Interactional Behavior of Polyelectrolyte Poly Sodium 4-Styrene Sulphonate (NaPSS) with
|
|
- Monica Morton
- 5 years ago
- Views:
Transcription
1 Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 215 Interactional Behavior of Polyelectrolyte Poly Sodium 4-Styrene Sulphonate (NaPSS) with Imidazolium based Surface Active Ionic Liquids in Aqueous Medium Electronic supporting information Renu Sharma, Ajar Kamal, Tejwant Singh Kang*, Rakesh Kumar Mahajan* * Department of Chemistry, UGC-Centre for Advanced Studies-I, Guru Nanak Dev University, Amritsar-1435, India *To whom correspondence should be addressed: rakesh_chem@yahoo.com; tejwantsinghkang@gmail.com; Fax:
2 Annexure SI Methods (Detailed Description) Surface tension measurements were carried out using Kruss (Hamburg, Germany) Easy dyne tensiometer using ring detachment method at K with an accuracy of ±.15 mn m -1. A mixing time of two minutes followed by an equilibration time of 5 minutes was adopted prior to measurement. Steady-state fluorescence measurements were performed using HITACHI F- 16 Fluorescence Spectrophotometer using a 1 mm path length quartz cuvette at K employing ANS as fluorescent probe. ANS (concentration) was excited at an excitation wavelength of 35 nm and emission spectrum was recorded in the wavelength range of 38 nm using an excitation and emission slit width of 2.5 nm, each. The solution was allowed to equilibrate for 5 minutes to reach the thermal equilibrium after each addition prior to measurement. Conductivity was measured at different temperatures using a digital Systronics conductivity meter model 36 with a dip-type conductivity cell having a cell constant of 1.1 cm - 1. Temperature of the measurement cell was controlled using an Escy IC21 thermostatic bath within the accuracy of ±.1 K. The specific conductivity of deionised double distilled water used in this study was measured to be around 2µS cm -1. Cyclic voltammetric (CV) measurements were carried out on a PC controlled CHI66D (Austin, USA) electrochemical workstation equipped with a conventional three electrode system comprising of a working Pt electrode (2 mm in diameter), a counter Pt wire and a reference Ag/AgCl electrode. All the solutions were deoxygenated with N 2 and working electrodes were polished with slurry of alumina powder. The CV measurements were carried out in the presence of.1 M KCl as a supporting electrolyte. In order to study the interactions between NaPSS and SAILs, successive additions of small aliquots of concentrated SAILs to TEMPO solution (2mM) containing polyelectrolyte have been carried out. The potentiometric measurements were carried out by using an Equiptronics digital potentiometer, Model EQ2 employing the following electrochemical cell assembly: 2
3 Ag/AgCl 3M KCl Test Solution PVC Internal Reference 3M KCl Ag/AgCl membrane Solution The neutral ion-pair complexes of SAILs and sodium dodecylsulfate as C n mim+ds were prepared by the procedure earlier described by us [1, 2]. Equimolar aqueous solutions of (C n mimcl) and sodium dodecylsulfate (SDS) were mixed and after continuous stirring for a considerable time, the white precipitates of C n mim+ds were obtain ed. The precipitates so obtained were washed repeatedly with water to remove NaCl and recrystallized thrice from acetone. The PVC (176 mg), ion-pair (5 mg) and plasticizer (55 mg) were mixed and dissolved in minimum quantity of THF. The resulting mixture was poured in 5-mm petri dish after removing the air-bubbles. The solvent THF was allowed to evaporate at room temperature. The resulting membrane was cut to required size and attached to PVC tubes with PVC glue and equilibrated in 1mM of respective SAIL solution. The internal reference solution was 1mM SAIL in 1mM NaCl. The given composition of the components used for membrane formation represents the best system in terms of slope values, correlation coefficient, linear range and detection limit. The EMF measurements were carried out by titration method at K in the presence of 1mM NaCl solution. Turbidity measurements were performed using Systronics Digital Nepheloturbidity Meter model 132 after equilibrating the solution for 5 minutes. All the measurements were repeated thrice. Dynamic light scattering measurements were performed using a Malvern Nano-ZS Zetasizer instrument employing a He-Ne laser (λ = 632 nm) at a scattering angle of 173 using quartz cuvette having path length of 1 cm. The bare autocorrelation function has been analysed by cumulants fit method. The temperature of the measurement was maintained by built-in temperature controller having an accuracy of ±.1 K. Calorimetric measurements were carried out using MicroCal ITC2 microcalorimeter. The titrations were done by adding 2 µl aliquots of stock solutions of SAILs in 24 µl of aqueous polymer solution using Hamilton syringe. All the measurements were repeated twice. The time of addition and interval between each addition are controlled by software equipped with the instrument. 3
4 Annexure SII. The maximum surface excess concentration (Г max ) and minimum area per molecule [3, 4] at the air-solution interface can be calculated using equation (1) and (2) as follows: d d lnc T nrt max (1) A min =1 2 / (N A. Г max ) (2) The Gibbs free energy of adsorption (ΔG ads ) [5] is calculated using the equation (3) ΔG ads = ΔG mic - П cmc / Г max (3) Annexure SIII The Gibbs free energy of micelle formation, ΔG mic [6] was calculated using the equation (4) ΔG mic = (1+ β) RT ln X cmc (4) Where, β, R, T and X cmc are counter-ion binding, gas constant, temperature on Kelvin scale and cmc expressed in mole fraction. The enthalpy of micelle formation, ΔH mic was calculated by employing Gibbs-Helmholtz equation using free energy of micellization H mic = RT 2 (1 + β) dx cmc dt (5) Then the entropy of micelle formation, ΔS mic is obtained as: S mic H mic G T mic (6) 4
5 Table S1 Interfacial parameters i.e. surface tension at cmc (γ cmc ), effective surface tension reduction (Π cmc ), surface excess (Г max ), minimum area per molecule (A min ), Gibbs free energy of adsorption (ΔG ads ) of SAILs in the absence and presence of polyelectrolyte NaPSS (.2 and ) at K. NaPSS % γ cmc (mn m -1 ) π cmc (mn m -1 ) Γ max 1 6 (mol m -2 ) A min (nm 2 ) ΔG ads kj mol -1 [C 1 mim][cl] [C 12 mim[cl] [C 14 mim][cl] The error estimate in interfacial parameters γ cmc, π cmc, Г max, A min and ΔG ads are ±.1 mn m -1, ±.1 mn m -1, ±.5 mol m -2, ±.5 nm 2 and ±.15 kj mol -1 respectively. 5
6 Table S2 Critical micelle concentration (cmc), counter-ion binding (β), Gibbs free energy of micellization (ΔG m ), enthalpy of micellization (ΔH m ) and entropy of micellization (ΔS m ) of SAILs in aqueous solution at different temperatures. T (K) cmc (mmol dm -3 ) β ΔG m (kj mol -1 ) ΔH m (kj mol -1 ) TΔS m (kj mol -1 ) [C 1 mim][cl] [C 12 mim][cl] [C 14 mim][cl] The error estimate in cmc, β, ΔG m, ΔH m and ΔS m are ±.1 mmol dm -3, ±.2, ±.5 kj mol -1, ±.7 kj mol -1 and ±.13 kj mol -1 respectively. 6
7 Table S3 Critical aggregation concentration (cac), critical micelle concentration (cmc), counterion binding (β), Gibbs free energy of micellization (ΔG m ), enthalpy of micellization (ΔH m ) and entropy of micellization (ΔS m ) of SAILs in NaPSS solution at different temperatures. NaPSS T (K) cac (mmol dm -3 ) cmc β (mmol dm -3 ) [C 1 mim][cl] ΔG m (kj mol -1 ) ΔH m ( kj mol -1 ) TΔS m ( kj mol -1 ) [C 12 mim][cl] [C 14 mim][cl] The error estimate in cac, cmc, β, ΔG m, ΔH m and ΔS m are ±.5 mmol dm -3, ±.1 mmol dm -3, ±.2, ±.5 kj mol -1, ±.7 kj mol -1 and ±.13 kj mol -1 respectively. 7
8 Table S4 Critical aggregation concentration (cac), critical micelle concentration (cmc), counter-ion binding (β), Gibbs free energy of micellization (ΔG m ), enthalpy of micellization (ΔH m ) and entropy of micellization (ΔS m ) of SAILs in NaPSS solution at different temperatures. NaPSS T (K) cac (mmol dm -3 ) cmc β (mmol dm -3 ) [C 1 mim][cl] ΔG m (kj mol -1 ) ΔH m ( kj mol -1 ) TΔS m ( kj mol -1 ) [C 12 mim][cl] [C 14 mim][cl] The error estimate in cac, cmc, β, ΔG m, ΔH m and ΔS m are ±.5 mmol dm -3, ±.1 mmol dm -3, ±.2, ±.5 kj mol -1, ±.7 kj mol -1 and ±.13 kj mol -1 respectively. 8
9 Table S5 Inter-micellar interaction parameter (k d ), self-diffusion coefficient (D m) and diffusion coefficient (D m ) of SAILs in the absence and presence of polyelectrolyte NaPSS (.2 and ). System k d D m D m (M -1 ) (1 5 cm 2 s -1 ) (1 5 cm 2 s -1 ) [C 1 mim][cl] [C 1 mim][cl]+napss () [C 1 mim][cl]+napss () [C 12 mim][cl] [C 12 mim][cl]+napss () [C 12 mim][cl]+napss () [C 14 mim][cl] [C 14 mim][cl]+napss () [C 14 mim][cl]+napss () The error estimate in k d, D m and D m are ±.1 M -1, ± cm 2 s -1 and ± cm 2 s -1 respectively. 9
10 C 1 55 C 1 mn m -1 5 C 3 (C s ) / mn m C 2 (cac) C 3 (C s ) 4 C 4 (cmc) C 2 (cac) 25 C 4 (cmc) log log Fig. S1 Variation of surface tension (γ) as a function of logarithm of concentration of SAILs at.2 and concentrations of NaPSS for [C 12 mim][cl] and [C 14 mim][cl] (c) S cm Fig.S2 Variation of specific conductivity ( ) as a function of concentration of concentration of SAILs in aqueous solution at different temperatures [C 1 mim][cl] [C 12 mim][cl] (c) [C 14 mim][cl]. 1
11 K Fig.S3 Variation of specific conductivity ( ) as a function of concentration of [C 12 mim][cl] in the presence of ; and NaPSS at different temperatures K S cm K Fig. S4 Variation of specific conductivity ( ) as a function of concentration of [C 14 mim][cl] in the presence of ; and NaPSS at different temperatures. 11
12 I/I Turbidity / NTU Turbidity / NTU I/I [C 1 mim][cl] [C 12 mim][cl] [C 14 mim][cl] E-4 1E-3 C / mol dm -3 1E-4 1E-3.1 1E-4 1E-3.1 1E-4 1E-3.1 I/I I/I Turbidity / NTU (c) Fig.S5 Fluorescence intensity of ANS in NaPSS solution as a function of concentration of SAILs. and (c) represents fluorescence intensity of ANS in aqueous and aqueous NaPSS solutions at.2 and concentrations as a function of concentration of [C 12 mim][cl and [C 14 mim][cl]. [C 1 mim][c] [C 12 mim][c] [C 14 mim][c] C 3 (C s ) (c) 3 3 C 3 (C s ) C 2 (cac) C 4 (cmc) 2 C 2 (cac) C 4 (cmc) E Fig.S6. Variation of turbidity versus concentration of three SAILs in polyelectrolyte (NaPSS) solution at a concentration of ; and (c) Variation of turbidity versus concentration of [C 12 mim][cl] and [C 14 mim][cl] at.2 and concentrations of NaPSS. 12
13 % Intensity % Intensity % Intensity 35 5mM 35 5mM mM 4mM 2 2 3mM 3mM mM 2mM 1 14mM 1 14mM 2.2mM 2.2mM 5 5.mM.mM 1 1 D h / nm D h / nm 22 (c) 2 5.mM mM mM 1.5mM 8 1.mM 6.5mM 4 2.mM D h / nm D h / nm 16 (d) [C 1 mim][cl] 1 12 [C 12 mim][cl] [C 14 mim][cl] Fig.S7.Size distribution for concentrations of NaPSS in the presence of increasing concentrations of [C 1 mim][cl], [C 12 mim][cl] and (c) [C 14 mim][cl]. (d) Variation of hydrodynamic diameter (D h ) as a function of concentration of SAILs in NaPSS. 13
14 2 1-2 H / kj mol -1 H / kj mol -1 H / kj mol (c) 1. I II III -4 I II III I II III (d) 6. (e) 11.5 (f) dp / µcal sec dp / µcal sec dp / µcal sec Time / min Time / min Time / min (g) 1. (h) (i) dp / µcal sec dp / µcal sec -1. dp / µcal sec Time / min Time / min Time / min Fig.S8. Calorimetric profiles of SAILs as a function of concentration of [C 1 mim][cl]; [C 12 mim][cl] and (c) [C 14 mim][cl] in the absence and presence of polyelectrolyte, NaPSS (.2 and ) at K. Variation of differential power (dp) versus time for aqueous solution of (d) [C 1 mim][cl] (e) [C 12 mim][cl] (f) [C 14 mim][cl] and for the interaction of NaPSS with SAILs at a concentration of (g) [C 1 mim][cl] (h) [C 12 mim][cl] (i) [C 14 mim][cl]. 14
15 v v EMF / mv EMF / mv.1. C 3 (C 2 ) C 4 (cmc) C 3 (C s ) C 4 (cmc) C 2 (cac) log -.2 C 2 (cac) log Fig.S9 EMF as a function of logarithm of concentration of SAILs in the absence and presence of.2 and NaPSS for [C 12 mim][cl] and [C 14 mim][cl]. 2.x x1 9 3x x x1 9 2x x1 9 I II III 1.x1 9 I II III x log log Fig.S1 Binding isotherms of v versus logarithm of concentration of SAILs in the presence of.2 and NaPSS for [C 12 mim][cl] and [C 14 mim][cl]. 15
16 3.x1 2.5x1 3 i 1 / A P 1.x1 2 2.x1. ip / A 1 1. ip 1 /A ip / A 5.x1 1.5x1 1.x1 5.x C / mol dm x v1/2 / (V s-1)1/ Potential / V Potential / V Fig.S11 Reversible cyclic voltammograms of TEMPO in supporting electrolyte KCl in micellar solution of [C12mim][Cl] at different scan rates in the presence of NaPSS. [Inset of plot shows the variation of ip (A) versus v1/2 for TEMPO ion in aqueous [C12mim][Cl] solution and in the presence of NaPSS Differential pulse voltammograms (DPV) of TEMPO (2mM) in supporting electrolyte KCl (.1 M) for varying concentrations of [C12mim][Cl] in the presence of NaPSS [Inset of plot shows the variation of ip as a function of [C12mim][Cl] in aqueous and aqueous NaPSS solution (.2 and ). 1.2x1 3.x1 2.5x1 3. i 1 / A P 8.x x ip / A ip / A 4.x1 1.5x x1-8.x1 ip 1 /A x1 5.x1.5.1 C / mol dm-3.3 v1/2 / (V s-1)1/ Potential / V Potential / V Fig.S12 Reversible cyclic voltammograms TEMPO (2 mm) in supporting electrolyte KCl (.1 M) in micellar solution of [C14mim][Cl] at different scan rates in the presence of NaPSS [Inset of plot shows the variation of ip (A) versus v1/2 (V s-1)1/2 for TEMPO ion in aqueous [C12mim][Cl] solution and in the presence of NaPSS Differential pulse voltammograms (DPV) of TEMPO (2mM) in supporting electrolyte KCl (.1 M) for varying concentrations of [C14mim][Cl] in the presence of NaPSS [Inset of plot shows the variation of ip as a function of [C14mim][Cl] in aqueous and aqueous NaPSS solution (.2 and ). 16
17 References 1. A. Shaheen, I. Kaur, R.K. Mahajan, Ind. Eng. Chem. Res., 27, 46, R.K. Mahajan, A. Shaheen, J. Colloid Interface Sci., 28, 326, D.K. Chattoraj, K.S. Birdi, Adsorption and Gibbs Surface Excess, Plenum, New York, 1984 (Chapter 3). 4. K. Anand, O.P. Yadav, P.P. Singh, Colloids Surf. A, 1991, 55, P. Mukherjee, Adv. Colloid Interface Sci., 1967, 1, M.J. Rosen, Surfactant and Interfacial Phenomenon, 2 nd edn; John Wiley and Sons: New York,
PCCP PAPER. 1. Introduction. Renu Sharma, Ajar Kamal, Tejwant Singh Kang* and Rakesh Kumar Mahajan* View Article Online View Journal View Issue
PAPER View Article Online View Journal View Issue Cite this: Phys. Chem. Chem. Phys., 2015, 17, 23582 Received 7th May 2015, Accepted 6th August 2015 DOI: 10.1039/c5cp02642c www.rsc.org/pccp 1. Introduction
More informationSupporting information for: Interactional Behaviour of Surface Active Ionic Liquids with Gelling Biopolymer Agarose in Aqueous Medium
Supporting information for: Interactional Behaviour of Surface Active Ionic Liquids with Gelling Biopolymer Agarose in Aqueous Medium Pankaj Bharmoria and Arvind Kumar * Salt & Marine Chemicals Division,
More informationElectronic Supporting Information for
Electronic Supporting Information for An efficient long fluorescence lifetime polymer-based sensor based on europium complex as chromophore for the specific detection of F -, CH 3 COO - -, and H 2 PO 4
More informationCritical Micellization Concentration Determination using Surface Tension Phenomenon
Critical Micellization Concentration Determination using Phenomenon 1. Introduction Surface-active agents (surfactants) were already known in ancient times, when their properties were used in everyday
More informationComparative Study of Pure Micelles and Mixed Micelles in the presence of Polymer
Comparative Study of Pure Micelles and Mixed Micelles in the presence of Polymer Paray Aijaz Ahmad Department of chemistry, University of Kashmir, Hazratbal, Srinagar,J&K, (India) A B S T R A C T In this
More informationStimulating Electrocatalytic Oxygen Reduction Activity on Nitrogen doped Graphene through Noncovalent Molecular Functionalisation
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 206 Supporting Information Stimulating Electrocatalytic Oxygen Reduction Activity on Nitrogen doped
More informationMicellization behavior of mixed surfactants in pure water and methanol-water mixed solvent media by density methods
Ajaya Bhattarai et al. / BIBECHANA 13 (2016) 114-120: RCOST p. 114 (Online Publication: Dec., 2015) BIBECHANA A Multidisciplinary Journal of Science, Technology and Mathematics ISSN 2091-0762 (Print),
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Journal Name Chemicals Electronic Supplementary Information Two kinds of commercial anion exchange
More informationModule 4: "Surface Thermodynamics" Lecture 22: "" The Lecture Contains: Examples on Effect of surfactant on interfacial tension. Objectives_template
The Lecture Contains: Examples on Effect of surfactant on interfacial tension file:///e /courses/colloid_interface_science/lecture22/22_1.htm[6/16/2012 1:10:07 PM] Example Consider liquid, its vapors and
More informationSITARAM K. CHAVAN * and MADHURI N. HEMADE ABSTRACT INTRODUCTION
Int. J. Chem. Sci.: 11(1), 013, 619-67 ISSN 097-768X www.sadgurupublications.com DENSITIES, VISCOSITIES AND EXCESS THERMODYNAMIC PROPERTIES OF MONOMETHYL AMMONIUM CHLORIDE IN TETRAHYDROFURAN AND WATER
More informationHierarchical Host-Guest Assemblies Formed on Dodecaborate-Coated Gold Nanoparticles
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 17 Hierarchical Host-Guest Assemblies Formed on Dodecaborate-Coated Gold Nanoparticles
More informationConductometric Studies and Thermodynamic Behaviour of Neodymium Soaps in 60/40 Benzene-dimethylsulphoxide Mixture (V/V)
J. Biol. Chem. Chron. 2015, 1(1), 66-70 ISSN (Print): 2454 7468 ISSN (Online): 2454-7476 www.eresearchco/jbcc/ Conductometric Studies and Thermodynamic Behaviour of Soaps in 60/40 Benzene-dimethylsulphoxide
More informationMaterials. The three sulfonated calixarene host molecules, p- molecules, 5,6-dihydropyrazion[1,2,3,4-lmn][1,10]phenanthroline-4,7-diium (DP 2+ ) 4
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 214 Experimental Section Materials. The three sulfonated calixarene host molecules, p- sulfonatocalix[4]arene
More informationStrikingly different miscibility of n-octanol in highly-confined and quasi-confined water
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Strikingly different miscibility of n-octanol in highly-confined and quasi-confined water Aparajita
More informationExploiting the Interaction of Pyranine-3 with Poly(L-Lysine) to Mediate Nanoparticle Assembly: Fabrication of Dynamic ph-responsive Nanocontainers
Exploiting the Interaction of Pyranine-3 with Poly(L-Lysine) to Mediate Nanoparticle Assembly: Fabrication of Dynamic ph-responsive Nanocontainers Arlin Jose Amali, a Shashi Singh, b Nandini Rangaraj,
More informationElectrogenerated Upconverted Emission from Doped Organic Nanowires
Electrogenerated Upconverted Emission from Doped Organic Nanowires Qing Li, Chuang Zhang, Jian Yao Zheng, Yong Sheng Zhao*, Jiannian Yao* Electronic Supplementary Information (ESI) 1 Experimental details
More informationAwanish Kumar, Anjeeta Rani and Pannuru Venkatesu* Department of Chemistry, University of Delhi, Delhi
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2014 Supplimentary Informations
More informationElectronic Supporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Electronic Supporting Information A fast and selective probe for detection of CN - and F -
More informationElectronic Supplementary Information
Electronic Supplementary Information Uniform and Rich Wrinkled Electrophoretic Deposited Graphene Film: A Robust Electrochemical Platform for TNT Sensing Longhua Tang, Hongbin Feng, Jinsheng Cheng and
More informationThermodynamics of Dissociation and Micellization of Carboxylates of Dysprosium in Organic Solvent
Research Article Thermodynamics of Dissociation and Micellization of Carboxylates of in Organic Solvent Sangeeta* and M. K. Rawat Department of Chemistry, Agra College, Agra 282002, India Abstract myristate
More informationElectronic Supplementary Information
Electronic Supplementary Information Acid induced acetylacetonato replacement in biscyclometalated iridium(iii) complexes Yanfang Li, a,b Yang Liu * a,c and Ming Zhou* a,c a Suzhou Institute of Nano-Tech
More informationSupporting Information
Supporting Information Characterizing Emulsions by Observation of Single Droplet Collisions Attoliter Electrochemical Reactors Byung-Kwon Kim, Aliaksei Boika, Jiyeon Kim, Jeffrey E. Dick, and Allen J.
More informationPractical 1P3 Electrode Potentials
Practical 1P3 Electrode Potentials What you should learn from this practical Science This experiment will familiarise you with the thermodynamics of solutions and show how easily thermodynamic quantities
More informationSupplementary Information
Catalytically Efficient Palladium anoparticles Stabilized by Click rrocenyl Dendrimers Cátia rnelas, Lionel Salmon, Jaime Ruiz Aranzaes, Didier Astruc Supplementary Information Cyclic Voltammetry (CV),
More informationCobalt-Porphyrin /Dansyl Piperazine Complex Coated Filter. Paper for Turn on Fluorescence Sensing of Ammonia Gas
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 215 Electronic Supplementary Information Cobalt-Porphyrin /Dansyl Piperazine Complex Coated Filter
More informationSupplementary information for Organically doped palladium: a highly efficient catalyst for electroreduction of CO 2 to methanol
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2015 Supplementary information for rganically doped palladium: a highly efficient catalyst for
More informationExp.3 Determination of the Thermodynamic functions for the Borax Solution
Exp.3 Determination of the Thermodynamic functions for the Borax Solution Theory: The relationship between Gibb s energy (ΔG), Enthalpy (ΔH), Entropy (ΔS) and the equilibrium constant (K) for a chemical
More informationElectronic Supporting Information
This journal is The Royal Society of Chemistry 211 Electronic Supporting Information to: Unspecific ligand binding yielding stable colloidal ITO-nanoparticle dispersions by C. Grote, K. J. Chiad, D. Vollmer,
More informationA supramolecular approach for fabrication of photo- responsive block-controllable supramolecular polymers
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2014 Supporting Information A supramolecular approach for fabrication of photo- responsive
More informationProton-Coupled Electron Transfer Kinetics for the Hydrogen Evolution Reaction of Hangman Porphyrins
Electronic Supplementary Information Proton-Coupled Electron Transfer Kinetics for the Hydrogen Evolution Reaction of Hangman Porphyrins Manolis M. Roubelakis, D. Kwabena Bediako, Dilek K. Dogutan and
More informationSupporting Information
Supporting Information Carbon Nanodots: Supramolecular Electron Donor Acceptor Hybrids Featuring Perylenediimides** Volker Strauss, Johannes T. Margraf, Konstantin Dirian, Zois Syrgiannis, Maurizio Prato,
More informationSupramolecular Free Radicals: Near-infrared Organic Materials with Enhanced Photothermal Conversion. Supporting Information
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2015 Supramolecular Free Radicals: Near-infrared Organic Materials with Enhanced Photothermal
More informationElectronic Supplementary Material (ESI) for Dalton Transactions This journal is The Royal Society of Chemistry Supplementary Information
Supplementary Information 1 2-(2-Hydroxyphenyl)-1H-benzimidazole-manganese oxide hybrid as a promising structural model for Tyrosine 161/Histidine 190-manganese cluster in Photosystem II Mohammad Mahdi
More informationCHEM 254 EXPERIMENT 5. Solubility and Enthalpy of Fusion of Ammonium Oxalate in Water
CHEM 254 EXPERIMENT 5 Solubility and Enthalpy of Fusion of Ammonium Oxalate in Water In general solubility (g/100 ml) is defined as amount of substance that dissolved in a given solvent at a given temperature.
More informationElectronic Supplementary Information (ESI) for:
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information (ESI) for: A novel photoelectrocatalytic approach for
More informationSupporting information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting information Supercapacitor devices for energy storage and capacitive dye removal
More informationThermodynamics of Borax Dissolution
Thermodynamics of Borax Dissolution Introduction In this experiment, you will determine the values of H, G and S for the reaction which occurs when borax (sodium tetraborate octahydrate) dissolves in water.
More informationElectronic Supplementary Information. Selective detection of Al 3+ and citric acid with a fluorescent amphiphile
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Selective detection of Al 3+ and citric
More informationSupplementary Information. Seeding Approach to Noble Metal Decorated Conducting Polymer Nanofiber Network
Supplementary Information Seeding Approach to Noble Metal Decorated Conducting Polymer Nanofiber Network Zhen Liu, Selcuk Poyraz, Yang Liu, Xinyu Zhang* Department of Polymer and Fiber Engineering, Auburn
More informationNitroxide polymer networks formed by Michael addition: on site-cured electrode-active organic coating
Supporting information for: Nitroxide polymer networks formed by Michael addition: on site-cured electrode-active organic coating Takeshi Ibe, a Rainer B. Frings, b Artur Lachowicz, b Soichi Kyo, a and
More informationSupplementary Information: Phase Behavior and Molecular Thermodynamics of Coacervation
1 Supplementary Information: Phase Behavior and Molecular Thermodynamics of Coacervation in Oppositely Charged Polyelectrolyte/Surfactant System: Cationic Polymer JR 400 and Anionic Surfactant SDS Mixture
More informationMOF-76: From Luminescent Probe to Highly Efficient U VI Sorption Material
MOF-76: From Luminescent Probe to Highly Efficient U VI Sorption Material Weiting Yang, a Zhi-Qiang Bai, b Wei-Qun Shi*, b Li-Yong Yuan, b Tao Tian, a Zhi-Fang Chai*, c Hao Wang, a and Zhong-Ming Sun*
More informationTEM image of derivative 1 and fluorescence spectra of derivative 1 upon addition of
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2016 Supramolecular ensemble of PBI derivative and Cu 2 O NPs: Potential photo catalysts for
More informationUnusual ph-dependent Surface Adsorption and Aggregation Behavior of a series of Asymmetric Gemini Amino-acid Surfactants
Electronic Supplementary Material (ESI) for Soft Matter. This journal is The Royal Society of Chemistry 2015 Supplementary Information for: Unusual ph-dependent Surface Adsorption and Aggregation Behavior
More informationSupplementary Figure 1. XRD pattern for pristine graphite (PG), graphite oxide (GO) and
Supplementary Figure 1. XRD pattern for pristine graphite (PG), graphite oxide (GO) and expanded graphites (EG-1hr and EG-5hr). The crystalline structures of PG, GO, EG-1hr, and EG-5hr were characterized
More informationElectronic Supplementary Information : assembly of ph responsive branched copolymer-stabilised emulsion via electrostatic forces
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 01 Electronic Supplementary Information : Reversible assembly of ph responsive branched copolymer-stabilised
More informationTHE THERMODYNAMICS OF POTASSIUM NITRATE DISSOLVING IN WATER 1
THE THERMODYNAMICS OF POTASSIUM NITRATE DISSOLVING IN WATER 1 OBJECTIVE In this experiment, the changes in free energy (ΔG), enthalpy (ΔH), and entropy (ΔS) of the potassium nitrate (KNO 3 ) dissolving
More informationSupplementary Information
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2015 Supplementary Information Visualization of equilibrium position of colloidal particles at fluid-water
More informationNovel Supercapacitor Materials Including OLED emitters
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2015 Supporting Information Novel
More informationA Conjugated Polyelectrolyte-Based New Strategy. for In Situ Detection of Carbon Dioxide
Supporting Information A Conjugated Polyelectrolyte-Based New Strategy for In Situ Detection of Carbon Dioxide Yibing Fan, Chengfen Xing, *, Hongbo Yuan, Ran Chai, Linfei Zhao, and Yong Zhan Key Laboratory
More informationMonolayers. Factors affecting the adsorption from solution. Adsorption of amphiphilic molecules on solid support
Monolayers Adsorption as process Adsorption of gases on solids Adsorption of solutions on solids Factors affecting the adsorption from solution Adsorption of amphiphilic molecules on solid support Adsorption
More informationSupporting Information. Electrochemical Reduction of Carbon Dioxide on Nitrogen-Doped Carbons: Insights from Isotopic Labeling Studies
Supporting Information Electrochemical Reduction of Carbon Dioxide on Nitrogen-Doped Carbons: Insights from Isotopic Labeling Studies Dorottya Hursán 1,2 and Csaba Janáky 1,2* 1 Department of Physical
More informationSupporting Information
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 217 Supporting Information Catalyst preparation A certain of aqueous NiCl 2 6H 2 O (2 mm), H 2 PtCl
More informationThermodynamics of Micellization of Nonionic Surfactant Tween-40 in Presence of Additive Chloramine-T Using Clouding Phenomenon
http://www.e-journals.net ISSN: 973-4945; CDEN ECJHA E- Chemistry 21, 7(S1), S33-S334 Thermodynamics of Micellization of Nonionic Surfactant Tween-4 in Presence of Additive Chloramine-T Using Clouding
More information8. ELECTROCHEMICAL CELLS. n Electrode Reactions and Electrode Potentials a. H 2 2H + + 2e. Cl 2 + 2e 2Cl. H 2 + Cl 2 2H + + 2Cl ; z = 2
8. ELECTROCHEMICAL CELLS n Electrode Reactions and Electrode Potentials 8.1. a. H H + + e Cl + e Cl H + Cl H + + Cl ; z = E = E RT F ln ( a H +a Cl ) b. Hg(l)+ Cl Hg Cl + e H + + e H Hg + H + + Cl Hg Cl
More informationSolution reduction synthesis of amine terminated carbon quantum dots
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Solution reduction synthesis of amine terminated carbon quantum dots Keith Linehan and Hugh
More informationEffect of the Single and Double Chain Surfactant Cobalt(III) Complexes on Their Hydrophobicity, Micelle Formation,
Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers. This journal is the Partner Organisations 2014 Supplementary Information Effect of the Single and Double Chain Surfactant Cobalt(III)
More informationSupporting Information s for
Supporting Information s for # Self-assembling of DNA-templated Au Nanoparticles into Nanowires and their enhanced SERS and Catalytic Applications Subrata Kundu* and M. Jayachandran Electrochemical Materials
More informationBulk graphdiyne powder applied for highly efficient lithium storage
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Bulk graphdiyne powder applied for highly efficient lithium storage Shengliang Zhang, ab Huibiao
More informationThe thermodynamics of the solubility of borax
Chemistry 1 6 3 The thermodynamics of the solubility of borax Purpose: To determine the thermodynamic quantities ΔH and ΔS for the solvation reaction of borax in water by measuring the solubility product
More informationImpact of multivalent charge presentation on peptide
Supporting Information File 1 for Impact of multivalent charge presentation on peptide nanoparticle aggregation Daniel Schöne 1, Boris Schade 2, Christoph Böttcher 2 and Beate Koksch* 1 Address: 1 Institute
More informationA Highly Selective Fluorescent Probe for Fe 3+ in Living Cells: A Stress Induced Cell Based Model Study
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information A Highly Selective Fluorescent Probe
More informationThermodynamics of cationic and anionic surfactant interaction
Thermodynamics of cationic and anionic surfactant interaction Vytautas Petrauskas Department of Biothermodynamics and Drug Design Institute of Biotechnology, Vilnius University October 16, 2014 Vytautas
More informationREADING A. INTRODUCTION CHE425L POTENTIOMETRY WITH K + ION-SELECTIVE ELECTRODE. Skoog, Holler and Crouch: Chapter 23 and Appendix 3.
CHE425L POTENTIOMETRY WITH K + ION-SELECTIVE ELECTRODE READING Skoog, Holler and Crouch: Chapter 23 and Appendix 3. A. INTRODUCTION Potentiometry is a static electroanalytical method in which the potential
More informationChapter 2. Materials and Methods
Chapter 2 Materials and Methods 2. Materials and Methods This chapter describes the chemicals, reagents and instruments used for carrying out this study. A brief discussion of the methods used for the
More informationV(STP) No.of mequivalents = n. Analytical chemistry
Analytical chemistry 1-qualitative analysis. Is concerned with the identification of ions molecules elements and compounds present in sample 2- Quantitative analysis :- Is concerned with the Determination
More informationA dual redox-responsive supramolecular amphiphile fabricated by selenium-containing pillar[6]arene-based molecular recognition
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 A dual redox-responsive supramolecular amphiphile fabricated by selenium-containing pillar[6]arene-based
More informationCHAPTER - 2 EXPERIMENTAL. Sodium dodecyl benzene sulphonate (SDBS) and Sodium dodecyl sulfate
2.1 Materials CHAPTER - 2 EXPERIMENTAL 2.1.1 Surfactants Sodium dodecyl benzene sulphonate (SDBS) and Sodium dodecyl sulfate (SDS) were procured from Sigma and used as received without any further purification.
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary material (ESI) for Nanoscale Electronic Supplementary Information (ESI) Synthesis of Nanostructured Materials by Using Metal-Cyanide Coordination Polymers and Their Lithium Storage
More informationComplex equilibria and calculations of formation constants from potentiometric data
Experiment 8: /Ag 2 Based Ion elective Electrode Determination of Lead/Hydroxide Equilibria While lead hydroxide does not give a good quantitative measure of lead, particularly in the presence of competing
More informationSelf-discharge of electrochemical capacitors based on soluble or grafted quinone
Electronic Supplementary Material (ESI for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2016 Electronic Supplementary Information Self-discharge of electrochemical capacitors
More informationFinal Exam Review-Honors Name Period
Final Exam Review-Honors Name Period This is not a fully comprehensive review packet. This packet is especially lacking practice of explanation type questions!!! You should study all previous review sheets
More informationSupporting Information
Supporting Information 1-(2-Naphthyl)benzimidazolium based tripod for the fluorescence enhancement based recognition of surfactants in water Sandeep Kumar, Shafali, Prabhpreet Singh and Subodh Kumar *
More informationSupplementary Information. Carolyn Richmonds, Megan Witzke, Brandon Bartling, Seung Whan Lee, Jesse Wainright,
Supplementary Information Electron transfer reactions at the plasma-liquid interface Carolyn Richmonds, Megan Witzke, Brandon Bartling, Seung Whan Lee, Jesse Wainright, Chung-Chiun Liu, and R. Mohan Sankaran*,
More informationElectronic Supplementary Information. Jiani Wang, Lei Zhang, Qiong Qi, Shunhua Li* and Yunbao Jiang
Electronic Supplementary Information Specific ratiometric fluorescent sensing of Hg 2+ via the formation of mercury(ii) barbiturate coordination polymers Jiani Wang, Lei Zhang, Qiong Qi, Shunhua Li* and
More informationDendritic Star Polymer of Polyacrylamide Based on β-cyclodextrin Trimer: A. Flocculant and Drug Vehicle
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2016 Electronic Supporting Information
More informationHighly efficient hydrogen evolution of platinum via tuning the interfacial dissolved-gas concentration
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2018 Supporting Information for Highly efficient hydrogen evolution of platinum via tuning
More informationCarbon powder modification. Preparation of NS1, NS2, NS3 and NS4.
SUPPORTING INFORMATION EXPERIMENTAL SECTION Reagents. Carbon powder (Norit-S50) was purchased from Norit, 4-aminobenzene sulfonic acid (99%), lithium perchlorate (99%, potassium ferricyanide (99%) and
More informationA new concept of charging supercapacitors based on a photovoltaic effect
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Electronic supporting information (ESI) A new concept of charging supercapacitors based on a photovoltaic
More informationUnit 12. Thermochemistry
Unit 12 Thermochemistry A reaction is spontaneous if it will occur without a continuous input of energy However, it may require an initial input of energy to get it started (activation energy) For Thermochemistry
More informationComposition of Surface Layer at the Water Air Interface and Micelles of Triton X Rhamnolipid Mixtures
J Solution Chem (2017) 46:1251 1271 DOI 10.1007/s10953-017-0642-7 Composition of Surface Layer at the Water Air Interface and Micelles of Triton X-100 + Rhamnolipid Mixtures Diana Mańko 1 Anna Zdziennicka
More informationTHE THERMODYNAMICS OF POTASSIUM NITRATE DISSOLVING IN WATER V010516
THE THERMODYNAMICS OF POTASSIUM NITRATE DISSOLVING IN WATER V010516 OBJECTIVE The ΔG, ΔH and ΔS of the potassium nitrate (KNO3) dissolving reaction will be determined by measuring the equilibrium constant
More informationconcentrations (molarity) rate constant, (k), depends on size, speed, kind of molecule, temperature, etc.
#80 Notes Ch. 12, 13, 16, 17 Rates, Equilibriums, Energies Ch. 12 I. Reaction Rates NO 2(g) + CO (g) NO (g) + CO 2(g) Rate is defined in terms of the rate of disappearance of one of the reactants, but
More informationSupporting Information
Supporting Information High Performance Electrocatalyst: Pt-Cu Hollow Nanocrystals Xiaofei Yu, a Dingsheng, a Qing Peng a and Yadong Li* a a Department of Chemistry, Tsinghua University, Beijing, 100084
More informationSupporting information
Electronic Supplementary Material (ESI) for Analyst. This journal is The Royal Society of Chemistry 2014 Supporting information Quantized double layer charging of Au 130 (SR) 50 Nanomolecules Vijay Reddy
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supporting Information Experimental section Synthesis of Ni-Co Prussian
More informationSupporting Information. Autocatalytic Cycles in a Copper-Catalyzed Azide-Alkyne Cycloaddition Reaction
Supporting Information Autocatalytic Cycles in a Copper-Catalyzed Azide-Alkyne Cycloaddition Reaction Sergey N. Semenov, a Lee Belding, a Brian J. Cafferty, a Maral P.S. Mousavi, a Anastasiia M. Finogenova,
More informationSupporting Information
Supporting Information Determination of the critical micelle concentration of SDS Electrical conductivity and light scattering measurements were used to determine the CMC value of SDS. Since the mobility
More informationA novel electrolyte system without Grignard reagent for rechargeable magnisium battery
Electronic Supplementary Information A novel electrolyte system without Grignard reagent for rechargeable magnisium battery Fei-fei Wang, a,b Yong-sheng Guo, a,b Jun Yang,* a,b Yanna Nuli, a,b Shin-ichi
More informationDirect Ion Speciation Analysis with Ion-selective Membranes Operated in a Sequential Potentiometric/Time Resolved Chronopotentiometric Sensing Mode
Supporting information for: Direct Ion Speciation Analysis with Ion-selective Membranes Operated in a Sequential Potentiometric/Time Resolved Chronopotentiometric Sensing Mode Majid Ghahraman Afshar a,b,
More informationPhysical Chemistry Advanced laboratory course. Excimer formation
Physical Chemistry Advanced laboratory course Excimer formation 02-2010 Experimental Make a 1*10-2 M solution of pyrene (C 16 H 10, molecular weight M = 202.25 g/mol) in methylcyclohexane. From
More informationElectronic Supplementary Information. Hydrogen Evolution Reaction (HER) over Electroless- Deposited Nickel Nanospike Arrays
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Hydrogen Evolution Reaction (HER) over Electroless- Deposited
More informationUnit 2 Electrochemical methods of Analysis
Unit 2 Electrochemical methods of Analysis Recall from Freshman Chemistry: Oxidation: Loss of electrons or increase in the oxidation number Fe 2 e - Fe 3 Reduction: Gain of electrons or decreases in the
More informationLecture Notes 1: Physical Equilibria Vapor Pressure
Lecture Notes 1: Physical Equilibria Vapor Pressure Our first exploration of equilibria will examine physical equilibria (no chemical changes) in which the only changes occurring are matter changes phases.
More informationHighly Ordered Binary Assembly of Silica Mesochannels. and Surfactant Micelles for Extraction and Electrochemical
Supporting Information to Highly Ordered Binary Assembly of Silica Mesochannels and Surfactant Micelles for Extraction and Electrochemical Analysis of Trace Nitroaromatic Explosives and Pesticides Fei
More informationIn-situ potentiometry and ellipsometry: a promising tool to study biofouling of potentiometric sensors
In-situ potentiometry and ellipsometry: a promising tool to study biofouling of potentiometric sensors Grzegorz Lisak 1,2,3, *, Thomas Arnebrant 2,3, Andrzej Lewenstam 1,4, Johan Bobacka 1, Tautgirdas
More informationAP CHEMISTRY 2007 SCORING GUIDELINES (Form B)
AP CHEMISTRY 2007 SCORING GUIDELINES (Form B) Question 1 A sample of solid U O 8 is placed in a rigid 1.500 L flask. Chlorine gas, Cl 2 (g), is added, and the flask is heated to 862 C. The equation for
More informationModule 4: "Surface Thermodynamics" Lecture 21: "" The Lecture Contains: Effect of surfactant on interfacial tension. Objectives_template
The Lecture Contains: Effect of surfactant on interfacial tension file:///e /courses/colloid_interface_science/lecture21/21_1.htm[6/16/2012 1:10:36 PM] Surface Thermodynamics: Roles of Surfactants and
More informationThe underlying prerequisite to the application of thermodynamic principles to natural systems is that the system under consideration should be at equilibrium. http://eps.mcgill.ca/~courses/c220/ Reversible
More informationInterfacial bonding stabilizes rhodium and rhodium oxide nanoparticles on layered Nb- and Ta-oxide supports
Interfacial bonding stabilizes rhodium and rhodium oxide nanoparticles on layered Nb- and Ta-oxide supports Megan E. Strayer, 1 Jason M. Binz, 2 Mihaela Tanase, 3,4 Seyed Mehdi Kamali Shahri, 2 Renu Sharma,
More information