Synthesis of Dextran Graft Copolymers The synthesis route of the dextran graft copolymers is shown in Scheme S1. The details for
|
|
- Emily Hensley
- 5 years ago
- Views:
Transcription
1 Supportin information Synthesis of Dextran Graft Copolymers The synthesis route of the dextran raft opolymers is shown in Sheme S1. The details for the synthesis of raft opolymers are as follows. Sheme S1. The synthesis route of Dex--PMAGGCNTyr-NPEG 3k (II), Dex--P(MPEG-o-MAGGCNTyr) (III), Dex--P(PMA-o-MAGGCNTyr) (IV). Synthesis of Dex--P(MPEG-o-MAGGCNTyr) and Dex--P(PMA-o- MAGGCNTyr). Dextran (250 m) was firstly dissolved in 6 ml water and then K 2 S 2 8 (2.7 m, 0.01 mmol), NaS 3 (1.4 m, 0.01 mmol) were added. The solution was uled with nitroen at room temperature for 30 min to remove the oxyen. Then 4 ml MAGGC/MPEG or MAGGC/PMA mixed aqueous solution was added slowly 1
2 under nitroen atmosphere. The resultant reation solutions were dialyzed aainst water, and then were freeze-dried to otain Dex--P(MPEG-o-MAGGC) or Dex--P(PMA-o- MAGGC). The details on the seletion of the optimal onditions are listed in Tales S1 and S2. From run 1 to 4 (Tale S1), when n(-c):n(mpeg) is kept at 1.95:1, DS -C /DS MPEG 1, so the raft monomer MAGGC/MPEG reativity ratio is around 1:2, From run 1 to 3 (Tale S2), when n(-c):n(pma) is kept at 0.77:1, DS -C /DS MPEG 0.8, so the raft monomer reativity ratio MAGGC/PMA is around 1:1. In order to synthesize raft opolymer with a deree of sustitution of C roups around , the reation feedin ratios of the MAGGC were adjusted as those listed in Tales S1 and S2. DS PMA and DS MPEG inrease with the inrease of the mass of the added monomer PMA or MPEG. The influenes of MPEG and PMA mononmer onentrations on the raft ratio (G) are listed in Tales S1 and S2. Graftin ratio (G) was alulated y the followin formula. G = W 2 /W 1 100%, where W 1 and W 2 the mass of pure raft opolymer and raft hains, respetively. DS PMA = A 2 /2A 1, where A 1 and A 2 are the interated areas of the protons on dextran akone (δ = 4.95 ppm) and the methylene of =C N C 2 roups of the PPMA side hains (δ = ppm) on 1 NMR spetra, respetively. DS MPEG = A 3 /2A 1, where A 3 is the methylene of =C C 2 roups of the PMPEG side hains (δ = ppm) on 1 NMR spetra, respetively. Moleular weiht of Dex--P(MPEG-o- MAGGC) raft opolymer was alulated y M w,dex--p(mpeg-o-maggc) = M w,dex + n(184 DS C DS MPEG ), where M w,dex is the moleular weiht of dextran, 184 is the molar mass of MAGGC. Moleular weiht of Dex--P(PMA-o-MAGGC) raft opolymer was alulated y M w,dex--p(pma-o-maggc) = M w,dex + n(184 DS C DS PMA ), where 143 is the molar mass of PMA. n is the averae numers of luose unit per dextran hain. The raft opolymers are haraterized y usin 1 NMR, and the 2
3 typial 1 NMR data is shown in Fiure S1 and S2. The onjuation of the L-Tyrosine is similar to the previous work. 1 Dex--P(MPEG-o-MAGGCNTyr). Yield 74%. 1 NMR (400 Mz, D 2, δ, ppm): (3, m, -C 3 ), (2, m, -C-C 2 -), 2.70 (2, s, -C 2 - from L-Tyrosine), (2, m, =C--C 2 - from PMPEG), (9, m, dextran), 4.95 (1, s, 1 from rin of dextran), 6.70 (2, s, m-phenyl hydroen), 7.10 (2, s, o-phenyl hydroen). Dex--P(PMA-o-PMAGGCNTyr). Yield 79.6%. 1 NMR (400 Mz, D 2, δ, ppm): (3, m, -C 3 ), (2, m, -C-C 2 -), 2.70 (2, s, -C 2 - from L-Tyrosine), (2, m, -C 2 - from PMA), (9, m, dextran), 4.95 (1, s, 1 from rin of dextran), 6.70 (2, s, m-phenyl hydroen), 7.10 (2, s, o-phenyl hydroen). Tale S1. Details of synthesis and information for Dex--P(MPEG-o-MAGGC). a m Dex :m [-C] n [-C] : DS -C / G MAGGC G MPE M w Run m Dex DS -C DS MPEG :m [MPEG] n [MPEG] DS MPEG % G% (kda) :0.25:0.25 2: :0.5:0.5 2: :1:1 2: :1.5:1.5 2: :1.5: a [K 2 S 2 8 ] = [NaS 3 ] =1 mmol/l. All the reations were arried out at 30 C for 9 h. The deree of sustitution of the MAGGC (DS MAGGC ) and MPEG (DS MPEG ) per luose unit were alulated y 1 NMR. M w is the moleular weiht of Dex--P(MPEG-o-MAGGC), and is alulated y 1 NMR. Tale S2. Details of synthesis and information for for Dex--P(PMA-o-MAGGC). a Run m Dex (m) m [Dex] :m [-C] :m [PMA] n [-C] : n [MPEG] DS -C DS PMA DS -C / DS PMA G -C % G PMA % M w (kda) :0.25: : :0.5: : :1:1 0.8: :1: a [K 2 S 2 8 ] = [NaS 3 ] =1 mmol/l. All the reations were arried out at 30 C for 9 h. The deree of sustitution of the MAGGC (DS MAGGC ) and PMA (DS PMA ) per luose unit were alulated y 1 NMR. M w is the moleular weiht of Dex--P(PMA-o-MAGGC), and is alulated y 1 NMR. 3
4 6 6 Eletroni Supplementary Material (ESI) for Polymer Chemistry Dex N N N N C e f N d e f d Dex N N * C 2 a n a Chemial shift (ppm) Fiure S1. 1 NMR spetra of Dextran, Dex--P(MPEG-o-MAGGC) and Dex--P(MPEG-o-MAGGCNTyr) at 400 Mz in D 2. y Dex x-y m N N N e f C N 3 N N C d ef d Dex x-y m N N C 3 N * C 2 a n a ppm Chemial shift Fiure S2. 1 NMR spetra of Dextran, Dex--P(PMA-o-MAGGC) and Dex--P(PMA-o-MAGGCNTyr) at 400 Mz in D 2. 4
5 Synthesis of Dex--PMAGGCNPEG 3k -NTyr Copolymers. Dex--PMAGGC (DS -C = 0.57) (50 m) was dissolved in water to otain a solution with p of Then ertain amounts of EDC/NS were added and stirred for 10 min for pre-ativation, after whih L-Tyrosine, N 2 PEG 3k and Na 2 C 3 mixed solution was added dropwise. The reation mixture was kept in water ath at 25 C and stirred for 3 h. Dex--PMAGGCNPEG 3k -NTyr was otained y the previous purified method. The optimism of the reation onditions are listed in Tale S3. Dex--PMAGGC with 0.57 of DS C was hosen for amide reation aordin to our previous work, DS NPEG3k is determined y the mass of the added N 2 PEG 3k. The ontent of N 2 PEG 3k in the side hain PMAGGC of raft opolymers, whih was defined as the averae N 2 PEG 3k roups per luopyranose unit (DS NPEG3k ), an e estimated y DS NPEG3k = (A 4 -A 5 )/280, where A 4 : the interated areas from δ 3.45 to 4.12 ppm of raft opolymer Dex--PMAGGCNPEG 3k -NTyr, A 5 : the interated areas from δ 3.45 to 4.12 ppm of raft opolymer Dex--PMAGGC, 280: all the numers of hydroen atom per PEG hain. Moleular weiht of Dex--PMAGGCNPEG 3k -NTyr raft opolymers were alulated y M w, Dex--PMAGGCNPEG3k = M w,dex + n(184 ( DS NPEG3k ) DS NPEG3k ) where M w,dex is the moleular weiht of dextran, n is the averae numers of luose unit per dextran hain. 184 is the molar mass of MAGGC, 0.57 is the DS C of the Dex--PMAGGC raft opolymers that used for the amide formation Dex--PMAGGCNPEG 3k -NTyr. Yield 71%. 1 NMR (400 Mz, D 2, δ, ppm): (3, m, -C 3 ), (2, m, -C-C 2 -), 2.70 (2, s, -C 2 - from L-Tyrosine), (m, dextran and -C 2 -C 2 - from N 2 PEG 3k ), 4.95 (1, s, 1 from rin of dextran), 6.70 (2, s, m-phenyl hydroen), 7.10 (2, s, o-phenyl hydroen). 5
6 Tale S3. Details of synthesis and information for Dex--PMAGGCNPEG 3k -NTyr. a Run m Dex--PMAGGC (m) m PEG (m) m Tyr (m) n [C] :n [PEG] :n [ Tyr]:n [EDC] :n [NS] DS PEG3k N Tyr M w (kda) :0.025:1:1: :0.05:0:1: :0.1:1:1: :0.2:0:1: :0.3:0:1: a Reation at p = 10-11, adjusted y Na 2 C 3, pre-ativited for 10 min, All the reations were arried out at 25 C for 3 h. The averae numers of MAGGC per luose rin is M w is the moleular weiht of Dex--PMAGGCNPEG 3k -NTyr, and is alulated y 1 NMR. Fiure S3. Representative ITLC hromatorams of 125 I laeled Dex--PMAGGCNPEG 3k -NTyr. (a) the oriinal kit and () after purifiation. 6
7 Fiure S4. Representative ITLC hromatorams of 125 I laeled Dex--P(MPEG-o-MAGGCNTyr). (a) the oriinal kit and () after purifiation. Referene 1. D. Wan, J. Shi, J. Tan, X. Jin, Q. Li,. Kan, R. Liu, B. Jia and Y. uan, Biomaromoleules, 2011, 12,
properties via a simple hydrolysis-based approach
Eletroni Supplementary Material (ESI) for Journal of Materials Chemistry A This journal is The Royal Soiety of Chemistry 01 Supporting Information Salable synthesis of hollow O nanoubes with unique optial
More informationSelf-Healing Polymers with PEG Oligomer Side Chains. Based on Multiple H-Bonding and Adhesion Properties
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2015 Supporting Information Self-Healing Polymers with PEG Oligomer Side Chains Based on Multiple
More informationSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information Synthesis of Poly(dihydroxystyrene-block-styrene) (PDHSt-b-PSt) by the RAFT
More informationHow does A Tiny Terminal Alkynyl End Group Drive Fully Hydrophilic. Homopolymers to Self-Assemble into Multicompartment Vesicles and
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 04 Electronic Supplementary Information for How does A Tiny Terminal Alkynyl End Group Drive
More informationPolymer Science, Series A, 2017, Vol. 59, No. 3 SUPPORTING INFORMATION. The Screening and Evaluating of Chitosan/β-cyclodextrin
Polymer Science, Series A, 2017, Vol. 59, No. 3 SUPPORTING INFORMATION The Screening and Evaluating of Chitosan/β-cyclodextrin Nanoparticles for Effective Delivery Mitoxantrone Hydrochloride Yiwen Wang,
More informationSupporting information
Eletroni Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Soiety of Chemistry 2016 Supporting information Polymerisation of 2-arylamio-2-methylpropane sulfoni ai soium salt
More informationAziridine in Polymers: A Strategy to Functionalize Polymers by Ring- Opening Reaction of Aziridine
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information (ESI) Aziridine in Polymers: A Strategy to Functionalize
More informationHIV anti-latency treatment mediated by macromolecular prodrugs of histone deacetylase inhibitor, panobinostat
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 206 Supporting information HIV anti-latency treatment mediated by macromolecular prodrugs of
More informationSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Supporting Information TEMPO-catalyzed Synthesis of 5-Substituted Isoxazoles from Propargylic
More informationSynthesis and Characterization of Well-defined PAA- PEG Multi-responsive Hydrogels by ATRP and Click Chemistry
Electronic Supplementary Material (ES) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Support information Synthesis and Characterization of Well-defined PAA- PEG Multi-responsive
More informationRed Color CPL Emission of Chiral 1,2-DACH-based Polymers via. Chiral Transfer of the Conjugated Chain Backbone Structure
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2015 Red Color CPL Emission of Chiral 1,2-DACH-based Polymers via Chiral Transfer of the Conjugated
More informationSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Rh 2 (Ac) 4 -Catalyzed 2,3-Migration of -rrocenecarboxyl -Diazocarbonyl
More informationRevisiting the complexation between DNA and polyethylenimine when and where S S linked PEI is cleaved inside the cell
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry B. This journal is The Royal Society of Chemistry 214 Revisiting the complexation between DNA and polyethylenimine when and where
More information(A) Effect of I-EPI-002, EPI-002 or enzalutamide on dexamethasone (DEX, 10 nm)
Supplemental Figure Legends Supplemental Figure 1. (A) Effect of I-EPI-002, EPI-002 or enzalutamide on dexamethasone (DEX, 10 nm) induced GR transcriptional activity in LNCaP cells that were transiently
More informationSupporting information
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2015 Supporting information Influence
More informationElectronic Supplementary Information (12 pages)
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 A C 2 -responsive pillar[5]arene: synthesis and self-assembly in water Kecheng Jie, Yong Yao, Xiaodong
More informationSUPPORTING INFORMATION
SUPPORTING INFORMATION Polymerization-induced Self-Assembly of Homopolymer and Diblock copolymer: A Facile Approach for preparing Polymer Nano-objects with Higher Order Morphologies Jianbo Tan *a,b, Chundong
More informationSupplementary Material
Supplementary Material Part 1 Experimental Materials Chitooligosaccharide (M n =1800, the degrees of deacetylation is 96%), purchased from Shenzhen Bright Way Novel Bio-Material Tech. Co. Ltd.(P. R. China),
More informationNovel Tri-Block Copolymer of Poly (acrylic acid)-b-poly (2,2,3,3,4,4,4- hexafluorobutyl acrylate)-b-poly (acrylic acid) Prepared via Two-Step
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry Please do 2016 not adjust margins Electronic Supplementary Information (ESI) for Novel Tri-Block
More informationSupporting Information
Supporting Information Syntheses and characterizations: Compound 1 was synthesized according to Scheme S-1. Scheme S-1 2 N N 5 i N 4 P Et Et iii N 6 ii P Et Et iv v, vi N N i) Fmoc-Su, DIPEA, Acetone;
More informationSupporting Information
Supporting Information of Appointed exploding microcapsules as drug carriers By Jing Zhang, Cao Li, Ya Wang, Ren-Xi Zhuo and Xian-Zheng Zhang * Materials Propargyl alcohol (PA-OH), dextran (M w ~20 k &
More informationElectronic Supplementary Information
Electronic Supplementary Information Effect of polymer chain conformation on field-effect transistor performance: synthesis and properties of two arylene imide based D-A copolymers Dugang Chen, a Yan Zhao,
More informationA supramolecular approach for fabrication of photo- responsive block-controllable supramolecular polymers
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2014 Supporting Information A supramolecular approach for fabrication of photo- responsive
More informationSensitive and reliable detection of glass transition of polymers. by fluorescent probes based on AIE luminogens
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2015 Supporting information Sensitive and reliable detection of glass transition of polymers
More informationSyntheses of a pillar[4]arene[1]quinone and a difunctionalized. pillar[5]arene by partial oxidation. Electronic Supplementary Information (11 pages)
Syntheses of a pillar[4]arene[1]quinone and a difunctionalized pillar[5]arene by partial oxidation Chengyou an, Zibin Zhang, Guocan Yu and Feihe uang* Department of Chemistry, Zhejiang University, angzhou
More informationAmphiphilic diselenide-containing supramolecular polymers
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2014 Amphiphilic diselenide-containing supramolecular polymers Xinxin Tan, Liulin Yang, Zehuan
More information1G (bottom) with the phase-transition temperatures in C and associated enthalpy changes (in
Supplementary Figure 1. Optical properties of 1 in various solvents. UV/Vis (left axis) and fluorescence spectra (right axis, ex = 420 nm) of 1 in hexane (blue lines), toluene (green lines), THF (yellow
More informationElectronic Supplementary Information
Electronic Supplementary Information Novel [2]pseudorotaxanes constructed by self-assembly of bis-urea-functionalized pillar[5]arene and linear alkyl dicarboxylates Qunpeng Duan, Wei Xia, Xiaoyu Hu, Mengfei
More informationYujuan Zhou, Kecheng Jie and Feihe Huang*
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 A redox-responsive selenium-containing pillar[5]arene-based macrocyclic amphiphile: synthesis,
More informationLight-Controlled Switching of a Non- Photoresponsive Molecular Shuttle
Supporting Information Light-Controlled Switching of a Non- Photoresponsive Molecular Shuttle Liu-Pan Yang, a,b Fei Jia, a Jie-Shun Cui, a Song-Bo Lu, a and Wei Jiang* a a Department of Chemistry, South
More informationEnantioselectivity switch in copper-catalyzed conjugate addition. reaction under influence of a chiral N-heterocyclic carbene-silver complex
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Supplementary Information Enantioselectivity switch in copper-catalyzed conjugate addition
More informationSupporting Information for
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017 Supporting Information for
More informationThe Graft Copolymerisation of Acrylamide onto Cellulose using Enhanced Fe 2+ / H 2 O 2 redox initiator system
JASEM ISSN 1119-8362 All rights reserved Full-text Available Online at www.bioline.org.br/ja J. Appl. Si. Environ. Mgt. September, 6 Vol. (3) 11-1 The Graft Copolymerisation of Arylamide onto Cellulose
More informationEffect of Conjugation and Aromaticity of 3,6 Di-substituted Carbazole On Triplet Energy
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2018 Electronic Supporting Information (ESI) for Effect of Conjugation and Aromaticity of 3,6 Di-substituted
More informationUnusual ph-dependent Surface Adsorption and Aggregation Behavior of a series of Asymmetric Gemini Amino-acid Surfactants
Electronic Supplementary Material (ESI) for Soft Matter. This journal is The Royal Society of Chemistry 2015 Supplementary Information for: Unusual ph-dependent Surface Adsorption and Aggregation Behavior
More informationSupporting Information
Electronic upplementary Material (EI) for Journal of Materials Chemistry B. This journal is The Royal ociety of Chemistry 216 upporting Information A dual-functional benzobisthiadiazole derivative as an
More informationSupporting information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 2015 Supporting information Porosity induced emission: exploring color-controllable
More informationph dependent thermoresponsive behavior of acrylamide-acrylonitrile UCSTtype copolymers in aqueous media
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2016 Supporting Information ph dependent thermoresponsive behavior of acrylamide-acrylonitrile
More informationDrastically Decreased Reactivity of Thiols and Disulfides Complexed by Cucurbit[6]uril
SUPPORTING INFORMATION Drastically Decreased Reactivity of Thiols and Disulfides Complexed by Cucurbit[6]uril Lidia Strimbu Berbeci, Wei Wang and Angel E. Kaifer* Center for Supramolecular Science and
More informationAlkali α-mno 2 /Na x MnO 2 collaboratively catalyzed ammoxidation-pinner tandem reaction of aldehydes
Electronic Supplementary Material (ESI) for Catalysis Science & Technology. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information for Alkali α-mno 2 /Na x MnO 2 collaboratively
More informationSupplementary Note 1 : Chemical synthesis of (E/Z)-4,8-dimethylnona-2,7-dien-4-ol (4)
Supplementary Note 1 : Chemical synthesis of (E/Z)-4,8-dimethylnona-2,7-dien-4-ol (4) A solution of propenyl magnesium bromide in THF (17.5 mmol) under nitrogen atmosphere was cooled in an ice bath and
More informationSupplementary Materials: SRG Inscription in Supramolecular Liquid Crystalline Polymer Film: Replacement of Mesogens
Supplementary Materials: SRG Inscription in Supramolecular Liquid Crystalline Polymer Film: Replacement of Mesogens Shun Mitsui, Mitsuo Hara, Shusaku Nagano, and Takahiro Seki S. Synthesis Materials Sodium
More informationSupporting information. Cooperatively Enhanced Ion Pair Binding with a Hybrid Receptor
Supporting information Cooperatively Enhanced Ion Pair Binding with a Hybrid Receptor Toni Mäkelä, a Elina Kalenius a and Kari Rissanen a* a University of Jyvaskyla, Department of Chemistry, Nanoscience
More information2,5-bis(4-alkoxycarbonylphenyl)-1,4-diaryl-1,4-dihydropyrrolo[3,2- b]pyrrole (AAPP) AIEgens: tunable RIR and TICT characteristics
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2017 2,5-bis(4-alkoxycarbonylphenyl)-1,4-diaryl-1,4-dihydropyrrolo[3,2- b]pyrrole (AAPP) AIEgens:
More informationSupporting Information for
Electronic Supplementary Material (ES) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2016 Supporting nformation for BODPY-Containing
More informationSupplementary Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supplementary Information A Novel Single-Side Azobenzene-Grafted Anderson-Type Polyoxometalate
More informationRadical Polymerization and Click Chemistry. Surfaces using Gamma Irradiation. Supporting Information*
Synthesis of Block Copolymers via Atom Transfer Radical Polymerization and Click Chemistry grafted from Pre-functionalized Polypropylene Surfaces using Gamma Irradiation Supporting Information* Ollie Foster,
More informationA dual redox-responsive supramolecular amphiphile fabricated by selenium-containing pillar[6]arene-based molecular recognition
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 A dual redox-responsive supramolecular amphiphile fabricated by selenium-containing pillar[6]arene-based
More informationElectronic supplementary information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Electronic supplementary information Heterogeneous nucleation and growth of highly crystalline
More informationSupporting information. An improved photo-induced fluorogenic alkene-tetrazole reaction for protein labeling
Supporting information An improved photo-induced fluorogenic alkene-tetrazole reaction for protein labeling X. Shang, 1 R. Lai, 1,3 X. Song, 1 H. Li, 1,3 W. Niu, 2 and J. Guo 1 * 1. Department of Chemistry,
More informationCompound Number. Synthetic Procedure
Compound Number 1 2 3 4 5 Synthetic Procedure Compound 1, KY1220, (Z)-5-((1-(4-nitrophenyl)-1H-pyrrol-2-yl)methylene)-2-thioxoimidazolidin-4-one was purchased from Chemdiv, Catalog #3229-2677, 97% HPLC
More informationSupporting information for
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2017 Supporting information for A new thermoresponsive polymer of poly(n-acryloylsarcosine
More informationSupplementary Information. Rational Design of Soluble and Clickable Polymers Prepared by. Conventional Free Radical Polymerization of
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2017 Supplementary Information Rational Design of Soluble and Clickable Polymers Prepared by
More informationPD Research Report for the 2014 year
PD Research Report for the 2014 year Name(Research group) GAYEN KRISHNANKA SHEKHAR (Professor T. Hamura s group, Graduate School of Science and Technology) Research Theme Synthesis of functionalized heptacenes
More informationLi + Solvation in Glyme-Li Salt Solvate Ionic Liquids
Eletroni Supplementary Material (ESI) for Physial Chemistry Chemial Physis. This journal is the Owner Soieties 15 Supplementary Information: + Solvation in Glyme- Salt Solvate Ioni quids Kazuhide Ueno,
More informationSupporting Information. Cells. Mian Wang, Yanglei Yuan, Hongmei Wang* and Zhaohai Qin*
Electronic Supplementary Material (ESI) for Analyst. This journal is The Royal Society of Chemistry 2015 Supporting Information Fluorescent and Colorimetric Probe Containing Oxime-Ether for Pd 2+ in Pure
More informationTuning Porosity and Activity of Microporous Polymer Network Organocatalysts by Co-Polymerisation
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information Tuning Porosity and Activity of Microporous Polymer Network Organocatalysts
More informationSupporting Information
Supporting Information Wiley-VCH 2008 69451 Weinheim, Germany Concise Stereoselective Synthesis of ( )-Podophyllotoxin by Intermolecular Fe III -catalyzed Friedel-Crafts Alkylation Daniel Stadler, Thorsten
More informationDiblock Metallocopolymers Containing Various Iron Sandwich Complexes: Living ROMP Synthesis and Selective Reversible Oxidation
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 206 Diblock Metallocopolymers Containing Various Iron Sandwich Complexes: Living ROMP Synthesis
More informationSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2017 Supporting Information Synthesis and Characterization of Amide Linked Triazolyl Glycolipids
More informationFluorescent Chemosensor for Selective Detection of Ag + in an. Aqueous Medium
Electronic supplementary information For A Heptamethine cyanine -Based Colorimetric and Ratiometric Fluorescent Chemosensor for Selective Detection of Ag + in an Aqueous Medium Hong Zheng *, Min Yan, Xiao-Xing
More informationOne polymer for all: Benzotriazole Containing Donor-Acceptor Type Polymer as a Multi-Purpose Material
One polymer for all: Benzotriazole Containing Donor-Acceptor Type Polymer as a Multi-Purpose Material Abidin Balan a, Derya Baran a, Gorkem Gunbas a,b, Asuman Durmus a,b, Funda Ozyurt a and Levent Toppare
More informationSupporting information for A simple copper-catalyzed two-step one-pot synthesis of indolo[1,2-a]quinazoline
Supporting information for A simple copper-catalyzed two-step one-pot synthesis of indolo[1,2-a]quinazoline Chunpu Li 1,2, Lei Zhang 2, Shuangjie Shu 2 and Hong Liu* 1,2 Address: 1 Department of Medicinal
More informationOne-pot Solvent-free Synthesis of Sodium Benzoate from the Oxidation of Benzyl Alcohol over Novel Efficient AuAg/TiO 2 Catalysts
Electronic Supplementary Information One-pot Solvent-free Synthesis of Sodium Benzoate from the Oxidation of Benzyl Alcohol over Novel Efficient AuAg/TiO 2 Catalysts Ying Wang, Jia-Min Zheng, Kangnian
More informationSupporting Information
Supporting Information An L-proline Functionalized Metallo-organic Triangle as Size-Selective Homogeneous Catalyst for Asymmertry Catalyzing Aldol Reactions Xiao Wu, Cheng He, Xiang Wu, Siyi Qu and Chunying
More informationSupplementary Information. Development of a conjugated polymer-based fluorescent probe for selective detection of HOCl
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 2015 Supplementary Information Development of a conjugated polymer-based fluorescent
More informationSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information Nanoparticle-to-vesicle and nanoparticle-to-toroid transitions of ph-sensitive
More informationSupplementary Table 1. Small molecule screening data
Supplementary Table 1. Small molecule screening data Category Parameter Description Assay Type of assay Cell-based Target Primary measurement Key reagents Assay protocol PS1/BACE1 interaction Detection
More informationInvestigation into the mechanism of photo-mediated RAFT polymerization involving the reversible photolysis of the chain-transfer agent
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2017 Investigation into the mechanism of photo-mediated RAFT polymerization involving the reversible
More informationSupplementary Information
Supplementary Information riented Crystallization of Hydroxyapatite by the Biomimic Amelogenin anospheres from the Self-Assemblies of Amphiphilic Dendrons Sheng Yang a, Hai He b, Lei Wang a*, Xinru Jia
More informationSupporting Information
Supporting Information UCST or LCST? Composition-Dependent Thermoresponsive Behavior of Poly(N-Acryloylglycinamide-co-Diacetone Acrylamide) Wenhui Sun, Zesheng An*, Peiyi Wu * Experimental Materials Glycinamide
More informationSupporting Information
Supporting Information Total Synthesis of (±)-Grandilodine B Chunyu Wang, Zhonglei Wang, Xiaoni Xie, Xiaotong Yao, Guang Li, and Liansuo Zu* School of Pharmaceutical Sciences, Tsinghua University, Beijing,
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information for Construction of reverse vesicles from pseudo-graft
More informationSupplementary Material
10.1071/CH17506_AC CSIRO 2018 Australian Journal of Chemistry 2018, 71(5), 341-347 Supplementary Material Magnesium alkoxide complexes of (benzimidazolylmethyl)amino ligands: Synthesis and applications
More informationSupplementary Information (Manuscript C005066K)
Supplementary Information (Manuscript C005066K) 1) Experimental procedures and spectroscopic data for compounds 6-12, 16-19 and 21-29 described in the paper are given in the supporting information. 2)
More informationSupplementary Material for
www.sciencemag.org/content/343/6173/873/suppl/dc1 Supplementary Material for Nonswellable Hydrogel Without Mechanical Hysteresis Hiroyuki Kamata, Yuki Akagi, Yuko Kayasuga-Kariya, Ung-il Chung, Takamasa
More informationEfficient Magnesium Catalysts for the Copolymerization of Epoxides and CO 2 ; Using Water to Synthesize Polycarbonate Polyols
Supporting Information for Efficient Magnesium Catalysts for the Copolymerization of Epoxides and CO 2 ; Using Water to Synthesize Polycarbonate Polyols Michael R. Kember, Charlotte K. Williams* Department
More informationPhotooxidations of 2-(γ,ε-dihydroxyalkyl) furans in Water: Synthesis of DE-Bicycles of the Pectenotoxins
S1 Photooxidations of 2-(γ,ε-dihydroxyalkyl) furans in Water: Synthesis of DE-Bicycles of the Pectenotoxins Antonia Kouridaki, Tamsyn Montagnon, Maria Tofi and Georgios Vassilikogiannakis* Department of
More informationSynthesis and characterization of innovative well-defined difluorophosphonylated-(co)polymers by RAFT polymerization
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 205 Supporting Information Synthesis and characterization of innovative well-defined difluorophosphonylated-(co)polymers
More information*Corresponding author. Tel.: , ; fax: ; Materials and Method 2. Preparation of GO nanosheets 3
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Synthesis of 2,3-dihydroquinazolinones and quinazolin-4(3h)-one catalyzed by Graphene Oxide
More informationSupporting Information. Light-induced Wide Range Color Switching of Liquid Crystal. Blue Phase doped with Hydrogen-bonded Chiral Azobenzene.
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Light-induced Wide Range Color Switching of Liquid Crystal Blue Phase
More informationSupporting Information. Vesicles of double hydrophilic pullulan and. poly(acrylamide) block copolymers: A combination
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2017 Supporting Information Vesicles of double hydrophilic pullulan and poly(acrylamide) block
More informationMultivalent manganese complexes decorated amphiphilic dextran micelles as sensitive MRI probes
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry B. This journal is The Royal Society of Chemistry 2015 Multivalent manganese complexes decorated amphiphilic dextran micelles
More informationThiol-reactive amphiphilic block copolymer for coating gold nanoparticles with neutral and functionable surfaces
Supporting information for: Thiol-reactive amphiphilic block copolymer for coating gold nanoparticles with neutral and functionable surfaces Hongwei Chen 1,*, Hao Zou 1,2, Hayley J. Paholak 1, Masayuki
More information(Supplementary Information)
(Supplementary Information) Peptidomimetic-based Multi-Domain Targeting Offers Critical Evaluation of Aβ Structure and Toxic Function Sunil Kumar 1*, Anja Henning-Knechtel 2, Mazin Magzoub 2, and Andrew
More informationESI. Core-Shell Polymer Nanoparticles for Prevention of GSH Drug Detoxification and Cisplatin Delivery to Breast Cancer Cells
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2015 ESI Core-Shell Polymer Nanoparticles for Prevention of GSH Drug Detoxification and Cisplatin Delivery
More informationDepartment of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, MA USA
Supporting Information SELF-DECONTAMINATING FIBROUS MATERIALS REACTIVE TOWARD CHEMICAL THREATS Lev Bromberg, a Xiao Su, a Vladimir Martis, b Yunfei Zhang, a and T. Alan Hatton a* a Department of Chemical
More informationSupporting Information. A turn-on fluorescent probe for detection of Cu 2+ in living cells based on signaling mechanism of N=N isomerization
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2016 Supporting Information A turn-on
More informationSupporting Information
Supporting Information In Situ Ratiometric Quantitative Tracing Intracellular Leucine Aminopeptidase Activity via an Activatable Near- Infrared Fluorescent Probe Kaizhi Gu, Yajing Liu, Zhiqian Guo,*,,#
More informationPostsynthetic modification of unprotected peptides via S-tritylation reaction
Supporting Information Postsynthetic modification of unprotected peptides via S-tritylation reaction Masayoshi Mochizuki, Hajime Hibino and Yuji Nishiuchi *,, SAITO Research Center, Peptide Institute,
More informationSUPPORTING INFORMATION
SUPPORTING INFORMATION Dual Stimuli-Responsive, Rechargeable Micropumps via Host-Guest Interactions ** Debabrata Patra, Hua Zhang, Samudra Sengupta, Ayusman Sen * Department of Chemistry, The Pennsylvania
More informationSynthesis of Trifluoromethylated Naphthoquinones via Copper-Catalyzed. Cascade Trifluoromethylation/Cyclization of. 2-(3-Arylpropioloyl)benzaldehydes
Supporting Information to Synthesis of Trifluoromethylated Naphthoquinones via Copper-Catalyzed Cascade Trifluoromethylation/Cyclization of 2-(3-Arylpropioloyl)benzaldehydes Yan Zhang*, Dongmei Guo, Shangyi
More informationAminoacid Based Chiral N-Amidothioureas. Acetate Anion. Binding Induced Chirality Transfer
Aminoacid Based Chiral -Amidothioureas. Acetate Anion Binding Induced Chirality Transfer Fang Wang, a Wen-Bin He, a Jin-He Wang, a Xiao-Sheng Yan, a Ying Zhan, a Ying-Ying Ma, b Li-Cai Ye, a Rui Yang,
More informationSimple Solution-Phase Syntheses of Tetrahalodiboranes(4) and their Labile Dimethylsulfide Adducts
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 Supporting Information for: Simple Solution-Phase Syntheses of Tetrahalodiboranes(4) and their
More informationSupporting Information for. Silver-catalyzed intramolecular hydroamination of alkynes in
Supporting Information for Silver-catalyzed intramolecular hydroamination of alkynes in aqueous media: efficient and regioselective synthesis for fused benzimidazoles Xu Zhang, a, b Yu Zhou, b Hengshuai
More informationMaksim A. Kolosov*, Olesia G. Kulyk, Elena G. Shvets, Valeriy D. Orlov
1 Synthesis of 5-cinnamoyl-3,4-dihydropyrimidine-2(1H)-ones Supplementary Information Maksim A. Kolosov*, lesia G. Kulyk, Elena G. Shvets, Valeriy D. rlov Department of organic chemistry, V.N.Karazin Kharkiv
More informationSupporting Information.
Supporting Information. Materials. Polyethyleneglycol monomethylether methacrylate (PEGMA) (~475 Da), trifluoroethyl acrylate (tfea) and ethyleneglycol dimethacrylate (EGDMA) were purchased from Sigma
More informationSupporting Information. A Robust Ni(II) α-diimine Catalyst for High Temperature Ethylene Polymerization
Supporting Information A Robust Ni(II) α-diimine Catalyst for High Temperature Ethylene Polymerization Jennifer L. Rhinehart, Lauren A. Brown and Brian K. Long* Univeristy of Tennessee, Department of Chemistry,
More informationDendritic Star Polymer of Polyacrylamide Based on β-cyclodextrin Trimer: A. Flocculant and Drug Vehicle
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2016 Electronic Supporting Information
More informationSYNTHESIS AND COMPARISON OF GRAFT COPOLYMERS USING METHACRYLIC MONOMERS AND CELLULOSE VIA ATRP
CELLULSE CHEMISTRY AND TECHNLGY SYNTHESIS AND CMPARISN F GRAFT CPLYMERS USING METHACRYLIC MNMERS AND CELLULSE VIA ATRP YUE SHEN, * LIN DAI, * MING-FEI LI, * JING HE, * B WANG * and RUN-CANG SUN *,** *
More information