Polymer Science, Series A, 2017, Vol. 59, No. 3 SUPPORTING INFORMATION. The Screening and Evaluating of Chitosan/β-cyclodextrin

Size: px
Start display at page:

Download "Polymer Science, Series A, 2017, Vol. 59, No. 3 SUPPORTING INFORMATION. The Screening and Evaluating of Chitosan/β-cyclodextrin"

Transcription

1 Polymer Science, Series A, 2017, Vol. 59, No. 3 SUPPORTING INFORMATION The Screening and Evaluating of Chitosan/β-cyclodextrin Nanoparticles for Effective Delivery Mitoxantrone Hydrochloride Yiwen Wang, Fei Qin, Mei Lu, Li Gao, and Xin Yao School of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing , China yaox@ucas.ac.cn (Xin Yao) Received August 8, 2016 Revised Manuscript Received December 31, 2016

2 Preparation and Characterization of CMβ-CD and GCS-CMβ-CD Polymers Preparation of CM m β-cd and GCS n -CM m β-cd Polymers. Briefly, 4.53 g chloroacetic acid was dissolved in 5 ml water, and then 8 ml NaOH solution with different concentration (3.75, 7.5, 10 M) was added with continuous stirring, β-cd (7.57 g) was then added to the solution. The mixture was stirred at 55 C for 12 h. During this process, another 2 ml different concentration of NaOH solution was added dropwise. After the reaction, the mixture was adjusted to ph 4.0 with HCl solution (1 : 1, v/v) and then extensively dialyzed against water (M w cutoff 1000). The final solution was precipitated with acetone, and the precipitate was dried under vacuum for 12 h at room temperature to obtain the final product, which with different number of carboxymethyl for each β-cd(cm m β-cd). GCS (10.6 mg) and three different CM m β-cds (24 mg) were separately dissolved in 10 ml water. 15 mg 1-(3-dimethylaminopropyl)-3- ethylcarbodiimide hydrochloride (EDC, Sigma) was added to CM m β-cd solutions as cross-linking agent with magnetic stirring at 300 rpm and stirred for 1 h at room temperature, then the prepared GCS solutions were added. The reaction mixture was continuously stirred for another 24 h, and then dialyzed by gradient against distilled water (M w cut-off 8000). The solution was freeze-dried to obtain cotton-like GCS n -CM m β-cd

3 powder with different amount of carboxymethyl and β-cd. Characterization of CM m β-cd and GCS n -CM m β-cd Polymers. The synthesized CM m β-cd was characterized by FTIR (VERTEX 70), matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS, Autoflex III), and high-performance liquid chromatography (HPLC, Agilent 1100) with electrospray ionization mass spectrometry (ESI-MS, LCQDECA XP, Thermo Finnigan). Fig. S1. FTIR spectra of (1) β-cd, (2) CM 2-8 β-cd, (3) CM 0-5 β-cd, and (4) CM 3-7 β-cd.

4 The FTIR spectrum of CM m β-cd is shown in Fig. S1. The strong peak at cm -1 could be ascribed to the stretching vibration of carbonyl group [1, 2], which is not observed in β-cd. The existence of this characteristic peak indicates that the carboxymethylation of β-cd was successful. The components of CMβ-CD were measured by MALDI-TOF MS (Fig. S2). For an example of CMβ-CD, according to the mass-to-charge ratios (m/z), up to seven carboxymethyl groups could be added, generating β-cd-ch 2 COOH to β-cd-(ch 2 COOH) 7. HPLC/ESIMS was used to determine the relative CMβ-CD components contents (Fig. S3b, middle). There are six main peaks (Fig. S3a upper), and the relative contents of β-cd-(ch 2 COOH) 2 to β-cd-(ch 2 COOH) 7 were calculated from Fig. S3b (middle) as 3.00, 34.50, 32.75, 10.64, 9.90, and 6.10%, respectively. β-cd-(ch 2 COOH) 3 through β-cd-(ch 2 COOH) 7 are the main components, then taking about the content of carboxymethyl, this production is named CM 3-7 β-cd. Considering the content of every CMβ- CD component, the calculated average molar molecular weight (M w ) of CMβ-CD is 1328 g/mol. Except for one carboxymethyl group of CMβ- CD that reacted with the amino groups of GCS, the other carboxylic acid groups around the β-cd cavity are free [3, 4]. Similarly, for CMβ-CD a the relative contents of β-cd-(ch 2 COOH) 2 to β-cd-(ch 2 COOH) 8 were calculated as 11.72, 15.60, 16.42, 14.21, 11.72, 16.14, and 14.21% and

5 named CM 2-8 β-cd, the calculated average molar molecular weight (M w ) of CM 2-8 β-cd is 1426 g/mol; for CMβ-CD c the relative contents of β- CD to β-cd-(ch 2 COOH) 5 were calculated as 13.11, 16.81, 21.56, 18.86, 13.34, and 16.13% and named CM 0-5 β-cd, the calculated average molar molecular weight (M w ) of CMβ-CD C is 1277 g/mol. Fig. S2. MALDI-TOF MS spectra of (a) CM 2-8 β-cd, (b) CM 3-7 β-cd, and (c) CM 0-5 β-cd.

6 Fig. S3. (a) Total ion current chromatogram of seven CMβ-CD components. (b) The selected ion chromatograms of CMβ-CD components. CMβ-CD (upper): (1) β-cd-(ch 2 COOH) 2,m/z: ; (2) β-cd-(ch 2 COOH) 3,m/z: ; (3) β-cd- (CH 2 COOH) 4, m/z: ; (4) β-cd-(ch 2 COOH) 5, m/z:

7 ; (5) β-cd-(ch 2 COOH) 6, m/z: ; (6) β-cd- (CH 2 COOH) 7, m/z: ; (7) β-cd-(ch 2 COOH) 8, m/z: ; CMβ-CDV (middle): (1) β-cd-ch 2 COOH, m/z: ; (2) β-cd-(ch 2 COOH) 2, m/z: ; (3) β-cd- (CH 2 COOH) 3, m/z: ; (4) β-cd-(ch 2 COOH) 4, m/z: ; (5) β-cd-(ch 2 COOH) 5, m/z: ; (6) β-cd- (CH 2 COOH) 6, m/z: ; (7) β-cd-(ch 2 COOH) 7, m/z: ; CMβ-CD (down): (1) β-cd, m/z: ; (2) β- CD-CH 2 COOH, m/z: ; (3) β-cd-(ch 2 COOH) 2, m/z: ; (4) β-cd-(ch 2 COOH) 3, m/z: ; (5) β-cd- (CH 2 COOH) 4, m/z: ; (6) β-cd-(ch 2 COOH) 5, m/z: The graft amount of CMβ-CD was determined by the concentrated sulfuric acid and phenol colorimetric method with UV-vis [5]. CMβ-CD can be dehydrated to its furfurol derivative after being treated with concentrated H 2 SO 4. The derivative can react with phenol, forming an orange acetal compound with maximum absorption at 489 nm. The GCS dehydrated derivative does not have an aldehyde group, so no orange compound can form after the addition of phenol. Therefore, the UV-vis method can not only recognize the existence of CMβ-CD but also determine the amount of CMβ-CD.

8 Here Q is used to express the degree of substitution as: Q C V M w m, where C is the concentration of CMβ-CD calculated from the calibration formula. V is the volume of the sample solution. M w is the molar average molecular weight of CMβ-CD. Table S1 also shows the degree of substitution of three GCS n -CM m β- CD. With the increasing amount of CMβ-CD, Q decreased from 510 to 282 μmol/g. Thus, it is easy to obtain high ratio of N GCS /N CMβ-CD polymer. Table S1. The synthesis conditions of GCS n -CM m β-cd and results polymer GCS 2.8 -CM 2-8 β-cd GCS 7.5 -CM 3-7 β-cd GCS CM 0-5 β-cd CMβ-CD, M w, g/mol CMβ-CDA 1426 CMβ-CDB 1328 CMβ-CDC 1277 GCS/CMβ-CD Q, μmol/g N GCS /N CMβ-CD 3 : : : The Graft Amount of CMβ-CD. Through three different CMβ-CD used during synthesis, three polymers with different amounts of CMβ-CD were prepared. The products are called GCS n -CM m β-cd, with n

9 indicating how many GCS units have one CMβ-CD (N GCS /N CMβ-CD ). Curves 1, 2, and 3 and 4 in Fig. S4 are the UV spectrum of the three polymers and GCS at the same concentration. As noted above, there is obvious absorption of the three polymers, while there is no absorption for GCS because it had no aldehyde group, further proving that CMβ-CD was cross-linked onto the GCS backbone and that the GCS-CMβ-CD was successfully synthesized. Fig. S4. UV-vis spectra of (1) GCS 2.8 -CM 2-8 β-cd, (2) GCS 7.5 -CM 3-7 β- CD, and (3) GCS CM 0-5 β-cd; (4) GCS. The inset showed the UV-vis calibration curve of (1) CM 2-8 β-cd, (2) CM 3-7 β-cd, and (3) CM 0-5 β-cd.

10 The inset of Fig. S4 is the calibration curve of different CM m β-cd, and the calibration formula is CM 2-8 β-cd: A = C CMβ-CD (mg/ml), CM 3-7 β-cd: A = C CMβ-CD (mg/ml), CM 0-5 β-cd: A = C CMβ-CD (mg/ml). The degree of substitution Q was obtained based on equation 1 and is show in Table S1. N GCS /N CMβ-CD can be calculated from the calibration formula. For the three polymers, they are 2.8, 7.5 and11.0. Overall, we obtained three different GCS n -CM m β- CDs: GCS 2.8 -CM 2-8 β-cd, GCS 7.5 -CM 3-7 β-cd, and GCS CM 0-5 β-cd. REFERENCES 1. M. Prabaharan and S. Gong, Carbohydr. Polym. 73(1), 117 (2008). 2. J. Ji, Sh. Hao, W. Liu, J. Zhang, D. Wu, and Y. Xu, Polym. Bull. 67(7), 1201 (2011). 3. J.-M. Yu, Y.-J. Li, L.-Y. Qiu, and Y. Jin, Eur. Polym. J. 44(3), 555 (2008). 4. H. Tan, Y. Xue, Q. Luan, and X. Yao, Anal. Methods 4(9), 2784 (2012). 5. M. DuBois, G. K. A. Gilles, J. K. Hamilton, and P. A. Rebers, Anal. Chem. 28, 350 (1956).

Yujuan Zhou, Kecheng Jie and Feihe Huang*

Yujuan Zhou, Kecheng Jie and Feihe Huang* Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 A redox-responsive selenium-containing pillar[5]arene-based macrocyclic amphiphile: synthesis,

More information

Amphiphilic diselenide-containing supramolecular polymers

Amphiphilic diselenide-containing supramolecular polymers Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2014 Amphiphilic diselenide-containing supramolecular polymers Xinxin Tan, Liulin Yang, Zehuan

More information

A Visible Near-Infrared Chemosensor for Mercury Ion

A Visible Near-Infrared Chemosensor for Mercury Ion A Visible Near-Infrared Chemosensor for Mercury Ion Mei Zhu, Mingjian Yuan, Xiaofeng Liu, Jialiang Xu, Jing Lv, Changshui Huang Huibiao Liu, Yuliang Li,* Shu Wang, Daoben Zhu Beijing National Laboratory

More information

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Au nanoparticles supported on magnetically separable Fe 2 O 3 - graphene

More information

Supporting Information

Supporting Information Supporting Information A Low-Temperature Solid-Phase Method to Synthesize Highly Fluorescent Carbon Nitride Dots with Tunable Emission Juan Zhou, Yong Yang, and Chun-yang Zhang* Single-Molecule Detection

More information

Electronic Supplementary Information For. Facile fabrication of glycopolymer-based iron oxide nanoparticles

Electronic Supplementary Information For. Facile fabrication of glycopolymer-based iron oxide nanoparticles Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information For Facile fabrication of glycopolymer-based iron

More information

Microwave-Assisted Synthesis of BSA-Protected Small Gold. Nanoclusters and Their Fluorescence-Enhanced Sensing of Silver(Ι) Ions

Microwave-Assisted Synthesis of BSA-Protected Small Gold. Nanoclusters and Their Fluorescence-Enhanced Sensing of Silver(Ι) Ions Microwave-Assisted Synthesis of BSA-Protected Small Gold Nanoclusters and Their Fluorescence-Enhanced Sensing of Silver(Ι) Ions (Supporting Information) Yuan Yue, a,b Tian-Ying Liu, a Hong-Wei Li,* a Zhongying

More information

Fluorescent Bilayer Nanocoils from an Asymmetric Perylene Diimide with Ultrasensitivity for Amine Vapors

Fluorescent Bilayer Nanocoils from an Asymmetric Perylene Diimide with Ultrasensitivity for Amine Vapors Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Fluorescent Bilayer Nanocoils from an Asymmetric Perylene Diimide with Ultrasensitivity for Amine

More information

Growth of silver nanocrystals on graphene by simultaneous reduction of graphene oxide and silver ions with a rapid and efficient one-step approach

Growth of silver nanocrystals on graphene by simultaneous reduction of graphene oxide and silver ions with a rapid and efficient one-step approach Growth of silver nanocrystals on graphene by simultaneous reduction of graphene oxide and silver ions with a rapid and efficient one-step approach Xiu-Zhi Tang, a Zongwei Cao, b Hao-Bin Zhang, a Jing Liu

More information

One-pot, green, rapid synthesis of flower-like gold. nanoparticles/reduced graphene oxide with. regenerated silk fibroin as efficient oxygen reduction

One-pot, green, rapid synthesis of flower-like gold. nanoparticles/reduced graphene oxide with. regenerated silk fibroin as efficient oxygen reduction Supporting Information One-pot, green, rapid synthesis of flower-like gold nanoparticles/reduced graphene oxide with regenerated silk fibroin as efficient oxygen reduction electrocatalysts Shengjie Xu,

More information

Supporting Information

Supporting Information Supporting Information An L-proline Functionalized Metallo-organic Triangle as Size-Selective Homogeneous Catalyst for Asymmertry Catalyzing Aldol Reactions Xiao Wu, Cheng He, Xiang Wu, Siyi Qu and Chunying

More information

Supporting Information. for. Advanced Materials, adma Wiley-VCH 2006

Supporting Information. for. Advanced Materials, adma Wiley-VCH 2006 Supporting Information for Advanced Materials, adma.200601546 Wiley-VCH 2006 69451 Weinheim, Germany Supporting Information Synthesis of Magnetic Microspheres with Immobilized Metal Ions for Enrichment

More information

Supplementary Materials. Synthesis of Reusable Silica Nanosphere-Supported Pt(IV) Complex for. Formation of Disulfide Bonds in Peptides

Supplementary Materials. Synthesis of Reusable Silica Nanosphere-Supported Pt(IV) Complex for. Formation of Disulfide Bonds in Peptides Supplementary Materials Synthesis of Reusable Silica Nanosphere-Supported Pt(IV) Complex for Formation of Disulfide Bonds in Peptides Xiaonan Hou, Xiaowei Zhao, Yamei Zhang, Aiying Han, Shuying Huo*, and

More information

Supplementary Information

Supplementary Information Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supplementary Information A Novel Single-Side Azobenzene-Grafted Anderson-Type Polyoxometalate

More information

Light-Controlled Switching of a Non- Photoresponsive Molecular Shuttle

Light-Controlled Switching of a Non- Photoresponsive Molecular Shuttle Supporting Information Light-Controlled Switching of a Non- Photoresponsive Molecular Shuttle Liu-Pan Yang, a,b Fei Jia, a Jie-Shun Cui, a Song-Bo Lu, a and Wei Jiang* a a Department of Chemistry, South

More information

Characterization of partially reduced graphene oxide as room

Characterization of partially reduced graphene oxide as room Supporting Information Characterization of partially reduced graphene oxide as room temperature sensor for H 2 Le-Sheng Zhang a, Wei D. Wang b, Xian-Qing Liang c, Wang-Sheng Chu d, Wei-Guo Song a *, Wei

More information

Permeable Silica Shell through Surface-Protected Etching

Permeable Silica Shell through Surface-Protected Etching Permeable Silica Shell through Surface-Protected Etching Qiao Zhang, Tierui Zhang, Jianping Ge, Yadong Yin* University of California, Department of Chemistry, Riverside, California 92521 Experimental Chemicals:

More information

Preparation and adsorption properties of cyclodextrin modified chitosan inclusion compound crosslinked by glutaraldehyde

Preparation and adsorption properties of cyclodextrin modified chitosan inclusion compound crosslinked by glutaraldehyde Preparation and adsorption properties of cyclodextrin modified chitosan inclusion compound crosslinked by glutaraldehyde Junfeng Wei a, Jinglan Liu, Jianjun Zheng, Zhongli Li, Ze Shi, Zhongxin Zhang and

More information

How does A Tiny Terminal Alkynyl End Group Drive Fully Hydrophilic. Homopolymers to Self-Assemble into Multicompartment Vesicles and

How does A Tiny Terminal Alkynyl End Group Drive Fully Hydrophilic. Homopolymers to Self-Assemble into Multicompartment Vesicles and Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 04 Electronic Supplementary Information for How does A Tiny Terminal Alkynyl End Group Drive

More information

Supporting information

Supporting information Electronic Supplementary Material (ESI) for Analyst. This journal is The Royal Society of Chemistry 2014 Supporting information Quantized double layer charging of Au 130 (SR) 50 Nanomolecules Vijay Reddy

More information

Supplementary Information

Supplementary Information Supplementary Information Fabrication of Novel Rattle-Type Magnetic Mesoporous carbon Microspheres for Removal of Microcystins Xinghua Zhang and Long Jiang* Beijing National Laboratory for Molecular Science

More information

Synthesis of renewable diesel with hydroxyacetone and 2-methyl-furan

Synthesis of renewable diesel with hydroxyacetone and 2-methyl-furan Supporting Information Synthesis of renewable diesel with hydroxyacetone and 2-methyl-furan Guangyi Li, a,b Ning Li, a Shanshan Li, a,b Aiqin Wang, a Yu Cong, a Xiaodong Wang a and Tao Zhang a * a State

More information

Supporting Information. Cells. Mian Wang, Yanglei Yuan, Hongmei Wang* and Zhaohai Qin*

Supporting Information. Cells. Mian Wang, Yanglei Yuan, Hongmei Wang* and Zhaohai Qin* Electronic Supplementary Material (ESI) for Analyst. This journal is The Royal Society of Chemistry 2015 Supporting Information Fluorescent and Colorimetric Probe Containing Oxime-Ether for Pd 2+ in Pure

More information

Supporting Information for

Supporting Information for Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017 Supporting Information for

More information

Revisiting the complexation between DNA and polyethylenimine when and where S S linked PEI is cleaved inside the cell

Revisiting the complexation between DNA and polyethylenimine when and where S S linked PEI is cleaved inside the cell Electronic Supplementary Material (ESI) for Journal of Materials Chemistry B. This journal is The Royal Society of Chemistry 214 Revisiting the complexation between DNA and polyethylenimine when and where

More information

Vitamin E-Labeled Polyethylenimine for in vitro and in vivo Gene Delivery

Vitamin E-Labeled Polyethylenimine for in vitro and in vivo Gene Delivery Supporting Information Vitamin E-Labeled Polyethylenimine for in vitro and in vivo Gene Delivery Jinxing Liu, Mengke Feng, Duanwei Liang, Jiali Yang, Xinjing Tang* State Key Laboratory of Natural and Biomimetic

More information

Electronic Supplementary Information (12 pages)

Electronic Supplementary Information (12 pages) Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 A C 2 -responsive pillar[5]arene: synthesis and self-assembly in water Kecheng Jie, Yong Yao, Xiaodong

More information

Supporting Information. Light-induced Wide Range Color Switching of Liquid Crystal. Blue Phase doped with Hydrogen-bonded Chiral Azobenzene.

Supporting Information. Light-induced Wide Range Color Switching of Liquid Crystal. Blue Phase doped with Hydrogen-bonded Chiral Azobenzene. Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Light-induced Wide Range Color Switching of Liquid Crystal Blue Phase

More information

Red Color CPL Emission of Chiral 1,2-DACH-based Polymers via. Chiral Transfer of the Conjugated Chain Backbone Structure

Red Color CPL Emission of Chiral 1,2-DACH-based Polymers via. Chiral Transfer of the Conjugated Chain Backbone Structure Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2015 Red Color CPL Emission of Chiral 1,2-DACH-based Polymers via Chiral Transfer of the Conjugated

More information

Responsive supramolecular polymer formed by orthogonal metal-coordination and cryptand-based host guest interaction

Responsive supramolecular polymer formed by orthogonal metal-coordination and cryptand-based host guest interaction Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Responsive supramolecular polymer formed by orthogonal metal-coordination and cryptand-based host

More information

Double Mesoporous Silica Shelled Spherical/Ellipsoidal Nanostructures: Synthesis and Hydrophilic/Hydrophobic Anticancer Drug Delivery

Double Mesoporous Silica Shelled Spherical/Ellipsoidal Nanostructures: Synthesis and Hydrophilic/Hydrophobic Anticancer Drug Delivery Supporting information for Supplementary Material (ESI) for Journal of Materials Chemistry Double Mesoporous Silica Shelled Spherical/Ellipsoidal Nanostructures: Synthesis and Hydrophilic/Hydrophobic Anticancer

More information

Electronic Supplementary Information (ESI) Tunable Phase and Visible-Light Photocatalytic Activity

Electronic Supplementary Information (ESI) Tunable Phase and Visible-Light Photocatalytic Activity Electronic Supplementary Information (ESI) Metallic-Zinc Assistant Synthesis of Ti 3+ Self-Doped TiO 2 with Tunable Phase and Visible-Light Photocatalytic Activity Zhaoke Zheng, a Baibiao Huang,* a Xiaodong

More information

Supplementary Information for Efficient catalytic conversion of fructose into hydroxymethylfurfural by a novel carbon based solid acid

Supplementary Information for Efficient catalytic conversion of fructose into hydroxymethylfurfural by a novel carbon based solid acid Supplementary Information for Efficient catalytic conversion of fructose into hydroxymethylfurfural by a novel carbon based solid acid Jianjian Wang, Wenjie Xu, Jiawen Ren*, Xiaohui Liu, Guanzhong Lu,

More information

2,5-bis(4-alkoxycarbonylphenyl)-1,4-diaryl-1,4-dihydropyrrolo[3,2- b]pyrrole (AAPP) AIEgens: tunable RIR and TICT characteristics

2,5-bis(4-alkoxycarbonylphenyl)-1,4-diaryl-1,4-dihydropyrrolo[3,2- b]pyrrole (AAPP) AIEgens: tunable RIR and TICT characteristics Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2017 2,5-bis(4-alkoxycarbonylphenyl)-1,4-diaryl-1,4-dihydropyrrolo[3,2- b]pyrrole (AAPP) AIEgens:

More information

Supplementary Information

Supplementary Information Supplementary Information C aryl -C alkyl bond formation from Cu(ClO 4 ) 2 -mediated oxidative cross coupling reaction between arenes and alkyllithium reagents through structurally well-defined Ar-Cu(III)

More information

enzymatic cascade system

enzymatic cascade system Electronic Supplementary Information Fe 3 O 4 -Au@mesoporous SiO 2 microsphere: an ideal artificial enzymatic cascade system Xiaolong He, a,c Longfei Tan, a Dong Chen,* b Xiaoli Wu, a,c Xiangling Ren,

More information

Visible-light Driven Plasmonic Photocatalyst Helical Chiral TiO 2 Nanofibers

Visible-light Driven Plasmonic Photocatalyst Helical Chiral TiO 2 Nanofibers Visible-light Driven Plasmonic Photocatalyst Ag/AgCl @ Helical Chiral TiO 2 Nanofibers Dawei Wang, Yi Li*, Gianluca Li Puma, Chao Wang, Peifang Wang, Wenlong Zhang, and Qing Wang Fig. S1. The reactor of

More information

Supplementary Figure 2. Full power on times. Histogram showing on times of bursts with 100 pm 1, 100 pm 2 and 1 nm Et 3 N at full laser power.

Supplementary Figure 2. Full power on times. Histogram showing on times of bursts with 100 pm 1, 100 pm 2 and 1 nm Et 3 N at full laser power. S1 Supplementary Figures Supplementary Figure 1. Time-correlated still frame images. Expanded still frames images from TIRFM video of CuAAC of 1 and 2 and corresponding intensity trajectory of a single

More information

Synthesis of homochiral zeolitic imidazolate frameworks via solvent-assisted linker exchange for enantioselective sensing and separation

Synthesis of homochiral zeolitic imidazolate frameworks via solvent-assisted linker exchange for enantioselective sensing and separation Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2018 Supporting Information Synthesis of homochiral zeolitic imidazolate frameworks via solvent-assisted

More information

Supporting Information. Oxidation Catalyst. Jingqi Guan, Chunmei Ding, Ruotian Chen, Baokun Huang, Xianwen Zhang, Fengtao

Supporting Information. Oxidation Catalyst. Jingqi Guan, Chunmei Ding, Ruotian Chen, Baokun Huang, Xianwen Zhang, Fengtao Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2017 Supporting Information CoO x Nanoparticle Anchored on Sulfonated-graphite as Efficient

More information

Electronic supplementary information

Electronic supplementary information Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Electronic supplementary information Heterogeneous nucleation and growth of highly crystalline

More information

Supporting Information

Supporting Information Supporting Information Potential-resolved Multicolor Electrochemiluminescence of N-(4-Aminobutyl)-N-ethylisoluminol/tetra(4-carboxyphenyl) porphyrin/tio 2 Nanoluminophores Jiangnan Shu, Zhili Han, Tianhua

More information

In situ formation of metal Cd x Zn 1-x S nanocrystals on graphene surface: A novel method to synthesis sulfide-graphene nanocomposites

In situ formation of metal Cd x Zn 1-x S nanocrystals on graphene surface: A novel method to synthesis sulfide-graphene nanocomposites Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 In situ formation of metal Cd x Zn 1-x S nanocrystals on graphene surface: A novel method to

More information

A rapid and highly selective colorimetric method for direct detection of tryptophan in proteins via DMSO acceleration

A rapid and highly selective colorimetric method for direct detection of tryptophan in proteins via DMSO acceleration A rapid and highly selective colorimetric method for direct detection of tryptophan in proteins via DMSO acceleration Yanyan Huang, Shaoxiang Xiong, Guoquan Liu, Rui Zhao Beijing National Laboratory for

More information

Supporting Information for. A Fluorescence Ratiometric Sensor for Trace Vapor Detection of. Hydrogen Peroxide

Supporting Information for. A Fluorescence Ratiometric Sensor for Trace Vapor Detection of. Hydrogen Peroxide Supporting Information for A Fluorescence Ratiometric Sensor for Trace Vapor Detection of Hydrogen Peroxide Miao Xu 1,, Ji-Min Han 1,, Chen Wang 1, Xiaomei Yang 1, Jian Pei 2 and Ling Zang 1, * 1 Department

More information

1,1,3,3-Tetramethylguanidine-Promoted Ring-Opening Polymerization of N-Butyl N-Carboxyanhydride Using Alcohol Initiators

1,1,3,3-Tetramethylguanidine-Promoted Ring-Opening Polymerization of N-Butyl N-Carboxyanhydride Using Alcohol Initiators Supporting Information 1,1,3,3-Tetramethylguanidine-Promoted Ring-Opening Polymerization of N-Butyl N-Carboxyanhydride Using Alcohol Initiators Brandon A. Chan, Sunting Xuan, Matthew Horton, and Donghui

More information

In Situ synthesis of architecture for Strong Light-Matter Interactions

In Situ synthesis of architecture for Strong Light-Matter Interactions In Situ synthesis of Ag@Cu2O-rGO architecture for Strong Light-Matter Interactions Shuang Guo 1, 2, Yaxin Wang 1, *, Fan Zhang 1, Renxian Gao 1, Maomao Liu 1, Lirong Dong 1, Yang Liu 2, Yongjun Zhang 2,

More information

Supporting Information

Supporting Information Supporting Information Materials Multiwalled carbon nanotubes (MWNTs, φ = 10-30 nm) were purchased from Nanotech Port Co. Ltd. (Shenzhen, China). Tetraethylorthosilicate (TEOS, >98 %), Triton X-100 and

More information

Supporting Information

Supporting Information Supporting Information Copyright Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, 2013 ph-controlled Reversible Formation of a Supramolecular Hyperbranched Polymer Showing Fluorescence Switching Bingran

More information

Electronic Supplementary Information

Electronic Supplementary Information Electronic Supplementary Information Novel [2]pseudorotaxanes constructed by self-assembly of bis-urea-functionalized pillar[5]arene and linear alkyl dicarboxylates Qunpeng Duan, Wei Xia, Xiaoyu Hu, Mengfei

More information

SUPPLEMENTARY INFORMATION

SUPPLEMENTARY INFORMATION SUPPLEMENTARY INRMATIN doi:10.1038/nature16185 Improved Synthesis of P-CDP H H H 7 + 1 TH/DM: 9/1 K 2 C 3 / 85 o C 2 days / under N 2 45% H R R 7 P-CDP 2 n A flame dried 20 ml scintillation vial equipped

More information

Well-organized Supramolecular Self-Assembly of a Novel Acene Diimide Derivatives

Well-organized Supramolecular Self-Assembly of a Novel Acene Diimide Derivatives Well-organized Supramolecular Self-Assembly of a Novel Acene Diimide Derivatives Sheshanath V. Bhosale, a, * Mohammad Al Kobaisi, a Rajesh S. Bhosale b and Sidhanath V. Bhosale b a Supramolecular Chemistry

More information

Supporting Information

Supporting Information Supporting Information Enhanced Photocatalytic Activity of Titanium Dioxide: Modification with Graphene Oxide and Reduced Graphene Oxide Xuandong Li,* Meirong Kang, Xijiang Han, Jingyu Wang, and Ping Xu

More information

1 Answer. 2 Answer A B C D

1 Answer. 2 Answer A B C D 216 W10-Exam #1 Page 1 of 9. I. (8 points) 1) Given below are infrared (IR) spectra of four compounds. The structures of compounds are given below. Assign each spectrum to its compound by putting the letter

More information

Supporting Information

Supporting Information Supporting Information UCST or LCST? Composition-Dependent Thermoresponsive Behavior of Poly(N-Acryloylglycinamide-co-Diacetone Acrylamide) Wenhui Sun, Zesheng An*, Peiyi Wu * Experimental Materials Glycinamide

More information

Supporting Information

Supporting Information Supporting Information of Appointed exploding microcapsules as drug carriers By Jing Zhang, Cao Li, Ya Wang, Ren-Xi Zhuo and Xian-Zheng Zhang * Materials Propargyl alcohol (PA-OH), dextran (M w ~20 k &

More information

Facile Synthesis and Catalytic Properties of CeO 2 with Tunable Morphologies from Thermal Transformation of Cerium Benzendicarboxylate Complexes

Facile Synthesis and Catalytic Properties of CeO 2 with Tunable Morphologies from Thermal Transformation of Cerium Benzendicarboxylate Complexes Electronic Supplementary Information Facile Synthesis and Catalytic Properties of CeO 2 with Tunable Morphologies from Thermal Transformation of Cerium Benzendicarboxylate Complexes Yuhua Zheng, Kai Liu,

More information

A new water-soluble pillar[5]arene: synthesis and application in the preparation of gold nanoparticles

A new water-soluble pillar[5]arene: synthesis and application in the preparation of gold nanoparticles A new water-soluble pillar[5]arene: synthesis and application in the preparation of gold nanoparticles Yong Yao, a Min Xue, a Xiaodong Chi, a Yingjie Ma, a Jiuming e, b Zeper Abliz, b and Feihe uang a,

More information

A novel smart polymer responsive to CO 2

A novel smart polymer responsive to CO 2 A novel smart polymer responsive to CO 2 Zanru Guo, a,b Yujun Feng,* a Yu Wang, a Jiyu Wang, a,b Yufeng Wu, a,b and Yongmin Zhang a,b a Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences,

More information

Supporting Information. Graphene Oxide-Palladium Modified Ag-AgBr: A Novel Visible-Light- Responsive Photocatalyst for the Suzuki Coupling Reaction**

Supporting Information. Graphene Oxide-Palladium Modified Ag-AgBr: A Novel Visible-Light- Responsive Photocatalyst for the Suzuki Coupling Reaction** Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Graphene Oxide-Palladium Modified Ag-AgBr: A Novel Visible-Light- Responsive

More information

Division of Fuel Cells, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese

Division of Fuel Cells, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Supporting information Tuned Depositing Ag clusters on ZrO 2 Nanocrystals from Silver Mirror

More information

Supporting Information. Morphological Transformation between Nanocoils and Nanoribbons

Supporting Information. Morphological Transformation between Nanocoils and Nanoribbons Supporting Information Morphological Transformation between Nanocoils and Nanoribbons via Defragmentation Structural Rearrangement or Fragmentationrecombination Mechanism Yibin Zhang, Yingxuan Zheng, Wei

More information

Efficient Magnesium Catalysts for the Copolymerization of Epoxides and CO 2 ; Using Water to Synthesize Polycarbonate Polyols

Efficient Magnesium Catalysts for the Copolymerization of Epoxides and CO 2 ; Using Water to Synthesize Polycarbonate Polyols Supporting Information for Efficient Magnesium Catalysts for the Copolymerization of Epoxides and CO 2 ; Using Water to Synthesize Polycarbonate Polyols Michael R. Kember, Charlotte K. Williams* Department

More information

Chemistry 216. First Exam (March 16, 2010) (1 hr 15 min, 80 points) Dr. Kyoung Moo Koh. Lab section. GSI name. Name Please print.

Chemistry 216. First Exam (March 16, 2010) (1 hr 15 min, 80 points) Dr. Kyoung Moo Koh. Lab section. GSI name. Name Please print. Chemistry 216 First Exam (March 16, 2010) (1 hr 15 min, 80 points) Dr. Kyoung Moo Koh Lab section GSI name Name Please print Signature Student ID# I 8 II 10 III 6 IV 12 V 12 VI 10 VII 14 VIII 8 Total 80

More information

Supplementary Material for

Supplementary Material for www.sciencemag.org/content/343/6173/873/suppl/dc1 Supplementary Material for Nonswellable Hydrogel Without Mechanical Hysteresis Hiroyuki Kamata, Yuki Akagi, Yuko Kayasuga-Kariya, Ung-il Chung, Takamasa

More information

Supporting information. One-step facile synthesis of novel β-amino alcohol functionalized

Supporting information. One-step facile synthesis of novel β-amino alcohol functionalized Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Supporting information One-step facile synthesis of novel β-amino alcohol functionalized carbon

More information

Spectrum-resolved Dual-color Electrochemiluminescence Immunoassay for Simultaneous Detection of Two Targets with Nanocrystals as Tags

Spectrum-resolved Dual-color Electrochemiluminescence Immunoassay for Simultaneous Detection of Two Targets with Nanocrystals as Tags Supporting Information Spectrum-resolved Dual-color Electrochemiluminescence Immunoassay for Simultaneous Detection of Two Targets with Nanocrystals as Tags Guizheng Zou, *, Xiao Tan, Xiaoyan Long, Yupeng

More information

Supporting Information. for

Supporting Information. for Supporting Information for From N-vinylpyrrolidone anions to modified paraffin-like oligomers via double alkylation with 1,8-dibromooctane: access to covalent networks and oligomeric amines for dye attachment

More information

Down-conversion monochrome light-emitting diodeswith the color determined

Down-conversion monochrome light-emitting diodeswith the color determined Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 2015 Electronic supplementary information (ESI) for Down-conversion monochrome

More information

Modify morphology of colloidal Ag 2 Se nanostructures by laser irradiation

Modify morphology of colloidal Ag 2 Se nanostructures by laser irradiation Supporting information for Modify morphology of colloidal Ag 2 Se nanostructures by laser irradiation Ling-Ling Zhao a, Zhi-Ming Gao a, Hui Liu a, Jing Yang a, Shi-Zhang Qiao a,b, Xi-Wen Du a a School

More information

Supporting Information. Detection and Occurrence of Chlorinated By-products of Bisphenol A, Nonylphenol and

Supporting Information. Detection and Occurrence of Chlorinated By-products of Bisphenol A, Nonylphenol and 1 2 3 Supporting Information Detection and Occurrence of Chlorinated By-products of Bisphenol A, Nonylphenol and Estrogens in Drinking Water of China: Comparison to the Parent Compounds 4 5 6 7 8 1 Laboratory

More information

Supporting Informations for. 1,8-Naphthyridine-based molecular clips for off-on fluorescence sensing

Supporting Informations for. 1,8-Naphthyridine-based molecular clips for off-on fluorescence sensing Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Supporting Informations for 1,8-aphthyridine-based molecular clips for off-on fluorescence

More information

5th International Conference on Measurement, Instrumentation and Automation (ICMIA 2016)

5th International Conference on Measurement, Instrumentation and Automation (ICMIA 2016) 5th International Conference on Measurement, Instrumentation and Automation (ICMIA 2016) Synthesis and characterization of amino-terminated polyethylene glycol functionalized mesoporous silica nanoparticles

More information

Supporting Information. Simple Bacterial Detection and High-Throughput Drug Screening. Based on Graphene-Enzyme Complex

Supporting Information. Simple Bacterial Detection and High-Throughput Drug Screening. Based on Graphene-Enzyme Complex Supporting Information Simple Bacterial Detection and High-Throughput Drug Screening Based on Graphene-Enzyme Complex Juan-Li, Ling-Jie Wu, Shan-Shan Guo, Hua-E Fu, Guo-Nan Chen* and Huang-Hao Yang* The

More information

Supplementary Material

Supplementary Material 10.1071/CH18138_AC CSIRO 2018 Australian Journal of Chemistry Supplementary Material Efficient hydrolytic breakage of β 1,4 glycosidic bond catalyzed by a difunctional magnetic nano catalyst Ren-Qiang

More information

Trapping Lithium into Hollow Silica Microspheres. with a Carbon Nanotube Core for Dendrite-Free

Trapping Lithium into Hollow Silica Microspheres. with a Carbon Nanotube Core for Dendrite-Free Supporting Information Trapping Lithium into Hollow Silica Microspheres with a Carbon Nanotube Core for Dendrite-Free Lithium Metal Anodes Tong-Tong Zuo,, Ya-Xia Yin,, Shu-Hua Wang, Peng-Fei Wang,, Xinan

More information

supramolecular hyperbranched polymers for controllable self-assembly

supramolecular hyperbranched polymers for controllable self-assembly Electronic upplementary Material (EI) for Polymer Chemistry. This journal is The Royal ociety of Chemistry 2017 upplementary Information AB x -type amphiphilic macromonomer-based supramolecular hyperbranched

More information

Supplementary Material for. Zinc Oxide-Black Phosphorus Composites for Ultrasensitive Nitrogen

Supplementary Material for. Zinc Oxide-Black Phosphorus Composites for Ultrasensitive Nitrogen Electronic Supplementary Material (ESI) for Nanoscale Horizons. This journal is The Royal Society of Chemistry 2018 Supplementary Material for Zinc Oxide-Black Phosphorus Composites for Ultrasensitive

More information

Supporting Information

Supporting Information Supporting Information Tuning Supramolecular Structure and Functions of Peptide bola-amphiphile by Solvent Evaporation-Dissolution Anhe Wang,, Lingyun Cui,, Sisir Debnath, Qianqian Dong, Xuehai Yan, Xi

More information

Rational design of light-directed dynamic spheres

Rational design of light-directed dynamic spheres Electronic Supplementary Information (ESI) Rational design of light-directed dynamic spheres Yumi Okui a and Mina Han* a,b a Department of Chemistry and Department of Electronic Chemistry Tokyo Institute

More information

Molecular weight of polymers. Molecular weight of polymers. Molecular weight of polymers. Molecular weight of polymers. H i

Molecular weight of polymers. Molecular weight of polymers. Molecular weight of polymers. Molecular weight of polymers. H i Gel Permeation Chromatography (GPC) : Size Exclusion Chromatography GPC : 1. Chromatogram (V R vs H) H i Detector response Baseline N i M i 130 135 140 145 150 155 160 165 Elution volume (V R ) (counts)

More information

Electronic Supplementary Information. Jiani Wang, Lei Zhang, Qiong Qi, Shunhua Li* and Yunbao Jiang

Electronic Supplementary Information. Jiani Wang, Lei Zhang, Qiong Qi, Shunhua Li* and Yunbao Jiang Electronic Supplementary Information Specific ratiometric fluorescent sensing of Hg 2+ via the formation of mercury(ii) barbiturate coordination polymers Jiani Wang, Lei Zhang, Qiong Qi, Shunhua Li* and

More information

Supporting Information for

Supporting Information for Supporting Information for Probing the Anticancer Action of Oridonin with Fluorescent Analogues: Visualizing Subcellular Localization to Mitochondria Shengtao Xu,#, Shanshan Luo,#, Hong Yao, Hao Cai, Xiaoming

More information

Ammonium-Bearing Dinuclear Copper(II) Complex: A Highly Selective and Sensitive Colorimetric Probe for Pyrophosphate

Ammonium-Bearing Dinuclear Copper(II) Complex: A Highly Selective and Sensitive Colorimetric Probe for Pyrophosphate Ammonium-Bearing Dinuclear Copper(II) Complex: A Highly Selective and Sensitive Colorimetric Probe for Pyrophosphate Wenxiang Yu, Jian Qiang, Jun Yin, Srinivasulu Kambam, Fang Wang, Yong Wang, and Xiaoqiang

More information

Supporting Information

Supporting Information Supporting Information A Rational Design of Highly Controlled Suzuki-Miyaura Catalyst-Transfer Polycondensation for Precision Synthesis of Polythiophenes and their Block Copolymers: Marriage of Palladacycle

More information

Structural effects on catalytic activity of carbon-supported magnetite. nanocomposites in heterogeneous Fenton-like reactions

Structural effects on catalytic activity of carbon-supported magnetite. nanocomposites in heterogeneous Fenton-like reactions Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2018 Supplementary Information Structural effects on catalytic activity of carbon-supported magnetite

More information

A Simple Fluorescein Derived Colorimetric and Fluorescent off - on Sensor For The Detection of Hypochlorite

A Simple Fluorescein Derived Colorimetric and Fluorescent off - on Sensor For The Detection of Hypochlorite Electronic Supplementary Material (ESI) for Analytical Methods. This journal is The Royal Society of Chemistry 2018 Supporting information A Simple Fluorescein Derived Colorimetric and Fluorescent off

More information

Please do not adjust margins. Flower stamen-like porous boron carbon nitride nanoscrolls for water cleaning

Please do not adjust margins. Flower stamen-like porous boron carbon nitride nanoscrolls for water cleaning Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry Please do 2017 not adjust margins Electronic Supplementary Information (ESI) Flower stamen-like porous

More information

Supplementary Information

Supplementary Information Supplementary Information riented Crystallization of Hydroxyapatite by the Biomimic Amelogenin anospheres from the Self-Assemblies of Amphiphilic Dendrons Sheng Yang a, Hai He b, Lei Wang a*, Xinru Jia

More information

Electronic Supplementary Information. Microwave-assisted, environmentally friendly, one-pot preparation. in electrocatalytic oxidation of methanol

Electronic Supplementary Information. Microwave-assisted, environmentally friendly, one-pot preparation. in electrocatalytic oxidation of methanol Electronic Supplementary Information Microwave-assisted, environmentally friendly, one-pot preparation of Pd nanoparticles/graphene nanocomposites and their application in electrocatalytic oxidation of

More information

Zinc-Blende CdS Nanocubes with Coordinated Facets for Photocatalytic Water Splitting

Zinc-Blende CdS Nanocubes with Coordinated Facets for Photocatalytic Water Splitting Supporting Information Zinc-Blende CdS Nanocubes with Coordinated Facets for Photocatalytic Water Splitting Yangyang Zhang, a Lili Han, a Changhong Wang, b Weihua Wang,* c Tao Ling, a Jing Yang, a Cunku

More information

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information Nanoparticle-to-vesicle and nanoparticle-to-toroid transitions of ph-sensitive

More information

Laser desorption/ionization on the layer of graphene nanoparticles coupled with mass spectrometry for characterization of polymer

Laser desorption/ionization on the layer of graphene nanoparticles coupled with mass spectrometry for characterization of polymer Laser desorption/ionization on the layer of graphene nanoparticles coupled with mass spectrometry for characterization of polymer Minghua Lu, a Yongquan Lai, a Guonan Chen, b and Zongwei Cai* a a Department

More information

Synthesis of two novel indolo[3,2-b]carbazole derivatives with aggregation-enhanced emission property

Synthesis of two novel indolo[3,2-b]carbazole derivatives with aggregation-enhanced emission property Supporting Information for: Synthesis of two novel indolo[3,2-b]carbazole derivatives with aggregation-enhanced emission property Wen-Bin Jia, Hao-Wei Wang, Long-Mei Yang, Hong-Bo Lu, Lin Kong, Yu-Peng

More information

Support Information. for. Topological structure influences on gel formation process and mechanical properties of L-lysine based Supramolecular gels

Support Information. for. Topological structure influences on gel formation process and mechanical properties of L-lysine based Supramolecular gels Electronic Supplementary Material (ESI) for RS Advances. This journal is The Royal Society of hemistry 2015 Support Information for Topological structure influences on gel formation process and mechanical

More information

Electronic Supplementary Information

Electronic Supplementary Information Electronic Supplementary Information Pillar[5]arene-Based Supramolecular Polypseudorotaxanes Constructed from Quadruple Hydrogen Bonding Xiao-Yu Hu, Pingyuan Zhang, Xuan Wu, Wei Xia, Tangxin Xiao, Juli

More information

Unraveling Surface Plasmon Decay in Core Shell Nanostructures towards Broadband Light-Driven Catalytic Organic Synthesis

Unraveling Surface Plasmon Decay in Core Shell Nanostructures towards Broadband Light-Driven Catalytic Organic Synthesis Supporting Information Unraveling Surface Plasmon Decay in Core Shell Nanostructures towards Broadband Light-Driven Catalytic Organic Synthesis Hao Huang,, Lei Zhang,, Zhiheng Lv, Ran Long, Chao Zhang,

More information

Supporting information A Porous Zr-cluster-based Cationic Metal-Organic Framework for Highly Efficient Cr 2 O 7

Supporting information A Porous Zr-cluster-based Cationic Metal-Organic Framework for Highly Efficient Cr 2 O 7 Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Supporting information A Porous Zr-cluster-based Cationic Metal-Organic Framework for Highly Efficient

More information

Supplementary Materials

Supplementary Materials Supplementary Materials First synthesis of a new fullerene oximes bis(9-[hydroxo]-1-[1'-hydroxymino-2'-oxo-2'-alkyl-ethyl])1,9-dihydro-[с60-ih][5,6]fullerenes via reaction of C60 with ketones and NaNO2

More information

A dual-model and on off fluorescent Al 3+ /Cu 2+ - chemosensor and the detection of F /Al 3+ with in situ prepared Al 3+ /Cu 2+ complex

A dual-model and on off fluorescent Al 3+ /Cu 2+ - chemosensor and the detection of F /Al 3+ with in situ prepared Al 3+ /Cu 2+ complex Supporting Information (SI) A dual-model and on off fluorescent Al 3+ /Cu 2+ - chemosensor and the detection of F /Al 3+ with in situ prepared Al 3+ /Cu 2+ complex Xiaoya Li, Mingming Yu, Faliu Yang, Xingjiang

More information