Page 2. Q1.Which one of the following is not a correct general formula for the non-cyclic compounds listed? alcohols C nh 2n+2O. aldehydes C nh 2n+1O
|
|
|
- Howard Norton
- 6 years ago
- Views:
Transcription
1 Q1.Which one of the following is not a correct general formula for the non-cyclic compounds listed? A B alcohols C nh 2n+2O aldehydes C nh 2n+1O C esters C nh 2nO 2 C primary amines C nh 2n+3N (Total 1 mark) Q2. (a) Consider the following pair of isomers. (i) Name compound C. Identify a reagent which could be used in a test-tube reaction to distinguish between C and D. In each case, state what you would observe. Reagent... Observation with C... Observation with D... (4) (b) Consider the following pair of isomers. Page 2
2 (i) Name compound E. Identify a reagent which could be used in a test-tube reaction to distinguish between E and F. In each case, state what you would observe. Reagent... Observation with E... Observation with F... (4) (c) Draw the structure of the chain isomer of F which shows optical isomerism. (1) (Total 9 marks) Q3.For this question refer to the reaction scheme below. Which one of the following statements is not correct? A Reaction of W with sodium cyanide followed by hydrolysis of the resulting product gives propanoic acid. Page 3
3 B C Mild oxidation of Z produces a compound that reacts with Tollens reagent, forming a silver mirror. Z reacts with ethanoic acid to produce the ester propyl ethanoate. C W undergoes addition polymerisation to form poly(propene). (Total 1 mark) Q4. Esters have many important commercial uses such as solvents and artificial flavourings in foods. Esters can be prepared in several ways including the reactions of alcohols with carboxylic acids, acid anhydrides, acyl chlorides and other esters. (a) Ethyl butanoate is used as a pineapple flavouring in sweets and cakes. Write an equation for the preparation of ethyl butanoate from an acid and an alcohol. Give a catalyst used for the reaction. (4) (b) Butyl ethanoate is used as a solvent in the pharmaceutical industry. Write an equation for the preparation of butyl ethanoate from an acid anhydride and an alcohol. (3) Page 4
4 (c) Name and outline a mechanism for the reaction of CH 3COCl with CH 3OH to form an ester. (5) (d) The ester shown below occurs in vegetable oils. Write an equation to show the formation of biodiesel from this ester. CH 2OOCC 17H 31 CHOOCC 17H 33 CH 23OOCC 17H 29 (3) (e) Draw the repeating unit of the polyester Terylene that is made from benzene-1,4-dicarboxylic acid and ethane-1,2-diol. Page 5
5 Although Terylene is biodegradeable, it is preferable to recycle objects made from Terylene. Give one advantage and one disadvantage of recycling objects made from Terylene. (4) (Total 19 marks) Q5. Consider the sequence of reactions below. (a) Name and outline a mechanism for Reaction 1. Name of mechanism... Mechanism (5) Page 6
6 (b) (i) Name compound Q The molecular formula of Q is C 4H 7NO. Draw the structure of the isomer of Q which shows geometrical isomerism and is formed by the reaction of ammonia with an acyl chloride. (3) (c) Draw the structure of the main organic product formed in each case when R reacts separately with the following substances: (i) methanol in the presence of a few drops of concentrated sulphuric acid; acidified potassium dichromate(vi); (iii) concentrated sulphuric acid in an elimination reaction. Page 7
7 (3) (Total 11 marks) Q6.Propanoic acid reacts with methanol in the presence of a small amount of concentrated sulphuric acid. The empirical formula of the ester formed is A CH 2O B C 2H 6O 2 C C 2H 4O 2 D C 2H 4O (Total 1 mark) Q7. (a) Compound A, HCOOCH 2CH 2CH 3, is an ester. Name this ester and write an equation for its reaction with aqueous sodium hydroxide. Name... Equation... (2) (b) The initial rate of reaction between ester A and aqueous sodium hydroxide was measured in a series of experiments at a constant temperature. The data obtained are shown below. Experiment Initial concentration of NaOH / mol dm 3 Initial concentration of A / mol dm 3 Initial rate / mol dm 3 s Page 8
8 to be calculated Use the data in the table to deduce the order of reaction with respect to A and the order of reaction with respect to NaOH. Hence calculate the initial rate of reaction in Experiment 4. Order with respect to A... Order with respect to NaOH... Initial rate in Experiment 4... (3) (c) In a further experiment at a different temperature, the initial rate of reaction was found to be mol dm 3 s 1 when the initial concentration of A was mol dm 3 and the initial concentration of NaOH was 2.00 mol dm 3. Under these new conditions with the much higher concentration of sodium hydroxide, the reaction is first order with respect to A and appears to be zero order with respect to sodium hydroxide. (i) Write a rate equation for the reaction under these new conditions. Calculate a value for the rate constant under these new conditions and state its units. Calculation... Units... (iii) Suggest why the order of reaction with respect to sodium hydroxide appears to be zero under these new conditions. Page 9
9 (6) (d) A naturally-occurring triester, shown below, was heated under reflux with an excess of aqueous sodium hydroxide and the mixture produced was then distilled. One of the products distilled off and the other was left in the distillation flask. (i) Draw the structure of the product distilled off and give its name. Structure Name... Give the formula of the product left in the distillation flask and give a use for it. Formula... Use... (4) (Total 15 marks) Q8.Which one of the following is not a correct statement about vitamin C, shown below? Page 10
10 A B C D It is a cyclic ester. It can form a carboxylic acid on oxidation. It decolourises a solution of bromine in water. It is a planar molecule. (Total 1 mark) Page 11
A drug is designed to simulate one of the following molecules that adsorbs onto the active site of an enzyme.
1 drug is designed to simulate one of the following molecules that adsorbs onto the active site of an enzyme. Which molecule requires the design of an optically active drug? 2 Which one of the following
Section A. 1 at a given temperature. The rate was found to be first order with respect to the ester and first order with respect to hydroxide ions.
2 Section A Answer all questions in the spaces provided. Question 1:The N/Arate of hydrolysis of an ester X (HCOOCH2CH2CH3) was studied in alkaline 1 at a given temperature. The rate was found to be first
CHEM4. General Certificate of Education Advanced Level Examination June Unit 4 Kinetics, Equilibria and Organic Chemistry
Centre Number Surname Candidate Number For Examiner s Use Other Names Candidate Signature Examiner s Initials General Certificate of Education Advanced Level Examination June 2010 Question 1 2 Mark Chemistry
Isomerism and Carbonyl Compounds
Isomerism and Carbonyl Compounds 18 Section B Answer all questions in the spaces provided. 7 Esters have many important commercial uses such as solvents and artificial flavourings in foods. Esters can
It belongs to a homologous series with general formula C n H 2n+1 O
1 Propene can be made by the dehydration of propan-2-ol. What is the percentage yield when 30 g of propene (M r = 42.0) are formed from 50 g of propan-2-ol (M r = 60.0)? 60% 67% 81% 86% 2 Which statement
Q1. Which one of the following is not a correct general formula for the non-cyclic compounds listed?
C Step 4 : concentrated H SO 4 (Total 1 mark) Q1. Which one of the following is not a correct general formula for the non-cyclic compounds listed? A B alcohols C n H n+ O aldehydes C n H n+1 O C esters
Q1. The following pairs of compounds can be distinguished by simple test tube reactions.
Q1. The following pairs of compounds can be distinguished by simple test tube reactions. For each pair of compounds, give a reagent (or combination of reagents) that, when added separately to each compound,
Name/CG: 2012 Term 2 Organic Chemistry Revision (Session II) Deductive Question
Name/G: 2012 Term 2 rganic hemistry Revision (Session II) Deductive Question 1(a) A yellow liquid A, 7 7 N 2, reacts with alkaline potassium manganate (VII) and on acidification gives a yellow solid B,
CHEM4. (JUN15CHEM401) WMP/Jun15/CHEM4/E5. General Certificate of Education Advanced Level Examination June 2015
Centre Number Candidate Number For Examiner s Use Surname Other Names Candidate Signature Examiner s Initials General Certificate of Education Advanced Level Examination June 2015 Question 1 2 Mark Chemistry
AQA A2 CHEMISTRY TOPIC 4.10 ORGANIC SYNTHESIS AND ANALYSIS TOPIC 4.11 STRUCTURE DETERMINATION BOOKLET OF PAST EXAMINATION QUESTIONS
AQA A2 CHEMISTRY TOPIC 4.10 ORGANIC SYNTHESIS AND ANALYSIS TOPIC 4.11 STRUCTURE DETERMINATION BOOKLET OF PAST EXAMINATION QUESTIONS 1 1. Consider the following reaction sequence. CH 3 CH 3 CH 3 Step 1
International School of Johannesburg. Diploma Chemistry. Organic Chemistry (HL) Revision Questions. D. ( HNCH 2 CH 2 NHCOCH 2 NH ) (Total 1 mark)
International School of Johannesburg Diploma Chemistry Organic Chemistry (HL) Revision Questions 1. The compounds H 2 NCH 2 CH 2 NH 2 and HOOCCH 2 COOH react to form a polymer. What is the structure of
Draw the structure of the alkene that would form 1,2-dibromo-3-methylbutane when reacted with bromine.
Q1.In each of the following questions, you should draw the structure of the compound in the space provided. (a) Draw the structure of the alkene that would form 1,2-dibromo-3-methylbutane when reacted
CHEMISTRY FOR THE IB DIPLOMA CAMBRIDGE UNIVERSITY PRESS
10 rganic chemistry Revision checklist I am able to: explain, using an example, what is meant by the term homologous series sketch a graph of boiling point against number of carbons for the straight-chain
CHEM4. (JAN13CHEM401) WMP/Jan13/CHEM4. General Certificate of Education Advanced Level Examination January 2013
Centre Number Surname Candidate Number For Examiner s Use Other Names Candidate Signature Examiner s Initials General Certificate of Education Advanced Level Examination January 2013 Question 1 2 Mark
Page (Extra space) (4) Benzene can be converted into amine U by the two-step synthesis shown below.
Q1. The hydrocarbons benzene and cyclohexene are both unsaturated compounds. Benzene normally undergoes substitution reactions, but cyclohexene normally undergoes addition reactions. (a) The molecule cyclohexatriene
Module 4 revision guide: Compounds with C=O group
opyright N Goalby Bancroft's School Module 4 revision guide: ompounds with = group arbonyls: Aldehydes and Ketones arbonyls are compounds with a = bond, they can be either aldehydes or ketones. 3 ethanal
10.2 ALCOHOLS EXTRA QUESTIONS. Reaction excess conc, H SO 180 C
10.2 ALOOLS EXTRA QUESTIONS 1. onsider the reaction scheme below which starts from butanone. N Reaction 1 3 2 3 3 2 3 O Reaction 2 O A 3 O B 2 3 excess conc, SO 180 2 4 but 1 ene and but 2 ene (a) When
3.2.8 Haloalkanes. Nucleophilic Substitution. 267 minutes. 264 marks. Page 1 of 36
3.2.8 Haloalkanes Nucleophilic Substitution 267 minutes 264 marks Page 1 of 36 Q1. (a) The equation below shows the reaction of 2-bromopropane with an excess of ammonia. CH 3 CHBrCH 3 + 2NH 3 CH 3 CH(NH
(07) 3 (e) Calculate the ph of this buffer solution at 298 K. Give your answer to 2 decimal places
7 3 (e) An acidic buffer solution is formed when 10.0 cm3 of 0.125 mol dm 3 aqueous sodium hydroxide are added to 15.0 cm3 of 0.174 mol dm 3 aqueous HX. The value of Ka for the weak acid HX is 3.01 10
CHEM4. General Certificate of Education Advanced Level Examination January Unit 4 Kinetics, Equilibria and Organic Chemistry
Centre Number Surname Candidate Number For Examiner s Use Other Names Candidate Signature Examiner s Initials General Certificate of Education Advanced Level Examination January 2011 Question 1 2 Mark
Chirality, Carbonyls and Carboxylic Acids
hirality, arbonyls and arboxylic Acids Questions on this unit may include material from UNIT 2 see syllabus Isomerism Structural isomerism. Structural isomerism was dealt with in UNIT 2. All isomers are
4. Carbonyl chemistry
4. Carbonyl chemistry 4.1. Oxidation of alcohols 4.2 Tests for aldehydes and ketones 4.3 Carbonyl functional groups 4.4 Reactions of carboxylic acids 4.5 Reductions of carbonyl groups 4.6 Esters 4.7 Preparing
3.2.9 Alkenes. Addition Reactions. 271 minutes. 268 marks. Page 1 of 35
..9 Alkenes Addition Reactions 71 minutes 68 marks Page 1 of 5 Q1. Propene reacts with bromine by a mechanism known as electrophilic addition. (a) Explain what is meant by the term electrophile and by
(07) 2 (c) 2 (c) (i) Calculate the ph of this buffer solution at 25 oc (3 marks) (Extra space)
7 The value of Ka for methanoic acid is 1.78 10 4 mol dm 3 at 25 oc. A buffer solution is prepared containing 2.35 10 2 mol of methanoic acid and Question 1: N/A 1.84 10 2 mol of sodium methanoate in 1.00
OCR (A) Chemistry A-level. Module 6: Organic Chemistry and Analysis
OCR (A) Chemistry A-level Module 6: Organic Chemistry and Analysis Organic Synthesis Notes by Adam Robertson DEFINITIONS Heterolytic fission: The breaking of a covalent bond when one of the bonded atoms
1 Summarised directions for recording responses to multiple completion questions
Summarised directions for recording responses to multiple completion questions A (i), (ii) and (iii) only B (i) and (iii) only C (ii) and (iv) only D (iv) alone Products from the acid hydrolysis of the
CHEM4. General Certificate of Education Advanced Level Examination January Kinetics, Equilibria and Organic Chemistry
Centre Number Surname Candidate Number For Examiner s Use Other Names Candidate Signature Examiner s Initials General Certificate of Education Advanced Level Examination January 2010 Question 1 2 Mark
*P51939A0124* Pearson Edexcel WCH04/01. P51939A 2018 Pearson Education Ltd.
Write your name here Surname Other names Pearson Edexcel International Advanced Level Centre Number Candidate Number Chemistry Advanced Unit 4: General Principles of Chemistry I Rates, Equilibria and Further
M08/4/CHEMI/SP2/ENG/TZ2/XX CHEMISTRY. Thursday 8 May 2008 (afternoon) Candidate session number. 1 hour 15 minutes INSTRUCTIONS TO CANDIDATES
M08/4/CHEMI/SP2/ENG/TZ2/XX 22086117 CHEMISTRY standard level Paper 2 Thursday 8 May 2008 (afternoon) 1 hour 15 minutes 0 0 Candidate session number INSTRUCTIONS TO CANDIDATES Write your session number
H H O C C O H Carboxylic Acids and Derivatives C CH 2 C. N Goalby chemrevise.org. Strength of carboxylic acids.
19 arboxylic Acids and Derivatives Naming arboxylic acids These have the ending -oic acid but no number is necessary for the acid group as it must always be at the end of the chain. The numbering always
Alcohols. Ethanol Production. 182 minutes. 181 marks. Page 1 of 25
3..10 Alcohols Ethanol Production 18 minutes 181 marks Page 1 of 5 Q1. Ethanol is produced commercially by fermentation of aqueous glucose, C 6 H 1 O 6 State two conditions, other than temperature, which
Page 2. PhysicsAndMathsTutor.com
Page 2 Q1.Ethanol can be oxidised by acidified potassium dichromate(vi) to ethanoic acid in a two-step process. ethanol ethanal ethanoic acid (a) In order to ensure that the oxidation to ethanoic acid
(a) Which test always gives a positive result with carbonyl compounds? (b) Which test would give a positive result with ethane-1,2-diol?
1 Some chemical tests are described below. Warm with Fehling s (or enedict s) solution Warm with acidified potassium dichromate(vi) solution dd sodium carbonate solution dd 2,4-dinitrophenylhydrazine solution
Topic 4.10 ORGANIC SYNTHESIS AND ANALYSIS. Organic analysis Organic synthesis
Topic 4.10 ORGANIC SYNTHESIS AND ANALYSIS Organic analysis Organic synthesis DISTINGUISHING BETWEEN DIFFERENT ORGANIC COMPOUNDS Many of the organic compounds prepared in AS Unit 2 and in A2 Unit 4 can
Organic Chemistry Review: Topic 10 & Topic 20
Organic Structure Alkanes C C σ bond Mechanism Substitution (Incoming atom or group will displace an existing atom or group in a molecule) Examples Occurs with exposure to ultraviolet light or sunlight,
17 Alcohols H H C C. N Goalby chemrevise.org 1 H H. Bond angles in Alcohols. Boiling points. Different types of alcohols H 2 C CH 2 CH 2
17 Alcohols General formula alcohols n 2n+1 Naming Alcohols These have the ending -ol and if necessary the position number for the group is added between the name stem and the ol If the compound has an
UNIT 4 REVISION CHECKLIST CHEM 4 AS Chemistry
UNIT 4 REVISION CHECKLIST CHEM 4 AS Chemistry Topic 4.1 Kinetics a) Define the terms: rate of a reaction, rate constant, order of reaction and overall order of reaction b) Deduce the orders of reaction
Organic Chemistry. Alkanes are hydrocarbons in which the carbon atoms are joined by single covalent bonds.
Organic Chemistry Organic compounds: The branch of chemistry which deals with the study of carbon compounds is called organic chemistry. Catenation: The carbon atom has a property to undergo self linking
PMT. This question is about the reaction sequence shown below
1. The quality of written communication will be assessed in this question. To gain full marks you must explain your ideas clearly using equations and diagrams where appropriate. This question is about
ACIDS, BASES, PH, BUFFERS & TITRATION WEBINAR. Dr Chris Clay
ACIDS, BASES, PH, BUFFERS & TITRATION WEBINAR Dr Chris Clay http://drclays-alevelchemistry.com/ Q1.Titration curves, labelled E, F, G and H, for combinations of different aqueous solutions of acids and
... (b) (i) Identify the isomer in part (a) which can be oxidised to a ketone. Give the structure of the ketone formed.
Q1. (a) One of the isomers in part (a) is resistant to oxidation by acidified potassium dichromate(vi). Identify this isomer. This isomer can be dehydrated. Give a suitable dehydrating agent and write
CHAPTER 19: Carboxylic Acids and Derivatives I
CHAPTER 19: Carboxylic Acids and Derivatives I 19.1 Carboxylic Acids 19.2 Reactions of Carboxylic Acids 19.3 Esters Learning outcomes: (a) describe the formation of carboxylic acids from alcohols, aldehydes
IB Topics 10, 20 & 21 MC Practice
IB Topics 10, 20 & 21 MC Practice 1. What is the major product of the reaction between HCl and but-2-ene? 1,2-dichlorobutane 2,3-dichlorobutane 1-chlorobutane 2-chlorobutane 2. Which compound can be oxidized
EXTRA QUESTIONS FOR 2.8 HALOALKANES. 1. Methylbenzene is converted into (chloromethyl)benzene in a free radical substitution reaction....
EXTRA QUESTIONS FOR 2.8 HALOALKANES 1. Methylbenzene is converted into (chloromethyl)benzene in a free radical substitution reaction. C 6 H 5 3 + Cl 2 C 6 H 5 2 Cl + HCl Write an equation for the initiation
Haloalkanes. Isomers: Draw and name the possible isomers for C 5 H 11 Br
Haloalkanes The basics: The functional group is a halogen atom: F, Cl, Br or I General formula C n H 2n+1 X Use the prefixes: fluoro, chloro, bromo and iodo. Isomers: Draw and name the possible isomers
Mechanisms. . CCl2 F + Cl.
Mechanisms 1) Free radical substitution Alkane à halogenoalkane Initiation: Propagation: Termination: Overall: 2) Ozone depletion UV light breaks the C Cl bond releasing chlorine radical CFCl 3 F à. CCl2
Page 2. The tripeptide shown is formed from the amino acids alanine, threonine and lysine.
Q1.(a) The tripeptide shown is formed from the amino acids alanine, threonine and lysine. Draw a separate circle around each of the asymmetric carbon atoms in the tripeptide. Draw the zwitterion of alanine.
Monday 19 June 2017 Morning Time allowed: 2 hours
Please write clearly in block capitals. Centre number Candidate number Surname Forename(s) Candidate signature A-level CHEMISTRY Paper 2 Organic and Physical Chemistry Monday 19 June 2017 Morning Time
Further Synthesis and Analysis
Further Synthesis and Analysis 12 4 In 2008, some food products containing pork were withdrawn from sale because tests showed that they contained amounts of compounds called dioxins many times greater
The structures and common names of two amino acids are shown. Draw the structure of the zwitterion of proline.
Q1.(a) The structures and common names of two amino acids are shown. (i) Draw the structure of the zwitterion of proline. Draw the structure of the tripeptide formed when a proline molecule bonds to two
Chemistry 2.5 AS WORKBOOK. Working to Excellence Working to Excellence
Chemistry 2.5 AS 91165 Demonstrate understanding of the properties of selected organic compounds WORKBOOK Working to Excellence Working to Excellence CONTENTS 1. Writing Excellence answers to Cis-Trans
, by reacting CH 3 with ethanoic anhydride, (CH 3
1 A chemist prepares and analyses some esters. (a) The chemist prepares an ester of propan-2-ol, H 3 H(H)H 3, by reacting H 3 H(H)H 3 with ethanoic anhydride, (H 3 ) 2. Using structural formulae, write
CHEM4. General Certificate of Education Advanced Level Examination June Unit 4 Kinetics, Equilibria and Organic Chemistry
Centre Number Surname Candidate Number For Examiner s Use ther Names Candidate Signature Examiner s Initials General Certificate of Education Advanced Level Examination June 2012 Question 1 2 Mark Chemistry
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS General Certificate of Education Advanced Subsidiary Level and Advanced Level CHEMISTRY
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS General Certificate of Education Advanced Subsidiary Level and Advanced Level CEMISTRY Paper 2 Structured Questions AS Core Candidates answer on the Question
A-level CHEMISTRY (7405/3)
SPECIMEN MATERIAL A-level CHEMISTRY (7405/3) Paper 3 Specimen 2015 Session Time allowed: 2 hours Materials For this paper you must have: the Data Booklet, provided as an insert a ruler a calculator. Instructions
(a) (i) Give the equation representing the overall reaction. (1) Give the equation representing the formation of the electrophile.
1. Benzene reacts with concentrated nitric acid in the presence of concentrated sulphuric acid at about 50 º in an electrophilic substitution reaction to give nitrobenzene. (a) Give the equation representing
C. CH CH COH CH CCH. 6. Which substance(s) could be formed during the incomplete combustion of a hydrocarbon?
1. Which of the structures below is an aldehyde? O O A. CH 3CH 2 CH B. CH 3CCH3 C. CH 3CH 2 COH D. CH COCH 2. What product results from the reaction of CH 2 ==CH 2 with Br 2? A. CHBrCHBr B. CH 2 CHBr C.
Aromatic Compounds and Amines
Aromatic Compounds and Amines 22 8 Consider compound P shown below that is formed by the reaction of benzene with an electrophile. O C CH 2 CH 3 P 8 (a) Give the two substances that react together to form
F322: Chains, Energy and Resources Modern Analytical Techniques
F322: hains, Energy and Resources 2.2.3 Modern Analytical Techniques 1. Alcohol E is one of the following alcohols. butan-2-ol 2-methylpentan-3-ol propan-1-ol ethane-1,2-diol 2-methylpropan-2-ol propan-2-ol
NATIONAL 5 CHEMISTRY
Farr High School NATIONAL 5 CHEMISTRY Unit 2 Nature s Chemistry Exam Questions 1 Homologous series 1. 2006 I2 13MC The above structural formulae represent A the same hydrocarbon B Different hydrocarbons
Le Lycee Mauricien. Proposed Syllabus Chemistry (5070) - Form 5
Le Lycee Mauricien Proposed Syllabus 2017 Chemistry (5070) - Form 5 First Term 1. Metals Properties of metals - Physical properties of metals - Structure of alloys and uses Reactivity Series - Place metals
H 5. CH(OH)COOH, is used in some skin creams and can be converted into a condensation polymer., is used to make some artificial fingernails.
1 Mandelic acid (2-phenyl-2-hydroxyethanoic acid), 6 5 (), is used in some skin creams and can be converted into a condensation polymer. The addition polymer of ethyl methacrylate (ethyl 2-methyl-2-propenoate),
TOK: The relationship between a reaction mechanism and the experimental evidence to support it could be discussed. See
Option G: Further organic chemistry (15/22 hours) SL students study the core of these options and HL students study the whole option (the core and the extension material). TOK: The relationship between
4.4, 4.5 HW MS 1. (a) nucleophilic addition 1 M2. (b) (i) 2-hydroxybutanenitrile 1 (ii) 2 H 3C O H
4.4, 4.5 W MS 1. (a) nucleophilic addition 1 M N N M1 M M4 4 (b) (i) -hydroxybutanenitrile 1 (ii) N (allow 1 for amide even if not 4 7 N, i.e. RN ) (if not amide, allow one for any isomer of 4 7 N which
Alcohols, Phenols and Ethers
SUBJECTIVE PROBLEMS: Alcohols, Phenols and Ethers Q1. An organic liquid (A), containing C, H and O with boiling point: 78 o C, and possessing a rather pleasant odour, on heating with concentrated sulphuric
2 Set up an apparatus for simple distillation using this flask.
The following instructions are from an experimental procedure for the preparation of cyclohexene from cyclohexanol and concentrated phosphoric acid. Read these instructions and answer the questions that
Chapter 10: Carboxylic Acids and Their Derivatives
Chapter 10: Carboxylic Acids and Their Derivatives The back of the white willow tree (Salix alba) is a source of salicylic acid which is used to make aspirin (acetylsalicylic acid) The functional group
GRADE 11F: Chemistry 6. UNIT 11FC.6 10 hours. Some functional groups. Resources. About this unit. Previous learning. Expectations
GRADE 11F: Chemistry 6 Some functional groups UNIT 11FC.6 10 hours About this unit This unit is the sixth of six units on for Grade 11 foundation. The unit is designed to guide your planning and teaching
Paper Reference. Paper Reference(s) 6246/02 Edexcel GCE Chemistry Advanced Unit Test 6B (Synoptic)
Centre No. Paper Reference Surname Initial(s) Candidate No. 6 2 4 6 0 2 Signature Paper Reference(s) 6246/02 Edexcel GCE Chemistry Advanced Unit Test 6B (Synoptic) Tuesday 28 June 2005 Morning Time: 1
Unit 3(a) Introduction to Organic Chemistry
Surname Other Names Leave blank Centre Number Candidate Number Candidate Signature General Certificate of Education January 2002 Advanced Subsidiary Examination CHEMISTRY Unit 3(a) Introduction to Organic
For more sample papers visit : CHEMISTRY. Paper 1 (THEORY) (Three Hours)
CHEMISTRY Paper 1 (THEORY) (Three Hours) (Candidates are allowed additional 15 minutes for only reading the paper. They must NOT start writing during this time) --------------------------------------------------------------------------------------------------------------------------
CARBONYLS CARBONYLS CHEMISTRY CHEMISTRY CARBONYLS CARBONYLS CHEMISTRY CHEMISTRY
CRBONYLS CRBONYLS Outline mechanism for reaction methanol with propanoyl chloride. Clearly start curly arrow from middle lone pair or middle a bond. CRBONYLS CRBONYLS display formula butanoic anhydride.
3.5 Alcohols H H C C. N Goalby chemrevise.org 1 H H. Bond angles in Alcohols. Boiling points. Different types of alcohols H 2 C CH 2 CH 2
3.5 Alcohols General formula alcohols n 2n+1 Naming Alcohols These have the ending -ol and if necessary the position number for the group is added between the name stem and the ol If the compound has an
Organic Chemistry SL IB CHEMISTRY SL
Organic Chemistry SL IB CHEMISTRY SL 10.1 Fundamentals of organic chemistry Understandings: A homologous series is a series of compounds of the same family, with the same general formula, which differ
Chemistry Assessment Unit A2 1
Centre Number 71 Candidate Number ADVANCED General Certificate of Education January 2011 Chemistry Assessment Unit A2 1 assessing Periodic Trends and Further Organic, Physical and Inorganic Chemistry [AC212]
Q1. Pentanenitrile can be made by reaction of 1-bromobutane with potassium cyanide.
Q1. Pentanenitrile can be made by reaction of 1-bromobutane with potassium cyanide. Which of these is the correct name for the mechanism of this reaction? A B C D Electrophilic addition Electrophilic substitution
3 Answer all the questions.
CHERRY HILL TUITIN CR A CHEMISTRY A2 PAPER 18 3 Answer all the questions. 1 Benzene is an important industrial chemical and is used in a wide range of manufacturing processes. ver time our understanding
Acyl chloride/ acid anhydride
3.14 Synthetic routes poly(alkene) dihalogenoalkane KH aqueous under reflux Nu Sub diol high pressure catalyst Step 1 H 2 S 4 EAdd Step 2 H 2 warm hydrolysis alcohol alkene conc. H 2 S 4 or conc. H 3 P
1. Which of the structures below is an aldehyde? O A. CH CH CH O B. CH CCH O C. CH CH COH O D. CH COCH
1. Which of the structures below is an aldehyde? O A. CH CH CH 3 2 O B. CH CCH 3 3 O C. CH CH COH 3 2 O D. CH COCH 3 3 2. What product results from the reaction of CH 2 ==CH 2 with Br 2? A. CHBrCHBr B.
QUESTIONSHEETS ORGANIC REACTION MECHANISMS I FREE RADICAL SUBSTITUTION I FREE RADICAL SUBSTITUTION II ELECTROPHILIC ADDITION TO SYMMETRICAL ALKENES
CHEMISTRY QUESTIONSHEETS AS Level AS TOPIC 14 ORGANIC REACTION MECHANISMS I Questionsheet 1 Questionsheet 2 Questionsheet 3 Questionsheet 4 Questionsheet 5 Questionsheet 6 Questionsheet 7 Questionsheet
Carbon and its Compounds
CHAPTER4 Carbon and its Compounds Multiple Choice Questions 1. Carbon exists in the atmosphere in the form of carbon monoxide only carbon monoxide in traces and carbon dioxide carbon dioxide only coal
CARBONYL COMPOUNDS. Section A. Q1 Acrylic acid is produced from propene, a gaseous product of oil refineries.
MCQs Section A Q1 Acrylic acid is produced from propene, a gaseous product of oil refineries. Which statement about acrylic acid is not correct? A Both bond angles x and y are approximately 120. B It decolourises
The mechanism of the nitration of methylbenzene is an electrophilic substitution.
Q1.Many aromatic nitro compounds are used as explosives. One of the most famous is 2-methyl-1,3,5-trinitrobenzene, originally called trinitrotoluene or TNT. This compound, shown below, can be prepared
Analyse this information to suggest possible structures for compounds F, G and H.
1 In this question, you are asked to suggest structures for several organic compounds. (a) ompounds F, G and are unbranched alkenes that are isomers, each with a relative molecular mass of 70.0. ompounds
CHEM 112 Name: (Last) (First). Section No.: VISUALIZING ORGANIC REACTIONS THROUGH USE OF MOLECULAR MODELS
CHEM 112 Name: (Last) (First). Section No.: VISUALIZING ORGANIC REACTIONS THROUGH USE OF MOLECULAR MODELS 1) HYDROCARBONS: a. Saturated Hydrocarbons: Construct a model for propane, C 3 H 8, using black
The butan-1-ol produced can be analysed by mass spectrometry.
1. Bromobutane, H 3 H 2 H 2 H 2 Br, can be reacted with hot aqueous sodium hydroxide to prepare butan-1-ol. H 3 H 2 H 2 H 2 Br + OH H 3 H 2 H 2 H 2 OH + Br The butan-1-ol produced can be analysed by mass
(a) Name the alcohol and catalyst which would be used to make X. (2)
1 The chemical X is an ester with formula CH 3 COOC(CH 3 ) 3 which occurs in raspberries and pears. It can be prepared in the laboratory by refluxing ethanoic acid with an alcohol in the presence of a
Level 3 Chemistry Demonstrate understanding of the properties of organic compounds
1 ANSWERS Level 3 Chemistry 91391 Demonstrate understanding of the properties of organic compounds Credits: Five Achievement Achievement with Merit Achievement with Excellence Demonstrate understanding
Module 4: Further Organic, Physical and Inorganic Chemistry
Centre Number 71 Candidate Number ADVANCED General Certificate of Education January 2010 Chemistry Assessment Unit A2 1 assessing Module 4: Further Organic, Physical and Inorganic Chemistry [A2C11] *A2C11*
Chem!stry. Organic Chemistry Multiple Choice Questions
hem!stry Name: lass: ate: / / rganic hemistry Multiple hoice Questions 1. n organic compound, X, has the empirical formula 24 and a relative molecular mass of 88. It reacts with ethanol in the presence
CAMBRIDGE INTERNATIONAL EXAMINATIONS General Certificate of Education Advanced Subsidiary Level and Advanced Level
Centre Number Candidate Number Candidate Name CAMBRIDGE INTERNATIONAL EXAMINATIONS General Certificate of Education Advanced Subsidiary Level and Advanced Level CHEMISTRY 9701/2 PAPER 2 OCTOBER/NOVEMBER
HYDROXY COMPOUNDS. Section A. Q1 In the reaction pathway below, an alkane is converted into a carboxylic acid through several stages.
MCQs Section A Q1 In the reaction pathway below, an alkane is converted into a carboxylic acid through several stages. Which processes occur at stage 1 and at stage 3? Q2 Which isomer of C6H13OH gives
Summary of mechanisms. Type of reaction: Nucleophilic subsitution/hydrolysis
S Summary of mechanisms S Summary of mechanisms electrophilic addition Electrophiles: H δ in H (Ni catalyst needed), H δ in H-X; X δ in X ; H δ in H O (g) (conc H 3 PO 4 cat needed); H δ in NH 3 ; H δ
TWO correct Names and / or structure. Definition correct OR Isomer correct
NZIC 2015 Assessment Schedule for Chemistry 3.5 AS 91391: DEMONSTRATE UNDERSTANDING OF THE PROPERTIES OF SELECTED GANIC COMPOUNDS Question Evidence Achieved Merit Excellence 1(a) (2)-methylpropanoyl chloride
Q.1 Which of the structures is/are classified as phenols?
Alcohols 1 ALOOLS Aliphatic Aromatic general formula n 2n+1 O - provided there are no rings named as substituted alkanes by removing the final -e and adding -ol for isomers the position of the O is given
2. An aldehyde can be obtained by the dehydrogenation of an alcohol. The catalyst used in the reaction is
Class: 12 Subject: Chemistry Topic: Organic Chemistry of O compounds No. of Questions: 20 Duration: 60 Min Maximum Marks: 60 1. Rectified spirit is converted to absolute alcohol taking advantage of the
Unit 4: General Principles of Chemistry I Rates, Equilibria and Further Organic Chemistry (including synoptic assessment)
Write your name here Surname Other names Edexcel GCE Centre Number Chemistry Advanced Unit 4: General Principles of Chemistry I Rates, Equilibria and Further Organic Chemistry (including synoptic assessment)
*AC212* Chemistry Assessment Unit A2 1. Periodic Trends and Further Organic, Physical and Inorganic Chemistry. New Specification.
New Specification Centre Number 71 Candidate Number ADVANCED General Certificate of Education 2010 Chemistry Assessment Unit A2 1 assessing Periodic Trends and Further Organic, Physical and Inorganic Chemistry
CH 3 CH 2 CH 2 CH 2 OH
1 Alcohols are used in the industrial production of many organic compounds. (a) Complete the flowchart below to show the organic product formed in each of the reactions of butan-1-ol. K 2 Cr 2 O 7 (aq)