Technological Interventions for Managing Chemical Waste
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1 Technological Interventions for Managing Chemical Waste DOWA Eco-System CO., Ltd Hiroyuki ITO, Eng. Dr. 11 April, 2018 at 3R Forum in Asia and the Pacific 1
2 Table of Content Diverse of Chemical Substances/materials Management of Chemical Substances in Japan (PRTR Act) Utilization of Waste Data Sheet (WDS) for Secure and Safe Waste Treatment Examples of Chemical Waste Chemical Waste Treatment in DOWA Japan 2
3 Diverse of Chemical Substances/materials More than 138 Million Substances ( More than 67,000 Substances in Japan (Ministry of Health, Labour and Welfare Japan) Continuous Growth of Newly Produced Substances Necessity to Understand Global Trend for Chemical Substances Production 3
4 Management of Chemical Substances in Japan (PRTR Act) PRTR (Pollutant Release and Transfer Register) System has been implemented. Law concerning PRTR was Enforced in 1999 and Amended in Class I Designated Chemical Substance Specified Class I Designated Chemical Substance Class II Designated Chemical Substance Target Entities 4
5 Chemical Substances Designated in PRTR Law Classification Enforced in 1999 Amended in 2008 Class I Designated Chemical Substance Specified Class I Designated Chemical Substance Class II Designated Chemical Substance 354 Substances 462 Substances 12 Substances 15 Substances 81 Substances 100 Substances Target Entities 23 Entities 24 Entities 5
6 What are Specified Class I Designated Chemical Substance? PRTR number Specified Class I Designated Chemical Substance 33 Asbestos 56 Ethylene Oxide 75 Cd and its compounds 88 Cr(VI) compounds 94 Vinyl Chloride 243 Dioxins 305 Pb compounds 309 Ni compounds 332 As and its inorganic compounds 351 1,3-Butadiene Bromopropane 394 Be and its compounds 397 Benzylidyne Trichloride 400 Benzene 411 Formaldehyde 6
7 What is Needed for Proper Treatment? WDS System Sharing the information for Secure, Safe and Proper Treatment. Based on Waste Management and Public Cleansing Act, Guideline for Waste Data Sheet (WDS) was issued in 2006 and Amended in Waste Generators must fulfill all information in WDS together with submitting Supporting Documents such as MSDS, Samples, Pictures, Analysis Data etc. 7
8 Utilization of Waste Data Sheet (WDS) for Secure and Safe Waste Treatment Waste Generator s Information Waste Criteria and Classification PRTR Registration Shape of Packaging etc WDS Template (in Japan) Generators must Complete WDS with Supporting Documents such as MSDS, Waste Samples, Pictures, Analysis Data. 8
9 Examples of Chemical Waste CFCs PCBs Asbestos Lab Wastes Solvents Pesticides 9
10 Chemical Waste Treatment in DOWA CFCs Dispose End Users Collection and Storage CFCs Extraction Thermal Destruction Stored in Cylinder 10
11 Chemical Waste Treatment in DOWA PCBs Oil Phase Chemical Decomposition Cabinet Body PCBs Extraction PCBs hours 25m length Chemical Destruction After Treatment
12 Chemical Waste Treatment in DOWA Asbestos Proper PPEs Prevention Work Double Packing Secure Transport (Double Packing) Pre-Treatment - Stabilization - Melting - etc Secure Landfill 12
13 Chemical Waste Treatment in DOWA Lab Wastes Variety of lab Wastes - Bottles - Glass Bins - etc Thermal Treatment (Batch Kiln) Secure Packing 13
14 Infectious Waste Treatment in DOWA Thermal Destruction (Singapore) Thermal Destruction 14 Secure (Double) Packing to prevent leakage Direct Feeding into the kiln to prevent contact of wastes
15 Odor from Waste Regulations Related to Operation Offensive Odor Control Law SCC sec or more Receipt Rotary Kiln DM Ignition Loss Less than 10% Bottom Ash Pb Cd As Se Hg Dioxins Less than 0.3mg/L Less than 0.3mg/L Less than 0.3mg/L Less than 0.3mg/L Less than 0.005mg/L Less than 3ng-TEQ/g Waste Management and Public Cleansing Act
16 Regulations Related to Emission Offensive Odor Control Law Odor Emission Boiler Cooling Tower ESP Bag Filter A. Carbon Fly Ash Scrubber Waste Management and Public Cleansing Act Air Pollution Control Law Law Concerning Special Measures against Dioxins Pb Cd As Less than 0.3mg/L Less than 0.3mg/L Less than 0.3mg/L Soot and dust Less than0.04g/m3 SOX q=k 10-3 He 2 (m 3 N/h) NOX Less than 250ppm Dioxins Less than 0.1ng- TEQ/m3N Se Less than 0.3mg/L HCl Less than 700mg/m3 Hg Less than 0.005mg/L Gas Flow Rate(wet) Depends on location Dioxins Less than 3ng- TEQ/g Gas Flow Rate(dry) Depends on location
17 Thank you for your attention. DOWA Eco-System CO., Ltd,
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