. 2014. 2.. 225 234. DOI: 10.14258/jcprm.1402225 661.723+547.362.365. 1,3*,. 2,. 1,. 3,. 3 1..,., 1,, 664033 ( ), e-mail: alfgoga@mail.ru 2,., 79,, 660041 ( ) 3,., 83,, 664074 ( ) -. 5 15. -,,. -. :,, -,. ( ), - [1].,.,., 1,2,3- [2]. -,,,.: (3952) 42-82-25, e-mail: alfgoga@mail.ru,,.: (391) 236-19-64, e-mail: WKiselev001@yandex.ru,,,.: (3952) 51-14-84, e-mail: val_stankevich@irioch.irk.ru,,.: (3952) 40-51-06, e-mail: panaska_84@mail.ru,,.: (3952) 40-54 26, e-mail: angrigoryeva@istu.edu, [3]. -,, -. -.,, [4]., - [5] *,.
226.,.,.. [6]. [7, 8], - ( ),., -,,. ( 1,3- ) : CH 2-OH CH-O-Lign CH 2-O-R 11 CH-O-Lign CH-OH ClCH 2 CH 2 CH 2 Cl CH-O-CH 2 CH 2 CH 2 -O-R 1 OH NaOH O CH 2 CH 2 CH 2 -O-R +NaCl -,., - NaOH ~40 50%., - [9],. -,,, [10].,., [7, 8] - -, 2 -,.,. -,,.. 46 52% 6,2% : 68,1%; 6,4%; - 12,3%, 2, - 100 ( ), - 1 3 7,0 14,0 3 ( - 5 15 ). 1 2,. - - -. 40 60%.. 3,5 28,8%.
227. - ( l 14,2%, 57,9%, 6,6%) 50 ( - ),,, 200 3, 41,86 Na 2 S 9H 2 O (13,6 Na 2 S), 5,6 7,2 NaOH., 60 95 1. ( 1,2-, 1,3-, 1,3-1,2,3-13,2 ) - 1 3 15 60 95 3 4. ( 30 ) ( 8). 2,, -.. : 33,1%, 7,1%, S 9,6%, l 3,2%.,.. 12801-98.., - [11, 12]. [10].,, [13, 14]., I, -., - [3], -,.,, [15] (.).
228.,.,.. (5 15 ), [16]. : CH 2-OH CH-O-Lign CH-OH CH 2 Cl CH-O- Lign CHCl Cl 2 H2O Cl OH OH - 5 15., - [17, 18]. [19] :,,,,,,.. [20], -,..,, - ( ), - [21],.,, - [19]. - 7 14 3 ( ) 28%. [22] - 30%.,., -. 1612 1610-1, -, 1465,1461 1125-1, 3, 730 850-1, C Cl.,,, (, - : CH 2 Cl CH-O- Lign CHCl + Cl-R-Cl + Na 2 S x+1 NaOH CH 2 -S( x+1 )[-R-S (x+1) ] y -R-Cl CH-O- Lign CH-S( x+1 )[-R-S (x+1) ] z -R-Cl Cl Cl OH OH
229 -. -., -., S (x+1),.,. - -.. ( ) ( ),, 1. 1,,,. - (C Cl) 730 850-1, - Cl 680-1.,,.,,,,, [19]. Cl. 1, - -. ( ) -. -.,.,. [15]. 2. 1. ( ) * 50 c Cl, %, Na 2 S -, S, NaOH, - S,% Cl,% - 1 [7]; Cl - 1,2,3-13,2 72,0 0,4 2 3,5 1,2-7,0 6,8 1,4 6,0 4,2 0,9 3 7,3 1,3-8,8 6,8 2,1 6,0 5,4 1,3 4 10,2 1,3-10,2 10,2 2,8 6,6 6,8 2,2 5 14,2 1,2,3- - 13,2 13,6 5,6 7,2 9,2 2,8 6 14,2 13,2 13,6 5,6 7,2 9,6 3,2 7 20,9 26,4 20,4 8,4 7,5 25,8 4,1 8 28,8 35,0 27,2 11,2 9,0 31,7 8,1 * : ; ; ; H.
230.,.,.. 2. : = 95 : 5) 25, 0,1,, -, 163 5 ** 1 90/130 128 17,0 45.0 52,0 2 + 121 19,0 46.0 50,5 [7] 3* + - 118 20,1 47.5 51,5-4 + - - 104 20,8 49.0 53,0 3, 4 5 7 1; ** - 18180-72.,,, - - 6 7 20 22% -., -. 25,,. ( - ). -. ( 1) 11,76% ( 2), 18,23% ( 3), 22,35% ( 4). -,. 2, -, 2 3, 18180-72. -. 60/90 3,5 10% (% ): 5 10 18 10 20 17 53 12 60/90 +. (7,8% ) 7 ( 100), - 160 170, - - :. -,. -17,0. -19,0-20,8 222245-90 -17 ). -. 222245-90 -1,0 +1,0; 70. 3.
231 3., -,,,,, 3 10 5, %, % R 20 R 50 1. 14. 30. 0* 2,30 0,43 5,30 26,2 10,6 0,76 0,67 1 2,33 0,45 6,11 29,9 11,8 0,88 0,74 2 2,37 0,59 3,83 36,0 13,4 1,15 0,96 0,62 3 2,34 0,14 4,70 37,6 16,2 1,14 0,97 0,91 4 2,39 0,32 2,71 33,1 11,2 0,89 0,75 5 2,36 0,13 4,07 34,2 12,8 0,90 0,82 ; 1 5, : 1 [7]; 2 (10,2% Cl); 3, 4, 5-4, 5, 6 1. - 3, -, 20 50, (1.)., - 7,8% - 30-25 30%, 25 / 20 38%., -, 8,8 10%,,,.,., - 9128-97. -. -.,, ( ) ;,. -,. -,,,, ( ) -., -, -, -., - ( ).,
232.,.,..,. -, -, -.,, -,,.,, -, -.,, ;,., -. -.,,. -. -. [15] «100» 2009. 1..,.,.,. - //,,., 2000.. 2.. 89 97. 2..,.,..., 1991. 272. 3..,.,.,.,. - //. 2001.. 9.. 541 546. 4. Chen Fan-geng, Lu Zhuo-min, i Bin. // Linchan huaxue i gongye Chem. and Ind. forest Prod. 2001. Vol. 21, N2, P. 39 43. 5...., 1972. 520 c. 6...., 2010. 167. 7. 2079477 ( ). /., -.,.,.,.. 1997. 14.. 185. 8..,.,.,.,.,. - // :.. I., 1994. 53. 9..,.,.,. -. 2. //. 2013. 6. C. 157 159. 10. Voitl Tobias and von Rohr Philipp Rudolf. Demonstration of a Process for the Conversion of Kraft Lignin into Vanillin and Methyl Vanillate by Acidic Oxidation in Aqueous Methanol. // Industrial Engeneering Chemical Research. 2010. Vol. 49. Pp. 520 525. 11.. 1541213 ( ). /.,.,.. 1990.. 5. C. 5.
233 12..,.,., - //.. 2000. 9. C. 45 50. 13.. 231368 ( ). /.. 1968.. 35. C. 102. 14.. 816996 ( ). /.,.,.,.. 1981.. 12. C. 98. 15. 2376275 ( ). /.,. -,.,.,.,.,.,.,... 2009. 35.. II. 631. 16..,.,.,. - //. 1961. 8.. 10. 17.. //.,,.. 1989. 9.. 15 17. 18.. //.,,.. 1989. 9.. 17 23. 19..,.,..., 1976. 368. 20.. //. 1961.. 137, 6.. 1389 1392. 21...., 1983. 212 c. 22.. 933669 ( ). /.,.,. -,.,... 1982. 21.. 106. 21 2013. Gogotov A.F. 1,3*, Kiselev V.P. 2, Stankevich V.K. 1, Panasenkova E.Y. 3, Chajka A.A. 3 THE USE OF HYDROLYTIC LIGNIN AS POLYMERIC BASE FOR CHEMICAL NEUTRALIZATION OF POLYCHLOROALIPHATIC WASTES 1 Irkutsk Institute of Chemistry SB RAS, Favorskogo st., 1, Irkutsk, 664033 (Russia), e-mail: alfgoga@mail.ru 2 Sibirsky Federal University, Svobodnyi ave., 79, Krasnoyarsk, 660041 (Russia) 3 National Research Irkutsk State Technical University, Lermontova st., 83, Irkutsk, 664074 (Russia) The critical analysis of opportunities of use hydrolytic lignin for recycling and neutralization toxic polychloroaliphatic compounds production wastes epichlorohydrin is lead. The variant of activation hydrolytic lignin by chlorination by chloric water is offered at temperature 5 15. Activated thus lignin together with chloroorganic waste enter into condensation with polysulfides of sodium therefore receive a product showing properties of the modifier of bitumen. Use of the received modifier of bitumen allows to expand a raw-material base for road construction. Keywords: hydrolytic lignin, polychloroaliphatic production wastes epichlorohydrin, polycondensation, polysulfides of sodium. * Corresponding author.
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