mail: (M. Danko), (J. Mosnacek) Lodz, Poland; (M.
|
|
- Stanley Booker
- 5 years ago
- Views:
Transcription
1 S1 Supporting information Functional polyesters with pendant double bonds prepared by coordination-insertion and cationic ring-opening copolymerizations of ε-caprolactone with renewable Tulipalin A Martin Danko 1,, Malgorzata Basko 2,, *, Slávka Ďurkáčová 1, Andrzej Duda 2, and Jaroslav Mosnáček 1, * 1 Polymer Institute, Slovak Academy of Sciences, Dúbravská cesta 9, Bratislava, Slovakia; e- mail: martin.danko@savba.sk (M. Danko), jaroslav.mosnacek@savba.sk (J. Mosnacek) 2 Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, Lodz, Poland; baskomeg@cbmm.lodz.pl (M. Basko) equally contributed authors; deceased April 2016; * corresponding authors Table of content: Materials Analytical methods Figure SI1: 1 H NMR spectra (CDCl 3 ) of reaction mixture of MBL/Al(OiPr) 3 after 3 hours of reaction at 20 C. Additional description of NMR spectra. Figure SI2: A) 1 H and B) 13 C NMR spectra (CDCl 3 ) of P(MBL-co-CL) precipitated polymer with 7 mol% MBL content (Table 1 9A). Figure SI3: FTIR spectra of of P(MBL-co-CL) with 25 mol% MBL content prepared by ROP using MBL/CL/Al(OiPr) 3 with molar ratio 9/0.9/0.002 after 48 hours at 0 C and after precipitation to MeOH (Table 1 14A). Figure SI4: The GPC traces of purified products obtained in cationic ROP of CL and MBL in the presence of isopropanol as initiator and TfA as catalyst conducted in two stages. (Table 2, Entry 2C). Copolymer B (M n (GPC) = 7.73 kg mol -1 ) obtained by chain extension from precursor A (M n (GPC) = 3.28 kg mol -1 ).
2 S2 Figure SI5: 1 H NMR spectra of purified product derived from the copolymerization of CL and MBL in the presence of isopropanol as initiator and DPP as catalyst, in CDCl 3 (top) and DMSO-d 6 (bottom), (F BML = 0.11). The asterisk indicates region characteristic for -CH 2 - groups formed by vinyl addition. Figure SI6: 1 H NMR spectra of purified product derived from the copolymerization of CL and MBL in the presence of ethylene glycol as initiator and DPP as catalyst. Figure SI7: 1 H NMR spectra of purified product derived from the copolymerization of CL and MBL in the presence of di(trimetylol)propane as initiator and DPP as catalyst. Figure SI8: MALDI-TOF spectrum of P(MBL-co-CL) copolymer prepared with multihydroxyl initiators and DPP as catalyst. Figure SI9: GPC traces and UV-Vis spectra of purified product derivate from AIBN/thermos-initiated thiolene post-functionalization of P(MBL-co-CL) with 3 mol% of tio-linkers with fluorescent benzotioxanthene fluorophore. Figure SI10: A) 1 H NMR spectra of purified product derived from the photo-initiated tiolene postfunctionalization of P(MBL-co-CL) copolyester with 3 mol% of functional methylene double bonds an B) enlarged chemical shift region with comparison with original unmodified P(MBL-co-CL) copolyester.
3 S3 Materials. During the first distillation, the metallic initiator aluminum tris(isopropoxide) (Al(O i Pr) 3, 98 %, Sigma- Aldrich) was distilled under reduced pressure into a small flask, and during the second distillation it was distilled into small glass bubbles and sealed in a vacuum. A trimer of Al(O i Pr) 3 (A 3 ) was obtained as described elsewhere. 41 Tin octoate (Sn(Oct) 2, 98 %, Sigma-Aldrich) was twice distilled under reduced pressure and was stored in a Schlenk flask in a vacuum. ε-caprolactone (CL, 98 %, Sigma- Aldrich) and α-methylene-γ-butyrolactone (MBL, 98 %, TCI Europe) were stirred over CaH 2 and were transferred to breakseals by distillation under reduced pressure and were sealed in a vacuum. Trifluoromethanesulfonic acid (TfA, triflic acid; Sigma-Aldrich) was purified by distillation. Diphenyl phosphate (DPP) (Sigma-Aldrich) was used as received. Propanol and butanol (98 %, anhydrous, Sigma-Aldrich) were dried with sodium wires (a few molar percent), were distilled and were stored in an ampoule in a vacuum. Ethylene glycol (99.8 %, Sigma-Aldrich), di(trimethylolpropane) (DTMP, 97 %, Sigma-Aldrich) and N-acetyl cysteine ( 99 %, Sigma-Aldrich) were used as received. 2-(2- Mercaptoethyl)thioxantheno[2,1,9-dej]-isoquinoline-1,3-dione (BTXI-SH) was synthetized from benzothioxanthone 3,4-dicarboxylic anhydride (BTXA) and cysteamine hydrochloride (98 %, Sigma- Aldrich) in dimethylformamide (DMF) as a solvent. Free amine was reacted first with 1 M NaOH in DMF solution followed by addition of BTXA. Evolved water that formed during condensation was distilled off by refluxing with DMF over 16 hours. After evaporation of the remaining DMF, the crude product was chromatographed on short silica gel column availing lower solubility of BTXA in chloroform used as eluent. 2,2 -Azobis(2-methylpropionitrile) (AIBN, 98 % Sigma-Aldrich) and 2,2- dimethoxy-2-phenylacetophenone (DMPA, 99 %, Sigma-Aldrich) were used as received. Tetrahydrofuran (THF, 99 %, POCh, Gliwice, Poland) was kept for several days over KOH pellets, was filtered off and was refluxed and distilled over sodium wires, then was degassed and distributed to an ampoule and was stored over small pieces of sodium. Toluene (analytical grade, Central Chem, Slovakia) was refluxed over sodium wires and was distilled into a round-bottomed flask equipped with freshly prepared sodium wires and was then degassed and distributed to an ampoule and was stored
4 S4 over small pieces of sodium. Dichloromethane (DCM, 99 %, POCh, Gliwice, Poland), after preliminary drying with CaCl 2 for 24 h, was refluxed in the presence of CaH 2 for 6 h and was distilled off. All other commercial solvents were of purity per analyses and were used as received. Analytical Methods NMR spectroscopy. Monomer conversion and the content of co-monomers in synthesized polyesters were determined by 1 H NMR using a 400 MHz VNMRS Varian NMR spectrometer equipped with a 5- mm 1H-19F/15N-31P PFG AutoX DB NB probe at 25 C or on Bruker DRX500 instrument operating at 500 MHz using CDCl 3 or d 6 -DMSO as solvents. 13 C NMR was measured using the same instruments operated at 100 MHz or 125 MHz. Gel permeation chromatography. The molar mass and dispersity of the polymers were determined using gel permeation chromatography (GPC) on three systems. The GPC of copolyesters prepared by coordination-insertion ROP was performed using an Agilent Technology 1260 Infinity system that consisted of a degasser, an autosampler, and a thermostatic box for columns and was equipped with a PSS SDV 10 µm precolumn and three PPS SDV 5-µm columns (d = 8 mm, l = 300 mm; 100 Å Å Å) thermostated at 30 C. A refractive index detector with THF as an eluent at a flow rate of 1.0 ml min -1 was used. Copolyesters prepared by cationic ROP were characterized using an Agilent 1100 system consisting of a degasser, an autosampler, a thermostatic box for columns and an Optilab Rex differential refractometer. Two PLGel 5-mm MIXED-C columns thermostated at 27 C were used for separation. DCM was used as a mobile phase at a flow rate of 0.8 ml min -1. The ASTRA software package (Wyatt Technology Corporation) was used for data collection and processing. The GPC of PMBL VA formed through vinyl addition was performed using a system consisting of a Shimadzu LC-20AT pump, PSS GRAM 10 µm precolumn and three PPS GRAM 5-µm columns (d = 8 mm, l = 300 mm; 100 Å Å Å) as well as a refractive index detector Shimadzu RID-10A with dimethylacetamide (DMAc) / lithium bromide (LiBr, 0.1 M) as an eluent at a flow rate of 1.0
5 S5 ml min -1. The same system was also used for GPC of fluorescently labeled polyesters prepared by post-functionalization of vinyl groups of P(MBL-co-CL) employing fluorescence detector Shimadzu RF-10A XL. The final system, used for polyesters prepared by cationic polymerization, was equipped with a Wyatt Optilab Rex interferometric refractometer as a detector. Dichloromethane was used as an eluent at a flow rate of 0.8 ml min -1 at room temperature. Molar masses were determined using polystyrene standards and anisole as an internal standard in all systems. Matrix-assisted laser desorption/ionization time-of-flight (MALDI TOF). Measurements were performed with the Voyager Elite (PerSeptive Biosystems, Framingham, MA) time-of-flight instrument equipped with a pulsed N 2 laser (337 nm) and time-delayed extraction source. An accelerating voltage of 20 kv was used. Dithranol was used as a matrix, CF 3 COO - K + was used as a cationating agent and THF was used as a solvent. Differential scanning calorimetry (DSC). DSC analysis was performed on a Mettler-Toledo DSC 821 e differential scanning calorimeter under a nitrogen atmosphere at a heating rate of 10 C min -1. Indium was used for the calibration of temperature and heat of fusion. The glass transition temperatures were determined from midpoints in the second heating using the STARe software of Mettler-Toledo. Thermogravimetric analysis (TGA). TGA of polymers was performed using a TGA Perkin-Elmer instrument at a heating rate of 20 C/min, from 0 to 600 C, under a nitrogen purge. FTIR and UV-Vis spectroscopy. FTIR spectra were obtained on a Nicolet 8700 spectrophotometer (Thermo, USA) in ATR mode using Ge crystals. UV-Vis spectra were obtained on a Shimadzu 1650PC spectrophotometer using a 1 1 cm quartz cuvette.
6 Figure SI1: S6
7 S7 Additional description of NMR spectra and assignments of signals from simple 1 H and 13 C NMR. Next, to MBL proton triplet signal 3, an additional proton triplet signal a appeared. Integrals of signals 3 and a are the same for all prepared copolyesters, and thus they could be attributed to oxomethylene protons of adjacent MBL and CL units in MBL-CL and/or CL-MBL hetero-sequences. In addition, a proton signal at 4.29 ppm (unlike the signal for monomeric triplet centered at 4.37 ppm) appeared in copolyesters with higher MBL content, and thus could be assigned to oxo-methylene protons in MBL-MBL homo-sequences. This observation was also confirmed by the appearance of signals 3 and a in the 13 C NMR in the region of 62 to 65 ppm attributed to carbons from oxomethylene moieties (Figure 2 in the main text). The similar intensity (visually, the integration was not performed) of both signals could again suggest their mutual relationship, similar to proton signals 3 and a in 1 H NMR. Moreover, a small signal 3 also appeared in this region in 13 C NMR for copolyesters with higher contents of MBL units. The carbonyl group of the CL units exhibited two signals, which can be attributed to homo- CL-CL and hetero- MBL-CL sequences at and ppm, respectively. Additionally, in the carbonyl region, a signal at ppm from carbon of the MBL unit in the CL-MBL hetero-sequence was for copolyesters with higher MBL content accompanied another side signal at ppm, which could be attributed to the MBL-MBL homo-sequence (Figure 2 in the main text). Figure S2 shows copolyester with lower MBL content where signals from expected MBL-MBL homo-sequences were not visible either in 1 H or 13 C NMR spectra.
8 Figure SI2: S8
9 S9 Figure SI3: Figure SI4:
10 Figure SI5: S10
11 S11 Figure SI6: Figure SI7:
12 S12 Figure SI8: Figure SI9:
13 Figure SI10: S13
One-pot polymer brush synthesis via simultaneous isocyanate coupling chemistry and grafting from RAFT polymerization
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2014 One-pot polymer brush synthesis via simultaneous isocyanate coupling chemistry and grafting
More informationChemically recyclable alternating copolymers with low polydispersity from
Electronic Supplementary Information Chemically recyclable alternating copolymers with low polydispersity from conjugated/aromatic aldehydes with vinyl ethers: selective degradation to another monomer
More informationSupporting Information
Supporting Information Controlled Radical Polymerization and Quantification of Solid State Electrical Conductivities of Macromolecules Bearing Pendant Stable Radical Groups Lizbeth Rostro, Aditya G. Baradwaj,
More informationSupporting Information
Supporting Information Solid Polymer Electrolytes Based on Functionalized Tannic Acids from Natural Resources for All-Solid-State Lithium- Ion Batteries Jimin Shim, [a] Ki Yoon Bae, [b] Hee Joong Kim,
More informationRing-Opening Polymerization of N-Carboxyanhydrides Initiated by a Hydroxyl Group
SUPPRTING INFRMATIN Ring-pening Polymerization of N-Carboxyanhydrides Initiated by a Hydroxyl Group Špela Gradišar, Ema Žagar, and David Pahovnik* National Institute of Chemistry, Department of Polymer
More information1,1,3,3-Tetramethylguanidine-Promoted Ring-Opening Polymerization of N-Butyl N-Carboxyanhydride Using Alcohol Initiators
Supporting Information 1,1,3,3-Tetramethylguanidine-Promoted Ring-Opening Polymerization of N-Butyl N-Carboxyanhydride Using Alcohol Initiators Brandon A. Chan, Sunting Xuan, Matthew Horton, and Donghui
More information1 Electronic Supplementary Information (ESI) 2 Healable thermo-reversible functional polymer via RAFT
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 1 Electronic Supplementary Information (ESI) 2 Healable thermo-reversible functional polymer via
More informationSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information Synthesis of Poly(dihydroxystyrene-block-styrene) (PDHSt-b-PSt) by the RAFT
More informationSupporting Information. for
Supporting Information for From N-vinylpyrrolidone anions to modified paraffin-like oligomers via double alkylation with 1,8-dibromooctane: access to covalent networks and oligomeric amines for dye attachment
More informationHigh Frequency sonoatrp of 2-Hydroxyethyl Acrylate in an Aqueous Medium
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2018 High Frequency sonoatrp of 2-Hydroxyethyl Acrylate in an Aqueous Medium Joe Collins, Thomas
More informationHyperbranched Poly(N-(2-Hydroxypropyl) Methacrylamide) via RAFT Self- Condensing Vinyl Polymerization
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2016 Hyperbranched Poly(N-(2-Hydroxypropyl) Methacrylamide) via RAFT Self- Condensing Vinyl
More informationSupporting Information
Supporting Information Solid-state Conversion of Processable 3,4-Ethylenedioxythiophene (EDOT) Containing Poly(arylsilane) Precursors to π-conjugated Conducting Polymers Jayesh G. Bokria, Arvind Kumar,
More informationSUPPLEMENTARY INFORMATION
DOI: 10.1038/NCHEM.2633 Mechanically controlled radical polymerization initiated by ultrasound Hemakesh Mohapatra, Maya Kleiman, Aaron P. Esser-Kahn Contents 1. Materials and methods 2 2. Procedure for
More informationSupporting information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Supporting information From competition to cooperation: a highly efficient strategy towards well-defined
More informationSupporting Information
Supporting Information Azo Polymer Janus Particles and Their Photoinduced Symmetry-Breaking Deformation Xinran Zhou, Yi Du, Xiaogong Wang* Department of Chemical Engineering, Laboratory of Advanced Materials
More informationSupporting information
Supporting information Temperature and ph-dual Responsive AIE-Active Core Crosslinked Polyethylene Poly(methacrylic acid) Multimiktoarm Star Copolymers ` Zhen Zhang,*,, and Nikos Hadjichristidis*, School
More informationSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information Nanoparticle-to-vesicle and nanoparticle-to-toroid transitions of ph-sensitive
More informationSupplementary Material (ESI) for Chemical Communications This journal is (c) The Royal Society of Chemistry 2008
Supplementary Information for: Scrambling Reaction between Polymers Prepared by Step-growth and Chain-growth Polymerizations: Macromolecular Cross-metathesis between 1,4-Polybutadiene and Olefin-containing
More informationSupporting Information
Supporting Information Precision Synthesis of Poly(-hexylpyrrole) and its Diblock Copolymer with Poly(p-phenylene) via Catalyst-Transfer Polycondensation Akihiro Yokoyama, Akira Kato, Ryo Miyakoshi, and
More informationSupporting Information
Supporting Information Facile polyisobutylene functionalization via thiol-ene Click chemistry Andrew J. D. Magenau, Justin W. Chan, Charles E. Hoyle, and Robson F. Storey School of Polymers and High Performance
More informationSupporting Information
Supporting Information Branched polyethylene mimicry by metathesis copolymerization of fatty acid-based α,ω-dienes. Thomas Lebarbé, a,b,d Mehdi Neqal, a,b Etienne Grau, a,b Carine Alfos, c and Henri Cramail
More informationSupporting Information
Supporting Information A Rational Design of Highly Controlled Suzuki-Miyaura Catalyst-Transfer Polycondensation for Precision Synthesis of Polythiophenes and their Block Copolymers: Marriage of Palladacycle
More informationA novel smart polymer responsive to CO 2
A novel smart polymer responsive to CO 2 Zanru Guo, a,b Yujun Feng,* a Yu Wang, a Jiyu Wang, a,b Yufeng Wu, a,b and Yongmin Zhang a,b a Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences,
More informationOptimizing Ion Transport in Polyether-based Electrolytes for Lithium Batteries
Supporting Information Optimizing Ion Transport in Polyether-based Electrolytes for Lithium Batteries Qi Zheng, 1 Danielle M. Pesko, 1 Brett M. Savoie, Ksenia Timachova, Alexandra L. Hasan, Mackensie C.
More informationAziridine in Polymers: A Strategy to Functionalize Polymers by Ring- Opening Reaction of Aziridine
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information (ESI) Aziridine in Polymers: A Strategy to Functionalize
More informationThermally Activated Delayed Fluorescence from Azasiline Based Intramolecular
Supporting information for : Thermally Activated Delayed Fluorescence from Azasiline Based Intramolecular Charge-Transfer Emitter (DTPDDA) and a Highly Efficient Blue Light Emitting Diode Jin Won Sun,
More informationMulticomponent Combinatorial Polymerization via the Biginelli Reaction
Supporting Information Multicomponent Combinatorial Polymerization via the Biginelli Reaction Haodong Xue a,b, Yuan Zhao a, Haibo Wu a,b, Zilin Wang a, Bin Yang a, Yen Wei a, Zhiming Wang b, Lei Tao a
More informationP. Lewinski, S. Sosnowski*, S. Kazmierski, S. Penczek* Centre of Molecular and Macromolecular Studies of Polish Academy of Sciences, Sienkiewicza
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2015 L-Lactide Polymerization Studied by 1 H NMR with Diffusion Ordered Spectroscopy (DOSY).
More informationELECTRONIC SUPPLEMENTARY INFORMATION
Unprecedented Scissor Effect of Macromolecular Cross-linkers on the Glass Transition Temperature of Poly(Nvinylimidazole), Crystallinity Suppression of Poly(tetrahydrofuran) and Molecular Mobility by Solid
More informationPhoto-Cleavage of Cobalt-Carbon Bond: Visible. Light-Induced Living Radical Polymerization Mediated by. Organo-Cobalt Porphyrins
Photo-Cleavage of Cobalt-Carbon Bond: Visible Light-Induced Living Radical Polymerization Mediated by Organo-Cobalt Porphyrins Yaguang Zhao, Mengmeng Yu, and Xuefeng Fu* Beijing National Laboratory for
More informationEfficient Magnesium Catalysts for the Copolymerization of Epoxides and CO 2 ; Using Water to Synthesize Polycarbonate Polyols
Supporting Information for Efficient Magnesium Catalysts for the Copolymerization of Epoxides and CO 2 ; Using Water to Synthesize Polycarbonate Polyols Michael R. Kember, Charlotte K. Williams* Department
More informationSupporting Information for
Supporting Information for AmPhos Pd-Catalyzed Suzuki-Miyaura Catalyst-Transfer Condensation Polymerization: Narrower Dispersity by Mixing the Catalyst and Base Prior to Polymerization Kentaro Kosaka,
More informationSupporting Information
Supporting Information UCST or LCST? Composition-Dependent Thermoresponsive Behavior of Poly(N-Acryloylglycinamide-co-Diacetone Acrylamide) Wenhui Sun, Zesheng An*, Peiyi Wu * Experimental Materials Glycinamide
More informationScheme 1: Reaction scheme for the synthesis of p(an-co-mma) copolymer
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Design and Development of Poly (acrylonitrile-co-methyl methacrylate) Copolymer to Improve
More informationSupporting Information
Supporting Information Efficient Temperature Sensing Platform Based on Fluorescent Block Copolymer Functionalized Graphene Oxide Hyunseung Yang, Kwanyeol Paek, and Bumjoon J. Kim * : These authors contributed
More informationSupporting Information
Supporting Information Controlled Ring-Opening Polymerization of O-Carboxyanhydrides Using a b-diiminate Zinc Catalyst Ruibo Wang, Jiawei Zhang, Qian Yin, Yunxiang Xu, Jianjun Cheng,* and Rong Tong* anie_201605508_sm_miscellaneous_information.pdf
More informationWell-defined polyethylene-based random, block and bilayered molecular cobrushes
Well-defined polyethylene-based random, block and bilayered molecular cobrushes Hefeng Zhang, 1,2 Zhen Zhang, 1,2 Yves Gnanou, 2 Nikos Hadjichristidis 1,2 * King Abdullah University of Science and Technology
More informationElectronic Supporting Information for
Electronic Supporting Information for An efficient long fluorescence lifetime polymer-based sensor based on europium complex as chromophore for the specific detection of F -, CH 3 COO - -, and H 2 PO 4
More informationAcid-Base Bifunctional Shell Cross-Linked Micelle Nanoreactor for One-pot Tandem Reaction
Supporting Information Acid-Base Bifunctional Shell Cross-Linked Micelle Nanoreactor for One-pot Tandem Reaction Li-Chen Lee, a# Jie Lu, b# Marcus Weck, b * Christopher W. Jones a * a School of Chemical
More informationBulk ring-opening transesterification polymerization of the renewable δ-decalactone using
Bulk ring-opening transesterification polymerization of the renewable δ-decalactone using an organocatalyst Mark T. Martello, Adam Burns, and Marc Hillmyer* *Department of Chemistry, University of Minnesota,
More informationSupporting Information
Supporting Information Supramolecular design for polymer/titanium oxo-cluster hybrids: An open door to new organic-inorganic dynamers Fabien Périneau, Sandrine Pensec, Clément Sanchez, Costantino Creton,
More informationSupporting Information. Copolymers of Tetrahydrofuran and Epoxidized Vegetable Oils: Application to Elastomeric Polyurethanes
Supporting Information Copolymers of Tetrahydrofuran and Epoxidized Vegetable Oils: Application to Elastomeric Polyurethanes Andrew J Clark,* Seng Soi Hoong Department of Chemistry, University of Warwick,
More informationMagnetic Iron Oxide Nanoparticles as Long Wavelength Photoinitiators for Free Radical Polymerization
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2015 SUPPORTING INFORMATION Magnetic Iron Oxide Nanoparticles as Long Wavelength Photoinitiators
More informationSupporting information
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2016 Supporting information Tripodal hydrogen bond donor binding with sulfonic acid enables
More informationSupporting Information
Supporting Information Preparation of a Library of Poly(N-sulfonylimidates) by Cu-Catalyzed Multicomponent Polymerization Hyunseok Kim and Tae-Lim Choi* Department of Chemistry, Seoul National University,
More informationNovel Supercapacitor Materials Including OLED emitters
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2015 Supporting Information Novel
More informationSupplementary Information
Facile Preparation of Fluorovinylene Aryl Ether Telechelic Polymers with Dual Functionality for Thermal Chain Extension and Tandem Crosslinking Scott T. Iacono, Stephen M. Budy, Dirk Ewald, and Dennis
More informationSUPPLEMENTARY INFORMATION
DOI: 10.1038/NCHEM.2346 Iterative exponential growth of stereo- and sequence-controlled polymers Jonathan C. Barnes, Deborah J. C. Ehrlich, Angela X. Gao, Frank A. Leibfarth, Yivan Jiang, Erica Zhou, Timothy
More informationDouble-decker-shaped Silsesquioxane Having
Supporting Information Hydrosilylation Polymerization of Double-decker-shaped Silsesquioxane Having Hydrosilane with Diynes Makoto Seino, Teruaki Hayakawa, Yoshihito Ishida, and Masa-aki Kakimoto* Department
More informationSupramolecular hydrogen-bonded photodriven actuators based on an azobenzenecontaining
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 2017 Supporting Information Supramolecular hydrogen-bonded photodriven actuators
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2019 Electronic Supplementary Information Synthesis and self-assembly of biobased poly(limonene
More informationRed Color CPL Emission of Chiral 1,2-DACH-based Polymers via. Chiral Transfer of the Conjugated Chain Backbone Structure
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2015 Red Color CPL Emission of Chiral 1,2-DACH-based Polymers via Chiral Transfer of the Conjugated
More informationSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 214 Supporting Information Lei Liu, ab Yijie Xia, b Jie Zhang* b a) China Center for Modernization
More informationOne polymer for all: Benzotriazole Containing Donor-Acceptor Type Polymer as a Multi-Purpose Material
One polymer for all: Benzotriazole Containing Donor-Acceptor Type Polymer as a Multi-Purpose Material Abidin Balan a, Derya Baran a, Gorkem Gunbas a,b, Asuman Durmus a,b, Funda Ozyurt a and Levent Toppare
More informationSupporting Information for
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017 Supporting Information for
More informationELECTRONIC SUPPORTING INFORMATION Pentablock star shaped polymers in less than 90 minutes via
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2015 ELECTRONIC SUPPORTING INFORMATION Pentablock star shaped polymers in less than 90 minutes
More informationXiangxiong Chen, Mohd Yusuf Khan and Seok Kyun Noh* School of Chemical Engineering, Yeungnam University, Dae-dong, Gyeongsan,
Electronic Supplementary Information For M Amount of Fe (III)-mediated ATR of MMA with hosphorus Containing Ligands in the Absence of Any Additives Xiangxiong Chen, Mohd Yusuf Khan and Seok Kyun Noh* School
More informationSupplementary Information T. Ebert, a A. Wollbrink, b A. Seifert, a R. John, a and S. Spange a
Electronic Supplementary Material (ESI for Polymer Chemistry. This journal is The Royal Society of Chemistry Please do 216 not adjust margins ARTICLE Supplementary Information T. Ebert, a A. Wollbrink,
More informationSUPPORTING INFORMATION
SUPPORTING INFORMATION Cis-Selective Ring-Opening Metathesis Polymerization with Ruthenium Catalysts Benjamin K. Keitz, Alexey Fedorov, Robert H. Grubbs* Arnold and Mabel Beckman Laboratories of Chemical
More informationSupporting Information
Supporting Information Molecular Weight Dependence of Zero-Shear Viscosity in Atactic Polypropylene Bottlebrush Polymers Samuel J. Dalsin, Marc A. Hillmyer,*, and Frank S. Bates*, Department of Chemical
More informationSupporting Information for
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 2014 Supporting Information for Application of thermal azide-alkyne cycloaddition
More informationEffect of Conjugation and Aromaticity of 3,6 Di-substituted Carbazole On Triplet Energy
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2018 Electronic Supporting Information (ESI) for Effect of Conjugation and Aromaticity of 3,6 Di-substituted
More informationPreparation of 1:1 alternating, nucleobase-containing copolymers for use in sequence-controlled polymerization
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2014 Supporting Information for Preparation of 1:1 alternating, nucleobase-containing copolymers
More informationHigh-Performance Semiconducting Polythiophenes for Organic Thin Film. Transistors by Beng S. Ong,* Yiliang Wu, Ping Liu and Sandra Gardner
Supplementary Materials for: High-Performance Semiconducting Polythiophenes for Organic Thin Film Transistors by Beng S. Ong,* Yiliang Wu, Ping Liu and Sandra Gardner 1. Materials and Instruments. All
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Information (ESI) Novel Semirigid Water-Soluble Thermoresponsive Polymers Based on Mesogen-Jacketed Liquid Crystal Polymers Chunhua Wang, a Fangkai Du, a Helou Xie, a Hailiang
More informationSupporting Information
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2016 Supporting Information Polystyrene Sulfonate Threaded in MIL-101Cr(III) as Stable and
More informationSupporting Information for
Supporting Information for Chelated Ruthenium Catalysts for Z-Selective Olefin Metathesis Koji Endo and Robert H. Grubbs* Arnold and Mabel Beckman Laboratory of Chemical Synthesis, Division of Chemistry
More informationMolecular Weight Distribution of Living Chains in Polystyrene Pre-pared by Atom Transfer Radical Polymerization
Molecular Weight Distribution of Living Chains in Polystyrene Pre-pared by Atom Transfer Radical Polymerization Joongsuk Oh, a Jiae Kuk, a Taeheon Lee, b Jihwa Ye, b Huyn-jong Paik, b* Hyo Won Lee, c*
More informationSupplementary Material for
www.sciencemag.org/content/343/6173/873/suppl/dc1 Supplementary Material for Nonswellable Hydrogel Without Mechanical Hysteresis Hiroyuki Kamata, Yuki Akagi, Yuko Kayasuga-Kariya, Ung-il Chung, Takamasa
More informationSupporting Information
Supporting Information 2-(Methylthio)ethyl Methacrylate: A Versatile Monomer for Stimuli Responsiveness and Polymerization-Induced Self-Assembly In The Presence Of Air Sihao Xu, a Gervase Ng, a Jiangtao
More informationControlling microenvironments and modifying anion binding. selectivities using core functionalised hyperbranched polymers
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Controlling microenvironments and modifying anion binding selectivities using core functionalised
More informationElectronic Supplementary Information. Reversible, Solid State Capture of Carbon Dioxide by Hydroxylated Amidines. Myungsook Kim, and Ji-Woong Park*
Electronic Supplementary Information Reversible, Solid State Capture of Carbon Dioxide by Hydroxylated Amidines Myungsook Kim, and Ji-Woong Park* Department of Materials Science and Engineering, Gwangju
More informationSupplementary Information. Rational Design of Soluble and Clickable Polymers Prepared by. Conventional Free Radical Polymerization of
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2017 Supplementary Information Rational Design of Soluble and Clickable Polymers Prepared by
More informationDirect Synthesis of Ethylene-Acrylic Acid Copolymers by Insertion Polymerization
Supporting information Direct Synthesis of Ethylene-Acrylic Acid Copolymers by Insertion Polymerization Thomas Rünzi, Dominik Fröhlich and Stefan Mecking* Chair of Chemical Materials Science, Department
More informationSupporting Information
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2015 A rare case of a dye co-crystal showing better dyeing performance Hui-Fen Qian, Yin-Ge Wang,
More informationFree radical and RAFT polymerization of vinyl
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information Free radical and RAFT polymerization of vinyl esters
More informationTuning Porosity and Activity of Microporous Polymer Network Organocatalysts by Co-Polymerisation
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information Tuning Porosity and Activity of Microporous Polymer Network Organocatalysts
More informationSupporting Information. Table of Contents. 1. General Notes Experimental Details 3-12
Supporting Information Table of Contents page 1. General Notes 2 2. Experimental Details 3-12 3. NMR Support for Timing of Claisen/Diels-Alder/Claisen 13 4. 1 H and 13 C NMR 14-37 General Notes All reagents
More informationSupporting Information
Supporting Information Polymerization-Induced Self-Assembly Using Visible Light Mediated Photoinduced Electron Transfer Reversible-Addition Fragmentation Chain Transfer Polymerization (PET-RAFT) Jonathan
More informationSupporting Information
Supporting Information α,β-d-cna Preorganization of unpaired loop moiety stabilize DNA hairpin Christelle Dupouy, Pierre Millard, Arnaud Boissonnet and Jean-Marc Escudier* Laboratoire de Synthèse et Physico-Chimie
More informationSupporting Information. Sequence-Regulated Copolymers via Tandem Catalysis of Living Radical Polymerization and In Situ Transesterification
Supporting Information Sequence-Regulated Copolymers via Tandem Catalysis of Living Radical Polymerization and In Situ Transesterification Kazuhiro Nakatani, Yusuke Ogura, Yuta Koda, Takaya Terashima*,
More informationSynthesis of Levulinic Acid based Poly(amine-co-ester)s
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2018 Synthesis of Levulinic Acid based Poly(amine-co-ester)s Yann Bernhard, Lucas Pagies, Sylvain
More informationSupporting information
Supporting information Imidazolium end-functionalized poly(l-lactide) for Efficient Carbon Nanotube Dispersion. Franck Meyer, a Jean-Marie Raquez, a Olivier Coulembier, a Julien De Winter, b Pascal Gerbaux,
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Information (ESI) A thin-layered chromatography plate prepared from naphthalimide-based receptor immobilized SiO 2 nanoparticles as a portable chemosensor and adsorbent for Pb
More informationTunable thermo-responsive water-dispersed multi walled. carbon nanotubes
Tunable thermo-responsive water-dispersed multi walled carbon nanotubes Gaojian Chen, Peter M. Wright, Jin Geng, Giuseppe Mantovani, and David M. Haddleton* Department of Chemistry, University of Warwick,
More informationHigh Molecular Weight Bile Acid and Ricinoleic Acid-Based Co-polyesters via Entropy-Driven Ring-Opening Metathesis Polymerisation
High Molecular Weight Bile Acid and Ricinoleic Acid-Based Co-polyesters via Entropy-Driven Ring-Opening Metathesis Polymerisation Julien E. Gautrot, X.X. Zhu * Département de Chimie, Université de Montréal,
More informationTetrahydrofuran (THF) was distilled from benzophenone ketyl radical under an argon
SUPPLEMENTARY METHODS Solvents, reagents and synthetic procedures All reactions were carried out under an argon atmosphere unless otherwise specified. Tetrahydrofuran (THF) was distilled from benzophenone
More informationSYNTHESIS AND PROPERTIES OF CROSS-LINKED POLYMERS CONTAINING DIARYLBIBENZOFURANONE BY ADMET POLYMERIZATION
SYNTHESIS AND PROPERTIES OF CROSS-LINKED POLYMERS CONTAINING DIARYLBIBENZOFURANONE BY ADMET POLYMERIZATION T. Ohishi, 1 K. Imato, 2 T. Kanehara, 2 A. Takahara, 1,2 and H. Otsuka 1,2 1 Institute for Materials
More informationA supramolecular approach for fabrication of photo- responsive block-controllable supramolecular polymers
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2014 Supporting Information A supramolecular approach for fabrication of photo- responsive
More informationSUPPORTING INFORMATION
SUPPORTING INFORMATION Polymerization-induced Self-Assembly of Homopolymer and Diblock copolymer: A Facile Approach for preparing Polymer Nano-objects with Higher Order Morphologies Jianbo Tan *a,b, Chundong
More informationA Rational Entry to Cyclic Polymers via Selective Cyclization by Self-Assembly and Topology Transformation of Linear Polymers
A Rational Entry to Cyclic Polymers via Selective Cyclization by Self-Assembly and Topology Transformation of Linear Polymers Daisuke Aoki,*, Gouta Aibara, Satoshi Uchida, and Toshikazu Takata*,, Department
More informationSupporting Information
Supporting Information Z-Selective Homodimerization of Terminal Olefins with a Ruthenium Metathesis Catalyst Benjamin K. Keitz, Koji Endo, Myles B. Herbert, Robert H. Grubbs* Arnold and Mabel Beckman Laboratories
More informationThe Journal of American Science, 4(1), 2008, ISSN ,
Free adical-induced Copolymerization of Norbornene and Methacrylate An-chi Yeh Department of Chemical and Material Engineering Chengshiu University, Niaosong, Kaohsiung, Taiwan, 833 C E-mail: acyeh1965@yahoo.com.tw
More informationSupporting Information. Complex Formation Between Lysozyme and Stabilized Micelles with a Mixed Poly(ethylene oxide)/poly(acrylic acid) Shell
Supporting Information Complex Formation Between Lysozyme and Stabilized Micelles with a Mixed Poly(ethylene oxide)/poly(acrylic acid) Shell Maria Karayianni 1,2, Valeria Gancheva 2, Stergios Pispas 1
More informationSupporting informations for
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 Supporting informations for Isoprene chain shuttling polymerization between cis and trans regulating
More informationRational design of light-directed dynamic spheres
Electronic Supplementary Information (ESI) Rational design of light-directed dynamic spheres Yumi Okui a and Mina Han* a,b a Department of Chemistry and Department of Electronic Chemistry Tokyo Institute
More informationSupporting information. For
Supporting information For Two-dimensional controlled syntheses of polypeptide molecular brushes via N-carboxyanhydride ring-opening polymerization and ring-opening metathesis polymerization Jingwei Fan,
More informationSupplementary Information. "On-demand" control of thermoresponsive properties of poly(n-isopropylacrylamide) with cucurbit[8]uril host-guest complexes
upplementary Information "n-demand" control of thermoresponsive properties of poly(n-isopropylacrylamide) with cucurbit[8]uril host-guest complexes Urs Rauwald, Jesús del Barrio, Xian Jun Loh, and ren
More informationSupporting Information for
Supporting Information for Visible-Light Induced Thiol Ene Reaction on Natural Lignin Hailing Liu and Hoyong Chung * Department of Chemical and Biomedical Engineering, Florida State University, Tallahassee,
More informationFrom Small Building Blocks to Complex Molecular Architecture
From Small Building Blocks to Complex Molecular Architecture Eugene R. Zubarev, Jun Xu, Jacob D. Gibson, Arshad Sayyad Department of Chemistry, Rice University, Houston, Texas 77005 Supporting Information
More information