Solid Phase Microextraction

Solid Phase Microextraction

Gangfeng Ouyang Ruifen Jiang Editors Solid Phase Microextraction Recent Developments and Applications 123

Editors Gangfeng Ouyang School of Chemistry Sun Yat-sen University Guangzhou, Guangdong China Ruifen Jiang School of Environment Jinan University Guangzhou, Guangdong China ISBN 978-3-662-53596-7 ISBN 978-3-662-53598-1 (ebook) DOI 10.1007/978-3-662-53598-1 Library of Congress Control Number: 2016953638 Springer-Verlag GmbH Germany 2017 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, express or implied, with respect to the material contained herein or for any errors or omissions that may have been made. Printed on acid-free paper This Springer imprint is published by Springer Nature The registered company is Springer-Verlag GmbH Germany The registered company address is: Heidelberger Platz 3, 14197 Berlin, Germany

Preface Solid-phase microextraction (SPME) is a sample preparation technique introduced by Dr. Janusz Pawliszyn, professor of University of Waterloo, in 1990. Compared with traditional sample preparation techniques, SPME combines sampling, enrichment, separation, and introduction into one step and becomes a simple, fast, efficient, and green sample preparation technique. Since its inception, SPME has been widely used in environmental, pharmaceutical, food, and aroma analyses, as well as the studies of chemistry, materials, biology, medicine, etc. In recent 10 years, the hot research areas of SPME include developing novel fiber coatings based on nano or porous materials, detecting free concentration of analyte in complex sample matrices, and nondestructive sampling of living systems using in vivo SPME. The purpose of this book is to summarize the applications of SPME in recent years. In this book, 10 representative chapters cover the recent development of SPME in coating preparation, environmental analysis, in vivo sampling, etc. Chapter 1 briefly introduces the fundamental knowledge of SPME technique. In Chap. 2, the progresses of the new SPME coating preparation in recent years are summarized. Then, from Chaps. 3 to 7, the applications of SPME for environmental samples, including aerosol particulate in air, complex water sample, and soil/sediment, are reviewed. The main feature of SPME for sensing the freely dissolved organic compounds in complex environmental samples using active and passive SPME sampler is highlighted in these chapters. In addition, SPME combined with derivatization techniques to overcome the challenge of polar compounds' analysis in environmental samples is also summarized and discussed. In the last three chapters, the most distinguished application of in vivo SPME technique is reviewed and discussed, including tracing volatile organic compounds' emission from plant and analyzing the metabolites of pharmaceuticals. v

vi Preface I believe this book will be useful to the researchers in the fields of chemistry, materials, environment, etc., especially who are doing works relative to SPME as well as the newcomers who want to employ the SPME techniques. I am especially grateful to the authors and my colleagues. This book cannot be done without their outstanding contributions. Guangzhou, China Gangfeng Ouyang Ruifen Jiang

Contents 1 Introduction of Solid-Phase Microextraction.... 1 Shuqin Liu and Gangfeng Ouyang 2 Development of Novel Solid-Phase Microextraction Fibers... 17 Jianqiao Xu and Gangfeng Ouyang 3 Application of Solid-Phase Microextraction in Gas Sampling... 63 Xiang Li 4 Solid Phase Microextraction for Sensing Freely Dissolved Analytes in Complex Water Sample... 75 Ruifen Jiang, Jianqiao Xu and Gangfeng Ouyang 5 Application of Solid Phase Microextraction in Aqueous Sampling... 113 Siming Huang, Juan Zheng and Gangfeng Ouyang 6 Application of Solid-Phase Microextraction in Soil and Sediment Sampling... 141 Ruifen Jiang and Gangfeng Ouyang 7 Application of Solid-Phase Microextraction Combined with Derivatization for Polar Compound Sampling in Environmental Analysis... 177 Lihua Yang and Tiangang Luan 8 Application of Solid Phase Microextraction in Food Analysis Flavor and Off-Flavor Sampling.... 223 Henryk Jeleń, Małgorzata Majcher and Anna Gracka vii

viii Contents 9 Applications of In Vivo and In Vitro Solid-Phase Microextraction Techniques in Plant Analysis... 247 Fang Zhu and Guosheng Chen 10 Solid-Phase Microextraction in Binding Studies... 287 Dajana Vuckovic

Contributors Guosheng Chen MOE Key Laboratory of Aquatic Product Safety/KLGHEI of Guangzhou, China Anna Gracka Faculty of Food Science and Nutrition, Poznań University of Life Sciences, Poznań, Poland Siming Huang MOE Key Laboratory of Aquatic Product Safety/KLGHEI of Guangzhou, People s Republic of China Henryk Jeleń Faculty of Food Science and Nutrition, Poznań University of Life Sciences, Poznań, Poland Ruifen Jiang School of Environment, Guangzhou Key Laboratory of Environmental Exposure and Health, and Guangdong Key Laboratory of Environmental Pollution and Health, Jinan University, Guangzhou, People s Republic of China Xiang Li Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention (LAP3), Department of Environmental Science and Engineering, Fudan University, Shanghai, China Shuqin Liu MOE Key Laboratory of Aquatic Product Safety/KLGHEI of Guangzhou, People s Republic of China Tiangang Luan MOE Key Laboratory of Aquatic Product Safety, School of Marine Sciences, Sun Yat-Sen University, Guangzhou, China Małgorzata Majcher Faculty of Food Science and Nutrition, Poznań University of Life Sciences, Poznań, Poland ix

x Contributors Gangfeng Ouyang MOE Key Laboratory of Aquatic Product Safety/KLGHEI of Guangzhou, People s Republic of China Dajana Vuckovic Department of Chemistry and Biochemistry and PERFORM Centre, Concordia University, Montreal, Canada Jianqiao Xu MOE Key Laboratory of Aquatic Product Safety/KLGHEI of Guangzhou, China Lihua Yang MOE Key Laboratory of Aquatic Product Safety, School of Marine Sciences, Sun Yat-Sen University, Guangzhou, China Juan Zheng MOE Key Laboratory of Aquatic Product Safety/KLGHEI of Guangzhou, PR, China Fang Zhu MOE Key Laboratory of Aquatic Product Safety/KLGHEI of Guangzhou, China