Water Quality Bacteria Cool, 4 C 30 Hours

Transcription

1 Water Quality Parameter Method Container Preserva0on Holding Time EPA B EPA SM 2320 B EPA SM ml, P or G 250 ml, P or G 250 ml, P or G, H2SO4 to ph<2 SM 9222 G. SM 9222 D. SM 9223 B. EPA SM 5210 EPA ml, P, sterile 100 ml, P, sterile 100 ml, P, sterile 1000 ml, P or G None Required 6 Hours 6 Hours 30 Hours 48 Hours EPA SM 4500 Br- EPA SM 3500 EPA Carbon, Total Organic (TOC) EPA x 40 ml, G Cool, H2SO4 to ph <2 Chemical Oxygen Demand (COD) EPA ml, P or G, H2SO4 to ph<2 Acidity Alkalinity Ammonia Bacteria Coliform, E. Coli Coliform, Fecal Coliform, Total Biochemical Oxygen Demand (BOD) Bromate Bromide Calcium

2 Chloride Chlorine, Residual EPA SM Cl D SM Cl H EPA 330 None Required None Required Analyze Immediately

3 Color Conductance Cyanide Amenable Total Weak Acid Dissociable (WAD) Flouride Formaldehyde Hardness Magnesium Nitrogen Ammonia (NH3) Nitrate (NO3) Nitrite (NO2) Nitrate + Nitrite Total Kjeldahl (TKN) Odor Oil & Grease Petroleum Hydrocarbons ph EPA SM 2120 EPA SM 2510B EPA EPA EPA EPA 300.0/SM 4110 SM F C NIOSH Hour NaOH to ph >12, NaOH to ph >12, NaOH to ph >12, 250 ml NA SM 2340 B Calc. EPA / SM 3120 SM 3500 EPA 350.1/SM NH3 EPA or EPA EPA or EPA EPA or EPA EPA EPA 140.1/SM 2150 H2SO4 to ph <2 H2SO4 to ph <2 H2SO4 to ph <2 48 Hours 48 Hours ASAP EPA 1664 EPA 413.1/SM 5520 see Organics 1000 ml, Glass HCl to ph <2, Cool H2SO4 to ph <2 EPA 150.1/SM H+ Analyze Immediately

4 Phenols Phosphorus Ortho Total Solids SeSeable Total Dissolved (TDS) Total Solids Total Suspended (TSS) Vola0le Specific Gravity Sulfur Sulfate Sulfide Sulfite Surfactant (Foaming Agents) Total Petroleum Hydrocarbons (TPH) Turbidity EPA 420.4/SM ml, Amber G H2SO4 to ph <2, EPA EPA H2SO4 to ph <2, 48 Hours (unpres.) EPA 160.5/SM 2540 F EPA 160.1/SM 2540 C EPA 160.3/SM 2540 B EPA 160.2/SM 2540 D EPA 160.4/SM 2540 E ASTM D Hydrometer 1000 ml, P or G 250 ml, P or G 250 ml, P or G None 48 Hours N/A EPA 375.4/SM SO4 EPA 300.0/SM 4110 EPA 376.2/SM S EPA 377.1/SM SO3 SM 5540 C 250 ml, P or G ZnAc,, NaOH ph>9 ASAP 48 Hours EPA EPA 1664 EPA 8015 (GRO) EPA 8015 (DRO) EPA ml, G (2) 40 ml VOA vials (2) 40 ml VOA vials HCl to ph <2, HCl to ph <2, HCl to ph <2, HCl to ph <2, 48 Hours

5 Radiochemistry Parameter Method Container Preserva0on Holding Time Gross Alpha E B E B E905.0 Mod. 1/2 Gallon P or G 1/2 Gallon P or G 1000 ml P or G RMO ml P or G E ml P or G Radium 226 SM 7500 Ra B 1/2 Gallon P or G Radium 228 SM 7500 Ra D 1/2 Gallon P or G Radon 222 ASTM D (2) 40 ml VOA vials 4 Days Thorium E ml P or G Tri0um E ml P or G Unpreserved Uranium E ml P or G Gross Beta Lead Polonium Radioac0ve Stron0um

6 Organics Parameter Method EXTRACTIONS Separatory Funnel Liquid - Liquid Method 3510C (SW- 846) Con0nuous Liquid - Liquid Method 3520C (SW- 846) Solid Phase Extrac0on Method 3535 (SW- 846) Soxhlet Extrac0on Method 3540C (SW- 846) Ultrasonic Extrac0on Method 3550B (SW- 846) Supercri0cal Fluid Extrac0on of TPH Method 3560 (SW- 846) Supercri0cal Fluid Extrac0on of PAH Method 3561 (SW- 846) Waste Dilu0on Method 3580A (SW- 846) Waste Dilu0on for Vola0le Organics Method 3585 (SW- 846) VOC's in Solids Using Headspace Method 5021 (SW- 846) Purge- and- Trap for Aqueous Samples Method 5030B (SW- 846) Purge- and- Trap for Soil and Waste Method 5035 (SW- 846) BTEX / BTEX- MTBE* Container Preserva0on Holding Time 1000 ml 1000 ml 1000 ml 2 x 40 ml, HCl to ph <2, HCl to ph <2, HCl to ph <2, HCl to ph <2, HCl to ph <2, HCl to ph <2, HCl to ph <2, HCl to ph <2, HCl to ph <2, HCl to ph <2 EPA SW B/water 2-40 ml VOA, G /soil EPA SW / water 2-40 ml VOA, G /soil EPA 602/water 2-40 ml VOA, G EPA 524.2/water 2-40 ml VOA, G Total Petroleum Hydrocarbons (TPH) EPA SW 8015M/water (2) 40 ml VOA /soil EPA 418.1/water 1000 ml Amber G /soil TX Method 1005/water (2) 40 ml VOA w/ HCl /soil Oil and Grease EPA water 1000 ml Amber G EPA 1664A water 1000 ml Amber G

7 Vola0le Organics (VOCs)* EPA SW 8260B/water /soil EPA EPA 624 Semivola0le Organics (SOCs) EPA SW 8270C/water** /soil EPA 625/water** EPA 525.2*** Polynuclear Aroma0c Hydrocarbons** EPA SW 8270C/water** /soil EPA 625/water** Base/Neutral/Acid Extractables** EPA SW 8270C/water** /soil EPA 625/water** Organohalide Pes0cides and PCBs** EPA ml VOA, G 2-40 ml VOA, G 2-40 ml VOA, G 2-40 ml VOA, G Organochlorine Pes0cides** 1000 ml, Amber G 2-40 ml VOA, G 4 C, monochlor0- ace,c EPA 608 / water EPA SW 8081A / water EPA SW 8081A / soil Polychlorinated Biphenyles (PCBs)** EPA SW 8082/water EPA SW 8082/soil Herbicides* EPA 8151 A/water EPA 8151 A/soil EPA 615/water EPA 515.1/water Phenols EPA SW 8270C/water** /soil EPA 625/water** EPA 604/water EPA 8041/water EPA 8041/soil Phthalate Esters EPA SW 8270C/water /soil EPA 625/water Carbamates** EPA 531.1/water, HCl to ph <2, HCl to ph <2, HCl to ph <2, HCl to ph <2

8 Diquat** EPA (2) 1000 ml, P or PVC EDB and DBCP** EPA ml VOA, G/teflon, add Sodium Th. Endothall** EPA ml, G E ml VOA, Amber G Haloace0c Acids (HAAs) EPA (3) 60 ml VOA, AG 4 C, Dark, NH4Cl Trihalomethanes (THMs)* EPA EPA Glyphosate** (2) 40 ml VOA, G/tefl., HCl to ph <2 * Add ascorbic acid to chlorinated water samples ** Add sodium thiosulfate to chlorinated water samples ***Add sodium sulfite to chlorinated water samples before adding acid

9 Metals Parameter DIGESTIONS Water Diges0on Water Diges0on Water Diges0on Oil Diges0on Soil/Sludge Diges0on Dissolved Metals Total Metals* Total Recoverable Metals* Chromium VI Ferrous Iron Mercury* *Requires Diges0on Method Container Preserva0on Holding Time EPA EPA SW 3005 SM 3030F EPA SW 3010 EPA SW 3020 EPA SW 3031 EPA SW 3050 EPA ml 100 g, P 100 g, P EPA EPA /water 6010B/soil EPA 200.8/water 6020B/soil EPA /water 6010B/soil EPA 200.8/water 6020B/soil SM Cr D/water SM Cr D/soil* EPA 200.7/water 4 oz, G 4 oz, G 4 oz, G 4 oz, G 4 oz, G EPA 245.1/water EPA 7471/soil 4 oz, G, N/A, Filter (0.45 micron), then,,,, Filter (0.45 micron), then per total or dissolved 24 Hours ASAP

10 Wastes Parameter Method Toxicity Characteris0c Leaching Procedure (TCLP) Prior to Analysis Vola0le Organics (VOCs) SW 1311 Extractable Organics SW 1311 Metals (other than Mercury) SW 1311 Mercury SW 1311 * Specific Reac0vity, Corrosivity, Ignitability (RCI) Cyanide, Reac0ve, water SW Sec,on Cyanide, Reac0ve, non- aqueous SW Sec,on Sulfide, Reac0ve, water SW Sec,on Sulfide, Reac0ve, non- aqueous SW Sec,on Corrosivity, PH SW 9045 C/ 9040 B Ignitability, flashpoint ASTM D Semi- vola0les (see Organics) Vola0les (see Organics) Pes0cides (see Organics) Herbicides (see Organics) Metals (see Metals) Mercury (see Metals) Container Preserva0on Holding Time Method/Matrix Spec.* Method/Matrix Spec.* Method/Matrix Spec.* Method/Matrix Spec.* NaOH to ph>12 None Zinc Acetate, NaOH ph>9 None None None NA NA ASAP NA 250 ml P or G 50g P or G 250 ml P or G 50g P or G 25 ml or 50 g 100 ml P or G

11 Soil and Overburden Parameter SAMPLE PREPARATION Acid Diges0on Acid Diges0on AB- DTPA Extract Coarse Fragments Composi0ng Grinding Coarse, 10 Mesh, Hammer Mill Fine, 60 Mesh, Pulverizer Hot Water Extract Mixing & Splifng Saturated Paste Extract 1:1 Paste AB- DTPA Metals Selenium Acid Poten0al (AP) Acid- Base Accoun0ng Method Container EPA SW 3050 Perchloric, HF & HCl 1 gallon resealable, P USDA No. 18 USDA No. 18 / ASA Mono 9 Calcula,on EPA- 600/ Acid- Base Poten0al Calcula,on Alkalinity EPA SM 2320 B EPA SM 4500 Ammonia Preserva0on Holding Time

12 Available Ca0ons Calcium Magnesium Potassium Sodium Base Satura0on Percentage EPA 6010B Calcula,on Bicarbonate ASA Bulk Density EPA- 600/ , Method 230 ASA USDA No. 60 (19) EPA SM Cl D EPA M3060A Exchangeable Acidity EPA SM 4500 CN- I Exchangeable Sodium Percentage USDA No. 60 EPA Calcium Carbonate Carbonate Carbon Total Total Organic Ca0on Exchange Capacity (CEC) Chloride Chromium, Hexavalent Cyanide Total WAD Electrical Conduc0vity Flouride

13 Lime Requirement (SMP Buffer) EPA- 600/ Moisture Percent Net Acid Genera0ng Poten0al Titra,on Neutraliza0on Poten0al (Calcium Carbonates) NDEP Profile I EPA 350.1/SM NH3 EPA or EPA EPA or EPA EPA or EPA EPA Calcula,on USDA No. 60 Hydrometer EPA EPA 365.1, EPA 6010B Loss on Igni0on NDEP Profile II Nitrogen Ammonia (NH3) Nitrate (NO3) Nitrite (NO2) Nitrate + Nitrite Total Kjeldahl (TKN) Organic Nitrogen Par0cle Density ph Par0cle Size Analysis Phosphorus Olsen Total Potassium

14 Satura0on Percent EPA 6010B EPA 6010B EPA 6010B EPA 375.4/SM SO4 EPA 300.0/SM 4110 EPA- 600/ EPA- 600/ EPA- 600/ EPA- 600/ Total Organic Carbon Total Organic MaSer Very Fine Sands Sieve Analysis Sodium Available Extractable Soluable Sodium Adsorp0on Ra0o Sulfate Sulfur Frac0ona0on Sulfur Forms Sulfur, Organic Sulfur, Pyri0c Sulfur, Sulfate Sulfur, Total Texture + USDA Class ID