Cryogenic Engineering

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Cryogenic Engineering 2017 Fall Semester Min Soo, Kim

Chapter 1. INTRODUCTION TO CRYOGENIC SYSTEMS

1.1 Introduction CRYOGENIC=CRYO+GENE Ice Generation CRYOGENICS REFRIGERATION -150 (123K) -40 (233K) 25

Time of I. Newton F. Bacon (1561 1621) The third of the seven modes [ ] relates to [ ] heat and cold. And herein man s power is clearly lame on one side. For we have the heat of fire which is infinitely more potent and intense than the heat of the sun as it reaches us, or the warmth of animals. But we have no cold save such as is to be got in wintertime, or in caverns, or by application of snow and ice, [ ] And so too all natural condensations caused by cold should be investigated, in order that, their causes being known, they may be imitated by art.

Time of I. Newton Known refrigeration methods - Refrigeration by a colder object(ex. Ice or snow) - Refrigeration by evaporation - Refrigeration by dissolving saltpeter in water (saltpeter = sodium nitrate NaNo 3 or potassium nitrate KNO 3 )

Time of I. Newton R. Boyle (1627 1691); E. Mariotte (1620 1684) PV= constant

Time of I. Newton G. Amontons (1663 1705)

Further development of thermodynamics J. Black (1728 1799) latent heat A. Lavoisier (1743 1794) caloric theory S. Carnot (1824) work R. Clausius (1865) entropy W. Gibbs (1867); R. Mollier (1923) enthalpy

Incentives for refrigeration and cryogenics Early 19 th century - Large scale refrigeration was only done by natural ice - Increasing demand for artificial refrigeration by - The butchers - The brewers and later on - The industrialists

Incentives for refrigeration and cryogenics Examples of first commercial refrigeration applications S.S. Strathleven equipped with Bell&Coleman air-cycle refrigerator. First meat cargo transported from Australia to London 1879. 6. 12. 1880. 2. 2

Incentives for refrigeration and cryogenics Examples of first commercial refrigeration applications Standard ammonia cycle ice machine from York s 1892 catalogue

Braking the cryo-barrier The successful liquefaction of Oxygen was announced at the meeting of the Académie de Sciences in Paris on December 24th, 1877 independently by the physicist Louis Paul Cailletet from Paris and the professor Raoul Pictet from Geneva.

Braking the cryo-barrier Cailletet s apparatus

Braking the cryo-barrier Pictet t apparatus - Production of Oxygen under pressure in a retort - Two pre-cooling refrigeration cycle : first stage SO 2 (-10 ) second stage CO 2 (-78 ) - Oxygen flow is pre-cooled by the means of heat exchangers and expands to atmosphere via a hand valve

Milestones in the history of cryogenic technology 1892 Dewar use of silvering and vacuum in double walled glass vessel 1895 Linde and Hampson build air liquefiers with recuperative heat exchangers 1898 Dewar liquefies hydrogen 1902 Claude use of piston expander 1908 Kamerlingh Onnes liquefies helium 1908 Becquerel freezes seeds and single cells 1910 Use of LOx in the production of steel 1911 Discovery of superconductivity

Chronology of cryogenic technology

1.3 Present areas involving cryogenic engineering Superconductivity Superconductivit> Meissner Effect Critical temperature of a superconductor

1.3 Present areas involving cryogenic engineering Magnet levitation Train

1.3 Present areas involving cryogenic engineering Rocket propulsion <Diagram of a liquid fuel rocket> <Rocket propulsion> <Carbon composite cryogenic fuel tank>

1.3 Present areas involving cryogenic engineering Studies in high-energy physics The hydrogen bubble chamber uses liquid hydrogen in large particle accelerators. The hydrogen bubble chamber is used to detect high-energy particle

1.3 Present areas involving cryogenic engineering Electronics Electronic device likes masers(sensitive microwave amplifiers), SQUIDs(superconducting quantum interference devices) are cooled to liquid nitrogen or liquid helium so that thermal vibrations of the atoms do not interfere devices operation. Maser

1.3 Present areas involving cryogenic engineering Space simulation and high-vacuum technology To produce a vacuum, one of the more effective methods involves low temperature : Cryopumping Cryopump traps gases and vapours by condensing them on a cold surface.

1.3 Present areas involving cryogenic engineering Biological and medical application To preserve biological material, the use of cryogenics, cryobiology has aroused much interest. Cryogenic surgery has been used for many disease.