Fractionation in Infrared Dark Cloud Cores

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1 15N Fractionation in Infrared Dark Cloud Cores Shaoshan (Sandy) Zeng, Izaskun Jiménez-Serra, Giuliana Cosentino, Serena Viti, Ashley Barnes, Jonathan Henshaw, Paola Caselli, Francesco Fontani, Piere Hily-Blant Zeng et al A&A 603, A22 arxiv: NITROGEN FRACTIONATION IN SPACE Niels Bohr Institute and Centre for Star and Planet Formation at University of Copenhagen 2017 November 8-9

2 Nitrogen fractionation Interstellar ratios spread in a wide range! Origin of N-fractionation is poorly constrained! The 14 N/ 15 N isotopic ratio has been measured across different astronomical environments: o o o o Small Solar System bodies e.g. comets, meteorites, interplanetary dust particles (IDPs) (Bockelée-Morvan et al. 2008, Manfroid et al. 2009, Floss et al. 2006, Alexander et al. 2007) Protoplanetary disks and Planets (Junk & Svec 1958, Hoffman et al. 1979, Fouchet et al. 2004, Wong et al. 2013, Guzmán et al. 2017) Low-mass prestellar/starless cores and protostars (Lis et al. 2010; Bizzocchi et al. 2013; Hily-Blant et al. 2013, Wampfler et al. 2014) High-mass regions with relatively active star-forming activities (Adande & Ziurys 2012, Fontani et al. 2015, Colzi et al. 2017)

3 Nitrogen fractionation The Birthplace of our Solar System? Most likely a high-mass star cluster containing at least 1000 stars with a few massive stars. (Adams+2010; Dukes & Krumholz 2012; Pfalzner+2013) Nitrogen chemistry depends on the temperature and density of the primordial gas in the parental cloud (Roueff et al. 2015) IRDCs cores show T kin 5-10 K + Densities ~ a factor of 10 higher than low-mass regions Establish how N-fractionation is transferred from the pristine conditions to the subsequent stages of planetary system formation Dependence of N-fractionation on T kin and density

4 IRDCs: general properties Infrared Dark Clouds (IRDCs) o Observed against the bright diffuse emission at mid-ir wavelength o Cores = coldest and densest region within Giant Molecular Clouds o Physical conditions resembling the early stages of the Solar System formation o T kin = K (Pillai et al. 2006) o n H 10 5 cm -3 (Bulter & Tan 2012) o H 2 column densities > cm -2 (Av~100 mag) (Kainulainen & Tan 2013) IRDCs o Size ~ few pc o Mass ~ few 1000M IRDC compact cores o Size ~ 0.5 pc o Mass ~ 100 M o Active/Star-forming (masers/mid-ir/uc HIIs) o Intermediate o Quiescent/Starless (Chambers et al. 2009, Rathborne et al. 2010)

5 IRDCs: our sample C Ø Selected from the IRDCs sample studied by Rathborne et al Mass surface density maps of targeted clouds and cores (Butler & Tan, 2012) Ø 10 of these clouds (studied in Bulter & Tan 2012) are selected with different morphologies and with different levels of starformation activity based on the detection of 24µm and 8µm sources Ø 4 IRDCs are targeted in this study: G H F

6 IRAM-30m telescope Observation & Analysis o GILDAS-CLASSsoftware package o Assuming LTE conditions and optically thin emission, T ex = 15K o Adopting Galactic gradient of 12 C/ 13 C ratio infer from CN (Milam et al. 2005) H 13 CN HN 13 C HCN HNC HC 15 N H 15 NC 12 C/ 13 C ratio calculated for each targeted IRDC regarding their galactocentric distance: Examples of molecular spectra (Zeng et al. 2017)

7 No correlation between HCN and HNC isotopologues and level of star formation in IRDCs cores Active Intermediate Quiescent N/A Cloud C Cloud F Cloud G Cloud H N tot (HC 15 N) [10 11 cm -2 ] N tot (H 13 CN) [10 12 cm -2 ] (Zeng et al. 2017)

8 No correlation between HCN and HNC isotopologues and level of star formation in IRDCs cores Active Intermediate Quiescent N/A Cloud C Cloud F Cloud G Cloud H N tot (H 15 NC) [10 11 cm -2 ] N tot (HN 13 C) [10 12 cm -2 ] (Zeng et al. 2017)

9 Comparison: literature studies HCN: ~ HNC: ~ ~ 541 Terrestrial Atmosphere (TA) = 272 (Junk & Svec 1958) Proto-solar Nebula (PSN) = 440 (Marty et al. 2011) Propose idea: Density of the parental molecular gas may be the governing parameter of nitrogen fractionation in IRDCs Cloud G shows relatively low 14 N/ 15 N ratio (70 293) compared to other IRDCs. Properties of Cloud G itself o Least massive o Lowest gas density o Most diffuse o No trace of starformation activity (Zeng et al. 2017)

10 Comparison: chemical model Model predictions: (Roueff et al. 2015) o T = 10 K o n H = 2 x 10 5 cm -3 o Significant 13 C depletion at evolution time ~ 1M yrs Ø Up to a factor of 2 difference depends on the molecule Ø We are using 12 C/ 13 C ratio inferred from CN to derive 14 N/ 15 N in HCN and HNC isotopologues Ø Affect our derived 14 N/ 15 N? Ø Misleading conclusion on nitrogen fractionation in IRDCs?

11 Comparison: chemical model Ø Direct measurement on HCN and its 15 N isotopologue Core HCN HC N/ 15 N N H 13 HC G1 43±9 70±28 CN 15 G3 67±3 181±54 N H2 282±5 366±132 H3 263±49 458±98 H4 121±24 142±34 H5 259±57 395±97 Ø Results: 14 N/ 15 N ratios are either consistent, or lower than those measured from the 13 C isotopologues Model predictions: (Roueff et al. 2015) o T = 10 K o n H = 2 x 10 5 cm -3 o Significant 13 C depletion at evolution time ~ 1M yrs Our Case for IRDCs: o T = K (Pillai+2006) o n H 10 5 cm -3 (Bulter & Tan 2012) o Time-scale for IRDC cores 10 5 yrs (Kong et al. 2017) i) Time-scales (age) of IRDCs cores ii) Kinetic temperature of the gas within IRDCs

12 Perspective Measuring the nitrogen fractionation as a function of Galactocentric distance using Planck Galactic cold clumps (PGCCs) Ø Single-dish observations with IRAM 30m telescope Ø Sample of dense PGCCs distributed across the Galactic disk (Zahorecz et al. 2016) Ø Tracers: N 2 H +, CN, and HNC and their 15 N isotopologues 1. To estimate the 14 N/ 15 N ratio and its gradient in the Galaxy using different N-bearing species 2. Provide an insight into the chemical fractionation of Nitrile- (CN) and Hydride-(NH) bearing molecules

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