TECHNICAL NOTE. Relating Photochemical and Photobiological Quantities to Photometric Quantities

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TECHNICAL NOTE Relating Photochemical and Photobiological Quantities to Photometric Quantities CIE TN 002:2014

CIE Technical Notes (TN) are short technical papers summarizing information of fundamental importance to CIE Members and other stakeholders, which either have been prepared by a TC, in which case they will usually form only a part of the outputs from that TC, or through the auspices of a Reportership established for the purpose in response to a need identified by a Division or Divisions. This Technical Note has been prepared by CIE Reportership 2-67 of Division 2 Physical Measurement of Light and Radiation" and has been approved by the Board of Administration as well as by Division 2 of the Commission Internationale de l'eclairage. The document reports on current knowledge and experience within the specific field of light and lighting described, and is intended to be used by the CIE membership and other interested parties. It should be noted, however, that the status of this document is advisory and not mandatory. Any mention of organizations or products does not imply endorsement by the CIE. Whilst every care has been taken in the compilation of any lists, up to the time of going to press, these may not be comprehensive. CIE 2014 - All rights reserved II CIE, All rights reserved

The following member of DR 2-67 Relating Photochemical and Photobiological Quantities to Photometric Quantities took part in the preparation of this Technical Note: Blattner, P. Switzerland CIE, All rights reserved III

CONTENTS Summary... 1 1 Background... 1 2 Proposal for New Terms... 2 3 Photobiological and Photochemical Evaluations Based on Photometric Measurements... 3 4 Further Considerations... 3 4.1 Relationship between the Proposed Terms... 3 4.2 Other Photochemical and Photobiological Effects... 3 4.3 Relation to Radiometric Quantities... 4 References... 4 IV CIE, All rights reserved

Summary Optical radiation has different effects on biological systems. To quantify these effects usually the spectral distribution of a radiant quantity is weighted with the action spectrum of that effect. By this a relation between the photobiological and radiometric quantities is made. In very recent publications, mainly in the field of photobiological safety, a link between an actinic quantity and the corresponding photometric quantity is made mainly to give a simplified risk assessment procedure by means of absolute photometric measurements in combination with relative spectroradiometric measurements instead of absolute spectroradiometric measurements. Unfortunately, different terms or even units are used, e.g. transformation factor (Halbritter, 2011), specific effective radiant ultraviolet power (EC, 2009; IEC, 2011a), proportionality factor (IEC, 2011b), WB/lm factor (IEC, 2011b), or new units are defined, e.g. Blue Watt, WB (IEC, 2011b). This Technical Note proposes the definition of new terms relating photobiological or photochemical quantities to photometric quantities. It adheres to the correct use of units within the present International System of Units SI (BIPM, 2006; ISO, 2009; ISO, 2008). 1 Background According to the present definition of the SI a photobiological or photochemical quantity is defined in purely physical terms as the quantity derived from the corresponding radiant quantity by evaluating the radiation according to its action upon a selective receptor. The quantity is given by the integral over wavelength of the spectral distribution of the radiant quantity weighted by the appropriate actinic action spectrum (BIPM, 2006, Appendix 3). Most of the action spectra are relative quantities and thus are dimensionless. Except for photometric quantities, the unit of the photobiological or photochemical quantity is the radiometric unit of the corresponding radiant quantity. When giving a quantitative value, it is essential to specify whether a radiometric or photobiological quantity is intended as the unit is the same. As an example the blue light hazard (BLH) weighted radiance 1, L B, (CIE, 2011, term 17-99) of a source is obtained by weighting the spectral radiance 2, Le, λ ( λ ), with the blue light hazard spectral weighting function 3, B( λ ), (CIE, 2011, term 17-102) (i.e. the effectiveness of radiation in respect of BLH) and integrating over all wavelengths λ present in the source spectrum. This can be expressed mathematically as LB = Le, λ ( λ ) B ( λ ) d λ. (1) The blue light hazard weighted radiance, L B, is usually quoted in the SI unit 2 1 W m sr. NOTE The use of new units (e.g. blue Watt or "circadian equivalent lux") is not allowed within the present definition of the SI. According to the SI (BIPM, 2006) the only photobiological quantities that are allowed to use specific units are related to the interaction of radiation with the human eye in vision (i.e. 1 Note that in the ILV (CIE, 2011) the term blue light hazard radiance, symbol L b, is used for the same quantity. This is an inconsistency in the ILV and will be corrected in the next revision. 2 Note that in the ILV (CIE, 2011) the symbol for spectral radiance is indicated as L λ (λ). This is an inconsistency in the ILV and will be corrected in the next revision. 3 Note that in the ILV (CIE, 2011) the symbol for the blue light hazard spectral weighting function is indicated as b(λ). In this document the symbol as introduced in IEC 62471:2006/CIE S 009:2002 (IEC/CIE, 2006) is used. The symbol in the ILV will be corrected in the next revision. CIE, All rights reserved 1

candela, lux, lumen). For photopic vision, the luminance Le, λ ( λ ) by (ISO/CIE, 2005; BIPM, 1983) Lv is related to the spectral radiance Lv = Km Le, λ ( λ ) V ( λ ) d λ. (2) where V( λ ) is the CIE spectral luminous efficiency function for photopic vision, and K m the -1 maximum luminous efficacy of radiation for photopic vision ( Km 683 lm W ). The luminance, L v, is quoted in the SI unit cd m 2. NOTE The above relation can be applied to any of the photometric quantities like luminous flux, illuminance, luminous intensity, luminous energy, luminous exitance (ISO/CIE, 2005). For example, luminous flux can be evaluated as Φv = Km Φe, λ( λ) V( λ) dλ where Φ e,λ (λ) is the spectral radiant flux. 2 Proposal for New Terms As already documented in the Summary with a few examples, a link between an actinic quantity and the corresponding photometric quantity is made in a number of very recent publications where different names are given for the same quantity. Based on the example of blue light hazard the following terms and definitions are proposed: 2.1 blue light hazard efficacy of luminous radiation (of a source) K B,v quotient of the blue light hazard weighted radiant flux 1, Φ B, to the luminous flux, Φ v, K B,v Φ Φ B e, λ( λ) B( λ) dλ = = Φ K Φ ( λ) V( λ) dλ v m e, λ (3) where λ is the wavelength; Φe, λ ( λ ) is the spectral radiant flux; B( λ ) is the blue light hazard spectral weighting function; V ( λ ) is the CIE spectral luminous efficiency function for photopic vision; K m is the maximum value of the spectral luminous efficacy (683,002 lm W 1 683 lm W 1 ) Note 1 to entry: The blue light hazard efficacy of luminous radiation is expressed in W lm 1, mw klm 1, μw klm 1, Note 2 to entry: Note 3 to entry: The term luminous radiation refers to optical radiation weighted with the CIE spectral luminous efficiency function for photopic vision, V(λ). The use of this term is only reasonable if parts of the optical radiation are in the visible range and thus Φ v 0. 1 Note that in the ILV (CIE, 2011) the term blue light hazard radiant flux, symbol Φ b, is used for the same quantity. This is an inconsistency in the ILV and will be corrected in the next revision. 2 CIE, All rights reserved

2.2 blue light hazard factor of luminous radiation a B,v ratio of the blue light hazard weighted radiant flux to the V( λ ) weighted radiant flux a B,v = Φ ( λ) B( λ) dλ e, λ Φ ( λ) V ( λ) dλ e, λ (4) where λ is the wavelength; Φe, λ ( λ ) is the spectral radiant flux; B( λ ) V ( λ ) Note 1 to entry: Note 2 to entry: Note 3 to entry: is the blue light hazard spectral weighting function; is the CIE spectral luminous efficiency function for photopic vision The blue light hazard factor of luminous radiation is dimensionless with the unit one. Luminous radiation refers to optical radiation weighted with the CIE spectral luminous efficiency function for photopic vision, V(λ). The use of this term is only reasonable if parts of the optical radiation are in the visible range and thus Φe, λ( λ) V ( λ) dλ 0. 3 Photobiological and Photochemical Evaluations Based on Photometric Measurements The newly defined terms are useful for the assessment of hazards in situations where the primary use of the source is related to its visible content. An example is the determination of BLH radiance through a measurement of the luminance and the spectral distribution of the source. In theory this relation is valid if the spectral distribution is independent of the angle and point of emission within the field of view as well as the acceptance angle of the luminance meter. In practice this independence should be verified and considered in the uncertainty determination of the measurement. In addition care should be taken when measuring spectrally narrow sources (for example a blue light emitting LED), as due to spectral mismatch of the photometer to the CIE spectral luminous efficiency function for photopic vision (V(λ)) large errors are possible. Further guidance is given in CIE S 023 (CIE, 2013). 4 Further Considerations 4.1 Relationship between the Proposed Terms The blue light hazard factor where a B,v is related to the blue light hazard efficacy K B,v by ab,v = Km KB,v. (5) K m is the maximum value of the spectral luminous efficacy (683,002 lm W 1 683 lm W 1 ). 4.2 Other Photochemical and Photobiological Effects Similarly, quantities related to other photobiological or photochemical effects can be defined to relate them to a photometric quantity analogous to 2.1, e.g. K c,v : circadian efficacy of luminous radiation; K er,v : erythemal efficacy of luminous radiation; K R,v : retinal thermal efficacy of luminous radiation; KUV A,v : UV-A efficacy of luminous radiation. CIE, All rights reserved 3

4.3 Relation to Radiometric Quantities If a relation to a radiometric quantity is made, the quantities shall be called xxx efficiency of radiation, where xxx stands for the photobiological or photochemical effect in question, e.g. the quantity BLH efficiency of radiation is defined as η B = Φe, λ( λ) B( λ) dλ. (6) Φ ( λ) dλ NOTE 1 Unit: 1. e, λ NOTE 2 The blue light hazard efficiency of radiation, η B, is related to the blue light hazard efficacy of luminous radiation, K B,v, through η B = K KB,v, where K is the luminous efficacy of radiation, and to the blue light hazard factor of luminous radiation, a B,v, through η B = V ab,v, where V is the luminous efficiency of radiation. NOTE 3 For some applications it might be necessary to state both η B and K B,v (Rebec et al., 2014). References BIPM, 1983. Principles governing photometry (Monographie 83/1). Available from: http://www.bipm.org/utils/en/pdf/monographie1983-1.pdf. BIPM, 2006. The International System of Units (SI), 8th edition. Available from: http://www.bipm.org/en/si/si_brochure/ and: http://www.bipm.org/en/si/si_brochure/appendix3/app3_2.html. CIE, 2011. CIE S 017/E:2011 ILV: International Lighting Vocabulary. CIE, 2013. CIE S 023/E:2013 Characterization of the Performance of Illuminance Meters and Luminance Meters. EC, 2009. Commission Regulation (EC) No 244/2009, implementing Directive 2005/32/EC of the European Parliament and of the Council with regard to ecodesign requirements for nondirectional household lamps, Annex I-1. HALBRITTER, W. et al. 2011. Simplified approach for classification the potential photobiological hazards of LEDs according CIE S009. In: CIE 197-2011 Proceedings of the 27th Session of the CIE, South Africa 2011, pp. 543ff. IEC/CIE, 2006. IEC 62471:2006/CIE S 009:2002 Photobiological safety of lamps and lamp systems. IEC, 2011a. PRESCO(RTK)157A, Proposal to amend IEC 61195 Double-capped fluorescent lamps safety specifications (non-public committee document). IEC, 2011b. Application of IEC 62471 to light sources and luminaires for the assessment of blue light hazard, Panel Status 20110714 (non-public committee document). ISO/CIE, 2005. ISO 23539:2005 / CIE S 010:2004 Photometry - The CIE System of Physical Photometry. ISO, 2008. ISO 80000-7:2008 Quantities and units, Part 7: Light. ISO, 2009. ISO 80000-1:2009 Quantities and units, Part 1: General. REBEC, K.M., GUNDE, M.K., BIZJAK, G. and KOBAV, M.B. 2014. White LED compared to other light sources age dependent photobiological effects and parameters for evaluation, International Journal of Occupational Safety (JOSE). In press (status September 2014). 4 CIE, All rights reserved