Table of contents. Ling-Yan Chen, a,b Stéphane Guillarme, a and Christine Saluzzo a *
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1 Supplementary Material Dianhydrohexitols: new tools for organocatalysis. Application in enantioselective Friedel-Crafts alkylation of indoles with nitroalkenes Ling-Yan Chen, a,b Stéphane Guillarme, a and Christine Saluzzo a * a IMMM, MS, UMR CRS 6283, Faculté des Sciences, Université du Maine, Av.. Messiaen, Le Mans Cedex 09, France b College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, , China Christine.saluzzo@univ-lemans.fr Table of contents MR data 1 MR spectrum of compound 7: S3 13 C MR spectrum of compound 7: S4 1 MR spectrum of compound 8: S5 13 C MR spectrum of compound 8: S6 1 MR spectrum of compound 9: S7 13 C MR spectrum of compound 9: S8 1 MR spectrum of compound 10: S9 13 C MR spectrum of compound 10: S10 1 MR spectrum of compound 6: S11 13 C MR spectrum of compound 6: S12 1 MR spectrum of compound 1: S13 13 C MR spectrum of compound 1: S14 1 MR spectrum of compound 2: S14 13 C MR spectrum of compound 2: S15 1 MR spectrum of compound 3: S16 13 C MR spectrum of compound 3: S17 1 MR spectrum of compound 4: S18 13 C MR spectrum of compound 4: S19 1 MR spectrum of compound 5: S20 13 C MR spectrum of compound 5: S21 1 MR spectrum of compound 14a: S22 13 C MR spectrum of compound 14a: S23 Page S1
2 1 MR spectrum of compound 14b: S24 13 C MR spectrum of compound 14b: S25 1 MR spectrum of compound 14c: S26 13 C MR spectrum of compound 14c: S27 1 MR spectrum of compound 14d: S28 13 C MR spectrum of compound 14d: S29 1 MR spectrum of compound 14e: S30 13 C MR spectrum of compound 14e: S31 1 MR spectrum of compound 14f: S32 13 C MR spectrum of compound 14f: S33 1 MR spectrum of compound 14g: S34 13 C MR spectrum of compound 14g: S35 1 MR spectrum of compound 14h: S36 13 C MR spectrum of compound 14h: S37 Catalytic enantioselective Friedel-Crafts alkylation in the presence of thiourea catalyst 2: PLC chromatograms Formation of compound 14a: S38 Formation of compound 14a: S39 Formation of compound 14b: S39 Formation of compound 14b: S40 Formation of compound 14c: S40 Formation of compound 14c: S41 Formation of compound 14d: S41 Formation of compound 14d: S42 Formation of compound 14e: S43 Formation of compound 14f: S44 Formation of compound 14g: S45 Formation of compound 14g: S46 Formation of compound 14h: S46 Formation of compound 14h: S47 Page S2
3 MR Spectra Ts Ts Page S3
4 Ts Ts Page S4
5 3 3 Page S5
6 3 3 Page S6
7 2 2 Page S7
8 2 2 Page S8
9 3 3 Page S9
10 3 3 Page S10
11 F 3 C S CF 3 F 3 C S CF 3 Page S11
12 F 3 C S CF 3 F 3 C S CF 3 Page S12
13 2 S CF 3 CF 3 Page S13
14 2 S CF 3 CF 3 F 3 C S CF 3 F 3 C S C F 3 Page S14
15 F 3 C S CF 3 F 3 C S C F 3 Page S15
16 S S Page S16
17 S S Page S17
18 S S Page S18
19 S S Page S19
20 S CF 3 S 2 CF 3 Page S20
21 S CF 3 S 2 CF 3 Page S21
22 Page S22
23 Page S23
24 Page S24
25 Page S25
26 Page S26
27 Page S27
28 Page S28
29 Page S29
30 Page S30
31 Page S31
32 Page S32
33 Page S33
34 Page S34
35 Page S35
36 Page S36
37 Page S37
38 PLC Data Ph * 14a 2 Page S38
39 Ph * 14a 2 Me * 2 14b Page S39
40 Me * 2 14b Br * 2 14c Page S40
41 Br * 2 14c * 2 Cl 14d Page S41
42 * 2 Cl 14d Page S42
43 * 2 F 14e * 2 F 14e Page S43
44 * 2 Me 14f * 2 Me 14f Page S44
45 * 2 Me 14g Page S45
46 * 2 Me 14g * Cl 14h 2 Page S46
47 * Cl 14h 2 Page S47
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