Supporting Information. M13 Virus-Incorporated Biotemplates on Electrode Surfaces to Nucleate Metal Nanostructures by Electrodeposition

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1 Supporting Informtion M13 Virus-Inorported iotempltes on Eletrode Surfes to Nulete Metl Nnostrutures y Eletrodeposition Shnmugm Mnivnnn [], Inhk Kng [],, Yeji Seo [], Hyo-Eon Jin [,], Seung-Wuk Lee [] nd Kyuwon Kim [], * [] Eletrohemistry Lortory for Sensors & Energy (ELSE Deprtment of hemistry, Inheon Ntionl University Inheon , Repuli of Kore. [] Deprtment of ioengineering, University of liforni, erkeley, liforni 94720, US [] Present ddress: ollege of Phrmy, jou University, Suwon 16499, Repuli of Kore *E-mil: kyuwon_kim@inu..kr S-1 P g e

2 Determintion of silite sol gel mtrix (SSG film thikness: The silite sol gel film thikness ws lulted y knowing the mount of the silite sol gel oted on the eletrode surfe nd using the density of silite sol gel. The density of the silite sol gel mtrix (SSG used in this study is nd g m 3. Using the following stndrd formule we hve mesured the thikness of the film. mount of polymer oted Thikness of polymer film (µm = 10 4 re of the eletrode density Frition of Pt/ modified eletrode: To prepre the working eletrode, 33 µl of 5% Nfion (Sigm-ldrih ws dded to the 1 ml of ethnol to prepre the diluted Nfion solution (0.165%. 5 mg of the Pt/ tlyst (20% Pt/, lf esr ws ultrsonilly dispersed in the ove prepred Nfion solution nd sonited for 30 min. Susequently, 1 µl of the suspension ws drop-sted on the working eletrode nd llowed to dry. The totl Pt loding ws 051 mg/m 2. Figure S1. SEM imges of ( ITO/SSG eletrode nd ( ITO/ eletrode. S-2 P g e

3 Figure S2. ( nd E SEM nd (,, D, F, G nd H EDX nlysis of (,, nd D ITO/SSG/M13Y3E/rGO/u eletrode nd (E, F, G nd H ITO/SSG/M13Y3E/rGO/Pt eletrode. Figure S3. SEM nd EDX line sn nlysis of ( to 2 ITO/(u Pt, ( to 2 ITO/SSG/(u Pt, ( to 2 ITO/SSG/M13Y3E/(u Pt, (D to D2 ITO/SSG/rGO/(u Pt nd (E to E2 ITO/SSG/M13Y3E/rGO/(u Pt eletrodes t different mgnifitions. S-3 P g e

4 Figure S4. SEM ( nd EDX nlysis of ITO/SSG/rGO/(u Pt eletrode. Figure S5. SEM nd EDX nlysis of ITO/ /rgo/(u Pt eletrode prepred t different preursor onentrtion s follows, (, 1 u 1.5 mm nd Pt 1.0 mm, (, 1 u 1.5 mm nd Pt 1.5 mm nd (, 1 u 1.5 mm nd Pt 2.0 mm. (2, 2 nd 2 Yellow line for snning EDX nd its results is given in grphs. S-4 P g e

5 Figure S6. (,, SEM nd (D EDX nlysis of ITO/SSG/M13 wild /rgo/(u Pt eletrode. (DYellow line for snning EDX nd its results is given in grphs. Figure S7. (,, SEM nd (D EDX nlysis of ITO/SSG/M13 4E /rgo/(u Pt eletrode. (DYellow line for snning EDX nd its results is given in grphs. S-5 P g e

6 O 1s Intensity (.u u Si Pt N Intensity (.u = -OH -OH -O -N inding Energy (ev N1s inding Energy (ev u4f7/2 u4f5/2 D Intensity (.u NH 2 Intensity (.u Pt4f7/2 Pt4f5/ inding Energy (ev inding Energy (ev Figure S8. XPS nlysis of ITO/ /rgo/(u Pt eletrode: ( Survey spetrum nd enlrged spetr for ( 1s, ( N 1s nd (D u Pt 4f regions of the modified eletrode. Mss tivity (/mg Pt d e E vs. g/gl (mv Figure S9. Vs of ( re ITO, ( ITO/SSG, ( ITO/, (d ITO/SSG/rGO nd (e ITO/ /rgo eletrodes in 0.1 M H 3 OH nd 0.1 M KOH t the sn rte of 50 mv/s. S-6 P g e

7 Ι (m E vs. g/gl (mv Mss tivity (/mg Pt E vs. g/gl (mv Figure S10. Vs reorded t ITO/ /rgo/(u Pt eletrode prepred t different preursor onentrtions ( (u 1.5 mm nd Pt 1.0 mm, (u 1.5 mm nd Pt 1.5 mm nd (u 1.5 mm nd Pt 2.0 mm in ( 0.5 M H 2 SO 4 t sn rte of 50 mv/s nd in ( 0.1 M H 3 OH nd 0.1 M KOH t sn rte of 50 mv/s. re (m /rgo/(u 64 Pt 36 /rgo/(u 58.9 Pt 41.1 ES /rgo/(u 57.7 Pt 42.3 re (m 2 /g Pt /rgo/(u 64 Pt 36 /rgo/(u 58.9 Pt 41.1 SSG/M13Y3E/rGO/(u 57.7 Pt 42.3 ES/g Pt Pek urrent (/mg Pt SSG/M13-Y3E/rGO/(u 64 Pt 36 SSG/M13-Y3E/rGO/(u 58.9 Pt 41.1 SSG/M13-Y3E/rGO/(u 57.7 Pt 42.3 Mss tivity Figure S11. ( ESs, ( ESs per Pt grm nd ( mss tivities of the /rgo/(u Pt tlyst t three different omposition. S-7 P g e

8 log j (/mg pt Mss tivity (/mg Pt E vs. g/gl (mv mv/s 30 mv/s ; K=0.203, R=0.998 ; K=0.162, R= log ν (mv/s Mss tivity (/mg Pt Ep (V mv/s 30 mv/s E vs. g/gl (mv D ; K=39, R=0.983 ; K=0.253, R= log ν (mv/s Figure S12. Vs of ( ITO/ /rgo/pt nd ( ITO/ /rgo/(u Pt eletrodes for 0.1 M H 3 OH nd 0.1 M KOH t different sn rtes (30, 50, 80, 120, 160, 200, 250, nd 300 mv/s from inner to outer. (, orresponding reltionship of log j vs. log (ν. D(, orresponding reltionship of pek potentil E p vs. log (ν. S-8 P g e

9 Ι (m Ι (m d e f E vs. g/gl (mv Figure S13. omprison of eletrohemil durility of ( ITO/ /rgo/pt, ( ITO/SSG/M13 wild /rgo/(u Pt nd ( ITO/ /rgo/(u Pt eletrodes in 0.5 M H 2 SO 4 t different yles ( initil, ( fter 250, ( fter 500, (d fter 750, (e fter 1000 nd (f fter 1250 yles t the sn rte of 50 mv/s. Potentil yles were snned from 0.6 to 1.1 V in 0.5 M H 2 SO 4 t the sn rte of 100 mv/s t room temperture. (D omprison of ES loss of modified eletrodes (,, ; f with the inrese of V yles d e f Ι (m E vs. g/gl (mv Normlized ES (% 0.9 d 0.6 e f E vs. g/gl (mv 100 D Numer of V yles S-9 P g e

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