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MONOLTHC EXTRNSC SLCON RCCDS A W Vere*, C T Elliott* and P Migliorato** ABSTRACT An analysis is presented which permits computation of the required dopant levels, thicknesses and other parameters of an extrinsic silicon infrared photoconductor to ensure that the photogenerated charge output is within the acceptance limits for direct injection into CCDs. NTRODUCTON When charge-coupled devices (CCDs) are used to read-out infra-red signals from an extrinsic silicon photoconductive R detector array, the photo-generated charge from each element may be transferred to the CCD and shifted to the edge of the detector array (direct injection) or may be used to modulate the gate voltage of the CCD (indirect injection). Where direct injection is employed it is important that the magnitude of the photogenerated charge is within the handling capability of the CCD, or, if larger, that some form of background subtraction can be performed prior to injection. The analysis below explores the parameters governing this compatibility for two types of devices. n the first a 100 pm thick photodetector is interfaced with a depletion mode CCD, whilst in the second the infra-req sensitive detector region is diffused or implanted into the surface region above a buried channel CCD. n this configuration the maximum detector thickness would be no more than one micron. THE PHOTOCONDUCTVE DETECTOR For thermal imaging applications detector systems with noise equivalent temperature differential (NE~T) values of better than O.l K are required. NE~T is a figure of merit for the complete detector/optics combination and is related to the detectivity D* of the detector element by the expression (ref 1) NE~T = (1) in which f is the aperture number of the lens sys'tem, B the electrical bandwidt1co:f the detector, a is a constant and A is the area of the element. For a background photon-noise limited R detector (ref 2) D* A. [n J! = 2hc 4>B (2) * Royal Signal~ and Radar Establishment, Malvern, England. ** Currently w1th: Laboratorio di Elettronica delle State Solido del CNR, Roma, taly 145

in which A is the wavelength of incident radiation, h Planck's constant, c the velocity of light, 4> the background photon flux and n the internal quantum efficiency of the device. n may be rewritten as n NTcrphd (3) where NT is the concentration of photo-ionisable centres, crph the photoionisation cross-section and c:l. tl:le de.tector th;i.ckp._e.ss. By substitution of equations (2) and (3) into equation (1) we can define the concentration of photo-ionisable impurity centres required to give O.l K thermal resolution, as a function of the detector thickness and charge integration time 1 t (t = 2B). The required expression is N K. 1 (4) T (0.1 K) td where K 32 X 10 2 h2c2 <j>b. a2a2. crpha Figure 1 shows this relationship for detectors of various thicknesses. CHARGE HANDLNG CAPABLTY OF THE CCD The dynamic range of the CCD can be defined in terms of input photogenerated charge N by the expression NN. o1se c ~ N ~ N.S max (5) which simply requires that the injected charge should exceed the product of the CCD self noise NN. and the inverse of the scene contrast ratio o1se c, whilst remaining below the charge-saturation limit of the CCD defined by the product of N and CCD electrode area S. max. 12-2 For a depletion mode CCD Nmax is approximately ~-0 electrons em and NNoise is about 7~0 e!.:-e!.:,?nf:l. Cr.~"~"'--~). One of the fundamental problems of R imaging is the low scene contrast ratio c, (0.004 for O.l~resolution) which considerably increases the lower limit of acceptable charge injection. Substituting the above values in equation (4) and assuming a CCD channel length of 10 vm and width of 25 vm gives c: 1. 75 X 10-' 6 2.5 x 10 electrons (6) The photogenerated charge input to the CCD is given by the expression where n is the quantum efficiency, <PB (7) the background photon flux, A the detector area, t the integration time and G the photoconductive gain. 146

Since n = NTcrphd (8) V1-L' and G = (9) d2 where V is the applied voltage, 1-1 the carrier mobility and T the carrier lifetime. Substitution of equations (7), (8) and (9) into equation (6), assuming that 15-2 -1 (f/1 FOV) gives: </>B = 2.7 x 10 photons em sec 4-1 -1 11 = 10 em volt sec -8 T = 10 sec ~ a ph = l0-16 cm2 '\~ -5 2 \_) A = 2.5 X 10 em (\(\J 2.6 X 10 14 ~ NTVt d ~ 3.7 X 10 15 Thus values of NT. and NT can be obtained. m1.n max t is now possible, by comparing equations (4) and (10), to examine the range of acceptable deep level centre concentrations, NT, as a function of integration time, detector thickness or photoconductive gain. Figure 2 shows the NT range as a function of integration time for a 100 11m thick photoconductor with a photoconductive gain of unity. A similar analysis may be performed for buried channel CCDs; in this case the maximum absorption depth d will be about 1.0 1-1m. Using a limiting noise value of 200 electrons and a well capacity of 10 electrons... 11 cm-2 (ref 2) gives~- (10) 3. 7 X 10 13 3.7 X 10 14 (11) The relationship between deep level centre concentration NT and integration time in buried channel devices is given in figure 3. Figure 4 shows the effect on this comparison of varying the photoconductive gain. Where photoconductive gain is present a minimum practical limit is defined by the requirement that the generation recombination noise should exceed the Johnson noise in the detector circuit. This limit is indicated by the broken vertical line in figure 4. The corresponding case for a buried-channel CCD is shown in fig 5, -2 the chosen integration time being 4 x 10 seconds and the absorption depth d, 1 ]lm. DSCUSSON Using equation 4 and figure 1 it is possible to examine the tradeoffs between integration time, deep-level centre concentration and detector thickness in achieving O.l K temperature resolution. n general the 147

maximum solid 10 16 and 1018 solubility of deep impurities in silicon lies between em -3 Assuming 10% electrical activity defines a maximum upper NT concentration limit of 1017 cm-3, which places a minimum detector thickness of about 100 ~m on high bandwidth systems (t = -4 4 x 10 sees), but still permits the choice of detectors approximately one micron thick for large-area staring arrays (t = 4 x 10-2 sees). The upper limit on detector thickness is governed by the on-set of optical cross talk between adjacent elements. Nummedal et al (ref 3) have recently shown that for 50 x 25 x 500 ~m detectors a cross talk value of 11% is expected. Accordingly the above analysis has been restricted to detectors less than 200 ~m thick. From figure 2 it is seen that the output from a 100 ~m thick detector is well-matched to a depletion mode CCD, the NT (O.l K NE~T) curve lying mid- way between the charge acceptance limits of the CCD. n contrast, figure 3 indicates that the use of a one micron thick detector in conjunction with a buried-channel CCD would require reduction of the R detector charge output prior to insertion into the CCD. This is a direct consequence of the reduced dy~amic range of the buried-channel CCD with respect to the depletion mode CCD. n the absence of photoconductive gain the curves for CCD and R detector bear the same relationship to one another irrespective of detector thickness - only the absolute value of the required NT concentration changes. f, however, photoconductive gain is present, equations (4) and (10) show an opposite dependence on gain and it is therefore possible, in principle at least, to correct for the mismatch between detector and CCD by adjustment of detector gain, as shown in figure 4. n each case there is a minimum limit to the acceptable gain in order to ensure that generation-recombination noise, rather than Johnson noise remains the dominant noise mechanism. This limit, together with the minimum deeplevel centre concentration limit for O.l K resolution and NT and max NT. defines the compatibility range, the shaded area in figure 4. For m1n compatibility between the 100 ~m thick R detector operating at unity photoconductive gain the NT concentration must lie between 3 x 10 14 and 9.5 x 10 14 cm- 3, the former being the optimum value. Decreasing the gain -1 to 2 x 10 broadens the acceptable NT range to cover values from 3 x 10 14 to 4.5 x 10 15, with an optimum concentration of 10 15 cm- 2 These values are for a full staring array (eg 105 picture points, 25 Hz frame time). Although the use of photoconductive gain permits additional flexibility in tailoring the R detector to suit the depletion mode CCD, care must be exercised in its use, particularly in large-area staring arrays, since variations in gain from element to element will lead to increases in fixed-pattern noise. Note also that, as indicated in fig 5, fractional gain cannot be used to reduce the unacceptably high charge injection level for a buried-channel CCD, since this would involve operation in a Johnson noise limited mode. 148

CONCLUSONS The charge output from an extrinsic silicon R photoconductor element of typical dimensions and doping level is well-matched to depletion mode CCDs for direct injection purposes. For use with buried-channel devices some form of background subtraction must be provided prior to injection. ACKNOWLEDGEMENTS The authors wish to thank Dr G Vanstone and Dr D McCaughan for useful discussions on detector/ccd interfacin~. Copyright Controller HM:SO London 1976. REFERENCES 1 J Sabey, Proc lee Conference on Low Light Level and Thermal maging Systems, London 1975. 2 D F Barbe, Proc EEE 63 No 1 Jan 1975 38-67. 3 K Nummedal, J C Fraser, S C Sze, R Baron and R M Fissnila, Proc San Diego Conference on CCD Applications (1975) 19-30. LST OF FGURES Fig 1 Fig 2 Fig 3 Fig 4 Fig 5 Deep level centre concentration required for O.l K resolution as a function of integration time for various detector thicknesses. Variation of required deep level centre concentration with integration time for a depletion mode CCD (unity photoconductive gain; d = 10-2 em) Variation of required deep level centre concentration with integration time for a buried-channel CCD (unity photoconductive gain; d = 10-4 em) Variation of required deep level centre concentration as a function of photoconductive gain for a depletion mode CCD -2-2 (d = 10 em; t = 4.10 sees) Variation of required deep level centre concentration as a function of photoconductive gain for a buried-channel CCD (d = 10-4 em, t = 4.10-2 sees). 149

- (Y') - E u.d (em.) 10-4 - ~ 0 ~ 0-1- z "1015 1014 10-3 10 2 150 d 3 10~ 1 ~----~----~----~----~ 10-4 10-3 102 10-1 ntegration Time t (sec.)

1 :: 1 OM ceo -- 1- z N Max. < T \ 1013 104 10-3 10-2 10-1 ntegration Time t (sec) NT min. 1013 10-4 10-3 10-2 10-1 ntegration Time (sec.)..~>;;.:minimum ~~~Gain ~~~Limit :)~1 ~ OM ceo BCCCO Minimum Gain Limit _, f z ~Min. Nr (0.1 Of<) --~-- 1 l 1012 '--::------'---=---'--'-:----""'=-------''-:---' 10'""3 10-2 10-1 1o0 101 Photoconductive Gain G 1014.. _j_-'----l-----ll...:o..._.l 10-3 10-2 10-1.. 10~.. Photoconductive Gain G