Analytical Approaches to Arsenic
|
|
- Phyllis Cole
- 6 years ago
- Views:
Transcription
1 Analytical Approaches to Arsenic (and Selenium) Analysis in Foods Brian Jackson Trace Element Analysis Core Dartmouth College
2 Arsenic in food
3 Arsenic levels in rice and rice products FDA data WHO data Frequency Inorganic arsenic concentration (ppb)
4 FDA proposes action level for As in juice 10 µg/l inorganic arsenic
5 Food analysis 0.25 g sample 2.5 ml optima acid HNO 3 or 9:1 HNO 3 :HCl 15 min ramp 20 min 200C Dilute final sample to 25 ml 100-fold dilution Collision or reaction cell ICP-MS
6 What affects arsenic and selenium analysis by ICP-MS? Polyatomic Interferences As, m/z 75, Se, 77,78, 80, 82 ArCl, CaCl, ArAr Solved by collision and reaction cell ICP-MS Matrix effects Low molecular weight organics cause dramatic sensitivity increases for As and Se. Doubly-charged ions ICP-MS actually measures m/z ratio, but we assume that z = 1. Elements at twice the mass of the analyte can interfere if they form 2+ ions in the plasma Mass 150 = samarium, neodymium Mass 156 = gadolinium
7 Sensitivity enhancement for As and Se Dramatic increase in ICP-MS response for As and Se in the presence of low molecular weight organics Well known effect, used to advantage in chromatography to increase ICP-MS sensitivity by adding methanol to mobile phase. Larsen and Sturup, J. Anal. Atom. Spectrom Add methane to carrier/makeup as optional gas
8 Overcoming the sensitivity effect Add a swamping amount of C to the samples or the sample introduction system. Methane as a optional gas 5% Butanol or IPA to the internal standard mixture Use an appropriate internal standard Te or Ge Matrix match standards or standard additions calibration
9 Analysis of diluted apple juice Internal standard External calibration Standard addition As value RSD As value RSD None % % Rh % % Te % % Ge % %
10 Selenium analysis in NIST 1849a Adult/infant nutritional formula
11 Doubly-charged ions 42 nd in crustal abundance* 7.4% abundant at m/z 150 Arsenic: 0.06 ± ppm Selenium: ± ppm Neodymium: 7 ppm Samarium: 1 ppm Gadolinium:1 ppm Collected from Peach County, GA 33 rd in crustal abundance* 5.6% abundant at m/z 150 * Arsenic is 46 th in crustal abundance Arsenic: ± ppm Selenium: ± ppm Neodymium:17 ppm Samarium: 3 ppm Gadolinium: 3 ppm Collected from PA fruit orchards
12 Collision (KED) and reaction cells Kinetic energy discrimination (use He as collision gas) Polyatomics lose more energy than analyte ions and do not leave the cell. Analytes suffer some sensitivity loss at high gas flow. Reaction cells use reactive gases Reaction gas reacts with interferent to remove it from m/z of analyte Reaction gas reacts with analyte to shift it to new m/z free of interferences
13 Doubly charged REEs in collision cell ICP-MS Arsenic Selenium
14 Doubly charged REEs in H 2 reaction cell ICP-MS Arsenic Selenium
15 Summary statistics and quantitative analysis of apple and peach leaves by He and H2 modes Arsenic KED-He reaction-h 2 Summary statistics Certified (mg/kg) uncorrected corrected uncorrected corrected Peach ± ± % doubly charged ± ± Detection limits ± Apple ± Nd ± Sm ± Gd As IDL ± (ppb) Se IDL (ppb) ± He -4.5 ml/min H 2-6 ml/min Selenium Peach ± ± ± ± n.a. Apple ± ± ± ± n.a.
16 O 2 as a reaction gas using QQQ -ICP-MS 40 Ar 35 Cl + 40 Ca 35 Cl Nd ++ /Sm As + 91 Zr Reaction gas (O 2 ) 40 Ar 35 Cl +, 40 Ca 35 Cl +, Nd ++ /Sm As 16 O + 94 SeO + 91 Zr + Q1 set to m/z 75, so rejects all ions except m/z Zr at mass 91 is rejected 75 As 91 AsO + 78 Se 94 SeO + As + reacts with O 2 cell gas to form AsO + product ion. 40 Ar 35 Cl +, 40 Ca 35 Cl +, Nd ++ /Sm ++ don t react and stay at m/z 75 Q2 set to m/z 91, AsO + product ion mass rejects original on-mass interferences Q1 set to m/z 78, so rejects all ions except m/z Zr/Mo at mass 94 is rejected Se + reacts with O 2 cell gas to form SeO + product ion. 40 Ar 38 Ar +, 40 Ca 35 Cl +, Gd ++ /Dy ++ don t react and stay at m/z 78 Q2 set to m/z 94, SeO + product ion mass rejects original on-mass interferences
17 Summary statistics and quantitative analysis of apple and peach leaves by O 2 modes 75 -> 91 As [ O2 ] 78 -> 94 Se [ O2 ] measured % doubly charged % recovery Certified Detection limits Certified (mg/kg) measured % recovery NIST 1515, Apple 0.038± Nd/Sm Gd As IDL ± (ppb) Se 0.053± IDL (ppb) leaves ± NIST 1547, Peach O ml/min n.a. ± ± ± Leaves 0.06 ± 0.018
18 Summary Collision cell and reaction cell ICP-MS effectively reduce polyatomic interferences for As and Se analysis in foods Standard additions, additional organic modifier and use of Ge or Te can normalize sensitivity differences due to food sample matrix Collision cell ICP-MS is not effective for doubly charged ions Reaction cell technology is effective H 2 or O 2 for Se O 2 for As QQQ-ICP-MS provides low detection limits and no interferences
19 Acknowledgements
Basic and Application Inductively coupled plasma mass spectrometry (ICPMS)
Basic and Application Inductively coupled plasma mass spectrometry (ICPMS) 2 What is ICP MS Inductively coupled plasma mass spectrometry (ICP-MS) is a type of mass spectrometry which is capable of detecting
More informationIMPROVING DATA QUALITY WITH ADVANCED INSTRUMENTATION UTILIZING MULTIPLE INTERFERENCE REDUCTION TECHNOLOGIES
DoD Environmental Data Quality Workshop, St. Louis, MO IMPROVING DATA QUALITY WITH ADVANCED INSTRUMENTATION UTILIZING MULTIPLE INTERFERENCE REDUCTION TECHNOLOGIES Jamie Fox Brooks Applied Labs www.brooksapplied.com
More informationDetermination of Chromium in Gelatin Capsules using an Agilent 7700x ICP-MS
Determination of Chromium in Gelatin Capsules using an Agilent 7700x ICP-MS Application note Pharmaceutical Authors Miao Jing, Yingping Ni, Yanping Wang and Zhixu Zhang Agilent Technologies, China Introduction
More informationMulti-Element Analysis of Cannabis using the Agilent 7800 ICP-MS
Authors Multi-Element Analysis of Cannabis using the Agilent 7800 ICP-MS Application Note Food safety Craig Jones and Jenny Nelson Agilent Technologies, USA Introduction In the U.S., marijuana remains
More informationAdvances in Interference Removal for Accurate Arsenic Analysis in Food and Beverages
Advances in Interference Removal for Accurate Arsenic Analysis in Food and Beverages National Environmental Monitoring Conference 2013 Austin TX Steve Wilbur and Amir Liba Agilent Technologies Let s Define
More informationThermo Scientific icap TQ ICP-MS: Typical limits of detection
TECHNICAL NOTE 43287 Thermo Scientific icap TQ ICP-MS: Typical limits of detection Authors Tomoko Vincent Keywords BEC, LOD, SQ-KED, TQ mass shift, TQ on mass, typical performance Introduction Inductively
More informationAccurate measurement of elemental impurities in metals and metal alloys using the Thermo Scientific icap TQ ICP-MS
APPLICATION NOTE 434 Accurate measurement of elemental impurities in metals and metal alloys using the Thermo Scientific icap TQ ICP-MS Authors Introduction Marcus Manecki, Daniel Kutscher, Shona McSheehy
More informationEnhancing the productivity of food sample analysis with the Agilent 7700x ICP-MS
Enhancing the productivity of food sample analysis with the Agilent 77x ICP-MS Application note Foods testing Authors Sebastien Sannac, Jean Pierre Lener and Jerome Darrouzes Agilent Technologies Paris,
More informationComparing Collision/Reaction Cell Modes for the Measurement of Interfered Analytes in Complex Matrices using the Agilent 7700 Series ICP-MS
Comparing Collision/Reaction Cell Modes for the Measurement of Interfered Analytes in Complex Matrices using the Agilent 7700 Series ICP-MS Technical Overview Abstract Inductively coupled plasma mass spectrometry
More informationTrace elemental analysis of distilled alcoholic beverages using the Agilent 7700x ICP-MS with octopole collision/ reaction cell
Trace elemental analysis of distilled alcoholic beverages using the Agilent 77x ICP-MS with octopole collision/ reaction cell Application note Food testing Author Glenn Woods Agilent Technologies Cheadle
More informationRapid, simple, interference-free analysis of environmental samples using the XSERIES 2 ICP-MS with 3 rd generation CCT ED
Application Note: 40852 Rapid, simple, interference-free analysis of environmental samples using the XSERIES 2 ICP-MS with 3 rd generation CCT ED - Interference-free analysis of 29 elements in environmental
More informationAnalysis of Arsenic, Selenium and Antimony in Seawater by Continuous-Flow Hydride ICP-MS with ISIS
ICP-MS Environmental Analysis of Arsenic, Selenium and Antimony in Seawater by Continuous-Flow Hydride ICP-MS with ISIS Application Note Steve Wilbur Analysis of arsenic and selenium in seawater at trace
More informationSimple, reliable analysis of high matrix samples according to US EPA Method 6020A using the Agilent 7700x/7800 ICP-MS
Simple, reliable analysis of high matrix samples according to US EPA Method 6020A using the Agilent 7700x/7800 ICP-MS Application note Environmental Authors Steve Wilbur, Craig Jones Agilent Technologies,
More informationKey Analytical Issues: Sample Preparation, Interferences and Variability. Tim Shelbourn, Eli Lilly and Company
Key Analytical Issues: Sample Preparation, Interferences and Variability Tim Shelbourn, Eli Lilly and Company Presentation Outline Sample preparation objectives and challenges Some common interferences
More informationAnalysis of Trace Metal Impurities in High Purity Hydrochloric Acid Using ICP-QQQ
Application Note Semiconductor Analysis of Trace Metal Impurities in High Purity Hydrochloric Acid Using ICP-QQQ Authors Kazuo Yamanaka and Kazuhiro Sakai Agilent Technologies, Japan Introduction Hydrochloric
More informationAccurate Analysis of Trace Mercury in Cosmetics using the Agilent 8900 ICP-QQQ
Application Note Consumer products Accurate Analysis of Trace Mercury in Cosmetics using the Agilent 8900 ICP-QQQ Effective removal of tungsten-based interferences on five Hg isotopes using MS/MS Authors
More informationThermo Scientific icap RQ ICP-MS: Typical limits of detection
TECHNICAL NOTE 43427 Thermo Scientific icap RQ ICP-MS: Typical limits of detection Author Tomoko Vincent Keywords BEC, interference removal, KED, LOD Introduction Inductively Coupled Plasma Mass Spectrometry
More informationRapid Analysis of High-Matrix Environmental Samples Using the Agilent 7500cx ICP-MS. Application. Author. Abstract. Introduction.
Rapid Analysis of High-Matrix Environmental Samples Using the Agilent 7500cx ICP-MS Application Environmental Author Steven Wilbur Agilent Technologies, Inc. 3380 146th Place, SE, Suite 300 Bellevue, WA
More informationImplementing EPA Method 6020 with the Agilent ICP-MS Portfolio
Implementing EPA Method 6020 with the Agilent ICP-MS Portfolio NEMC August 2018 Craig Jones Applications Specialist ICP-MS, ICP-MS/MS The Agilent Atomic Spectroscopy Lineup An Instrument for Any Application!
More informationDetermination of trace elements in ultrapure semiconductor grade sulfuric acid using the Agilent 8900 ICP-QQQ in MS/MS mode
Determination of trace elements in ultrapure semiconductor grade sulfuric acid using the Agilent 8900 ICP-QQQ in MS/MS mode Application note Semiconductor Authors Michiko Yamanaka, Kazuo Yamanaka and Naoki
More informationOutsmart Interferences with Triple Quadrupole ICP-MS. The world leader in serving science
Outsmart Interferences with Triple Quadrupole ICP-MS The world leader in serving science ICP-MS Performance for All Applications Thermo Scientific TM NEPTUNE TM Plus MC-ICP-MS Multicollector ICP-MS Thermo
More informationLead isotope analysis: Removal of 204 Hg isobaric interference from 204 Pb using ICP-QQQ in MS/MS mode
Lead isotope analysis: Removal of Hg isobaric interference from using ICP-QQQ in MS/MS mode Application note Authors Geochemistry and isotope analysis Glenn Woods Agilent Technologies, LDA UK Ltd., Stockport,
More informationAgilent ICP-MS. Fundamentals of ICP-MS Analysis and Its Applications for Low Level Elemental Determination in Cannabis
Agilent ICP-MS Fundamentals of ICP-MS Analysis and Its Applications for Low Level Elemental Determination in Cannabis High Sample Matrix Tolerance Superior & Simple Interference Removal Ultra Wide Linear
More informationicap TQ ICP-MS Applications Compendium
icap TQ ICP-MS Applications Compendium The best things come in threes The development of inductively coupled plasma - mass spectrometry (ICP-MS), followed by the introduction of the first commercial instruments
More informationThe Agilent 7700x ICP-MS Advantage for Drinking Water Analysis
The Agilent 77x ICP-MS Advantage for Drinking Water Analysis Application Note Environmental Authors Steve Wilbur Agilent Technologies, Inc. 338 146th Place SE, Suite 3, Bellevue Washington, 987 USA Introduction
More informationFergus Keenan Shona McSheehy Julian Wills
Novel QCell Technology for Inference Removal in ICP-MS - Combining Low Mass Filtration with Kinetic Energy Discrimination Fergus Keenan Shona McSheehy Julian Wills 1 The world leader in serving science
More informationUnmatched Removal of Spectral Interferences in ICP-MS Using the Agilent Octopole Reaction System with Helium Collision Mode Application
Unmatched Removal of Spectral Interferences in ICP-MS Using the Agilent Octopole Reaction System with Helium Collision Mode Application Metals Analysis Authors Ed McCurdy, Glenn Woods and Don Potter Agilent
More informationFundamentals of the ICP-MS Technique and How to Resolve Issues for Pharmaceutical Materials (In 20 Minutes) Tim Shelbourn, Eli Lilly and Company
Fundamentals of the ICP-MS Technique and How to Resolve Issues for Pharmaceutical Materials (In 20 Minutes) Tim Shelbourn, Eli Lilly and Company Why ICP Mass Spectrometry? Ultra-trace multi-element analytical
More informationTotal Elemental Analysis of Food Samples for Routine and Research Laboratories, using the Thermo Scientific icap RQ ICP-MS
Total Elemental Analysis of Food Samples for Routine and Research Laboratories, using the Thermo Scientific icap RQ ICP-MS Tomoko Vincent 1, Simon Lofthouse 2, Daniel Kutscher 1 and Shona McSheehy Ducos
More informationThe ultratrace determination of iodine 129 in aqueous samples using the 7700x ICP-MS with oxygen reaction mode
The ultratrace determination of iodine in aqueous samples using the 7700x ICP-MS with oxygen reaction mode Application note Nuclear Authors Kazumi Nakano, Yasuyuki Shikamori, Naoki Sugiyama and Shinichiro
More informationRapid determination of five arsenic species in polished rice using HPLC-ICP-MS
Rapid determination of five arsenic species in polished rice using HPLC-ICP-MS Application note Food safety Authors Bing Yue China National Center For Food Safety Risk Assessment, Beijing, China Juane
More informationTrace Analyses in Metal Matrices Using the ELAN DRC II
www.perkinelmer.com Trace Analyses in Metal Matrices Using the ELAN DRC II Introduction Analyses of matrices containing high levels of metals present a challenge for ICP-MS. First, the concentrations of
More informationLow Level Detection of Priority Inorganic Pollutants in Water. Anthony Neumann, MSc Darren Crichton, BSc
Low Level Detection of Priority Inorganic Pollutants in Water Anthony Neumann, MSc Darren Crichton, BSc Priority List of Pollutants Consists of 16 metals and/or transitional elements. Enter the human food
More informationAgilent 8800 Triple Quadrupole ICP-MS: Understanding oxygen reaction mode in ICP-MS/MS
Agilent 8800 Triple Quadrupole ICP-MS: Understanding oxygen reaction mode in ICP-MS/MS Agilent 8800 ICP-QQQ Technical Overview Introduction The use of oxygen as a reaction gas for the removal of interferences
More informationHigh Throughput Water Analysis using Agilent 7900 ICP-MS coupled with ESI prepfast
High Throughput Water Analysis using Agilent 7900 ICP-MS coupled with ESI prepfast Application Note Environmental Authors Austin Schultz and Jake Unnerstall, Elemental Scientific, Omaha NE, USA Steve Wilbur,
More informationICP/MS Multi-Element Standards
Standards Ultra Pure Matrix Special Packaging Traceability to National Reference Materials AccuStandard s ICP/MS Standards are formulated to meet the needs of this very special instrument. As matrix effect
More informationSemiquantitative Screening of Pharmaceutical Antiviral Drugs using the Agilent 7500ce ICP-MS in Helium Collision Mode
Semiquantitative Screening of Pharmaceutical Antiviral Drugs using the Agilent 7500ce ICP-MS in Helium Collision Mode Application Note Pharmaceutical Authors Rebeca Santamaria-Fernandez, SheilaMerson,
More informationApplications of ICP-MS for Trace Elemental Analysis in the Hydrocarbon Processing Industry
Applications of ICP-MS for Trace Elemental Analysis in the Hydrocarbon Processing Industry Fundamentals and Applications to the Petrochemical Industry Outline Some background and fundamentals of ICPMS
More informationSample Analysis Design PART III
Sample Analysis Design PART III Sample Analysis Design Generating high quality, validated results is the primary goal of elemental abundance determinations It is absolutely critical to plan an ICP-MS analysis
More informationA Comparison of Arsenic Speciation
A Comparison of Arsenic Speciation Methods for Biological Tissues Tamas Ugrai (tamas@brooksrand.com) Authors: T. Ugrai, T. Ellis, M. Nguyen, P. Petrov, J. Creswell, A. Carter, and M. Briscoe Brooks Rand
More informationDetermination of Trace Metals in Human Urine Using the NexION 300 ICP-MS
application Note ICP Mass Spectrometry Authors: David Bass Daniel Jones PerkinElmer, Inc. Shelton, CT USA Determination of Trace Metals in Human Urine Using the NexION 300 ICP-MS Abstract This application
More informationApplication note. Trace level analysis of sulfur, phosphorus, silicon and chlorine in NMP using the Agilent 8800 Triple Quadrupole ICP-MS
Trace level analysis of sulfur, phosphorus, silicon and chlorine in NMP using the Agilent 8800 Triple Quadrupole ICP-MS Application note Semiconductor Author Naoki Sugiyama Agilent Technologies, Tokyo,
More informationAnalysis of high matrix samples using argon gas dilution with the Thermo Scientific icap RQ ICP-MS
TECHNICAL NOTE 4322 Analysis of high matrix samples using argon gas dilution with the Thermo Scientific icap RQ ICP-MS Keywords Argon gas dilution, AGD, High matrix samples, Seawater Goal To critically
More informationHandling Interferences in the Modern Laboratory with Advanced Triple Quadrupole ICP-MS Technology
Handling Interferences in the Modern Laboratory with Advanced Triple Quadrupole ICP-MS Technology Shona McSheehy Ducos The world leader in serving science Elemental Analysis What are you trying to accomplish?
More informationAgilent 8900 Triple Quadrupole ICP-MS
Agilent 8900 Triple Quadrupole ICP-MS Technical Overview Introduction Agilent is the worldwide market leader in quadrupole ICP-MS, and the only supplier of triple quadrupole ICP-MS (ICP-QQQ). Introduced
More informationSample Analysis Design PART II
Sample Analysis Design PART II Sample Analysis Design Generating high quality, validated results is the primary goal of elemental abundance determinations It is absolutely critical to plan an ICP-MS analysis
More informationSpeciation of Bromine Compounds in Ozonated Drinking Water using Ion Chromatography and Inductively Coupled Plasma Mass Spectrometry
APPLICATION NOTE Speciation of Bromine Compounds in Ozonated Drinking Water using Ion Chromatography and Inductively Coupled Plasma Mass Spectrometry AN43227 Antonella Guzzonato 1, Shona McSheehy Ducos
More informationDISCLAIMER: This method:
Inorganic arsenic determination in fresh mussels using water bath extraction and anion exchange chromatography-inductively coupled plasma mass spectrometry DISCLAIMER: This method: - has to be considered
More informationLow Level Detection of Priority Inorganic Pollutants in Groundwater By Darren Crichton and Anthony Neumann
Low Level Detection of Priority Inorganic Pollutants in Groundwater By Darren Crichton and Anthony Neumann Abstract Introduction: Arsenic, selenium, vanadium and chromium are identified in the Priority
More informationApplication note. Accurate determination of sulfur in biodiesel using Isotope Dilution-Triple Quadrupole ICP-MS (ID-ICP-QQQ) Petrochemical
Accurate determination of sulfur in biodiesel using Isotope Dilution-Triple Quadrupole ICP-MS (ID-ICP-QQQ) Application note Petrochemical Author Lieve Balcaen, Frank Vanhaecke 1, Glenn Woods 2, Martín
More informationApplication of the Agilent 7900 ICP-MS with Method Automation function for the routine determination of trace metallic components in food CRMs
Application of the Agilent 7900 ICP-MS with Method Automation function for the routine determination of trace metallic components in food CRMs Application note Authors Food safety Kazuhiro Sakai 1, Junichi
More informationDirect Measurement of Trace Metals in Edible Oils by 7500cx ICP-MS with Octopole Reaction System
Direct Measurement of Trace Metals in Edible Oils by 7500cx ICP-MS with Octopole Reaction System Application Note Foods Author Glenn Woods ICP-MS Specialist Agilent Technologies UK Ltd. Lakeside Business
More informationWilliam O. Moellmer, Theron G. Miller, Steve Wilbur, and Emmett Soffey
32 Spectroscopy 22(1) January 2007 ICP-MS Analysis of Trace Selenium in the Great Salt Lake The Great Salt Lake in Utah is one of the Western Hemisphere s most important migratory bird habitats. Recent
More information1.0 ACCREDITATION / REGISTRATION 2.0 PRODUCT DESCRIPTION 3.0 CERTIFIED VALUES AND UNCERTAINTIES. Assay Information:
1.0 ACCREDITATION / REGISTRATION INORGANIC VENTURES is accredited to ISO Guide 34, "General Requirements for the Competence of Reference Material Producers" and ISO/IEC 17025, "General Requirements for
More informationIntercomparison of Extraction and Analytical Techniques for Inorganic Arsenic in Seaweed
Intercomparison of Extraction and Analytical Techniques for Inorganic Arsenic in Seaweed Ben Wozniak ben@brooksapplied.com www.brooksapplied.com Arsenic Overview Ubiquitous in the environment Exposure
More informationTotal elemental analysis of food samples for routine and research laboratories using the Thermo Scientific icap RQ ICP-MS
APPLICATION NOTE 43326 Total elemental analysis of food samples for routine and research laboratories using the Thermo Scientific icap RQ ICP-MS Authors Introduction Tomoko Vincent1, Simon Lofthouse2,
More information1.0 ACCREDITATION / REGISTRATION 2.0 PRODUCT DESCRIPTION 3.0 CERTIFIED VALUES AND UNCERTAINTIES. Assay Information:
1.0 ACCREDITATION / REGISTRATION INORGANIC VENTURES is accredited to ISO Guide 34, "General Requirements for the Competence of Reference Material Producers" and ISO/IEC 17025, "General Requirements for
More informationAdvanced ICP-MS techniques for overcoming interferences in LA-ICP-MS bioimaging
APPLICATION NOTE 43358 Advanced ICP-MS techniques for overcoming interferences in LA-ICP-MS bioimaging Authors Georgina M. Thyssen 1, Michael Sperling 1,2, Uwe Karst 1, Christoph A. Wehe 3 & Julian D.
More informationDirect Analysis of Trace Metal Impurities in High Purity Nitric Acid Using ICP-QQQ
Application Note Semiconductor Direct Analysis of Trace Metal Impurities in High Purity Nitric Acid Using ICP-QQQ Authors Kazuo Yamanaka and Kazuhiro Sakai Agilent Technologies, Tokyo, Japan Introduction
More informationReal World Analysis of Trace Metals in Drinking Water Using the Agilent 7500ce ICP-MS with Enhanced ORS Technology. Application. Authors.
Real World Analysis of Trace Metals in Drinking Water Using the Agilent 7500ce ICP-MS with Enhanced ORS Technology Part 2 of a 3 part series on Environmental Analysis Application Environmental Authors
More informationSamples compliant with the WATER
ENVIRONMENTAL analysis A routine method for the Quantitative Measurement of trace metals in WATER Samples compliant with the WATER Quality Standard EN ISO 17294 on the Agilent 7000 Series ICP-MS. Solutions
More informationSingle Analyte Custom Grade Solution g/ml (measured at 20 ± 1 ºC) ICP Assay NIST SRM 3103a Lot Number:
1.0 ACCREDITATION / REGISTRATION INORGANIC VENTURES is accredited to ISO Guide 34, "General Requirements for the Competence of Reference Material Producers" and ISO/IEC 17025, "General Requirements for
More informationChina Soil Pollution Survey: Elemental Analysis of Soil and Sediment Digests by ICP-MS
Application Note Environmental China Soil Pollution Survey: Elemental Analysis of Soil and Sediment Digests by ICP-MS Fast, accurate quantitative analysis of 16 elements using an Agilent 7800 ICP-MS with
More informationFlorida State University Libraries
Florida State University Libraries Electronic Theses, Treatises and Dissertations The Graduate School 2013 Accurate and Precise Determination of Low Concentration Iron, Arsenic, Selenium, Cadmium, and
More informationAuthors: C. Derrick Quarles, Jr. *, Patrick Sullivan, M. Paul Field, Hwan Kim, and Daniel R. Wiederin
Elemental Scientific prepfast IC: Inline Autodilution Method to Eliminate Species Interconversion for LC-ICPMS Based Applications Authors: C. Derrick Quarles, Jr. *, Patrick Sullivan, M. Paul Field, Hwan
More informationAdvantages of ICP-QQQ for nuclear waste characterisation
NKS-B ICPM Users seminar, 2017 Advantages of ICP-QQQ for nuclear waste characterisation Phil Warwick University of Southampton GAU-Radioanalytical Laboratories A major provider of radioanalytical expertise
More informationDetermination of challenging elements in ultrapure semiconductor grade sulfuric acid by Triple Quadrupole ICP-MS
Determination of challenging elements in ultrapure semiconductor grade sulfuric acid by Triple Quadrupole ICP-MS Application note Semiconductor Authors Junichi Takahashi Agilent Technologies, Japan Introduction
More informationSimplified workflows for the Thermo Scientific icap TQ ICP-MS
TECHNICAL NOTE 43401 Simplified workflows for the Thermo Scientific icap TQ ICP-MS Authors Marcus Manecki, Dhinesh Asogan Thermo Fisher Scientific Keywords Ease of use, Qtegra ISDS Software, Reaction Finder,
More informationCERTIFICATE OF. Single Analyte Custom Grade Solution. ICP Assay NIST SRM 3120a Lot Number: Calculated NIST SRM Lot Number: See Sec. 4.
300 Technology Drive Christiansburg, VA 24073. USA inorganicventures.com CERTIFICATE OF ANALYSIS tel: 800.669.6799. 540.585.3030 fax: 540.585.3012 info@inorganicventures.com 1.0 ACCREDITATION / REGISTRATION
More informationDartmouth Trace Element Analysis Core: Lab methods
Dartmouth Trace Element Analysis Core: Lab methods General All prices are based on analysis of up to 14 elements of interest to the investigator. More analytes can be included in the run after discussion
More informationProcedures for the determination of stable elements in construction materials from the nuclear reactors at Risø National Laboratory
Risø-R-1548(EN) Procedures for the determination of stable elements in construction materials from the nuclear reactors at Risø National Laboratory Lars Frøsig Østergaard Risø National Laboratory Roskilde
More informationMulti-Element Analysis of Petroleum Crude Oils using an Agilent 7900 ICP-MS
Multi-Element Analysis of Petroleum Crude Oils using an Agilent 7900 ICP-MS Application note Energy and fuels Authors Jenny Nelson, Agilent Technologies, USA Ed McCurdy, Agilent Technologies, UK Introduction
More information1.0 ACCREDITATION / REGISTRATION 2.0 PRODUCT DESCRIPTION 3.0 CERTIFIED VALUES AND UNCERTAINTIES. Assay Information:
1.0 ACCREDITATION / REGISTRATION INORGANIC VENTURES is accredited to ISO Guide 34, "General Requirements for the Competence of Reference Material Producers" and ISO/IEC 17025, "General Requirements for
More informationDeveloping ICP-MS-based methods for regulatory purposes: One example from a contract laboratory
Developing ICP-MS-based methods for regulatory purposes: One example from a contract laboratory Douglas C. Baxter, Emma Engström, Dieke Sörlin, Ilia Rodushkin ALS Scandinavia AB, SE-977 75 Luleå, Sweden
More informationANALYSIS CERTIFICATE OF 1.0 ACCREDITATION / REGISTRATION 2.0 PRODUCT DESCRIPTION 3.0 CERTIFIED VALUES AND UNCERTAINTIES. Assay Information:
300 Technology Drive Christiansburg, VA 24073. USA inorganicventures.com CERTIFICATE OF ANALYSIS tel: 800.669.6799. 540.585.3030 fax: 540.585.3012 info@inorganicventures.com 1.0 ACCREDITATION / REGISTRATION
More informationQuantitative analysis of high purity metals using laser ablation coupled to an Agilent 7900 ICP-MS
Quantitative analysis of high purity metals using laser ablation coupled to an Agilent 7900 ICP-MS Application note Metals Analysis & Production Authors Naoki Sugiyama and Mineko Omori Agilent Technologies,
More information1.0 ACCREDITATION / REGISTRATION 2.0 PRODUCT DESCRIPTION 3.0 CERTIFIED VALUES AND UNCERTAINTIES. Assay Information:
1.0 ACCREDITATION / REGISTRATION INORGANIC VENTURES is accredited to ISO Guide 34, "General Requirements for the Competence of Reference Material Producers" and ISO/IEC 17025, "General Requirements for
More informationLow Level Phosphorus: A Method Comparison Study
Low Level Phosphorus: A Method Comparison Study Katie Adams* Stephanie Le, Theresa McBride, Tom Pearson EPA Region 10 Laboratory August 2012 8/29/2012 1 U.S. Environmental Protection Agency Goal: 1 µg/l
More informationSingle Analyte Mass Spec Solution ± µg/ml g/ml (measured at 20 ± 1 ºC) METHOD NIST SRM# SRM LOT# Calculated See Sec. 4.
1.0 ACCREDITATION / REGISTRATION INORGANIC VENTURES is accredited to ISO Guide 34, "General Requirements for the Competence of Reference Material Producers" and ISO/IEC 17025, "General Requirements for
More informationSample Analysis Design Polyatomic Interferences
Sample Analysis Design Polyatomic Interferences More serious than isobaric interferences Result from possible, short-lived combination of atomic species in the plasma or during ion transfer Common recombinants
More informationThe Determination of Toxic, Trace, and Essential Elements in Food Matrices using THGA Coupled with Longitudinal Zeeman Background Correction
application Note Atomic Absorption Authors David Bass Senior Product Specialist Cynthia P. Bosnak Senior Product Specialist PerkinElmer, Inc. Shelton, CT 06484 USA The Determination of Toxic, Trace, and
More informationAnalysis for Arsenic and Hexavalent Chromium:
Analysis for Arsenic and Hexavalent Chromium: How to avoid false positives and increase data quality www.brooksrand.com Michelle Briscoe, CEO/President Hakan Gürleyük, Technical Director Brooks Rand Labs
More informationValidating performance of an Agilent 7800 ICP MS for USP <232>/<233> & ICH Q3D/Q2(R1): Elemental Impurity Analysis in Pharmaceuticals
Validating performance of an Agilent 7800 ICP MS for USP / & ICH Q3D/Q2(R1): Elemental Impurity Analysis in Pharmaceuticals Authors Lindsey Whitecotton, Ed McCurdy, Craig Jones and Amir Liba
More information1.0 ACCREDITATION / REGISTRATION 2.0 PRODUCT DESCRIPTION 3.0 CERTIFIED VALUES AND UNCERTAINTIES. Assay Information:
1.0 ACCREDITATION / REGISTRATION INORGANIC VENTURES is accredited to ISO Guide 34, "General Requirements for the Competence of Reference Material Producers" and ISO/IEC 17025, "General Requirements for
More informationSingle Analyte Custom Grade Solution ± 4 µg/ml g/ml (measured at 20 ± 1 ºC) Acidimetric NIST SRM 84L Lot Number: 84L
1.0 ACCREDITATION / REGISTRATION INORGANIC VENTURES is accredited to ISO Guide 34, "General Requirements for the Competence of Reference Material Producers" and ISO/IEC 17025, "General Requirements for
More informationSingle Analyte Custom Grade Solution. CGWH2O1 M2-W H2O µg/ml ea: Tungsten Ammonium Metatungstate
1.0 ACCREDITATION / REGISTRATION INORGANIC VENTURES is accredited to ISO Guide 34, "General Requirements for the Competence of Reference Material Producers" and ISO/IEC 17025, "General Requirements for
More informationHands on mass spectrometry: ICP-MS analysis of enriched 82 Se samples for the LUCIFER experiment
: ICP-MS analysis of enriched 82 Se samples for the LUCIFER experiment Max Planck Institute for Nuclear Physics, Heidelberg, Germany E-mail: mykola.stepaniuk@mpi-hd.mpg.de Stefano Nisi E-mail: stefano.nisi@lngs.infn.it
More informationInterference-free determination of ultra-trace levels of Arsenic and Selenium using methyl fluoride as reaction gas in ICP-MS/MS
Department of Analytical Chemistry Research group Atomic and Mass Spectrometry Interference-free determination of ultra-trace levels of Arsenic and Selenium using methyl fluoride as reaction gas in ICP-MS/MS
More information1.0 ACCREDITATION / REGISTRATION 2.0 PRODUCT DESCRIPTION 3.0 CERTIFIED VALUES AND UNCERTAINTIES. Assay Information:
1.0 ACCREDITATION / REGISTRATION INORGANIC VENTURES is accredited to ISO Guide 34, "General Requirements for the Competence of Reference Material Producers" and ISO/IEC 17025, "General Requirements for
More informationA Comparison of Three Methods for Arsenic Speciation in Biological Tissues. May Nguyen Brooks Rand Labs Seattle, WA
A Comparison of Three Methods for Arsenic Speciation in Biological Tissues May Nguyen Brooks Rand Labs Seattle, WA Select Arsenic Species Inorganic Species arsenite [As(III)] arsenate [As(V)] Organic Species
More informationApplication Note PlasmaQuant PQ 9000 Elite, PlasmaQuant MS Elite
Application Note PlasmaQuant PQ 9000 Elite, PlasmaQuant MS Elite Analysis of Rare Earth Elements by ICP-OES and ICP-MS Potentials and Limitations Challenge Interference-free determination of rare earth
More informationSolutions and Ions. Pure Substances
Class #4 Solutions and Ions CHEM 107 L.S. Brown Texas A&M University Pure Substances Pure substance: described completely by a single chemical formula Fixed composition 1 Mixtures Combination of 2 or more
More informationDetermination of Phosphorus and Sulfur with Dynamic Reaction Cell ICP-MS
FIELD APPLICATION REPORT ICP MASS SPECTROMETRY Determination of Phosphorus and Sulfur with Dynamic Reaction Cell ICP-MS Authors: Kenneth R. Neubauer, Ph.D. Perkin Elmer Life and Analytical Sciences 710
More informationAgilent s New 8800 ICP-QQQ. Transforming ICP-MS Technology
Agilent s New 8800 ICP-QQQ Transforming ICP-MS Technology 1 8800 ICP-QQQ Key Product Hardware High matrix introduction (HMI) technology Dual conical Extraction and Omega lens focuses ions across the mass
More informationDetermination of Impurities in Silica Wafers with the NexION 300S/350S ICP-MS
APPLICATION NOTE ICP - Mass Spectrometry Author Kenneth Ong PerkinElmer, Inc. Singapore Determination of Impurities in Silica Wafers with the NexION 300S/350S ICP-MS Introduction The control of impurity
More informationAgilent Technologies at TIAFT 2013
Agilent Technologies at TIAFT 2013 Analytical approaches for the measurement of trace metals in forensic samples Funchal, Madeira September 2-6 CRIMINALISTIC TOXICOLOGY DNA INVESTIGATION DOCUMENT EXAMINATION
More informationCERTIFICATE OF. Single Analyte Mass Spec Solution ± 0.1 µg/ml g/ml (measured at 20 ± 4 ºC)
CERTIFICATE OF ANALYSIS 300 Technology Drive Christiansburg, VA 24073. USA inorganicventures.com tel: 800.669.6799. 540.585.3030 fax: 540.585.3012 info@inorganicventures.com 1.0 ACCREDITATION / REGISTRATION
More informationJRP SIB09 Elements GOOD PRACTICE GUIDE ON DEALING WITH INTERFERENCES IN ICP-MS FOR INVESTIGATING HIGH PURITY MATERIALS. Deliverable 1.2.
JRP SIB09 Elements GOOD PRACTICE GUIDE ON DEALING WITH INTERFERENCES IN ICP-MS FOR INVESTIGATING HIGH PURITY MATERIALS Deliverable 1.2.32 (June 2015) Author : Guillaume Labarraque 1 Introduction High purity
More informationRapid Detection of Americium-241 in Food by Inductively-Coupled Plasma Mass Spectrometry
Rapid Detection of Americium-241 in Food by Inductively-Coupled Plasma Mass Spectrometry Zhichao Lin, Kathryn Emanuele, Stephanie Healey, and Patrick Regan Analytical Branch Winchester Engineering and
More informationSingle-Element Standards for AAS
Single-Element Standards for AAS for AAS Flame Silver Ag in 2-5% HNO 3 Aluminium Al in 2-5% HCl Aluminium Al in 2-5% HNO 3 Arsenic As in 2-5% HCl Arsenic As in 2-5% HNO 3 Gold Au in 2-5% HCl Boron B in
More information