Some Fundamental Definitions:
|
|
- Brice Chapman
- 6 years ago
- Views:
Transcription
1 Lecture 2. The GAS LAWS Some Fundamental Definitions: SYSTEM: the part of the universe being the subject of study 1
2 Some Fundamental Definitions: State of the System: condition of a system at any given time as defined by the experimental variables such as pressure, volume, temperature and composition. Surroundings: portion of the universe outside of the system and that interacts with the system Process: is an occurrence that changes the state of the system. Some Fundamental Definitions: 2
3 Some Fundamental Definitions: Thermodynamic variables are either extensive or intensive: Intensive variables: independent of the size of the system. Pressure, density and temperature. Extensive variables: variables that depend on the size of the system. Volume, mass, internal energy and entropy. 3
4 The Gas Laws: Boyle s Law Why pressurize the contents of gas canister? The effect of pressure on gas volume Robert Boyle (1662) discovered that: pv = constant (Boyle s Law) For a certain gas (at constant T), Boyle s law can be used to predict when its volume changes and vice versa: P 1 V 1 = P 2 V 2 (at constant gas mass and T) 4
5 The Gas Laws: Charles Law Why does a hot air balloon float? The effect of temperature on gas volume Small burner at the heart of the balloon heats the canvas hood of the balloon. Density of the gas inside the balloon decreases with heating ( since mass is assumed constant, the decreased in density must have been due to increase in volume. The balloon floats because the voluminous air inside has a lower density than the air outside. Balloon descends back to earth when the air it contains cools down The Gas Laws: Charles Law J. A. Charles: at constant pressure, the volume of the gas expands when heated and contracts when cooled. V T ; V/T = constant (Charles Law) An alternative is that at constant volume; P T; P/T = constant Volume-temperature and pressure-temperature values of a gas in states 1 and 2: V 1 /T 1 = V 2 /T 2 and P 1 /T 1 = P 2 /T 2 5
6 The Gas Laws: Avogadro s Law Proposed by Amedeo Avogadro in 1811: Equal volumes of gases at the same temperature and pressure contains the same number of molecules. V n ; V/n = constant (at constant T, P) 6
7 Combining the GAS LAWS How does a bubble-jet printer work? The Gas Laws: THE IDEAL GAS LAW; PV = nrt The volume of a gas is dependent on the temperature, pressure and the number of moles: at constant T and n: V 1/P Boyles Law at constant P and n: V T Charles Law at constant T and P: V n Avogadro s Law Therefore: V nt/p V = nrt/p 7
8 The Gas Laws: THE IDEAL GAS LAW; PV = nrt The values of R: R = L atm K -1 mol -1 R = N m K -1 mol -1 THE IDEAL GAS LAW: Sample Problem A Hydrogen Gas thermometer is found to have a volume of ml when placed in an ice water bath at 0 o C. When the same thermometer is immersed in boiling liquid chorine, the volume of hydrogen at the same pressure is found to be 87.2 ml. What is of the boiling point of chlorine? 8
9 THE IDEAL GAS LAW: Sample Problems A gas-filled weather balloon with a volume of 65.0 L is released at sea level conditions of 745 torr and 25 o C. The balloon can expand to a maximum volume of 835 L. When the balloon rises to an altitude at which the temperature is -5 o C and the pressure is atm, will it reach its maximum volume? - From Silberberg, Chemistry, Molecular Nature of Matter and Change. THE IDEAL GAS LAW: Sample Problem Atmospheric pollution is a problem that has received much attention. Not all pollution, however, comes from industrial sources. Volcanic eruptions can be significant source of air pollution. The Kilauea volcano in Hawaii emits on the average 250 tons of SO 2 per day. If this gas is emitted at 800 o C and at 1 atm, what volume of gas is emitted? - From Atkin s Physical Chemistry, 8 th, Oxford Press 9
10 THE IDEAL GAS LAW: Sample Problems A 2.50 g sample of XeF 4 gas is placed into an evacuated 3.00 liter container at 80 o C. What is the pressure in the container? GAS STOICHIOMETRY: Sample Problem A sample of Nitrogen gas has a volume of 1.75 L at STP. How many moles of N 2 are present? 10
11 GAS STOICHIOMETRY: Sample Problem Quicklime (CaO) is produced by the thermal decomposition of calcium carbonate (CaCO 3 ). Calculate the volume of CO 2 at STP produced from the decomposition of 152 g of CaCO 3 by the reaction: CaCO 3 (s) CaO(s) + CO 2 (g) GAS STOICHIOMETRY: Sample Problem A sample of methane gas having a volume of 2.8 L at 25 o C and 1.65 atm was mixed with a sample of oxygen gas having a volume 35.0 L at 31 o C and 1.25 atm. The mixture was then ignited to form carbon dioxide and water. Calculate the volume of CO 2 formed at a pressure of 2.5 atm and a temperature of 125 o C. 11
12 MOLAR MASS OF A GAS / DENSITY The molar mass of a gas was measured at 1.5 atm and 27 o C and found to be 1.95 g/l. Calculate the molar mass of the gas. DALTON s LAW of Partial Pressures For a system containing two or more different gases, the total pressure is the sum of the individual pressures that each gas would exert if it were alone and occupied the same volume. P T = (n 1 + n 2 + n n ) RT/V P 1 = x 1 P T where x 1 is the mole fraction of gas 1 P 2 = x 2 P T where x 2 is the mole fraction of gas 2 P n = x n P T where x n is the mole fraction of gas n 12
13 THE GAS LAWS: Sample Problems Mixtures of helium and oxygen can be used in scuba diving tanks to prevent the bends. For a particular dive, 46 L of He at 25 o C and 1.0 atm and 12 L of O 2 at 25 o C and 1.0 atm were pumped into a tank with volume of 5.0 L. Calculate the partial pressure of each gas and total pressure in the tank at 25 o C. - From Atkin s Physical Chemistry, 8 th, Oxford Press THE GAS LAWS: REAL GASES IDEAL GAS: Gas molecules have negligible volume. There are no attractive nor repulsive interaction between molecules. No such gases exist! 13
14 THE GAS LAWS: REAL GASES When gases are compressed, molecules are brought closer together, gases will deviate from ideal behavior! Measure of deviation from ideality: compressibility factor, Z Z = PV/nRT Z = 1 Z < 1 Z > 1 ideal behavior, when P approaches 0 for all gases easier to compress than an ideal gas harder to compress than an ideal gas THE GAS LAWS: REAL GASES 14
15 THE GAS LAWS: REAL GASES REVIEW Ideal Gases: V 1/P Boyles s Law V T Charles Law V n Avogadro s Law V nt/p ; PV = nrt 15
16 REVIEW Real Gases: - are not just points of mass; they have definite volumes - gas molecules interacts (attractive or repulsive) with each other. Compressibility factor is a measure for non-ideality of gases. REVIEW QUESTION: At what conditions of P, V, and T does real gases approaches ideality. 16
17 REAL GASES: The van der Waals equation Why is the molar volume of a gas not zero at 0 o K? -Gases have finite volume. REAL GASES: The van der Waals equation D. van der Waals proposes a law that accounts for: - Finite volume of individual molecules - Attractive forces between molecules. 17
18 REAL GASES: The van der Waals equation (P + an 2 /V 2 )(V-nb) = nrt Introduces two new constants to the ideal gas law: b - the finite volume of the non ideal gas and a - attractive forces between the gas molecules. (P + an 2 /V 2 ) - pressure of corrected for intermolecular forces (V-nb) - nb represents the total effective volume of the gas REAL GASES: The van der Waals equation 18
19 REAL GASES: The van der Waals equation The constant a reflects the strength of interaction between gas molecules: - a value of 4.25 for NH 3 suggests strong interaction: value of for He represent a negligible interaction The constant b reflects the physical size of the gas molecule: b for He; CO 2 = REAL GASES: Sample Problem Cylinders of compressed gas are typically filled to pressures of 200 atm. For oxygen, how many kg of this gas can be stored in a 50-liter cylinder at this pressure and 25 o C based on a) the ideal gas equation and b) van der Waals equation. For oxygen a = li 2 atm mol -2, b = 3.19 X10-2 li mol
20 REAL GASES: The Virial Equation of State Another way of expressing the non-ideal behavior of gases: Z = 1 + B/V + C/V 2 + D/V 3 + Where B, C, D are virial coefficients and are T dependent. Alternatively, a series expansion in terms of pressure Z = 1 + B P + C P2 + D P3 +.. when B >> C >> D Z = 1+ B P REAL GASES: Sample Problem Calculate the molar volume of methane at 300K and 100 atm, given that the second virial coefficient (B) of methane is L mol-1. Compare your result with that obtained using the ideal-gas equation. 20
21 Condensation of Gases ; Critical State From Physical Chemistry, R. Chang Condensation of Gases ; Critical State From Physical Chemistry, R. Chang 21
22 Van de Waals Equation and the Critical State Relationship between critical constants and a and b in van der Waals equation: As a function of P c and V c a = 3P c (V c /n) 2 b = V c /3n As a function of P c and T c a = 27R 2 T c2 /64P c b = RT c /8P c Critical State: Sample problem The critical constants for methane are P c = 45.6 atm, V c = li/mol and T c = K. Calculate the van der Waals parameters of the gas. 22
Lecture 2 PROPERTIES OF GASES
Lecture 2 PROPERTIES OF GASES Reference: Principles of General Chemistry, Silberberg Chapter 6 SOME FUNDAMENTAL DEFINITIONS: SYSTEM: the part of the universe being the subject of study 1 SOME FUNDAMENTAL
More informationApparatus for Studying the Relationship Between Pressure and Volume of a Gas
The Gas Laws Apparatus for Studying the Relationship Between Pressure and Volume of a Gas As P (h) increases V decreases Boyle s Law P x V = constant P 1 x V 1 = P 2 x V 2 Constant temperature Constant
More informationGases. Characteristics of Gases. Unlike liquids and solids, gases
Gases Characteristics of Gases Unlike liquids and solids, gases expand to fill their containers; are highly compressible; have extremely low densities. 1 Pressure Pressure is the amount of force applied
More informationUNIT 10.
UNIT 10 Pressure: F/A http://chemlab.truman.edu/chem130labs/calorimetryfiles/thermobackground.asp There are four variable needed to define the physical state of a gas. They are: o Temperature o Pressure
More informationChapter 5 The Gaseous State
Chapter 5 The Gaseous State Contents and Concepts Gas Laws We will investigate the quantitative relationships that describe the behavior of gases. 1. Gas Pressure and Its Measurement 2. Empirical Gas Laws
More informationChapter Elements That Exist as Gases at 25 C, 1 atm. 5.2 Pressure basic physics. Gas Properties
5.1 Elements That Exist as Gases at 25 C, 1 atm Chapter 5 The Gaseous State YOU READ AND BE RESPONSIBLE FOR THIS SECTION! Gaseous compounds include CH 4, NO, NO 2, H 2 S, NH 3, HCl, etc. Gas Properties
More informationGas Laws. Gas Properties. Gas Properties. Gas Properties Gases and the Kinetic Molecular Theory Pressure Gas Laws
Gas Laws Gas Properties Gases and the Kinetic Molecular Theory Pressure Gas Laws Gas Properties 1) Gases have mass - the density of the gas is very low in comparison to solids and liquids, which make it
More informationThe Gaseous State. Definition
The Gaseous State Lecture Material Basic Chemistry 1 2013/2014 Inneke Hantoro Definition A gas is a substance that is normally in the gaseous state at ordinary temperatures and pressures. A vapor is the
More informationChapter 5 The Gaseous State
Chapter 5 The Gaseous State Contents and Concepts Gas Laws We will investigate the quantitative relationships that describe the behavior of gases. 1. Gas Pressure and Its Measurement 2. Empirical Gas Laws
More informationChapter 11. Molecular Composition of Gases
Chapter 11 Molecular Composition of Gases PART 1 Volume-Mass Relationships of Gases Avogadro s Law Equal volumes of gases at the same temperature and pressure contain equal numbers of molecules. Recall
More informationGases. Chapter 5. Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
Gases Chapter 5 Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display. 1 Elements that exist as gases at 25 0 C and 1 atmosphere 2 3 Physical Characteristics of Gases
More informationChemistry 11. Unit 11 Ideal Gas Law (Special Topic)
Chemistry 11 Unit 11 Ideal Gas Law (Special Topic) 2 1. States of substances It has been studied in Unit 3 that there exist 3 states of matter in nature: gas, liquid and solid. (Technically there is the
More informationChapter 5 Gases. A Gas- Uniformly fills any container Mixes completely with any other gas Can easily be compressed Exerts pressure on its surroundings
Chapter 5 Gases A Gas- Uniformly fills any container Mixes completely with any other gas Can easily be compressed Exerts pressure on its surroundings The properties of a gas depends upon four variables-
More informationGases: Their Properties & Behavior. Chapter 09 Slide 1
9 Gases: Their Properties & Behavior Chapter 09 Slide 1 Gas Pressure 01 Chapter 09 Slide 2 Gas Pressure 02 Units of pressure: atmosphere (atm) Pa (N/m 2, 101,325 Pa = 1 atm) Torr (760 Torr = 1 atm) bar
More informationComparison of Solids, Liquids, and Gases
CHAPTER 8 GASES Comparison of Solids, Liquids, and Gases The density of gases is much less than that of solids or liquids. Densities (g/ml) Solid Liquid Gas H O 0.97 0.998 0.000588 CCl 4.70.59 0.00503
More informationProperties of Gases. 5 important gas properties:
Gases Chapter 12 Properties of Gases 5 important gas properties: 1) Gases have an indefinite shape 2) Gases have low densities 3) Gases can compress 4) Gases can expand 5) Gases mix completely with other
More informationGases. Chapter 5. Elements that exist as gases at 25 0 C and 1 atmosphere
Gases Chapter 5 Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display. 1 Elements that exist as gases at 25 0 C and 1 atmosphere 2 3 1 Physical Characteristics of Gases
More informationProperties of Gases. Gases have four main characteristics compared with solids and liquids:
1 Properties of Gases Gases have four main characteristics compared with solids and liquids: Gases take the volume and shape of their containers. Mix completely (homogeneously) with any other gas. Compressible:
More informationScientists and Their Discoveries: The Ideal Gas Law Poster Illustrated Teacher's Guide
Scientists and Their Discoveries: The Ideal Gas Law Poster Illustrated Teacher's Guide #35-1170 Paper #35-1171 Laminated Background Gas Law Basics Matter most frequently takes the form of a solid, liquid,
More informationSummary of Gas Laws V T. Boyle s Law (T and n constant) Charles Law (p and n constant) Combined Gas Law (n constant) 1 =
Summary of Gas Laws Boyle s Law (T and n constant) p 1 V 1 = p 2 V 2 Charles Law (p and n constant) V 1 = T 1 V T 2 2 Combined Gas Law (n constant) pv 1 T 1 1 = pv 2 T 2 2 1 Ideal Gas Equation pv = nrt
More informationA Gas Uniformly fills any container. Easily compressed. Mixes completely with any other gas. Exerts pressure on its surroundings.
Chapter 5 Gases Chapter 5 A Gas Uniformly fills any container. Easily compressed. Mixes completely with any other gas. Exerts pressure on its surroundings. Copyright Cengage Learning. All rights reserved
More informationGases. Chapter 5. Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
Gases Chapter 5 1 Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Elements that exist as gases at 250C and 1 atmosphere 2 3 Physical Characteristics of Gases
More informationGaseous States of Matter
Gaseous States of Matter Semester-1 : ICY-101: CHEMISTRY-I, Unit III Dr. Tapta Kanchan Roy Assistant Professor Department of Chemistry & Chemical Sciences Central University of Jammu 1 The simplest state
More informationLecture Presentation. Chapter 10. Gases. John D. Bookstaver St. Charles Community College Cottleville, MO Pearson Education, Inc.
Lecture Presentation Chapter 10 John D. Bookstaver St. Charles Community College Cottleville, MO Characteristics of Unlike liquids and solids, gases Expand to fill their containers. Are highly compressible.
More informationGases. Chapter 5. Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
Gases Chapter 5 Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display. 1 Elements that exist as gases at 25 0 C and 1 atmosphere 2 3 Physical Characteristics of Gases
More informationAP Chemistry Unit 5 - Gases
Common Gases at Room Temperature AP Chemistry Unit 5 - Gases Know these! HCN toxic slight odor of almonds HS toxic odor of rotten eggs CO toxic odorless CO odorless CH4 methane odorless, flammable CH4
More informationMind Catalyst Stick It!
Mind Catalyst Stick It! O With a partner, use the following scenarios as a guide to come up with the relationships of the gas properties. For each scenario, write the two properties and their relationship
More informationGases and Kinetic Molecular Theory
1 Gases and Kinetic Molecular Theory 1 CHAPTER GOALS 1. Comparison of Solids, Liquids, and Gases. Composition of the Atmosphere and Some Common Properties of Gases 3. Pressure 4. Boyle s Law: The Volume-Pressure
More informationChapter 10. Gases THREE STATES OF MATTER. Chapter 10 Problems 6/29/2012. Problems 16, 19, 26, 33, 39,49, 57, 61
Chemistry, The Central Science, 11th edition Theodore L. Brown; H. Eugene LeMay, Jr.; and Bruce E. Bursten Chapter 10 John Bookstaver St. Charles Community College Cottleville, MO Chapter 10 Problems Problems
More informationSubstances that are Gases under Normal Conditions
Chapter 5: Gases 5.1 Early Experiments 5.2 The gas laws of Boyle, Charles, and Avogadro 5.3 The Ideal Gas Law 5.4 Gas Stiochiometry 5.5 Dalton s Law of Partial Pressures 5.6 The Kinetic molecular Theory
More informationSTP : standard temperature and pressure 0 o C = 273 K kpa
GAS LAWS Pressure can be measured in different units. For our calculations, we need Pressure to be expressed in kpa. 1 atm = 760. mmhg = 101.3 kpa R is the Universal Gas Constant. Take note of the units:
More informationChapter 10 Gases. Measurement of pressure: Barometer Manometer Units. Relationship of pressure and volume (Boyle s Law)
Chapter 10 Gases Conditions of ideal gases: Ideal gases have no attractive forces between the molecules. the atoms volume taken into account when looking at the volume a gas occupies. Low pressure and
More informationWarning!! Chapter 5 Gases. Chapter Objectives. Chapter Objectives. Chapter Objectives. Air Pollution
Warning!! Larry Brown Tom Holme www.cengage.com/chemistry/brown Chapter 5 Gases These slides contains visual aids for learning BUT they are NOT the actual lecture notes! Failure to attend to lectures most
More informationGases. T boil, K. 11 gaseous elements. Rare gases. He, Ne, Ar, Kr, Xe, Rn Diatomic gaseous elements H 2, N 2, O 2, F 2, Cl 2
Gases Gas T boil, K Rare gases 11 gaseous elements He, Ne, Ar, Kr, Xe, Rn 165 Rn 211 N 2 O 2 77 F 2 90 85 Diatomic gaseous elements Cl 2 238 H 2, N 2, O 2, F 2, Cl 2 H 2 He Ne Ar Kr Xe 20 4.4 27 87 120
More informationChapter 10. Chapter 10 Gases
Chapter 10 Gases Earth is surrounded by a layer of gaseous molecules - the atmosphere - extending out to about 50 km. 10.1 Characteristics of Gases Gases low density; compressible volume and shape of container
More information5. What pressure (in atm) would be exerted by 76 g of fluorine gas in a 1.50 liter vessel at -37 o C? a) 26 atm b) 4.1 atm c) 19,600 atm d) 84 atm
Test bank chapter (5) Choose the most correct answer 1. A sample of oxygen occupies 47.2 liters under a pressure of 1240 torr at 25 o C. What volume would it occupy at 25 o C if the pressure were decreased
More informationGas Density. Standard T & P (STP) 10/29/2011. At STP, 1 mol of any ideal gas occupies 22.4 L. T = 273 K (0 o C) P = 1 atm = kpa = 1.
Standard T & P (STP) T = 73 K (0 o C) P = 1 atm = 101.35 kpa = 1.0135 bar At STP, 1 mol of any ideal gas occupies.4 L.4 L Gas Density We can use PV = nrt to determine the density of gases. What are the
More informationChemistry, The Central Science, 10th edition Theodore L. Brown; H. Eugene LeMay, Jr.; and Bruce E. Bursten. Chapter 10. Gases.
Chemistry, The Central Science, 10th edition Theodore L. Brown; H. Eugene LeMay, Jr.; and Bruce E. Bursten Chapter 10 Characteristics of Unlike liquids and solids, they Expand to fill their containers.
More informationGases. Measuring Temperature Fahrenheit ( o F): Exceptions to the Ideal Gas Law. Kinetic Molecular Theory
Ideal gas: a gas in which all collisions between atoms or molecules are perfectly elastic (no energy lost) there are no intermolecular attractive forces Think of an ideal gas as a collection of perfectly
More information(b) The measurement of pressure
(b) The measurement of pressure The pressure of the atmosphere is measured with a barometer. The original version of a barometer was invented by Torricelli, a student of Galileo. The barometer was an inverted
More informationChapter 11 Gases 1 Copyright McGraw-Hill 2009
Chapter 11 Gases Copyright McGraw-Hill 2009 1 11.1 Properties of Gases The properties of a gas are almost independent of its identity. (Gas molecules behave as if no other molecules are present.) Compressible
More informationStandard T & P (STP) At STP, 1 mol of any ideal gas occupies 22.4 L. The standard temperature and pressure for gases is:
Standard T & P (STP) The standard temperature and pressure for gases is: At STP, 1 mol of any ideal gas occupies 22.4 L T = 273 K (0 o C) P = 1 atm = 101.325 kpa = 1.01325 bar 22.4 L Using STP in problems
More informationChapter 13. Kinetic Theory (Kinetikos- Moving ) Based on the idea that particles of matter are always in motion
Chapter 3 Kinetic Theory (Kinetikos- Moving ) Based on the idea that particles of matter are always in motion The motion has consequences Behavior of Gases Physical Properties of Gases Ideal Gas an imaginary
More informationIMPORTANT CONCEPTS. 5.1 Pressure Units for pressure STP. 5.6 Kinetic Molecular Theory. 5.3 Ideal Gas Law. 5.4 Gas Stoichiometry Gas density Molar mass
TOPICS 1. Intermolecular Forces 2. Properties of Gases 3. Pressure 4. Gas Laws Boyle, Charles, Lussac 5. Ideal Gas Law 6. Gas Stoichiometry 7. Partial Pressure 8. Kinetic Molecular Theory 9. Effusion &
More informationChapter 6 The States of Matter. Examples of Physical Properties of Three States of Matter
Chapter 6 The States of Matter Examples of Physical Properties of Three States of Matter 1 Three States of Matter Solids: Fixed shape, fixed volume, particles are held rigidly in place. Liquids: Variable
More informationChapter 5. Gases and the Kinetic-Molecular Theory
Chapter 5 Gases and the Kinetic-Molecular Theory Macroscopic vs. Microscopic Representation Kinetic Molecular Theory of Gases 1. Gas molecules are in constant motion in random directions. Collisions among
More informationAP Chemistry Ch 5 Gases
AP Chemistry Ch 5 Gases Barometer - invented by Evangelista Torricelli in 1643; uses the height of a column of mercury to measure gas pressure (especially atmospheric) Manometer- a device for measuring
More informationGases. A gas. Difference between gas and vapor: Why Study Gases?
Gases Chapter 5 Gases A gas Uniformly fills any container. Is easily compressed. Mixes completely with any other gas. Exerts pressure on its surroundings. Difference between gas and vapor: A gas is a substance
More informationCHEMISTRY Matter and Change. Chapter 13: Gases
CHEMISTRY Matter and Change Chapter 13: Gases CHAPTER 13 Table Of Contents Section 13.1 Section 13.2 Section 13.3 The Gas Laws The Ideal Gas Law Gas Stoichiometry Click a hyperlink to view the corresponding
More information4. 1 mole = 22.4 L at STP mole/volume interconversions at STP
Ch. 10 Gases and the Ideal Gas Law(s) Chem 210 Jasperse Ch. 10 Handouts 1 10.1 The Atmosphere 1. Earth surrounded by gas 2. Major components: Nitrogen 78% Oxygen 21% Miscellaneous: All
More informationSection Using Gas Laws to Solve Problems
Gases and Gas Laws Section 13.2 Using Gas Laws to Solve Problems Kinetic Molecular Theory Particles of matter are ALWAYS in motion Volume of individual particles is zero. Consists of large number of particles
More informationChapter 10. Gases. Chemistry, The Central Science, 11th edition Theodore L. Brown; H. Eugene LeMay, Jr.; and Bruce E. Bursten
Chemistry, The Central Science, 11th edition Theodore L. Brown; H. Eugene LeMay, Jr.; and Bruce E. Bursten Chapter 10 John Bookstaver St. Charles Community College Cottleville, MO Characteristics of Unlike
More informationCHAPTER 13 Gases The Gas Laws
CHAPTER 13 Gases 13.1 The Gas Laws The gas laws apply to ideal gases, which are described by the kinetic theory in the following five statements. Gas particles do not attract or repel each other. Gas particles
More informationChapter 5 Gases - 4 Gas Stoichiometry. Dr. Sapna Gupta
Chapter 5 Gases - 4 Gas Stoichiometry Dr. Sapna Gupta Stoichiometry in Gases Amounts of gaseous reactants and products can be calculated by utilizing The ideal gas law to relate moles to T, P and V. Moles
More informationGases: Units of pressure: the pascal(pa)(1 Pa = 1 N/m2 = 1 kg m-1
Gases: Units of pressure: the pascal(pa)(1 Pa = 1 N/m 2 = 1 kg m -1 s -2 ) psi(pounds per square inch) atmosphere(atm) millimeters of mercury(mm Hg) torr(1 torr = 1 mm Hg) kilopascal(kpa) Mercury Barometer:
More informationvapors: gases of substances that are normally liquids or solids 1 atm = 760 mm Hg = 760 torr = kpa = bar
Gases A Chemistry Lecture Outline Name: Basics on Gases composition of the atmosphere: properties of gases: vapors: gases of substances that are normally liquids or solids Equation for pressure: 1 atm
More informationINTRODUCTORY CHEMISTRY Concepts and Critical Thinking
INTRODUCTORY CHEMISTRY Concepts and Critical Thinking Sixth Edition by Charles H. Corwin Chapter 11 The Gaseous State by Christopher Hamaker 2011 Pearson Education, Inc. Chapter 11 1 Properties of Gases
More informationChapter Ten- Gases. STUDY GUIDE AP Chemistry
STUDY GUIDE AP Chemistry Chapter Ten- Gases Lecture Notes 10.1 Characteristics of Gases All substances have three phases: solid, liquid and gas. Substances that are liquids or solids under ordinary conditions
More informationClass XI Chapter 5 States of Matter Chemistry
Question 5.1: What will be the minimum pressure required to compress 500 dm 3 of air at 1 bar to 200 dm 3 at 30 C? Initial pressure, p 1 = 1 bar Initial volume, V 1 = 500 dm 3 Final volume, V 2 = 200 dm
More informationChapter 1. The Properties of Gases Fall Semester Physical Chemistry 1 (CHM2201)
Chapter 1. The Properties of Gases 2011 Fall Semester Physical Chemistry 1 (CHM2201) Contents The Perfect Gas 1.1 The states of gases 1.2 The gas laws Real Gases 1.3 Molecular interactions 1.4 The van
More informationCentimeters of mercury
CHAPTER 11 PROPERTIES OF GASES Gases have an indefinite shape: a gas takes the shape of its container and fills it uniformly. If the shape of the container changes, so does the shape of the gas. Gases
More informationCh10.4 Attractive Forces
Ch10.4 Attractive Forces Intermolecular Forces are the forces holding molecules to each other. Solids have strong forces Gases (vapor) have weak forces Intermolecular forces determine the phase of matter.
More informationReal Gases 1. The value of compressibility factor for one mole of a gas under critical states is 1) 3/8 2) 2/3 3) 8/27 4) 27/8 2. an der Waal s equation for one mole of CO2 gas at low pressure will be
More informationChapter 10 Gases Characteristics of Gases Elements that exist as gases: Noble gases, O 2, N 2,H 2, F 2 and Cl 2. (For compounds see table 10.
Chapter 10 Gases 10.1 Characteristics of Gases Elements that exist as gases: Noble gases, O 2, N 2,H 2, F 2 and Cl 2. (For compounds see table 10.1) Unlike liquids and solids, gases expand to fill their
More informationC H E M 1 CHEM 101-GENERAL CHEMISTRY CHAPTER 5 GASES INSTR : FİLİZ ALSHANABLEH
C H E M 1 CHEM 101-GENERAL CHEMISTRY CHAPTER 5 GASES 0 1 INSTR : FİLİZ ALSHANABLEH CHAPTER 5 GASES Properties of Gases Pressure History and Application of the Gas Laws Partial Pressure Stoichiometry of
More informationGases and the Kinetic Molecular Theory
Gases and the Kinetic olecular Theory Importance in atmospheric phenomena, gas phase reactions, combustion engines, etc. 5.1 The hysical States of atter The condensed states liquid and solid The gaseous
More informationCalculate the mass of L of oxygen gas at 25.0 C and 1.18 atm pressure.
142 Calculate the mass of 22650 L of oxygen gas at 25.0 C and 1.18 atm pressure. Volume of a 10'x10'x8' room 1) First, find the MOLES of gas using the ideal gas equation and the information given. 2) Convert
More informationB 2, C 2, N 2. O 2, F 2, Ne 2. Energy order of the p 2p and s 2p orbitals changes across the period.
Chapter 11 Gases Energy order of the p p and s p orbitals changes across the period. Due to lower nuclear charge of B, C & N there is no s-p orbitals interaction Due to high nuclear charge of O, F& Ne
More informationGeneral Properties of Gases
Page III-9-1 / Chapter Nine Lecture Notes Gases and Their Properties Chapter 9 Importance of Gases Chemistry 222 Professor Michael Russell Airbags fill with N 2 gas in an accident. Gas is generated by
More informationLecture Presentation. Chapter 10. Gases. James F. Kirby Quinnipiac University Hamden, CT Pearson Education, Inc.
Lecture Presentation Chapter 10 James F. Kirby Quinnipiac University Hamden, CT Characteristics of Physical properties of gases are all similar. Composed mainly of nonmetallic elements with simple formulas
More informationChapter 10. Gases. The Gas Laws
Page 1 of 12 10.1 Characteristics of Gases. Chapter 10. Gases. All substances have three phases; solid, liquid and gas. Substances that are liquids or solids under ordinary conditions may also exist as
More informationPressure. Pressure Units. Molecular Speed and Energy. Molecular Speed and Energy
Pressure is defined as force per unit area. Pressure Pressure is measured with a device called a barometer. A mercury barometer uses the weight of a column of Hg to determine the pressure of gas pushing
More information--Lord Kelvin, May 3rd, 1883
When you can measure what you are speaking about and express it in numbers, you know something about it; but when you cannot measure it, when you cannot express it in numbers, you knowledge is of a meager
More informationINTRODUCTORY CHEMISTRY Concepts and Critical Thinking Seventh Edition by Charles H. Corwin
Lecture INTRODUCTORY CHEMISTRY Concepts and Critical Thinking Seventh Edition by Charles H. Corwin Gases by Christopher G. Hamaker Illinois State University Properties of Gases There are five important
More informationProperties of Gases. Properties of Gases. Pressure. Three phases of matter. Definite shape and volume. solid. Definite volume, shape of container
Properties of Gases Properties of Gases Three phases of matter solid Definite shape and volume liquid Definite volume, shape of container gas Shape and volume of container Properties of Gases A gas is
More informationImportance of Gases Airbags fill with N gas in an accident. Gas is generated by the decomposition of sodium azide, NaN.
Gas Laws Importance of Gases Airbags fill with N 2 gas in an accident. Gas is generated by the decomposition of sodium azide, NaN 3. 2 NaN 3 (s) 2 Na (s) + 3 N 2 (g) 2 Importance of Gases C 6 H 12 O 6
More informationUnit 08 Review: The KMT and Gas Laws
Unit 08 Review: The KMT and Gas Laws It may be helpful to view the animation showing heating curve and changes of state: http://cwx.prenhall.com/petrucci/medialib/media_portfolio/text_images/031_changesstate.mov
More informationSlide 1 / A gas at a pressure of 10.0 Pa exerts a force of N on an area of 5.5 m 2 A 55 B 0.55 C 5.5 D 1.8 E 18
Slide 1 / 76 1 A gas at a pressure of 10.0 Pa exerts a force of N on an area of 5.5 m 2 A 55 B 0.55 C 5.5 D 1.8 E 18 Slide 2 / 76 2 A pressure of 1.00 atm is the same as a pressure of of mm Hg. A 193 B
More informationCHEM1100 Summary Notes Module 2
CHEM1100 Summary Notes Module 2 Lecture 14 Introduction to Kinetic Theory & Ideal Gases What are Boyle s and Charles Laws? Boyle s Law the pressure of a given mass of an ideal gas is inversely proportional
More informationIdeal Gas & Gas Stoichiometry
Ideal Gas & Gas Stoichiometry Avogadro s Law V a number of moles (n) V = constant x n Constant temperature Constant pressure V 1 /n 1 = V 2 /n 2 Ammonia burns in oxygen to form nitric oxide (NO) and water
More informationChapter 10. Gases. Chemistry, The Central Science, 10th edition Theodore L. Brown; H. Eugene LeMay, Jr.; and Bruce E. Bursten
Chemistry, The Central Science, 10th edition Theodore L. Brown; H. Eugene LeMay, Jr.; and Bruce E. Bursten Chapter 10 John Bookstaver St. Charles Community College St. Peters, MO 2006, Prentice Hall, Inc.
More informationPart One: The Gas Laws. gases (low density, easy to compress)
CHAPTER FIVE: THE GASEOUS STATE Part One: The Gas Laws A. Introduction. 1. Comparison of three states of matter: fluids (flow freely) solids condensed states liquids (high density, hard to compress) gases
More informationCh 6 Gases 6 GASES. Property of gases. pressure = force/area
6 GASES Gases are one of the three states of matter, and while this state is indispensable for chemistry's study of matter, this chapter mainly considers the relationships between volume, temperature and
More information12.2. The Ideal Gas Law. Density and Molar Mass of Gases SECTION. Key Terms
SECTION 12.2 The Ideal Gas Law You have related the combined gas law to Avogadro s volume-mole gas relationship using two sets of conditions. This enabled you to make calculations of pressure, temperature,
More informationBoyle s law states the relationship between the pressure and the volume of a sample of gas.
The Ideal Gas Law Boyle s law states the relationship between the pressure and the volume of a sample of gas. Charles s law states the relationship between the volume and the absolute temperature of a
More informationChapter 10 Notes: Gases
Chapter 10 Notes: Gases Watch Bozeman Videos & other videos on my website for additional help: Big Idea 2: Gases 10.1 Characteristics of Gases Read p. 398-401. Answer the Study Guide questions 1. Earth
More informationHood River Valley High
Chemistry Hood River Valley High Name: Period: Unit 7 States of Matter and the Behavior of Gases Unit Goals- As you work through this unit, you should be able to: 1. Describe, at the molecular level, the
More informationThis should serve a s a study guide as you go on to do the problems in Sapling and take the quizzes and exams.
CHM 111 Chapter 9 Worksheet and Study Guide Purpose: This is a guide for your as you work through the chapter. The major topics are provided so that you can write notes on each topic and work the corresponding
More information1. What is the value of the quantity PV for one mole of an ideal gas at 25.0 C and one atm?
Real Gases Thought Question: How does the volume of one mole of methane gas (CH4) at 300 Torr and 298 K compare to the volume of one mole of an ideal gas at 300 Torr and 298 K? a) the volume of methane
More informationExam 1. Remember to refer to the Periodic Table handout that is separate from this exam copy.
001 version last name first name signature McCord CH301 unique: 49885 TTh 9:30 am - 11 am Exam 1 Sep 17, 2018 Monday 7:30-9:00 PM A - Mi in BUR 106 Mo - Z in JES A121A Remember to refer to the Periodic
More informationProperties of Gases. Occupy the entire volume of their container Compressible Flow readily and mix easily Have low densities, low molecular weight
Chapter 5 Gases Properties of Gases Occupy the entire volume of their container Compressible Flow readily and mix easily Have low densities, low molecular weight Atmospheric Pressure Atmospheric pressure
More informationUnit Outline. I. Introduction II. Gas Pressure III. Gas Laws IV. Gas Law Problems V. Kinetic-Molecular Theory of Gases VI.
Unit 10: Gases Unit Outline I. Introduction II. Gas Pressure III. Gas Laws IV. Gas Law Problems V. Kinetic-Molecular Theory of Gases VI. Real Gases I. Opening thoughts Have you ever: Seen a hot air balloon?
More informationTest Bank for Chemistry 9th Edition by Zumdahl
Test Bank for Chemistry 9th Edition by Zumdahl 1. Gases generally have A) low density B) high density C) closely packed particles D) no increase in volume when temperature is increased E) no decrease in
More informationKINETIC MOLECULAR DESCRIPTION OF THE STATES OF MATTER
KINETIC MOLECULAR DESCRIPTION OF THE STATES OF MATTER CHAPTER 9 The Gaseous State CHAPTER 10 Solids, Liquids, and Phase Transitions CHAPTER 11 Solutions 392 Gas Liquid Solid 9 THE GASEOUS STATE 9.1 The
More informationChapter 5 Gases and the Kinetic-Molecular Theory
Chapter 5 Gases and the Kinetic-Molecular Theory Name (Formula) Methane (CH 4 ) Ammonia (NH 3 ) Chlorine (Cl 2 ) Oxygen (O 2 ) Ethylene (C 2 H 4 ) Origin and Use natural deposits; domestic fuel from N
More informationGases 5-1. Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
Gases 5-1 Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display. An Overview of the Physical States of Matter The Distinction of Gases from Liquids and Solids 1. Gas
More informationThe Gas Laws. Types of Variation. What type of variation is it? Write the equation of the line.
The Gas Laws 1) Types of Variation 2) Boyle's Law + P V Investigation 3) Charles' Law + T V Thought Lab 4) Lussac's Law + T P Investigation 5) The Combined Gas Law 6) Avogadro and the Universal Gas Law
More informationWhy study gases? A Gas 10/17/2017. An understanding of real world phenomena. An understanding of how science works.
Kinetic Theory and the Behavior of Ideal & Real Gases Why study gases? n understanding of real world phenomena. n understanding of how science works. Gas Uniformly fills any container. Mixes completely
More informationAll gases display distinctive properties compared with liquid or solid. Among them, five properties are the most important and listed below:
CHEM 1111 117 Experiment 8 Ideal gas Objective: 1. Advance core knowledge of ideal gas law; 2. Construct the generator to produce gases; 3. Collect the gas under ambient temperature. Introduction: An ideal
More information10/15/2015. Why study gases? An understanding of real world phenomena. An understanding of how science works.
0/5/05 Kinetic Theory and the Behavior of Ideal & Real Gases Why study gases? An understanding of real world phenomena. An understanding of how science works. 0/5/05 A Gas fills any container. completely
More information