Introduction to Quantum Mechanics: Syllabus

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2 Introduction to Quantum Mechanics: Syllabus... 2 Introduction and History... 3 Introduction to Quantum Mechanics... 3 Historical Background... 4 A little digression on relativity theory... 5 Introduction to Quantum Mechanics: Syllabus Lectures: M W F 12:30 1:20 PHY 313 Tutorials: Friday 1:30 2:20 RCH 306 Website: science.uwaterloo.ca/~nooijen Grading: 20% Assignments (Biweekly) 40% Midterm 40% Final Exam Book: Quantum Chemistry 2 nd Ed. By Donald A. McQuarrie ISBN: Problems and Solutions for McQuarrie s Quantum Chemistry 2 nd Ed. By Helen O. Leung, Mark D. Marshall ISBN: *Lecture notes, to be provided Some Fridays, we will do MathCad sessions and use computers to solve problems For Midterm and Exam: you may bring a summary sheet (must write yourself however) Website: enabled, see nooijen waterloo; teaching; chem356 Lectures will focus on concepts, this can be somewhat abstract Tutorials: You ask questions Solving Problems (sometimes extended problems): digest material, learn by practice Introduction to Quantum Mechanics: Syllabus 2

3 Introduction and History Introduction to Quantum Mechanics Quantum Mechanics: fundamental theory of chemistry, together with statistical mechanics (Chem 350) forms the microscopic theories of matter Very few fundamental postulates; Derive all the rest. Everything we derive (correctly) should be possible to be confirmed by experiment (Popper, a philosopher of science). This is what we call a fundamental theory. Today: Quantum Chemistry programs (eg. Gaussian) are very powerful tools to obtain - Molecular structure - Spectroscopic data, IR, NMR, CD, UV- vis, Resonance Raman - Thermochemical data Δ H, Δ G, Δ S Calculations work very well for gas phase chemistry, and reasonably well for the solid state. Liquids are the most time- consuming to calculate. Simulations depend partly on classical mechanics, not purely quantum mechanics. If one combines with molecular simulations Properties of liquids Δ G for complicated reactions Kinetics, reaction rates In quantum mechanics, the equations are simple, BUT hard to solve Huge effort to develop software that can solve equations efficiently To be expected: Simple equation H Ψ = E Ψ describes bewildering set of microscopic phenomena The concepts underlying Quantum Mechanics are strange, puzzling, even today So how do we deal with and study, simple equations, difficult solutions yet funny concepts? Introduction and History 3

4 study model problems: - easy solution - Insight into solution - Phenomenological rule Quantum Mechanics is old by now, started seriously in 1926 Current Frontiers / Applications include Quantum Computing (exploiting the weirdness) Nanotechnology : Make materials that start to use quantum mechanics Solid state devices (computer hardware, based on quantum mechanics) Lasers (quantum properties of light) Our focus will be Quantum Mechanics as the fundamental theory of chemistry. Historical Background (Classical) Physics around Newtonian mechanics, Hamilton/Lagrange formulations (elegant) - Maxwell equations, optics, electro- magnetism - Thermodynamics: o Heat, work, energy, entropy - Statistical Mechanics o Boltzmann/Gibbs Power of theoretical description: Derive equations from the fundamental theory. Predicted phenomena should be verified experimentally and conversely. Theory can in principle describe everything. Any (reproducible) experimental fact that does not fit the theory is a disaster, and theory would not be universally valid; would need a change. But in practice our theories (fairly simple, really) work very well (so far so good). In 1900, most people thought everything is understood, just dotting the I s, as far as theory goes Introduction and History 4

5 Things that did not fall into place a. Velocity of light is constant b. Gravitational mass = inertial mass special and general theory of relativity (Einstein) c. Black body radiation (Planck) d. Specific heat of solids (Einstein) e. Photoelectric effect (Einstein) f. Atomic spectra (Bohr)..understanding chemistry! Quantum mechanics! Other new phenomena a. X- rays (Roentgen) b. Radioactivity (Becquerel, Curie) c. Super- conductivity, Super- fluidity (Kamerling Onnes) d. Discovery of electron 1898 (Thompson), nucleus 1911 (Rutherford) Something MORE than just dotting the i s!! A little digression on relativity theory (A prime example of logical thought) Situation: Go back to kids time, you are biking to the soccer field and throw a ball in the air with both hands. (no hands to steer!) Do you: Throw the ball slightly forward (anticipating where you will be)? OR Throw the ball straight up as if you were not cycling as all? Introduction and History 5

6 OR Throw the ball backwards? What is the answer? Let s change the question. You are in a steady moving train. How do you throw? You are running. How do you throw? Answer: We should throw straight up. WHY? Because the ball already has the velocity in the forward direction, we should throw straight up. Let s Draw a Picture If you toss a bottle from a moving car, it will fly with huge velocity (of the car). Velocity depends on perspective.but this is not true for light! the velocity of light is vacuum is constant, independent of perspective. What does this mean? Before we can answer this, let us consider the ball a bit more. Introduction and History 6

7 Question: if the boy on the bicycle, and the on the ground, measure the time of flight, do they get equal answers? Yes. Questions & Answers regarding ball on train (slow) From the boy on bicycle/train perspective: the distance travelled by the ball, 2h the (average) velocity of the ball, v y time of flight, Δ t From the ground s perspective: distance travelled is longer "2h + Δt v x ", details are cumbersome the (average) velocity of the ball, time: the same Δ t v + v 2 2 y x Angle of throwing the ball: o Straight from biking perspective o Angled from ground perspective Now shine a flashlight to a (far away) mirror, on a moving train Introduction and History 7

8 Speed of light is c always ( l+δl) Δ t = c Observation: My own light (standing still) bounces back quicker than light on moving train. For the same reason: person on train says their light has returned before mine! *note: It would also take some time to observe the distant event. This can be taken into account and corrected for. The math involved is a bit involved, no need for our purpose. It is a consequence of the constancy of light that time is not absolute. Like distance which depends on perspective, time duration also depends on perspective. The detailed equations of special relativity are not so hard to derive. The consequences are hard to accept, and it is pretty hard to get an intuitive feel for it. Another consequence/example. c = signal velocity (eg. Velocity of mail) For regular mail: world traveler sends postcards from Honolulu, New York, Tokyo: they might all arrive at the same time Compare receiving 3 phone calls from the same person at the same time: One from Honolulu, one from New York, one from Tokyo Cannot happen because we cannot travel faster than the speed of light c. Introduction and History 8

Class 5: Equivalence Principle

Class 5: Equivalence Principle In this class we will discuss the conceptual foundations of General Relativity, in which gravity may be associated with the reference frames in which perceive events Class