magnetic susceptibility is the ability to acquire induced magnetization, i.e. ability to get magnetized M = k H Contribution of selected minerals to whole rock susceptibility k = M / H

1. Definition and application in geology Anisotropy magnetic susceptibility (AMS) Magnetically isotropic material M 1 = k H 1 M 2 = k H 2 M 3 = k H 3 Magnetization of anisotropic materials M 1 = k 11 H 1 + k 12 H 2 + k 13 H 3 M 2 = k 21 H 1 + k 22 H 2 + k 23 H 3 M 3 = k 31 H 1 + k 32 H 2 + k 33 H 3 Matrix notation Vector of field intensity M 1 = k 11 k 12 k 13 H 1 M 2 = k 21 k 22 k 23 H 2 M 3 = k 31 k 32 k 33 H 3 Vector of magnetization Susceptibility tensor

1. Definition and application in geology Anisotropic magnetizing ellipsoidal grain If one magnetizes an ellipsoidal grain of magnetite and the magnetizing field is parallel to ellipsoid axes, the magnetization is parallel to the field. Otherwise, the magnetization deflects from the field. The relationship between field and magnetization is described by the susceptibility tensor. M = k H

1. Definition and application in geology Ellipsoid as geometrical visualization of tensor M 1 = k 11 k 12 k 13 H 1 M 2 = k 21 k 22 k 23 H 2 M 3 = k 31 k 32 k 33 H 3

1. Definition and application in geology Magnetic fabric Rock fabric defined from magnetic anisotropy X Y Principal susceptibilities k 1 k 2 k 3 Mean susceptibility k m = (k 1 + k 2 + k 3 ) / 3 Degree of anisotropy P = k 1 / k 3 Shape parameter T = (2 2-1 - ) / ( - ) where = ln k 1, = ln k 2, = ln k 3 +1 > T > 0 oblate (planar) fabric -1 < T < 0 prolate (linear) fabric

1. Definition and application in geology Shapes of anisotropy ellipsoids Rotational prolate Triaxial prolate Neutral Triaxial oblate Rotational oblate

1. Definition and application in geology Quantitative parametrs of anisotropy k 1 k 2 k 3 k m = (k 1 + k 2 + k 3 ) / 3 P = k 1 / k 3 L = k 1 / k 2 F = k 2 / k 3 principal susceptibilities mean susceptibility degree of anisotropy degree of magnetic lineation degree of magnetic foliation T = (2-1 - 3) / ( 1-3) where 1 = ln k 1, 2 = ln k 2, 3 = ln k 3 +1 > T > 0-1 < T < 0 Pj = P a a = (1+T 2 / 3) shape parameter oblate (planar) ellipsoid prolate (linear) ellipsoid corrected degree of anisotropy

1. Definition and application in geology Flinn diagram (L-F plot)

1. Definition and application in geology Jelinek diagram (Pj-T plot)

1. Definition and application in geology P T Lambert projection, Lower hemisphere Degree of anisotropy vs. Mean susceptibility 270 Geographic coordinate system N Equal-area projection N=35 90 1.10 1.09 1.08 1.07 1.06 1.05 1.04 1.03 1.02 1.01 1.00 50 55 60 65 70 75 80 85 90 95 100 105 Km [E-03 SI] P-T plot (Jelinek plot) Max Int Min 180 D 1.0 0.5 0.0-0.5-1.0 1.00 1.01 1.02 1.03 1.04 1.05 1.06 1.07 1.08 1.09 1.10 P

2. Magnetic anisotropy of minerals Agenda 1. Definition and application in geology 2. Magnetic anisotropy of minerals 3. Magnetic fabric vs. texture of rocks 4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks 5. Magnetic fabric of igneous rocks 6. Sampling, measurement and data processing

2. Magnetic anisotropy of minerals Shape anisotropy Magnetite Magnetocrystalline anisotropy All other minerals Biotite Biotite

2. Magnetic anisotropy of minerals Magnetocrystalline anisotropy Hematite k 1 = k 2 >> k 3 P > 100 Pyrrhotite k 1 = k 2 >> k 3 P > 300

2. Magnetic anisotropy of minerals Magnetocrystalline anisotropy

2. Magnetic anisotropy of minerals Magnetocrystalline anisotropy Biotite k 1 = k 2 > k 3 P = 1.2-1.6 Muscovite k 1 = k 2 > k 3 P = 1.3-1.4 Chlorite k 1 = k 2 > k 3 P = 1.2-1.8

2. Magnetic anisotropy of minerals Magnetic properties of selected minerals Mineral Susceptibility [10-6 ] Degree of anisotropy Shape of anisotropy Anisotropy type Magnetite 3000000 1.1 to 3.0 Variable Shape Hematite 1300 to 7000 >100 ~1.00 Magnetocrystalline Pyrrhotite 100 to 10000 ~1.00 Magnetocrystalline Actinolite 490 1.2 to 1.2-0.40 to 0.40 Magnetocrystalline Hornblende 746 to 1368 1.665-0.51 Magnetocrystalline Glaucophane 787 1.205 0.10 Magnetocrystalline Chlorite 70 to 1550 1.2 to 1.7 ~1.00 Magnetocrystalline Biotite 998 to 1290 1.2 to 1.6 ~1.00 Magnetocrystalline Phlogopite 1178 1.3 0.95 Magnetocrystalline Muscovite 122 to 165 1.4 0.44 Magnetocrystalline Quartz -13.4 to -15.4 1.01 1.00 Magnetocrystalline Calcite -13.8 1.11 1.00 Magnetocrystalline Aragonite -15.0 1.15 0.80 Magnetocrystalline

2. Magnetic anisotropy of minerals Contribution of selected minerals to whole rock susceptibility

3. Magnetic fabric vs. texture of rocks Agenda 1. Definition and application in geology 2. Magnetic anisotropy of minerals 3. Magnetic fabric vs. texture of rocks 4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks 5. Magnetic fabric of igneous rocks 6. Sampling, measurement and data processing

3. Magnetic fabric vs. texture of rocks Rock anisotropy degree as a function of preferred orientation of its minerals

3. Magnetic fabric vs. texture of rocks

3. Magnetic fabric vs. texture of rocks Magnetic fabrics of higher order oblate fabric prolate fabric

3. Magnetic fabric vs. texture of rocks Comparison of magnetic fabric and neutron texture goniometry

3. Magnetic fabric vs. texture of rocks Comparison of magnetic fabric and neutron texture goniometry Isolines of chlorite c-axes N AMS principal directions 1.00 1.20 1.40 1.60 Eigenvectors of Orientation tensor Neutron texture goniometer TEX2 GKSS Forschungszentrum Geesthacht GmbH, Germany Shale, Rhenohercynian Belt, Czech Republic

3. Magnetic fabric vs. texture of rocks

3. Magnetic fabric vs. texture of rocks Comparison of magnetic fabric and neutron texture goniometry Neogene basin, Southern Italy (courtesy F. Cifelli)

4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks Agenda 1. Definition and application in geology 2. Magnetic anisotropy of minerals 3. Magnetic fabric vs. texture of rocks 4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks 5. Magnetic fabric of igneous rocks 6. Sampling, measurement and data processing

4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks Magnetic susceptibility usually carried by paramagnetic minerals

4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks Relatively low magnetic susceptibility Anisotropy degree < 5% Oblate fabric Sedimentary rocks K < 300 10-6 P < 1.05 Anchimetamorphosed sediments K < 500 10-6 P < 1.30

4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks calm sedimentation slow current fast (turbulent) current (after Tauxe 2013)

4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks Examples of various sedimentary fabrics No current Current Turbidites

4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks Deformation of sediments T 1.0 0.5 2 1 5 6 0-0.5 3 1.05 4 1.10 1.15 P x 1 4 5 2 3-1.0 6 y z sedimentary fabric incipient deformation pencil structure weak cleavage strong cleavage deformational fabric x y

4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks Pencil structure (southern Pyrenees, Spain)

4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks

4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks Accretionary wedge

4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks Tertiary accretionary wedge, southern Pyrenees

4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks Tertiary accretionary wedge, southern Pyrenees (Parés & van der Pluijm 1999)

4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks Tertiary accretionary wedge, southern Pyrenees (Parés & van der Pluijm 1999)

4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks Paleozoic accretionary wedge Rhenohercynian Belt, Czech Republic

4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks Paleozoic accretionary wedge Rhenohercynian Belt, Czech Republic (Chadima et al. 2006)

4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks Anisotropy degree (P) Shape parameter (T)

4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks Extentional tectonic setting Extentional setting Neogene basin, southern Italy (courtesy F. Cifelli)

4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks

4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks loess paleosol loess paleosol silty paleosol loess

4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks N 270 90 K1 K2 K3 180 N=85

4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks (Hajná et al. 2010)

4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks (Hajná et al. 2010)

4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks (Hajná et al. 2010)

5. Magnetic fabric of igneous rocks Agenda 1. Definition and application in geology 2. Magnetic anisotropy of minerals 3. Magnetic fabric vs. texture of rocks 4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks 5. Magnetic fabric of igneous rocks 6. Sampling, measurement and data processing

5. Magnetic fabric of igneous rocks 1. Volcanic rocks 2. Dikes 3. Plutonic rocks

5. Magnetic fabric of igneous rocks Magnetic susceptibility dominantly carried by magnetite

5. Magnetic fabric of igneous rocks Igneous rocks Very high magnetic susceptibility Relatively low anisotropy degree K < 50 0000 10-6 P < 1.03

5. Magnetic fabric of igneous rocks

5. Magnetic fabric of igneous rocks Volcanic rocks

5. Magnetic fabric of igneous rocks Lava flows A a Pahoehoe

5. Magnetic fabric of igneous rocks Lipari Island, Tyrrhenian Sea, Italy

5. Magnetic fabric of igneous rocks Lipari Island, Tyrrhenian Sea

5. Magnetic fabric of igneous rocks Chaîne des Puys, Massif Central, France

5. Magnetic fabric of igneous rocks Section across lava flow (Loock et al. 2008)

5. Magnetic fabric of igneous rocks Pyroclastic flow, Pompeii, Italy (Gurioli et al. 2005)

5. Magnetic fabric of igneous rocks

5. Magnetic fabric of igneous rocks

5. Magnetic fabric of igneous rocks Pyroclastic flow, Pompeii, Italy (Gurioli et al. 2005)

5. Magnetic fabric of igneous rocks Dikes

5. Magnetic fabric of igneous rocks Estimate of flow direction

5. Magnetic fabric of igneous rocks Dikes

5. Magnetic fabric of igneous rocks magnetic lineation is not always parallel to flow direction preferably use imbrication of magnetic foliation

5. Magnetic fabric of igneous rocks Wilson, J. T. 1963. A possible origin of the Hawaiian Islands. Canadian Journal of Physics, 41, 863-670.

5. Magnetic fabric of igneous rocks

5. Magnetic fabric of igneous rocks Island of Oahu

5. Magnetic fabric of igneous rocks Geology of Oahu

5. Magnetic fabric of igneous rocks Koolau (Knight & Walker 1988) W Keneohe Bay 1 2 Kawainui Swamp 3 Waimanalo Bay SE

5. Magnetic fabric of igneous rocks Plutonic rocks

5. Magnetic fabric of igneous rocks Plutonic rocks bimodal distribution of magnetic susceptibility (granitoids of former USSR) weakly magnetic (paramagnetic) granitoides S type ( Sedimentary ) carrier of magnetization mainly biotite (hornblende) strongly magnetic (ferromagnetic) granitoides I type (Igneous) carrier of magnetization mainly magnetite

5. Magnetic fabric of igneous rocks

5. Magnetic fabric of igneous rocks Brno Massif

5. Magnetic fabric of igneous rocks

5. Magnetic fabric of igneous rocks Foliations and lineations in plutons originate by magma flow Magnetic foliation = magma flow plane Magnetic lineation = magma flow line Regional-scale investigation of magnetic fabric helps to decipher magma flow within whole pluton VELOCITY GRADIENT FLOW DIRECTION FLOW LINES RIGID WALL FLOW PLANES

5. Magnetic fabric of igneous rocks

5. Magnetic fabric of igneous rocks Magnetic anisotropy in pluton scale Magnetic foliation Magnetic lineation Monte Capanne granodiorite pluton (Elba Island, northern Tyrrhenian Sea, Italy) (Bouillin et al. 1993)

5. Magnetic fabric of igneous rocks

6. Sampling, measurement and data processing Agenda 1. Definition and application in geology 2. Magnetic anisotropy of minerals 3. Magnetic fabric vs. texture of rocks 4. Magnetic fabric of sedimentary, deformed, and metamorphosed rocks 5. Magnetic fabric of igneous rocks 6. Sampling, measurement and data processing

6. Sampling, measurement and data processing Oriented samples V = 11.15 ccm V = 8 ccm

6. Sampling, measurement and data processing Field Drilling Oriented Cores Petrol powered portable drilling machine

6. Sampling, measurement and data processing (Tauxe. 2005)

6. Sampling, measurement and data processing Block specimens

6. Sampling, measurement and data processing Sample to geographical coordinate system transformation R = T r, K = T k T', r, R vectors in sample or geographical coordinate systems k, K tensors in sample or geographical coordinate systems T transformation matrix (T transposed matrix of T)

6. Sampling, measurement and data processing

6. Sampling, measurement and data processing Kappabridge (and PC) evolution KLY-2 KLY-1 (1967) KLY-3 & 4 MFK1

6. Sampling, measurement and data processing MFK1-FA Three operating frequencies and respective field ranges (peak values): F1 (976 Hz): 2-700 A/m F2 (3904 Hz): 2-350 A/m F3 (15616 Hz): 2-200 A/m Accuracy within one range: 0.1 % Accuracy of absolute calibration: 3.0 %

6. Sampling, measurement and data processing 15 position design 15 directional measurements Duration: ca. 9 min X

6. Sampling, measurement and data processing Three plane rotation 64 readings during each rotation Multiple rotations Duration: ca. 3-4 min

6. Sampling, measurement and data processing 3D Rotator 320 readings during full rotation Repeated two times 640 directional measurements Duration: ca. 1.5 min X

6. Sampling, measurement and data processing Safyr - Data acquisition software

6. Sampling, measurement and data processing

6. Sampling, measurement and data processing

6. Sampling, measurement and data processing Anisoft - Data processing software

6. Sampling, measurement and data processing Anisoft - Data processing software File.ran File1.ran File2.ran File3.ran Open Open multiple Geological data (*.ged) Anisoft 4.2. Viewing & Editing Selection of data Spec to Geo Geo to Spec Mean tensor (Jelínek statistics) Append Mean.ran Mean.txt Print Export Save as Save selected records as File.wmf File.ran File.txt File.ss2

6. Sampling, measurement and data processing Mean tensor (Jelinek 1978, Hext 1963) Geographic coordinate system N Equal-area projection N=35 mean directions 270 90 confidence ellipses K1 K2 K3 180 D

6. Sampling, measurement and data processing Bootstrap (Constable & Tauxe 1990)

6. Sampling, measurement and data processing Data presentation in regional scale projection of mean susceptibilities magnetic lineation of mean tensor isolines of shape parameter (T)

Magnetic anisotropy of rocks Literature Tarling, D.H. & Hrouda, F. 1993. The Magnetic Anisotropy of Rock. Chapman & Hall, 217 pp. Lanza, R. & Meloni, A. 2006. The Earth s Magnetism: An Introduction for Geologist. Springer, 278 pp. (Chapter 5). Hrouda, F. 2007. Magnetic Susceptibility, Anisotropy. Encyclopedia of Geomagnetism and Paleomagnetism. Springer. 546-560. Sagnotti, L. 2009. Magnetic anisotropy. Encyclopedia of Solid Earth Geophysics. Springer. 717-729. Tauxe, L. 2013. Lectures in paleomagnetism. http://magician.ucsd.edu/essentials_2/webbook2ch13.html#x15-15500013. Hrouda, F., 1982. Magnetic anisotropy of rocks and its application in geology and geophysics. Geophysical Surveys, 5, 37 82. Borradaile, G. J. & Henry, B. 1997. Tectonic applications of magnetic susceptibility and its anisotropy. Earth Science Reviews, 42, 49 93. Jackson,M.J. & Tauxe, L. 1991. Anisotropy of magnetic susceptibility and remanence: developments in the characterization of tectonic, sedimentary, and igneous fabric. Reviews of Geophysics, 29, 371 376. Rochette, P., Jackson, M. J. & Aubourg, C. 1992. Rock magnetism and the interpretation of anisotropy of magnetic susceptibility. Reviews of Geophysics, 30, 209 226.

Magnetic anisotropy of rocks Thanks for your endurance! Martin Chadima AGICO Inc., Brno, Czech Republic Institute of Geology, ASCR, v.v.i., Prague, Czech Republic

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