. 213. 3.. 113 119. DOI: 1.14258/jcprm.133113 582.998.2:547.587. 1*,. 2,. 2,. 3,. 1 1..,., 4,, 119334 (), e-mail: Natnik48s@yandex.ru 2..,., 35, (), e-mail: phenolic@ippras.ru 3,., 3,, 6345, ), e-mail: eikor@mail.ru,,. 14 :, -. : K. scapigera K. rhombopilosa.-. :,,, -,, K. (Kalanchoe Adans.) 13.. [1]. -,,, [2, 3]. - -. -,,,, (),. -,,.: (495) 939-74-18, e-mail: Natnik48s@yandex.ru,,.: (499) 977-94-33, e-mail: p.lapshin@mail.ru,,.: (499) 977-94-33, e-mail: nzagoskina@mail.ru,,.: (3822) 56-38-32, e-mail: eikor@mail.ru,,.: (495) 939-74-9, e-mail: misin@sky.chph.ras.ru;. - [2 4]. - [5, 6]. :, -. *,.
114.,.,.,.,. 34 (Kalanchoe L.),.., - -12, -. :,, -, ()., «-1-», [7]. -, - 1,3. (R OH)., R R + e + H +,, [8],. - R R +. - [8].,, - ( )., -, -,.. (- ) 1%. [9] - ( 2 ),,. 2 - : 2 + (1) 2 2 + + HO 2 HO 2 + + + 2 2 2 2 + 2 + + 2 2 2 (4) [9] - 2, (1) (3). 2 (. 1). 1. 2 1,, 2, - * - - 2,,,,,, 3 N, S, Se--,, -, - 4 ), -, 2, - 2, - 2, -. :,. (2) (3) - - - - -
115, - ( 2, HO 2 ), 2 : = (1 I/I ), I, I 2 -, () [9]. - 3 4,. - 3%. ()» [1]., - in vivo. H 2 O 2 Hb,., (Hb( )Fe 4+ = O). -, LO 2 2, 3- ( 2 )*, 425. Hb-H 2 O 2 t, - [1]. «Lum- 5773». (k, -1 ), (t/t ) (m, ), : t/t = km+1, t. - 15%. 1 - m, 2 - t/t m, (k). 4 I,. m = 35 3 25,5 2 15,2 1,3,4 5 t, 2 4 6 8 1 t/t 9 21 8 7 4 6 5 6 4 3 2 1 1 m,,2,4,6,8 1. 1. () m,. 2. (t/t ) m,, 2-34., K. scapigera11 K. rhombopilosa 21 (1981 1911, ), - K. blossfeldiana K. laetivirens (25 186 )., K. pinnata K. daigremontiana, (294 55, )., -, 14, (- ).
116.,.,.,.,. 2.,., 1 K.pinnata 294 18 K.millotii 17 2 K.beauverdii 73 19 K.fedtschenkoi 64 3 K.orgyalis 393 2 K.serrata 383 4 K.imperialis 878 21 K.rhombopilosa 1911 5 K.tomentosa 593 22 K.kalandiva 55 6 K.daigremontiana 55 23 K.laciniata 358 7 K.thyrsiflora 22 24 K.tubiflora 423 8 K.hildebrandtii 1265 25 K.longiflora 33 9 K.velutina 545 26 K.bracteata 265 1 K.beharensis v.aureoneu 368 27 K.crenata 38 11 K.scapigera 1981 28 K.nyikae 514 12 K.citrina 328 29 K.sedoides 342 13 K.X kewensis 31 3 K.blossfeldiana 25 14 K.serratifolia 355 31 K.blossfeldiana mini 278 15 K.germanae 321 32 K.laetivirens 186 16 K.syncepala 247 33 K.figuereidoi 55 17 K.gastonis-bonnieri 43 34 K.pubescens 388., 3 2,., 1 (. 3), 8 (4, 8, 18, 21, 23, 28, 3, 33),, -, 4 1 (. 3). 2,. (R- OH) [9]: 2 + 2 + R-OH 2 + R ; (5) 2 + R-OH H 2 O 2 + R. (6), - 2,, (5) =+25 : 2 / = 2 / +,59lg(C2 / C). (7) ( 2 ) (5) (R-OH), C 2 -, (7), 2 -. 2 12. 2,, - 2, () [11]. 4 14 2., ) (. 4). 2, ) 4. 18, 2, 6,., -, 2,.,, r =,83. 4- «Hb H 2 O 2» (k, -1 )., -, 4, - r =,89. (r =,81).
117 ) ). 3. () () (V=2 ), () () 1. -1, ; I ( 1,37 ) 14 12 k, 1/ 12 1, 1 8 6 8 6 4 4 2 2. 4. (, ) ), (, ) (), (k, 1/) ) 25 2 15 1 5, 11 21 18 19 28 33 27 23 3 [2, 3],. :,,, ;,,. 15,,. (35 4%), -,,,, :,, :,,,,. [2]. [3].,., : K.scapigera K.rhombopilosa- K.pinnata1 K.daigremontiana 6. -
118.,.,.,.,. - -,,,., -. 14 :,. (r=,89). : K.scapigera K.rhombopilosa.-. 1..,... 1.., 23. 125. 2..,.,.,. : -, () //,. 21. 7.. 14 2. 3..,.,. //, -. 211. 8.. 3 6. 4..,.,.,. Kalanchoe daigremontiana (Hamet de la Bbthie) Jacobs et Perr. //.. 29. 6.. 669 676. 5..,.,.,. - //,. 21. 12.. 1 5. 6..,.,.,. - //. 28. 4.. 95 1. 7.. - //. 28.. LII, 2.. 13 135. 8. Peyrat-Maillard M.N, Bonnely S., Berset C. Determination of the antioxidant activity of phenolic compoundsby coulometric detection // Talanta. 2. Vol. 51. Pp. 79 715. 9. Korotkova E.I., Karbainov Y.A., Avramchik O.A. Investigation of antioxidant and catalytic properties of some biological-active substances by voltammetry // Anal. and Bioanal. Chem. 23. Vol. 375, N1-3. Pp. 465 468. 1..,.,.,.,. - // -. 1997.. 43, 2.. 87 93. 11..,.,. //. 211. 2.. 137 143. 19 212. 25 212.
119 Sazhina N.N. 1*, Lapshin P.V. 2, Zagoskina N.V. 2, Korotkova E.I. 3, Misin V.M. 1 COMPARATIVE ANALYSIS OF KALANCHOE JUICE ANTIOXIDATIC ACTIVITY 1 N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, ul. Kosygina, 4, Moscow, 119334 (Russia), e-mail: Natnik48s@yandex.ru 2 K.A. Timirjazev Institute of Plant Physiology, Russian Academy of Sciences, RAS, ul. Botanicheskaia, 35, Moscow (Russia), e-mail: phenolic@ippras.ru 3 Tomsk Polytechnic University, pr. Lenina, 3, Tomsk, 6345, (Russia), e-mail: eikor@mail.ru Now the special attention to studying of antioxidant activity of various herbs is given for the purpose of search among them the most active sources of biologically active components. In this work for this purpose the comparative analysis of measurement results of the total antioxidatic activity for juice of 14 different types of Kalanchoe (Kalanchoe L.) is carried out by three methods: ammetric, voltammetric and chemiluminescence. Among the studied samples two most active kinds of Kalanchoe are exposed: K.scapigera and K.rhombopilosa. They can appear more perspective sources of biologically active components in comparison with types which are used now. Keywords: antioxidants, ammetric, voltammetric, chemiluminescence methods, polyphenols, Kalanchoe. References 1. Semenova L.V., Iampol'skii Iu.V. Lekarstvennye ekzoticheskie rasteniia. [Medicinal exotic plants]. St. Petersburg, 23, no. 1, 125 p. (in Russ.). 2. Volzhanova M.I., Bail'man R.A., Suslina S.N., Bykov V.A. Voprosy biologicheskoi, meditsinskoi i farmatsevticheskoi khimii, 21, no. 7, pp. 14 2. (in Russ.). 3. Volzhanova M.I., Suslina S.N., Bykov V.A. Voprosy biologicheskoi, meditsinskoi i farmatsevticheskoi khimii, 211, no. 8, pp. 3 6. (in Russ.). 4. Anisimov M.M., Gerasimenko N.I., Chaikina E.L., Serebriakov Iu.M. Izvestiia RAN. Seriia biologicheskaia, 29, no. 6, pp. 669 676. (in Russ.). 5. Misin V.M., Sazhina N.N., Vandyshev V.V., Khomik A.S. Voprosy biologicheskoi, meditsinskoi i farmatsev-ticheskoi khimii, 21, no. 12, pp. 1 5. (in Russ.). 6. Olennikov D.N., Zilfikarov I.N., Toropova A.A., Ibragimov T.A. Khimiia rastitel'nogo syr'ia, 28, no. 4, pp. 95 1. (in Russ.). 7. Iashin A.Ia. Rossiiskii khimicheskii zhurnal, 28, vol. LII, no. 2, pp. 13 135. (in Russ.). 8. Peyrat-Maillard M.N, Bonnely S., Berset C. Talanta, 2, vol. 51, pp. 79 715. 9. Korotkova E.I., Karbainov Y.A., Avramchik O.A. Anal. and Bioanal. Chem., 23, vol. 375, no. 1-3, pp. 465 468. 1. Teselkin Iu.O., Babenkova I.V., Liubitskii O.B., Klebanov G.I., Vladimirov Iu.A. Voprosy meditsinskoi khimii, 1997, vol. 43, no. 2, pp. 87 93. 11. Sazhina N.N., Misin V.M., Korotkova E.I. Khimiia rastitel'nogo syr'ia, 211, no. 2, pp. 137 143. Received September 19, 212 Revised November 25, 213 * Corresponding author.