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1 DENIOS experimental presentation hazardous materials live! hazardous materials live / T. Authmann / wednesday June 27 th partner of environmen

2 topics accidents and follow-up damages danger potential in daily work flashpoint & self ignition temperature danger triangle explosive atmospheres acids & alkaline conclusion experimental lecture / T. Authmann / Mar. 30th 2016 Seite 2

3 topic: potential dangers dangerous situations: hazardous materials: Which dangers are existent in daily work situations? detergents, that do not obstensibly indicate danger Only if we identify danger, we react appropriately to avoid it! experimental lecture / T. Authmann / Mar. 30th 2016 Seite 3

4 topic: potential dangers situation: aerosol can lubricant flashpoint 47 C spraying into a flame question: will it burn? experimental lecture / T. Authmann / Mar. 30th 2016 Seite 4

5 topic: flashpoint and self ignition temperature what is the self ignition temperature? The lowest temperature, at which a flammable substanceat starts to burn without an ignition sources as sparkles or open fire. diesel: benzin: alcohol: acetone: acetylene: self ignition temperature: 220 C 240 C 425 C 540 C 305 C flashpoint: 55 C -20 C 12 C -18 C gas! experimental lecture / T. Authmann / Mar. 30th 2016 Seite 5

6 topic: gas most industrial gases have the following characteristics: F 2 colourless ( e.g. H 2 ; He ; ; C 2 H 2 ) no smell or taste O 2 heavier than air ( e.g.: ; CO 2 ; CO ; NO X ; Ne ; Kr ; Ar ; Xe Cl 2 ) they sink to the ground Why might this be dangerous?! displacement of respirable air experimental lecture / T. Authmann / Mar. 30th 2016 Seite 6

7 topic: gas repeated deaths by asphyxiation : - silos in agriculture / wine cellars - drains - mine shafts - reservoirs - roadtankers/ cargoships - ditches and any locations that are below the surrounding environment - industry, laboratories Production processes that set free gases or in which technical gases are used, as well as any use of gases from gas cylinders do generally require special : - knowledge experimental lecture / T. Authmann / Mar. 30th security - handling - warehousing Seite 7

8 topic: potential dangers DON`T! experimental lecture / T. Authmann / Mar. 30th 2016 Seite 8

9 topic: potential dangers for better : experimental lecture / T. Authmann / Mar. 30th 2016 Seite 9

10 topic: potential dangers for or better : experimental lecture / T. Authmann / Mar. 30th 2016 Seite 10

11 topic: potential dangers advice for fire prevention: - correct disposal / seperation of waste! - use of adequate disposal containers! - correct disposal also for oil- & tissues containing oil! experimental lecture / T. Authmann / Mar. 30th 2016 Seite 11

12 topic: the danger triangle combustible ignition source or self ignition temperature oxigen experimental lecture / T. Authmann / Mar. 30th 2016 Seite 12

13 topic: potential dangers oxygen accumulation flamable substance oxygen ignition source oxygen proportion between each substance effect the danger triangle oxygen accumulation acts extremely oxidising! experimental lecture / T. Authmann / Mar. 30th 2016 Seite 13

14 topic: potential dangers upper and lower explosibilitylimit upper explosibility limit fat mixture danger of fire Vol % Explosionsgefahr lower explosibility limit fatless mixture - no danger experimental lecture / T. Authmann / Mar. 30th 2016 Seite 14

15 topic: potential dangers how can explosions be avoided? avoid ignition sources Having to cope with dust use of explosion secure machinery and equipment steady removal of dust deposits (cleaning) avoid dispersion experimental lecture / T. Authmann / Mar. 30th 2016 Seite 15

16 topic: potential dangers Most important ignition sources for dust explosions: open flames hot spots ( pockets of ambers ) hot surfaces sparkles: mechanical ( from work processes ) electrical sparkles ( from non EX-safe machinery ) electrostatic discharges ( from pouring dusts, granulates or liquids ) experimental lecture / T. Authmann / Mar. 30th 2016 Seite 16

17 topic: acids und alkaline Situation: shelf containment for caustic soda containment for hydrochloric acid both containers stand sid by side question: what happens if acid and alkaline get in contact? experimental lecture / T. Authmann / Mar. 30th 2016 Seite 17

18 topic: conclusion risk minimising by secure storing of hazardous materials marking lockable electrical grounded ventilation explosion prevention collecting tray fire prevention experimental lecture / T. Authmann / Mar. 30th 2016 Seite 18

19 topic: potential dangers main causes for accidents in industry : all of us!!! human errors missing communication lack of knowledge ignorance haste and carelessness wrong labeling, handling, storing, displosal experimental lecture / T. Authmann / Mar. 30th 2016 Seite 19

20 We are responsible for what we do, but also for the, things we do not do. Voltaire, experimental lecture / T. Authmann / Mar. 30th 2016 Seite 20

21 For further informations for the use of flammable fluids : experimental lecture / T. Authmann / Mar. 30th 2016 Seite 21

22 Many thanks for your attention. partner of environmen

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