INFLUENCE OF JOULE THOMPSON EFFECT ON THE TEMPERATURE DISTRIBUTION IN VERTICAL TWO PHASE FLOW

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INFLUENCE OF JOULE THOMPSON EFFECT ON THE TEMPERATURE DISTRIBUTION IN VERTICAL TWO PHASE FLOW Daniel Merino Gabriel S. Bassani, Luiz Eduardo A. P. Duarte Deibi E. Garcia Angela O. Nieckele

Two-phase Flow is encountered in many application e.g. nuclear, refrigeration and Oil & Gas industries, presenting several flow patterns. Typical Deep Water Production Arrangement. Ghajar & Tang, 2010 Wax deposition may occur when oil temperature is below Wax Appearance Temperature, T WAT Wax deposition causes increase in the pumping power (flow reduction, increase in the oil viscosity, changes in the rheological characteristics).

Investigate numerically, with the commercial software Fluent, the influence of the Joule Thompson effect in two-phase flow, through vertical upward pipelines, considering three different flow patterns: dispersed bubble, annular and wavy annular (wispy) flows.

Hypotheses Vertical pipe with 200 m: two-dimensional, axis-symmetric Density: liquid - constant liquid Dynamic viscosity: constant for each phase Gas: ρ = Z P (R M W)T Absence of mass transfer Ideal Z=1 Peng-Robinson: Z 3 + Z 2 B 1 + Z A 2B 3B² + B 3 + B 2 AB = 0 A = a mp R²T² and B = b mp RT

Two-phase flow model: Volume fraction: α k = k Disperse bubbles: multiphase Eulerian Two sets of conservation equations (mass, momentum and energy), corresponding to each phase is solved Annular flow: VOF One set of conservation equation is solved, considering each phase as variable property fluid, and mass conservation of one phase Turbulence model: k-e realizable

Fluid - Volume Finite Method 1. Conservation equations are integrated over each volume. 2. Spatial discretization: Power-Law and 3rd order MUSCL 3. Convective flows: Second-order spatial approximation (TVD Scheme Van Leer Limiter Flux). 4. Volume fraction: i. 2 nd order QUICK scheme with the Eulerian model ii. Modified HRIC with VOF 5. Velocity-Pressure coupling: PISO 6. Discretized system of equations solved using Gauss-Seidel line-by-line algorithm, coupled with the additive multigrid method. 7. Mesh defined with a grid test: y + 25 along wall i. axial direction: 32 300 cells, ii. radial direction: 50 (bubble and annular case) and 80 (annular wispy case)

Test Cases Model D (m) ṁ L (kg/s) ṁ G (kg/s) a G P out (bar) Dispersed bubble 4.875 42.,33 0.61 0.05 259 Annular 6.000 3.63 25.36 0.91 345 Wavy annular (wispy) 8.955 29.63 24.20 0.72 234 Liquid holdup distribution Dispersed bubble Annular Annular wispy

Pressure and temperature drop Model Dispersed bubble Annular Wavy annular (wispy) Ideal gas Real gas Ideal gas Real gas Ideal gas Real gas - dp/dx 80.54 81.20 38.83 40.17 42.01 44.29 (bar/km) Dp (bar) 16.11 16.24 7.76 8.03 8.41 8.87 dt/dx 3.71 3.58-1.27-1.94 0.73-0.94 ( o C/km) D T ( o C) - 0.74-0.71 0.26 0.39-0.14 0.20

Radial temperature distribution. Dispersed bubble case r (m) r (m) (a) 0.5 mm bubbles diameters T ( o C) T ( o C) (b) different bubbles diameters

Radial temperature distribution. Annular case (a) x=150 m (b) x=195 m

Radial temperature distribution. Wispy annular case r (m) r (m) (a) Ideal Gas (GI) and Real Gas (GR) T ( o C) T ( o C) (b) detail for real gas (Peng Robinson)

Heat Flux Model Dispersed bubble Annular Wavy annular (wispy) Ideal gas Real gas Ideal gas Real gas Ideal gas Real gas Q w (kw) - 18.917-18.911-25.206-25.180-37.729-37.626 Q LG (kw) 4.934 7.851-19.136-17.456-37.798 66.630

Three scenarios were considered to investigate the Joule Thompson effect on the flow: dispersed bubble, annular and wavy annular (wispy) flows. Dispersed flow: Two-fluid model, with bubble size (0.01-5 mm). Bubble size did not present an impact in the solution, but a smaller friction contribution was obtained with bubbles of larger diameter. Similar liquid and gas temperatures for all cases investigated. Higher gas concentration near the wall. Small temperature decrease near wall region, due to heat loss to the environment. Slight temperature increase along the pipeline. Possible explanation: absence to the mass transfer between phases, and high insulation and flow governed by liquid, due to small amount of gas Joule Thompson effect acts to increase the temperature of an incompressible liquid, and it reduces the gas temperature, therefore, the mixture does not heat up as much as for the ideal gas case.

Annular flow: VOF method Liquid phase temperature increased along the pipeline, being higher than the gas temperature, which was flowing in the core region. Liquid flows along the wall, losing heat to the environment. Small amount of liquid, thus a negligible temperature variation was obtained with both equations of state. Joule Thompson effect induced a larger axial temperature drop for the real gas case. Insignificant differences from the thermal aspect of the problem. Wavy annular (wispy) case: VOF method Small temperature increase in the liquid phase along the pipeline for ideal case. Similar to dispersed bubble case, due to large amount of liquid Smaller mixture temperature reduction along pipeline due to Joule Thompson effect

Uniform pressure distribution along the cross section for all cases Pressure work in the radial direction is negligible, and although temperature is smaller in the inner region, the temperature variation is very small. The results showed for all flow patterns and operational conditions investigated (no phase change, high insulation), the Joule Thompson effect reduced the gas temperature and increased the liquid temperature. Depending on the gas volume fraction and flow regime, the contribution of one or another dominated the overall temperature variation along the riser. Having in mind the final objective, to assess the impact on wax deposition, only the wispy annular flow showed a significant temperature gradient towards the bulk of the fluid that could lead to a reduction in wax deposition

Acknowledgments