44th INTERNATIONAL CHEMISTRY OLYMPIAD. UK Round One
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- Piers Farmer
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1 th IERIOL HEMIRY OLYMID UK R O UDE QUEIO BOOKLE * * * * * h t llw s hs ttpt ll qsts Wt y sws th spcl sw klt I y clclts, pls wt ly th sstl stps th sw klt lwys gv th pppt ts f sgfct fgs Y pv wth cpy f th c l D O wt ythg th ght h g f th sw klt f th qsts wll ct tl y wll t fl wth Hwv, y lgclly pplyg th sklls y hv lt s chst, y shl l t wk thgh th pls h fft wys t ppch th tsks v f y ct cplt ct pts f qst, y y stll f ssqt pts stghtfw
2 H H L B l y s c t ltv tc ss B O F g M l l K c V M F Z G G s B K R Y Z M c R h R g I I X s B * L f H W R s O I t g H l B t R F R c + s h t L * E G y D H E Y L + s t c h U p k B f s E F M L
3 hs qst s t slf chsty lf fs y cyclc lltps wth fft g szs I th sl stt, th st stl lltp f slf s f f I th gs phs, ll g szs f t hv tct I th gs phs, th fft g szs ql; th qt f th ql tw (g) (g) s gv lw: (g) (g) () Gv tht th stgth s kj l s kj l, clclt th thlpy chg f th fw ct Wh sslv gc slvt,, w ll tct ql th fllwg ppts y ss: g sz % y ss () ) lclt th t, ls, f t ql wh g f slf s sslv f slvt ) Gv th xpss f th ql cstt f th ct tw s wtt v ) lclt th vl f ths ql cstt I th sl phs, cystllss tw wll kw fs: thhc clc h thlpy chgs f cst f ths tw fs s fllws: Δ c H (, thhc, K) = kj l, Δ c H (, clc, K) = kj l (c) ) Dt th thlpy chg t K f th ct (s, thhc) (s, clc) ) Whch s th stl f t K? lf ls fs - g cp wth tg,, whch fs glcl cystls () I, tg slf ts ltt th g h tg ts f th s; tw f th slf ts f tw s, tw f f s Dw th stct f ssg th css-lks wth th g () lttv f f th stct s s th s gt f ts xcpt th s tw th ps f ppst slf ts Evy slf t hs f s ths stct; tg ts g hv th s Dw ths lttv stct f (t t ttpt t w th D stct) (f) If gs s pss v slv tl t yls l ply, ply(slf t), tht ccts lctcty s spcct t vy lw tpts h ply cts jst tw typs f : = Ech t hs th s; ch hs tw f Dw pt t f ths ply
4 hs qst s t ctllg y h H h cssts lgly f pts (plyppts), sch s kt Kt s sl tht t cts vy lg ppt f th slf-ctg c cyst h slf ctt f h y f y cplt lkl hylyss, fllw y xt t cvt ll th slf t slft hs y s y pcpttg t t s slft g spl f h s hylys th slf ctt cvt t slft qs chl s tl pcptt tks plc, tkg th ttl vl t O fltt f th xt t, g f BO s cv ft yg () ) lclt th pctg y ss f slf th spl f h h t sgfct fgs ss tht ll th slf s cvt t BO pcptt ) Wth sch sll qtty f pcptt, cct st tk f ts sllty wt: g t lclt th pctg y ss f slf t sgfct fgs tkg ths sllty t cct yst s q gst cs g l t f cvlt css-lks tw cs t tw fft pts ppt ch hs cvlt css-lks cll slf s, tw cyst ss tht hv c lk ths wy f cyst s hs slf s spsl f th jty f th stctl stgth f h () Hw wl y clssfy ths ct f tw cyst ss t f cyst s? () Dhyt () Hylyss () Oxt (v) Rct
5 Bth h-pg lts h vl c s chcls tht k ths slf s s cs h stgth Bth f ths ths c s slts f thglyclc c t k th slf s hglyclc c hglyclc c hs tw cc pts h pk vls f th ssct f ths tw pts pk = lg K K = [H + ][ ]/[H] ph = lg [H + ] (c) Dw th pt f f thglyclc c tht s pst qs slt t ) ph ) ph ) ph () lclt th pctg f - pctg f - pst t ph Y y ss tht ths th ly tw spcs pst t ths ph h chcl ct c t y th thglyclc c tks plc tw stps: tp : K---K + R-H K---R + K--H tp : K---R + R-H R---R + K--H h fllwg vts s: R-H: thglyclc c (ll fs, -, - tc) K---K: cyst s kt pt K--H: cyst s kt pt () Wt qt f th vll chcl ct s th tl slf clvg s slw, t s ft f tht tp s th t tg stp f th ct Uslly th thglyclc c s pst lg xcss th s p ffs t th h U ths ct cts th clvg f th slf s fllws sc- ktcs gv y th qt lw, t th cctt f thglyclt s lg xcss s s sstlly chg g th cs f th ct t cctt [RH] (h t cstt, k, s ph pt css wth csg ph) (f) O th gph, whch l st csps wth hw th cctt f K---K vs wth t?
6 I pctc t s t pssl t s th f K---K lkgs ctly Hwv, t g ppxt, th f lkgs s pptl t th tsl stss f st f h, ppty tht c sly s chclly hs llws th fllwg qt t v ltg th tsl stss, F, t th tl tsl stss, F, th t, t : sts f h w tt wth l thglyclt slt ff t ph f p f h t K (g) Us th gph lw t clclt vl f th t cstt, k, t K Gv th pppt ts (h) Olyp lt s ph slt ctg thglyclt s vll c ttls Wht s th ss f thglyclt ttl f Olyp lt?
7 hs qst s t chsty gl kwlg () t th fllwg lts th whch thy w scv t th lgstkw lt fst O () Rk th fllwg lcls th f th lg pt f t Rk th lwst-lg-pt "" th hghst "" H O H H OH HOH H OH H HO H H O (c) Wt th chcl fl tht st scs th fllwg () Fl s gl () Eps slts () Lghg gs () Wht th systtc s f th fllwg chcls? () ct () l () hypchlt () Wht s th cl chg wh zc x s ht? (f) Lk t th chcl stcts shw lw I th qsts tht fllw, ch cp shl ssg ly c ) Whch tlly ccg stlt wl y f y t? ) Whch ght y tk wth cp f t f y hv hch? ) Whch cp ght y t y t f y lk t swt? v) Whch cp ght y t y t f y lk t swt t w lw sg t? v) Whch cp wl y v t cp f t?
8 hs qst s t th sythss f tp-sllg g Lpt Wth l sls wth lls f ps, f y ys fz's chlstl-lwg g Lpt hs th st-sllg phctcl th wl h fst stps f lt-stg sythss f Lpt shw lw Gv th xs th st chctstc IR sttchg fqcs f th tts th sythss sttchs t y H s cl; sttchg fqcs t sgl s th th s t hyg t shw p th g lst Y t xpct t kw ths sttchg fqcs, t thgh cfl sg, y shl l t s th t hlp wk t th stcts f th kws t tht t ll th y-pcts shw th ct schs () Gv th stcts f th cps B t G, v th cs f th whl qst, cplt th tl f IR spts f cps t M spt / c ~ ()?? -? - =O sll g? H? Est H s ptt y stg ss t gv th ctv c clphl, I h R gp th stct s lkyl ch whch s chg thght th t sythss () Dw th stct f th I
9 h sythss cts s shw lw: (c) Gv th stcts f th cps J, K L I spt ch f th sythss, cts wth phyl t gv cp O hs y ptt s t gv th c clphl, cts wth zlhy t gv Q ; Q th hyts t gv cp cts wth flzlhy th psc f ctlyst t gv cp () Gv th stcts f phyl -flzlhy () ggst stcts f O,, cps Q I th fl stg f th sythss, M ght tgth t gv cp U whch hylyss qs c gvs th tgt, th g Lpt (f) ggst stct f cp U
10 hs qst s t th wl's sllst pw c I v f, th p sctfc jl t plsh tcl ttl "Elctclly v ctl t f f-whl lcl tl sfc" Esstlly, ths pp pt th sythss svts f th wl's sllst pw c th "-c" O cplt f th sythss, th spl ws lys sg MR ss spctty t spsgly, th gp t st th pcs tl f cst lyss! () ) Gv qt f th cplt cst f -c ) lclt th pctg y ss f c, hyg tg tht wl pct w th lyss t pf Gv y sws t tw cl plcs cl th sg f th lcl th hxyl thyl gps shw xplctly th stct v It s cs f ths tht th tc "whls" f th c ctlly g t gl, stg th l tht ttchs th t th st f th stct hs l c k, tt f wh sffct lctc gy s pv sg th tp f scg tllg cscp h c ts t whch th thyl gps ttch chl cts ch hs f fft gps ttch t t hs k wth stsk th stct v h c s p f f t ts spt t t xsts s ptcl ss -sppsl gs cll ts hsts stgsh tw th wth th lls "R" "" s shw th ght h "whls" ch t t ppst cts s shw (s vw s f stg xt t th c fcg th whl) h l wg cs t f th pp; th hsh gs t th pl
11 I th sythss f th c, f fft stss w f hs shw ct f lw, th gts th chsts tct sfc f cpp ts (s vw f v) () I y sw klt, ssg th ll "R" "" t ch t t th cs -F th xs pv h tp lft t ch c hs ly ssg (c) Whch f th cs -F ptcl ss? () Bf g pst th cpp sfc, tt s pssl t th tpl s lkg th tw hlvs f th c kg ths t cct, whch f th cs -F th s lcl wh f f th sfc? () By csg th cts f tt f th f t ts ch c, ssg tht ll f ts ctv sltsly, cplt th tl th sw klt, ctg whth ch c wll : sp th cpp sfc clckws sp th cpp sfc t-clckws stty th cpp sfc v fws v th cpp sfc
12 ckwlgts & Rfcs Rfcs f qsts Q pst f Eltl lf lt F t l, J h c,, -, Eltl lf Bt My,hcl Rvws,, -, Q h ktcs f slf ct h y thglyclt thglyclc c, Mlss Mszk t l, J c st h,, -, Ktc sts f h ct sg sgl f tchq Rll Wcktt J c st h,, -, Q Elctclly v ctl t f f-whl lcl tl sfc, Kc t l, t,,, ls th R plct "h Ml" ss, Jy p h UK hsty Olyp s sppt y IEO s lg gll fct f ptchcls, spclty chcls l pcts It cpss ssss ch wth j chcl cpy htg h pct twk sps fctg fclts cts thght th wl h chcls IEO pc hc lst vy spct f lf
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Discovery Guide. Beautiful, mysterious woman pursued by gunmen. Sounds like a spy story...
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What areas are affected? Bucklands. Beach. Eastern. Beach. Half Moon Bay. Mellons. Bay. Howick. Highland. Cockle Bay. Park. Shelly. Botany Downs.
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