PRODUCT SAFETY SUMMARY (GPS) SODIUM-HYDROXIDE

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1 This Product Safety Summary is intended to provide a general overview of the chemical substance in the context of ICCA (International Council of Chemical Associations) Global Product Strategy. The information in the Summary is basic information and is not intended to provide emergency response, medical or treatment information. In-depth safety and health information can be found in the (extended) Safety Data Sheet (e)sds for the chemical substance. 1. GENERAL STATEMENT Pure sodium hydroxide is a solid at room temperature and is generated from sodium chloride (common salt) by electrolysis. Sodium hydroxide is a hydrophilic alkaline substance (high ph) and therefore it is corrosive and hazardous to human health. It is most commonly found as a liquid, which has a concentration of between 20% and 50 % sodium hydroxide in water and is usually referred to as caustic soda liquor. The substance is used in large amounts in a variety of industries. 2. CHEMICAL IDENTITY Name: sodium-hydroxide EC number: CAS number: Molecular formula: NaOH 3. USE AND APPLICATIONS Sodium hydroxide has many different functions and uses. For example, intermediates; ph-regulating agents; laboratory chemicals. Sodium hydroxide solution is used by the organic and inorganic chemical industry in the largest volume. The paper, cellulose, rayon and viscose silk and aluminium industries use it in large scale. In addition, the soap and detergent production as well as the glass and food industries are among the significant users. It is also used in water and waste water treatment operations. 4. PHYSICAL/CHEMICAL PROPERTIES Pure sodium hydroxide is a solid at room temperature, though it is often sold as a liquid (aqueous solution). The appearance of the substance and some physicochemical properties are mentioned in the table below. Physical state liquid (20ºC, 1013 hpa) Colour colourless Odour odourless Density g/cm 3 Melting point -26 C Boiling point 108 C Molecular weight 40 g/mol Version / 6

2 5. HUMAN HEALTH SAFETY ASSESSMENT Sodium hydroxide is a strongly alkaline hydrophilic substance and therefore solid sodium hydroxide is highly corrosive. It reacts with greases and fats, which can lead to irreversible damage to any site of contact with the body (for example skin or eyes). Depending on the concentration, solutions of sodium hydroxide in water are corrosive, irritating or non-irritating and they cause direct local effects at the site of contact with the body. Under normal conditions of handling and use of sodium hydroxide, when exposure is low, the substance will dissociate into its constituent ions and will not be systemically available in the body. As a consequence, sodium hydroxide will not cause systemic toxicity in any organs. 6. ENVIRONMENTAL SAFETY ASSESSMENT Sodium hydroxide is a strong alkaline substance that dissociates completely in water to Na+ and OH-. High water solubility and low vapour pressure indicate that NaOH will be found predominantly in aquatic environment. A high concentration in water will result in toxic effects for aquatic organisms e.g. fish. However, a low concentration in water will not result in effects on aquatic organisms because the sodium hydroxide will be neutralized by other substances present in water (for example dissolved carbon dioxide, organic acids) and thus the ph will not increase. Because sodium hydroxide is neutralized in the environment, the substance is not persistent and it will not accumulate in organisms or in the food chain. Bioaccumulation will not occur. 7. EXPOSURE 7.1 HUMAN HEALTH Consumers Sodium hydroxide is used in consumer products. It can be used, for example, in floor stripping products, wood stripping products, hair straightening agents, oven cleaners, drain cleaners or other cleaning products. It is also used in very small amounts in food products to adjust ph or as an additive (E524). This use poses no risk to consumers. Many different consumer products containing sodium hydroxide may be available. The instructions on the label of these products should be read and followed carefully to ensure safe use. Direct skin contact with products or solutions containing a low concentration of sodium hydroxide ( < 0.5% in water) is not a concern for human health because, at low concentrations, the substance is not irritating or corrosive. No other adverse effects on human health are expected to occur. Direct contact with products or solutions containing high concentrations of sodium hydroxide (>2% in water) should be prevented, because of the corrosive effects. Version / 6

3 Workers Because sodium hydroxide has many different functions and uses, it is extensively used in the industry. As mentioned above in the section on consumer exposure, skin contact for products or solutions with a low sodium hydroxide concentration is not a concern for human health because, at low concentrations, the substance is not irritating or corrosive (<0.5% in water). The sodium hydroxide which is manufactured and used in industry applications is usually corrosive and therefore automated and closed systems are used to prevent direct contact. In such situations, exposure to the substance for workers is very low. When exposure to an irritating or corrosive product could occur, appropriate personal protective equipment should be used. Workers should consult the manufacturer s Safety Data Sheet to obtain specific advice. 7.2 ENVIRONMENT The hazard of sodium hydroxide for the environment is caused by the hydroxide ion (ph effect). Because there is legislation for the ph control of waste water and surface water in many countries, a significant ph increase of the aquatic environment (e.g. a river or a sea) is not expected due to the manufacture or use of sodium hydroxide. Therefore significant effects of sodium hydroxide on the aquatic environment are not expected. Emissions to air are also not a concern because sodium hydroxide will be rapidly neutralised in air due the presence of carbon dioxide in air. Version / 6

4 8. RISK MANAGEMENT RECOMMENDATIONS General: Human health measures Eye wash bottles or eye wash stations in compliance with applicable standards. Take off contaminated clothing and shoes immediately. Handle in accordance with good industrial hygiene and safety practice. Eye / Face protection: Closed safety goggles. Protection Skin protection: Hand protection: Chemical resistant apron. Apron/boots of PVC, neoprene in case of dusts. Impervious gloves. Suitable material: PVC, Neoprene, Natural Rubber, butyl-rubber. Unsuitable material: Leather. Respiratory protection: In the case of dust or aerosol formation use respirator with an approved filter. Recommended Filter type: P2. Engineering controls: Ensure adequate ventilation. Apply technical measures to comply with the occupational exposure limits. Environment protective measures Should not be released into the environment. Do not flush into surface water or sanitary sewer system. Version / 6

5 9. REGULATORY INFORMATION / CLASSIFICATION AND LABELLING 9.1 REGULATORY INFORMATION The sodium-hydroxide has been registered under the European REACH Regulation EC/1907/2006 and the substance was found to be safe for the uses identified. 9.2 CLASSIFICATION AND LABELLING The substance is subject to harmonised classification under the EU Classification Labelling and Packaging (CLP) Regulation EC/1272/2008. Industry has adopted a more stringent self-classification, as follows: The classification for sodium-hydroxide depends on specific concentration limits: Sodium-hydroxide 5% : Hazard classes / categories Pictogram Hazard statements Skin Corr. 1A H314 Causes severe skin burns and eye damage. Eye Dam. 1 H318 Causes serious eye damage. Met.Corr. 1 H290 Fémekre korrozív hatású lehet. 2% Sodium-hydroxide 5% : Hazard classes / categories Pictogram Hazard statements Skin Corr. 1B H314 Causes severe skin burns and eye damage. Eye Dam. 1 H318 Causes serious eye damage. Met.Corr. 1 H290 May be corrosive to metals. 0.5% Sodium-hydroxide 2% : Hazard classes / categories Pictogram Hazard statements Skin irrit. 2 H315 Causes skin irritation. Eye irrit. 2 H319 Causes serious eye irritation. Met.Corr. 1 H290 May be corrosive to metals. Version / 6

6 10. CONTACT INFORMATION For further information on this substance or product safety summaries in general, please contact the following address: or visit our website at: Compilation 09/12/2015 Revision - This datasheet is prepared for the purpose of providing health, safety and environmental data. While the data and information contained in the present datasheet are provided in good faith, these are to be considered as guidance only. Thus, this datasheet shall not constitute a guarantee for any specific properties or quality standards. This document does not constitute a warranty or guarantee. Manufactured by: BorsodChem Zrt. Bolyai tér 1. H-3700 Kazincbarcika Hungary Phone: Fax: Version / 6

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