TitleProfessor Shigeo Taminoto, Cover &
|
|
|
- Mercy Harrington
- 5 years ago
- Views:
Transcription
1 TitleProfessor Shigeo Taminoto, Cover & Author(s) Citation Bulletin of the Institute for Chemi University (1992), 70(3) Issue Date URL Right Type Others Textversion publisher Kyoto University
2 ISSN BULLETIN OF THE INSTITUTE FOR CHEMICAL RESEARCH KYOTO UNIVERSITY Vol. 70, No. 3 Commemoration Issue Dedicated to Professor Shigeo TANIMOTO On the Occasion of His Retirement Published bi-monthly by THE INSTITUTE FOR CHEMICAL RESEARCH KYOTO UNIVERSITY KYOTO, JAPAN October 1992 (Bull. Inst. Chem. Res., Kyoto Univ.)
3
4
5 Professor Shigeo Taminoto On the 31 st of March, 1992, Dr. Shigeo Tanimoto retired after having completed his 39 years of service at Kyoto University. Dr. Tanimoto was born in Yamaguchi on the 26th of October, He graduated from Faculty of Engineering, Kyoto University in 1951 and then continued his studies on organic chemistry under the supervision of Professor R. Oda. After the graduation in 1953, he started his academic career as an instructor of the Institute for Chemical Research, Kyoto University, majoring in organic synthesis. He received his doctoral digree from Kyoto University in 1962 for his studies on the synthesis of compounds suitable for polymerization to the functionalized polymers. He was promoted to an associate professor of the Institute for Chemical Research in In 1974, on leave from Kyoto University, he stayed at Köln University, Bundesrepublik Deutschland (West Germany), and made a joint research with Professor E. Vogel on the chemistry of nonbenzenoid aromatic compounds. In 1989, Dr. Tanimoto was appointed full professor of Kyoto University and directed the Laboratory of Petroleum Chemistry, Institute for Chemical Research of the University. For the past forty years, he investigated extensively the field of preparative organic chemistry using 1, 3 butadienyl compounds, cyclic sulfur compounds, bovine serum albumin, and participation by arylthio group. He also developed a new field in which polar aprotic solvents were utilized as the reaction medium. In 1983, he was awarded a prize from the Society of Synthetic Organic Chemistry, Japan for the brilliant development in organic syntheses by the utilization of specific character of individual element of chalcogens. Dr. Tanimoto gave lectures on stereochemistry and chemistry of active intermediates at the graduate school of synthetic and hydrocarbon chemistry, Kyoto University and supervised the dessertation works of many graduate students. His sincere and warm personality is respected by many friends, colleagues, present associates, students, and all those who came in contact with him. This collection of papers by his colleagues, present associates, and students is dedicated to Dr. Taminoto in honor of his sincere service for a long period and retirement. August, 1992 Jun'ichi Oda Director for Chemical Research Institute Kyoto University
6 CONTENTS Commemoration Issue Dedicated to Professor Shigeo Tanimoto on the Occasion of His Retirement Kazumi Sakata, Yoshiaki Kimura and Yoshinori Fujiyoshi : Methods for Orienting Purple Membrane in Vitreous Ice Akio Toshimitsu, Takehiro Kusumoto and Shigeo Tanimoto : Formation of Carbocyclic Compounds from 1, 5-Hexadiene by the Reaction with Benzeneselenenyl Chloride in the Presence of Acid Akio Toshimitsu, Masaaki Ito and Shigeo Tanimoto : Pyridylseleno Group in Organic Synthesis. Part 7. Asymmetric Reduction of. (2-Pyridylseleno)- methyl Aryl Ketones Kiyoshi Kudo, Sadayuki Mori and Nobuyuki Sugita : Transcarboxylation of Naphthalene using the Alkali Metal Salts of Benzene Carboxylic Acids under Carbon Dioxide Pressure Tatsuo Oida, Masayuki Nakamura, Yoriyuki Takashima and Yoshiyuki Hayashi : The Reactions of 2-(Trimethylsilyl) ethyl Benzenesulfenate as an Equivalent of Sulfenate Anion or a Precursor of Sulfenyl Cation Kaoru Nakamura, Hideyuki Kondo, Patrick Metzner and Atsuyoshi Ohno : Lipase-catalyzed Asymmetric Transesterification of 3-Hydroxydithiopentanoate in an Organic Solvent Manabu Node, Tetsuya Kajimoto, Kiyoharu Nishide, Eiichi Fujita and Kaoru Fuji : Hard Acid and Soft Nucleophile Systems. Part 13. Aluminum Chloride Sodium Iodide Acetonitrile System : A Very Mild Reagent for Selective Dealkylation Kaoru Fuji, Takeo Kawabata, Masaru Ueda, Mayumi Fujimoto, Eiichi Fujita and Manabu Node : Hard Acid and Soft Nucleophile Systems. Part 14. On the Reactivity of a-nitroketones and Nitroolefins Toward a Aluminum Chloride and Ethanethiol System COMMUNICATIONS Naomichi Baba, Kazuyuki Ikeda and Junkichi Iwasa : Kinetic Partial Resolution of Racemic 4 -Hydroperoxy-Cyclophosphamide by Lipase in Vinyl Acetate...326
7 Toyonari Sugimoto, Masashi Sakaguchi, Hiroshi Ando, Yoshihisa Arai, Tomohiro Tanaka, Zen-ichi Yoshida and Jun Yamauchi : Participation of Several Different Electronically-Excited Biradical Structures in the Ground States of Bicyclic Tricalicene and Tricyclic Tetracalicene NOTE Katsumi Nakai, Jun Hiratake and Jun'ichi Oda : Kinetic Resolution of Racemic a-aminonitriles via Stereoselective N-Acetylation Catalyzed by Lipase in Organic Solvent REVIEWS Keiji Terao : a-chlorocarbonyl Compounds Their Synthesis and Applications Tohru Yoshimura, Nobuyoshi Esaki and Kenji Soda : Structure and Function of Alanine Racemase...378
8 e Received from the Library of Institute for Chemical Research, Kyoto University the following Publication(s) b"bulletin of Institute for Chemical Research, Kyoto University." Vol. 70, No. 3 (1992)copy/copies fd Institute : r.. Address : Date : Signature :
9
10
Citation ICR annual report (1996), 2:
TitlePERSONAL Author(s) Citation ICR annual report (1996), 2: 89-92 Issue Date 1996-03 URL http://hdl.handle.net/2433/65686 Right Type Others Textversion publisher Kyoto University PERSONAL 90 Retirement
Carboxylic Acid Derivatives. Citation University (1980), 57(5-6):
Preparation of 3-Aryl-2H-1,2,4-benz Titleby the Reaction of o-aminobenzenesu Carboxylic Acid Derivatives Author(s) Tanimoto, Shigeo; Yoshida, Norio; S Okano, Masaya Citation Bulletin of the Institute for
Author(s) Toshimitsu, Akio; Ito, Masaaki; Tan.
Pyridylseleno Group in Organic Synt Title Reduction of (2-Pyridylseleno)methy (Commemoration Issue Dedicated to P Tanimoto On the Occation of His Ret Author(s) Toshimitsu, Akio; Ito, Masaaki; Tan Citation
Title Heterogeneous Mixture of Metals and Initiator for Vinl Polymerization Author(s) Furukawa, Junji; Fueno, Takayuki Citation Bulletin of the Institute for Chemi University (1959), 37(4): 260-266 Issue
Spring Term 2012 Dr. Williams (309 Zurn, ex 2386)
Chemistry 242 Organic Chemistry II Spring Term 2012 Dr. Williams (309 Zurn, ex 2386) Web Page: http://math.mercyhurst.edu/~jwilliams/ jwilliams@mercyhurst.edu (or just visit Department web site and look
Synthesis of Nitriles a. dehydration of 1 amides using POCl 3 : b. SN2 reaction of cyanide ion on halides:
I. Nitriles Nitriles consist of the CN functional group, and are linear with sp hybridization on C and N. Nitriles are non-basic at nitrogen, since the lone pair exists in an sp orbital (50% s character
Hard Acid and Soft Nucleophile Syst Chloride-Sodium Iodide-Acetonitrile TitleReagent for Selective Dealkylation Dedicated to Professor Shigeo Tanim His Retirement) Author(s) Node, Manabu; Kajimoto, Tetsuya;
Chapter 10: Carboxylic Acids and Their Derivatives
Chapter 10: Carboxylic Acids and Their Derivatives The back of the white willow tree (Salix alba) is a source of salicylic acid which is used to make aspirin (acetylsalicylic acid) The functional group
CHEMISTRY (CHE) CHE 104 General Descriptive Chemistry II 3
Chemistry (CHE) 1 CHEMISTRY (CHE) CHE 101 Introductory Chemistry 3 Survey of fundamentals of measurement, molecular structure, reactivity, and organic chemistry; applications to textiles, environmental,
Raman Spectra of Benzene, Ethyl Ben Title Suito on the Occasion of his Retire. Author(s) Takenaka, Tohru; Harada, Kaoru; Nak
Raman Spectra of Benzene, Ethyl Ben Title Phthalate Solubilized in Aqueous So Agents (Commemoration Issue Dedicat Suito on the Occasion of his Retire Author(s) Takenaka, Tohru; Harada, Kaoru; Nak Citation
Homework - Chapter 9 Chem 2310
Homework - Chapter 9 Chem 2310 me:. ntroduction to organic halides 1. Draw a line structure for a compound with the following description: an alkyl halide with the formula C 5 H 11 a vinyl halide with
SINGLE ELECTRON TRANSFER IN REACTIONS INVOLVING ALKYL HALIDES AND ESTERS WITH NUCLEOPHILES A THESIS. Presented to
SINGLE ELECTRON TRANSFER IN REACTIONS INVOLVING ALKYL HALIDES AND ESTERS WITH NUCLEOPHILES A THESIS Presented to The Faculty of the Division of Graduate Studies By Won-Suh Park In Partial Fulfillment of
Synthesis and Reactivity of Vinyl Iodonium Salts
Chemistry Honors Final Report Mackenzie Liebl Synthesis and Reactivity of Vinyl odonium Salts Background n Dr. Zhdankin s research lab, one of our main focuses is on the chemistry of iodine. odine is the
Carboxylic Acids O R C + H + O - Chemistry 618B
arboxylic Acids R H R + H + - R - Nomenclature - IUPA IUPA names: drop the -e from the parent alkane and add the suffix -oic acid If the compound contains a carbon-carbon double bond, change the infix
DEPARTMENT: Chemistry
CODE CHEM 204 TITLE: Organic Chemistry II INSTITUTE: STEM DEPARTMENT: Chemistry COURSE DESCRIPTION: A continuation of CHEM-203, students will extend their studies into topics including aromatic hydrocarbons,
Lecture Topics: I. Electrophilic Aromatic Substitution (EAS)
Reactions of Aromatic Compounds Reading: Wade chapter 17, sections 17-1- 17-15 Study Problems: 17-44, 17-46, 17-47, 17-48, 17-51, 17-52, 17-53, 17-59, 17-61 Key Concepts and Skills: Predict and propose
Discussion Addendum for: Trifluoromethylation at the -Position of, -Unsaturated Ketones: 4-Phenyl-3-Trifluoromethyl-2-Butanone
DI:10.15227/orgsyn.089.0374 Discussion Addendum for: Trifluoromethylation at the -Position of, -Unsaturated Ketones: 4-Phenyl-3-Trifluoromethyl-2-Butanone C 3 Ph hcl(pph 3 ) 3 C 3 I C 3 Ph T C 3 Prepared
Rempei Gotoh On the Occasion of his.
Effects of Hydrostatic Pressure on TitleActive Agent (Commemoration Issue D Rempei Gotoh On the Occasion of his Author(s) Suzuki, Keizo; Tsuchiya, Masao Citation Bulletin of the Institute for Chemi University
JEFFERSON COLLEGE COURSE SYLLABUS CHM201 ORGANIC CHEMISTRY II. 5 Credit Hours. Prepared by: Richard A. Pierce
JEFFERSON COLLEGE COURSE SYLLABUS CHM201 ORGANIC CHEMISTRY II 5 Credit Hours Prepared by: Richard A. Pierce Revised Date: January 2008 by Ryan H. Groeneman Arts & Science Education Dr. Mindy Selsor, Dean
CHM 292 Final Exam Answer Key
CHM 292 Final Exam Answer Key 1. Predict the product(s) of the following reactions (5 points each; 35 points total). May 7, 2013 Acid catalyzed elimination to form the most highly substituted alkene possible
18.8 Oxidation. Oxidation by silver ion requires an alkaline medium
18.8 Oxidation Oxidation by silver ion requires an alkaline medium Test for detecting aldehydes Tollens reagent to prevent precipitation of the insoluble silver oxide, a complexing agent is added: ammonia
A. Loupy, B.Tchoubar. Salt Effects in Organic and Organometallic Chemistry
A. Loupy, B.Tchoubar Salt Effects in Organic and Organometallic Chemistry 1 Introduction - Classification of Specific Salt Effects 1 1.1 Specific Salt Effects Involving the Salt's Lewis Acid or Base Character
Chem 263 March 28, 2006
Chem 263 March 28, 2006 Properties of Carboxylic Acids Since carboxylic acids are structurally related to both ketones and aldehydes, we would expect to see some similar structural properties. The carbonyl
Synthesis of graphislactones A-D through a palladium-mediated biaryl coupling
Chemistry rganic Chemistry fields kayama University Year 2005 Synthesis of graphislactones A-D through a palladium-mediated biaryl coupling Hitoshi Abe Keisuke Nishioka Shigemitsu Takeda kayama University
CHE 321 Summer 2012 Exam 2 Form Select the correct number of chirality centers in heroin, the illicit drug shown below.
Multiple Choice Questions: 50 points 1. Select the correct number of chirality centers in heroin, the illicit drug shown below. A 4 B 5 C 6 D 7 E 8 F more than 8 2. Choose the correct IUPAC name for the
water methanol dimethyl ether Ether can only act as a hydrogen bond acceptor H-bond acceptor O R
Chapter 14: Ethers and Epoxides; Thiols and Sulfides 14.1 Introduction to Ethers An ether group is an oxygen atom that is bonded to two carbons. The ether carbons can be part of alkyl, aryl, or vinyl groups.
+ + CH 11: Substitution and Elimination Substitution reactions
C 11: Substitution and Elimination Substitution reactions Things to sort out: Nucleophile Electrophile -- > substrate Leaving Group S N 2 S N 1 E 1 E 2 Analysis Scheme Kinetics Reaction profile Substrates
VISUALIZING THE MECHANISMS OF ORGANIC REACTIONS
VISUALIZING THE MECHANISMS OF ORGANIC REACTIONS Carlos Rius-Alonso, Yolanda González-Quezada, Francisco Fuentes Pantoja, Jonathan Benítez Ramírez Universidad Nacional Autónoma de México (MEXICO) Abstract
Organic Chemistry CHM 224
rganic Chemistry CM 224 Final Exam Review Questions This is a compilation example final exam questions. Provide IUPAC names for each of the structures below. 2 ! Propose a structure for the compound that
KOT 222 Organic Chemistry II
KOT 222 Organic Chemistry II Course Objectives: 1) To introduce the chemistry of alcohols and ethers. 2) To study the chemistry of functional groups. 3) To learn the chemistry of aromatic compounds and
Organic Chemistry. M. R. Naimi-Jamal. Faculty of Chemistry Iran University of Science & Technology
Organic Chemistry M. R. Naimi-Jamal Faculty of Chemistry Iran University of Science & Technology Chapter 5-2. Chemistry of Benzene: Electrophilic Aromatic Substitution Based on McMurry s Organic Chemistry,
Chapter 6: Organic Halogen Compounds; Substitution and Elimination Reactions
Chapter 6: Organic Halogen Compounds; Substitution and Elimination Reactions Halogen compounds are important for several reasons. Simple alkyl and aryl halides, especially chlorides and bromides, are versatile
1/4/2011. Chapter 18 Aldehydes and Ketones Reaction at the -carbon of carbonyl compounds
Chapter 18 Aldehydes and Ketones Reaction at the -carbon of carbonyl compounds The Acidity of the Hydrogens of Carbonyl Compounds: Enolate Anions Hydrogens on carbons to carbonyls are unusually acidic
Chapter 20 Carboxylic Acid Derivatives Nucleophilic Acyl Substitution
Chapter 20 Carboxylic Acid Derivatives Nucleophilic Acyl Substitution Nomenclature: In carboxylic acid chlorides, anhydrides, esters and amides, the parent is the carboxylic acid. In each case be sure
CONTRIBUTIONS OF PROFESSOR SHO ITO IN ORGANIC CHEMISTRY
HETEROCYCLES, Vol. 54, No. 1, 2001 CONTRIBUTIONS OF PROFESSOR SHO ITO IN ORGANIC CHEMISTRY It is my great honor to introduce the research accomplishments of Professor Sh6 It6 in this special issue of Heterocycles.
BSc. II 3 rd Semester. Submitted By Dr. Sangita Nohria Associate Professor PGGCG-11 Chandigarh 1
BSc. II 3 rd Semester Submitted By Dr. Sangita Nohria Associate Professor PGGCG-11 Chandigarh 1 Introduction to Alkyl Halides Alkyl halides are organic molecules containing a halogen atom bonded to an
JEFFERSON COLLEGE COURSE SYLLABUS CHM200 ORGANIC CHEMISTRY I. 5 Credit Hours. Prepared by: Richard A. Pierce
JEFFERSON COLLEGE COURSE SYLLABUS CHM200 ORGANIC CHEMISTRY I 5 Credit Hours Prepared by: Richard A. Pierce Revised Date: January 2008 by Ryan H. Groeneman Arts & Science Education Dr. Mindy Selsor, Dean
Chemistry of Benzene: Electrophilic Aromatic Substitution
Chemistry of Benzene: Electrophilic Aromatic Substitution Why this Chapter? Continuation of coverage of aromatic compounds in preceding chapter focus shift to understanding reactions Examine relationship
CHEM4. General Certificate of Education Advanced Level Examination January Unit 4 Kinetics, Equilibria and Organic Chemistry
Centre Number Surname Candidate Number For Examiner s Use Other Names Candidate Signature Examiner s Initials General Certificate of Education Advanced Level Examination January 2011 Question 1 2 Mark
Full First and Last Name DO NOT WRITE YOUR NAME UNTIL TOLD TO START! CHEM 8B Organic Chemistry II EXAM 2, Winter 2017 (200 points)
UCSC, Binder Exam 2, W17 Full First and Last Name D NT WRITE YUR NAME UNTIL TLD T START! CHEM 8B rganic Chemistry II EXAM 2, Winter 2017 (200 points) In each of the following problems, use your knowledge
Alkyl phenyl ketones are usually named by adding the acyl group as prefix to phenone.
Aldehydes, Ketones and Carboxylic Acids Nomenclature of aldehydes and ketones Aldehydes: Often called by their common names instead of IUPAC names. Ketones: Derived by naming two alkyl or aryl groups bonded
ALCOHOLS AND PHENOLS
ALCOHOLS AND PHENOLS ALCOHOLS AND PHENOLS Alcohols contain an OH group connected to a a saturated C (sp3) They are important solvents and synthesis intermediates Phenols contain an OH group connected to
Title Ketone by X-ray Diffraction Method. Citation University (1963), 41(2-4):
Title Study on Molecular Structure of Pol Ketone by X-ray Diffraction Method Author(s) Koyama, Ryuzo Citation Bulletin of the Institute for Chemi University (1963), 41(2-4): 207-211 Issue Date 1963-10-10
Author(s) Min, Tea-Ik; Miyamoto, Takeaki; Ina.
Thin-Layer Chromatographic Separati TitleDifference in End-Group (Special Is XI) Author(s) Min, Tea-Ik; Miyamoto, Takeaki; Ina Citation Bulletin of the Institute for Chemi University (1975), 53(4): 381-386
Chapter 8. Substitution reactions of Alkyl Halides
Chapter 8. Substitution reactions of Alkyl Halides There are two types of possible reaction in organic compounds in which sp 3 carbon is bonded to an electronegative atom or group (ex, halides) 1. Substitution
Lecture Notes Chemistry Mukund P. Sibi Lecture 36 Synthesis of Amines
Lecture otes hemistry 42-2008 Mukund P. Sibi Synthesis of Amines Amines can be prepared from a variety of starting materials. All of these methods involve functional group transformations. The main methods
Synthesis of Polymers Prof. Paula Hammond Lecture 19: Metallocene Chemistry, Intro to New Developments from Brookhart, Others H H
10.569 Synthesis of Polymers Prof. Paula ammond Lecture 19: Metallocene Chemistry, Intro to ew Developments from Brookhart, thers Ionic Polymerization 1. Anionic 2. Cationic Anionic Polymerization - very
Carbonyl Chemistry V + C O C. Chemistry /30/02
arbonyl hemistry V Ō - + Keto-enol enol Tautomerism H 3 H 3 Ketone H H R 2 H R' H H 3 H 2 H Enol H Acid atalyzed α Halogenation R 2 R' + X 2 H + R 2 R' + HX H X X 2 can be l 2, Br 2, or I 2. Substitution
Background Information
ackground nformation ntroduction to Condensation eactions Condensation reactions occur between the α-carbon of one carbonyl-containing functional group and the carbonyl carbon of a second carbonyl-containing
Glendale Community College Chemistry 105 Exam. 3 Lecture Notes Chapters 6 & 7
Sevada Chamras, Ph.D. Glendale Community College Chemistry 105 Exam. 3 Lecture Notes Chapters 6 & 7 Description: Examples: 3 Major Types of Organic Halides: 1. Alkyl Halides: Chapter 6 (Part 1/2) : Alkyl
Title Hydroxypiperidine-1-Oxyl-4-Derivati.
Title ESR Studies of Stable Free Radicals Hydroxypiperidine-1-Oxyl-4-Derivati Author(s) Watanabe, Kohji; Yamauchi, Jun; Tak Hiroaki; Deguchi, Yasuo Citation Bulletin of the Institute for Chemi University
11/26/ Polycyclic Aromatic Compounds. Polycyclic Aromatic Compounds. Polycyclic Aromatic Compounds
9.5 Polycyclic Aromatic Compounds The general concept of aromaticity can be extended to include polycyclic aromatic compounds Benzo[a]pyrene is one of the cancer-causing substances found in tobacco smoke
Chem 251 Fall Learning Objectives
Learning Objectives Chapter 8 (last semester) 1. Write an electron-pushing mechanism for an SN2 reaction between an alkyl halide and a nucleophile. 2. Describe the rate law and relative rate of reaction
Chem 263 Oct. 4, 2016
Chem 263 ct. 4, 2016 ow to determine position and reactivity: Examples The strongest donating group wins: 2 3 2 S 4 + 3 2 2 S 4 2 2 + 2 2 3 2 S 4 2 2 2 2,4,6-trinitrophenol picric acid This reactivity
روشهای 2 سنتز مواد آلی
به نام خدا Advanced Organic Chemistry روشهای 2 سنتز مواد آلی Dr Morteza Mehrdad University of Guilan, Department of Chemistry, Rasht, Iran m-mehrdad@guilan.ac.ir 2 Francis A. Carey University of Virginia
COURSE UNIT DESCRIPTION. Dept. Organic Chemistry, Vilnius University. Type of the course unit
Course unit title Organic Chemistry II Lecturer(s) Rimantas Vaitkus COURSE UNIT DESCRIPTION Department Dept. Organic Chemistry, Vilnius University Cycle First Type of the course unit Mode of delivery Period
Partial Periodic Table
Printed ame: CEM 3371, Spring 2015 Professor Walba First our Exam March 10, 2015 CU onor Code Pledge: n my honor, as a University of Colorado at Boulder Student, I have neither given nor received unauthorized
Department of Chemistry SUNY/Oneonta. Chem Organic Chemistry I. Examination #4 - December 9, 2002 ANSWERS
INSTRUCTINS Department of Chemistry SUNY/neonta Chem 221 - rganic Chemistry I Examination #4 - December 9, 2002 ANSWERS This examination is in multiple choice format; the questions are in this Exam Booklet
16. Chemistry of Benzene: Electrophilic Aromatic Substitution. Based on McMurry s Organic Chemistry, 7 th edition
16. Chemistry of Benzene: Electrophilic Aromatic Substitution Based on McMurry s Organic Chemistry, 7 th edition Substitution Reactions of Benzene and Its Derivatives Benzene is aromatic: a cyclic conjugated
GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR (preparation of carboxylic acid esters by telomerisation C07C 67/47; telomerisation C08F)
CPC - C07B - 2017.08 C07B GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR (preparation of carboxylic acid esters by telomerisation C07C 67/47; telomerisation C08F) General methods for the preparation
Chapter 22 Amines. Nomenclature Amines are classified according to the degree of substitution at nitrogen.
CH. 22 Chapter 22 Amines Amines are very important in biological chemistry. Most of the bases in biological acid-base reactions are amines. They are also very important nucleophiles in biochemical reactions.
Chemistry 283g Experiment 4
Chemistry 283g xperiment 4 XPRIMNT 4: lectrophilic Aromatic Substitution: A Friedel-Craft Acylation Reaction Relevant sections in the text: Fox & Whitesell, 3 rd d. Chapter 11, especially pg. 524-526,
b.p.=100 C b.p.=65 C b.p.=-25 C µ=1.69 D µ=2.0 D µ=1.3 D
Alcohols I eading: Wade chapter 10, sections 10-1- 10-12 Study Problems: 10-35, 10-37, 10-38, 10-39, 10-40, 10-42, 10-43 Key Concepts and Skills: Show how to convert alkenes, alkyl halides, and and carbonyl
SURVEY ON ARYL COMPOUNDS
Journal of Plastic and Polymer Technology (JPPT) Vol. 1, Issue 1, Jun 2015, 111-132 TJPRC Pvt. Ltd SURVEY ON ARYL COMPOUNDS NAGHAM MAHMOOD ALJAMALI Organic Chemistry, Department of Chemistry, College of
Aromatic character and aromaticity
Aromatic character and aromaticity Cambridge Chemistry Textbook Series GENERAL EDITORS E. A. V. Ebsworth, Ph.D. Professor of Inorganic Chemistry, University of Edinburgh P. J. Padley, Ph.D. Lecturer in
Title of His Retirement) methyl] propenam. Author(s) Tanaka, Kazuhiko; Ushio, Hideki; Ho.
![Title of His Retirement) methyl] propenam. Author(s) Tanaka, Kazuhiko; Ushio, Hideki; Ho.](/thumbs/92/107930132.jpg "Title of His Retirement) methyl] propenam. Author(s) Tanaka, Kazuhiko; Ushio, Hideki; Ho.")
A New Synthetic Route to α-methylen Title Dianion of N-Phenyl-2-[ (phenylsulf Issue Dedicated to Professor Shinza of His Retirement) methyl] propenam Author(s) Tanaka, Kazuhiko; Ushio, Hideki; Ho Citation
Theophylline (TH), the structure of which is presented below, is a bronchial-dilator used for the treatment of asthma.
1 EXAM SCIETIIC CULTURE CEMISTRY PRBLEM 1: Theophylline (T), the structure of which is presented below, is a bronchial-dilator used for the treatment of asthma. 3 C 7 1 3 9 1.1 Structural study and acid-base
Palladium-Catalyzed Asymmetric Benzylic Alkylation Reactions
Palladium-Catalyzed Asymmetric Benzylic Alkylation Reactions Reporter: Hong-Qiang Shen Checker: Cong Liu Date: 2016/07/12 Masahiro Miura et al. Angew. Chem. Int. Ed. 2016, 55, 6973. Masahiro Miura Osaka
Chapter 15 Reactions of Aromatic Compounds
Chapter 15 1 Chapter 15 Reactions of Aromatic Compounds Electrophilic Aromatic Substitution Arene (Ar-H) is the generic term for an aromatic hydrocarbon The aryl group (Ar) is derived by removal of a hydrogen
12/27/2010. Chapter 15 Reactions of Aromatic Compounds
Chapter 15 Reactions of Aromatic Compounds Electrophilic Aromatic Substitution Arene (Ar-H) is the generic term for an aromatic hydrocarbon The aryl group (Ar) is derived by removal of a hydrogen atom
CHEM 303 Organic Chemistry II Problem Set III Chapter 14 Answers
CHEM 303 rganic Chemistry II Problem Set III Chapter 14 Answers 1) Give the major products of each of the following reactions. If a mixture is expected, identify the major product. + H 3 CHC CHCH 3 H 2
08. Chemistry of Benzene: Electrophilic Aromatic Substitution. Based on McMurry s Organic Chemistry, 6 th edition, Chapter 16
08. Chemistry of Benzene: Electrophilic Aromatic Substitution Based on McMurry s Organic Chemistry, 6 th edition, Chapter 16 Benzene is a nucleophile p electrons make benzene nucleophile, like alkenes.
CHEM 2312 practice final. Version - II
EM 2312 practice final Version - II The following standardized final examination covers the entire introductory year of organic chemistry (EM 2311 and 2312 at Georgia Tech). The exam consists of 70 multiple
State University of New York at Stony Brook Department of Chemistry. CHE 322, Organic Chemistry II Exam II March 17, 2004 Form 1
State University of New York at Stony Brook Department of Chemistry CHE 22, rganic Chemistry II Exam II March 17, 2004 Form 1 Please answer all questions specifically, concisely, and readably in the spaces
DAMIETTA UNIVERSITY. Energy Diagram of One-Step Exothermic Reaction
DAMIETTA UNIVERSITY CHEM-103: BASIC ORGANIC CHEMISTRY LECTURE 5 Dr Ali El-Agamey 1 Energy Diagram of One-Step Exothermic Reaction The vertical axis in this graph represents the potential energy. The transition
JEFFERSON COLLEGE COURSE SYLLABUS CHM201 ORGANIC CHEMISTRY II. 5 Credit Hours. Prepared by: Richard A. Pierce. Revised by: Sean Birke October, 2013
JEFFERSON COLLEGE COURSE SYLLABUS CHM201 ORGANIC CHEMISTRY II 5 Credit Hours Prepared by: Richard A. Pierce Revised by: Sean Birke October, 2013 Ms. Linda Abernathy, Math, Science & Business Division Chair
Learning Guide for Chapter 14 - Alcohols (I)
Learning Guide for Chapter 14 - Alcohols (I) I. Introduction to Alcohols and Thiols II. Acid/base Behavior of Alcohols, Phenols, and Thiols III. Nomenclature of Alcohols IV. Synthesis of Alcohols Previous
Sul Ross State University Syllabus for Organic Chemistry II: CHEM 3408 (Spring 2017)
Sul Ross State University Syllabus for Organic Chemistry II: CHEM 3408 (Spring 2017) Class: Organic Chemistry II Instructor: Dr. David J. Leaver Room: WSB 307 Office: WSB 318 Time: MWF 9:00-9:50am Office
Organic Reactions Susbstitution S N. Dr. Sapna Gupta
Organic Reactions Susbstitution S N 2 Dr. Sapna Gupta Kinetics of Nucleophilic Reaction Rate law is order of reaction 0 order is when rate of reaction is unaffected by change in concentration of the reactants
Mengying Li.
Investigating the Techniques of Acid- Base Extraction by separating three dye compounds & Recrystallization by purifying Methyl Orange Mengying Li Department of Chemical Engineering, The Pennsylvania State
A SURVEY OF ORGANIC CHEMISTRY CHEMISTRY 1315 TuTr 9:35-10:55 am, Boggs B6
GEORGIA INSTITUTE OF TECHNOLOGY School of Chemistry and Biochemistry Spring 2004 A SURVEY OF ORGANIC CHEMISTRY CHEMISTRY 1315 TuTr 9:35-10:55 am, Boggs B6 Instructor: Marcus Weck Office: Boggs 3-85 Phone:
Chemistry 2050 Introduction to Organic Chemistry Fall Semester 2011 Dr. Rainer Glaser
Chemistry 2050 Introduction to Organic Chemistry Fall Semester 2011 Dr. Rainer Glaser Examination #2 Practice Edition Arenes, Stereochemistry, and Organic Halogen Compounds, with Nucleophilic Substitution
Chapter 16 Chemistry of Benzene: Electrophilic Aromatic Substitution
John E. McMurry www.cengage.com/chemistry/mcmurry Chapter 16 Chemistry of Benzene: Electrophilic Aromatic Substitution Paul D. Adams University of Arkansas Substitution Reactions of Benzene and Its Derivatives
Chemistry 216. First Exam (March 16, 2010) (1 hr 15 min, 80 points) Dr. Kyoung Moo Koh. Lab section. GSI name. Name Please print.
Chemistry 216 First Exam (March 16, 2010) (1 hr 15 min, 80 points) Dr. Kyoung Moo Koh Lab section GSI name Name Please print Signature Student ID# I 8 II 10 III 6 IV 12 V 12 VI 10 VII 14 VIII 8 Total 80
Corey-Bakshi. Bakshi-Shibata Reduction. Name Reaction Nilanjana Majumdar
Corey-Bakshi Bakshi-Shibata Reduction Name Reaction Nilanjana Majumdar 02.27.09 utline Introduction Background CBS Reaction Application to Synthesis Introduction Born: 12 th July, 1928 in Methuen, Massachusetts,
Measuring enzyme (enantio)selectivity
Measuring enzyme (enantio)selectivity Types of selectivity - review stereoisomers Stereoselective synthesis (create) vs. resolutions (separate) Enantioselectivity & enantiomeric purity Ways to measure
Name: Student Number: University of Manitoba - Department of Chemistry CHEM Introductory Organic Chemistry II - Term Test 1
Name: Student Number: University of Manitoba - Department of Chemistry CHEM 2220 - Introductory Organic Chemistry II - Term Test 1 Thursday, February 11, 2016; 7-9 PM This is a 2-hour test, marked out
Aryl Halides. Structure
Aryl Halides Structure Aryl halides are compounds containing halogen attached directly to an aromatic ring. They have the general formula ArX, where Ar is phenyl, substituted phenyl. X= F,Cl,Br,I An aryl
CHEM 251 (4 credits): Description
CHEM 251 (4 credits): Intermediate Reactions of Nucleophiles and Electrophiles (Reactivity 2) Description: An understanding of chemical reactivity, initiated in Reactivity 1, is further developed based
CHEM4. (JAN13CHEM401) WMP/Jan13/CHEM4. General Certificate of Education Advanced Level Examination January 2013
Centre Number Surname Candidate Number For Examiner s Use Other Names Candidate Signature Examiner s Initials General Certificate of Education Advanced Level Examination January 2013 Question 1 2 Mark
Chapter 17: Alcohols and Phenols. Based on McMurry s Organic Chemistry, 7 th edition
Chapter 17: Alcohols and Phenols Based on McMurry s Organic Chemistry, 7 th edition Alcohols and Phenols Alcohols contain an OH group connected to a a saturated C (sp 3 ) They are important solvents and
CARBOXYLIC ACIDS AND THEIR DERIVATIVES. 3. Predict the relative acidity and basicity of compounds and ions. Important criteria include:
CARBXYLIC ACIDS AND TEIR DERIVATIVES A STUDENT SULD BE ABLE T: 1. Give the IUPAC name given the structure, and draw the structure given the name, of carboxylic acids and their metal salts, acyl chlorides,
NOT TO BE REMOVED FROM THE EXAMINATION HALL
A copy of the Level III (FHEQ Level 6) Equation and Data Sheet booklet is provided. The use of hand-held, battery-operated, electronic calculators will be permitted subject to the regulations governing
Dr. Mohamed El-Newehy
By Dr. Mohamed El-Newehy Chemistry Department, College of Science, King Saud University http://fac.ksu.edu.sa/melnewehy Carboxylic acids and Their Derivatives 1 Structure of Carboxylic Acids -The functional
Hour Examination # 3
CHEM 343 Principles of Organic Chemistry II Summer 2014 Exam # 3 Problem Booklet Page 1 of 8 CHEM 343 Principles of Organic Chemistry II Summer 2014 Instructor: Paul J. Bracher Hour Examination # 3 Tuesday,
Chem 263 Oct. 10, The strongest donating group determines where new substituents are introduced.
Chem 263 ct. 10, 2013 The strongest donating group determines where new substituents are introduced. N 2 N 3 2 S 4 + N 3 N 2 2 S 4 N 2 N 2 + 2 N N 2 N 3 2 S 4 N 2 2 N N 2 2,4,6-trinitrophenol picric acid
Nuggets of Knowledge for Chapter 17 Dienes and Aromaticity Chem 2320
Nuggets of Knowledge for Chapter 17 Dienes and Aromaticity Chem 2320 I. Isolated, cumulated, and conjugated dienes A diene is any compound with two or C=C's is a diene. Compounds containing more than two
Chapter 20: Carboxylic Acids
1 Chapter 20: Carboxylic Acids I. Introduction: Carboxylic acid structure: Classification of carboxylic acids: A carboxylic acid donates protons by the heterocyclic cleavage of the O-H bond, generating
Ethers. Synthesis of Ethers. Chemical Properties of Ethers
Page 1 of 6 like alcohols are organic derivatives of water, but lack the labile -OH group. As a result, ethers, except for epoxides, are usually not very reactive and are often used as solvents for organic
Title A Molecular Orbital Consideration o of quinones Author(s) Fueno, Takayuki; Furukawa, Junji Citation Bulletin of the Institute for Chemi University (1958), 36(4): 81-86 Issue Date 1958-07-31 URL http://hdl.handle.net/2433/75664