Table S1. Summary of target PCB congeners. Numbers are BZ numbers (Ballschmiter and Zell, 1980) listed in order of elution from an HT8-PCB column.
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1 This journal is The Royal Society of Chemistry 21 Table S1. Summary of target PCB congeners. Numbers are BZ numbers (Ballschmiter and Zell, 198) listed in order of elution from an HT8-PCB column. Homologue BZ# Homologue BZ# Homologue BZ# Mono-CBs #1 Penta-CBs #14 Hepta-CBs #188 #2 #96 #184 #3 #13 #179 Di-CBs #1 #1 #176 #4 #94 #186 #9 #12/#93 #178 #7 #98/#9 #17 #6 #88 #182/#187 #8/# #91 #183 #14 #121 #18 #11 #92 #174 #13/#12 #84 #181 # #89 #177 Tri-CBs #19 #9 #171 #3 #11 #173 #18 #113 #172 #17 #99 #192 #24 #112/#119 #18 #27 #83 #193 #32 #18 #191 #16 #86 #17 #23 #117/#97 #19 #34 #12/#116 #189 #29 #87/#1 Octa-CBs #22 #26 #111 #2 #2 #8 #24 #31 #12/#11 #197 #28 #82 #199 #21 #124 #198 #2/#33 #19/#17 #21 #22 #123 #196 #36 #16 #23 #39 #118 #19 #38 #114 #194 #3 #122 #2 #37 # Nona-CBs #28 Tetra-CBs #4 #127 #27 # #126 #26 #3 Hexa-CBs # Deca-CBs #29 #1 # #4 #2 #46 #14 #2/#69 #136 #73 #148 #43 #4 #49 #1 #6/#7 #13 #48/#47 #144 #62 #147 #44 #149/#139 #9 #14 #42 #143 #64 #134 #72 #142 #71 #131 #41 #133 #68 #16 #4 #146 #7 #132 #67 #161 #63 #3 #8 #168 #61 #141 #74 #137 #7 #13 #76 #164/#163 #8 #138 #66 #16 # #8 #6 #129 #6 #166 #79 #9 #78 #128 #81 #162 #77 #167 #6 #7 K. Ballschmiter and M. Zell, Analysis of polychlorinated biphenyls (PCB) by glass capillary gas chromatography, Fresenius' Journal of Analytical Chemistry, 198, 32, 2-31.
2 This journal is The Royal Society of Chemistry 21 Table S2. List of rate constants that were used for mass-balance analysis log K OW a Rate constant for Rate constant for chemical uptake via overall chemical the respiratory surface (k 1 ) b elimination (k 2 ) c L kg -1 d -1 d -1 Rate constant for chemical uptake via ingestion of suspended and bottom sediment (k sed ) d Average day 14 day 28 # # # #87/# # # # e.21 # #149/# e.17 #12/# # e.9 # e e e #164/# e.26 d -1 a Hawker and Connell (1988) b The rate constant k 1 was estimated using data from a bioconcentration study of the dioxin-like PCBs (tetra- to hepta-chlorinated, non-ortho-, and mono-ortho-substituted PCB congeners; the congeners had log Kow values of [Hawker and Connell, 1988]) in marbled sole (Fishery Agency, 23). We analyzed the data by using our own analysis of the reported data based on first-order kinetics. We used reliable k 1 values for congeners with K OW values ranging from 6.36 to 7.71; a good linear relationship was observed between k 1 and log K OW (see Fig. S1). c The rate constant k 2 was estimated using the empirical equation based on K OW (Equation 7) proposed by Hawker and Connell (1988). d For each congeners, we used the average, minimum, and maximum k sed values that were obtained at days 14 and 28. e The rate constant k 2 could not be calculated for #13, #149/#139, #128, #138, and #164/#163 because their C F-W values were greater than their C F values.
3 This journal is The Royal Society of Chemistry 21 8 k 1 (L kg -1 day -1 ) y = 418x R 2 = log K OW Fig. S1. Relationship between k 1 and log K OW. The reference rate constant k 1 was obtained by our own analysis of the data from a bioconcentration study of the dioxin-like PCBs (tetra- to hepta-chlorinated, non-ortho- and mono-ortho-substituted PCB congeners; the congeners had log Kow values of [Hawker and Connell, 1988]) in marbled sole (Fishery Agency, 23). Based on these reference k 1, we established a regression equation between k 1 and log K OW (k 1 = 418 log K OW ). We calculated the k 1 values that were used in the mass-balance analysis by using this regression equation.
4 This journal is The Royal Society of Chemistry 21 Proportion of each congeners in total PCBs [%] 2 1 Muscle (CT) Liver (CT) Internal organs (CT) Carcass (CT) Muscle (BST) Liver (BST) Internal organs (BST) Carcass (BST) <Tetra-CBs> #4 # #3 #1 #4 #46 #2/#69 #73 #43 #49 #6/#7 #48/#47 #62 #44 #9 #42 #64 #72 #71 #41 #68 #4 #7 #67 #63 #8 #61 #74 #7 #76 #8 #66 # #6 #6 #79 #78 #81 #77 s s <Penta-CBs> #14 #96 #13 #1 #94 #12/#93 #98/#9 #88 #91 #121 #92 #84 #89 #9 #11 #113 #99 #112/#119 #83 #18 #86 #117/#97 #12/#116 #87/#1 #111 #8 #12/#11 #82 #124 #19/#17 #123 #16 #118 #114 #122 # #127 #126 <Hexa-CBs> # # #2 #14 #136 #148 #4 #1 #13 #144 #147 #149/#139 #14 #143 #134 #142 #131 #133 #16 #146 #132 #161 #3 #168 #141 #137 #13 #164/#163 #138 #16 #8 #129 #166 #9 #128 #162 #167 #6 #7 Fig. S2a. Comparison of the proportions of each congener in the total accumulated PCBs among the different fish tissues CT: Control Tank BST: Bottom Sediment Tank
5 This journal is The Royal Society of Chemistry 21 Whole-fish form CT Whole-fish form SST Whole-fish from BST Particulate phase in water from BST Dissolved phase in water from BST Bottom sediment Food 2 1 <Tetra-CBs> #4 # #3 #1 #4 #46 #2/#69 #73 #43 #49 #6/#7 #48/#47 #62 #44 #9 #42 #64 #72 #71 #41 #68 #4 #7 #67 #63 #8 #61 #74 #7 #76 #8 #66 # #6 #6 #79 #78 #81 # <Penta-CBs> #14 #96 #13 #1 #94 #12/#93 #98/#9 #88 #91 #121 #92 #84 #89 #9 #11 #113 #99 #112/#119 #83 #18 #86 #117/#97 #12/#116 #87/#1 #111 #8 #12/#11 #82 #124 #19/#17 #123 #16 #118 #114 #122 # #127 # <Hexa-CBs> # # #2 #14 #136 #148 #4 #1 #13 #144 #147 #149/#139 #14 #143 #134 #142 #131 #133 #16 #146 #132 #161 #3 #168 #141 #137 #13 #164/#163 #138 #16 #8 #129 #166 #9 #128 #162 #167 #6 #7 Fig. S2b. Comparison of the proportions of each congener in the total PCBs between the fish samples and other media (food, water, and sediment) CT: Control Tank BST: Bottom Sediment Tank
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