Chemistry 1007: General Chemistry Summer Session, 2017 Course Syllabus Instructor Information Note: Course begins Richard Ault Wednesday 14 June, 5 PM Office: A-310 room D-214 Phone: (815) 224-0309 / 0563 E-mail: larry_ault@ivcc.edu Course home page: http://www.ivcc.edu/ault Lab Assistant: Zak Kauffman Office hours: Tuesday, Wednesday, Thursday: 3:45 pm to 4:45 pm in E-101 Course Hours Summer B Schedule The course meets on Tuesdays, Wednesdays, and Thursdays from 5:00 to 7:00 pm with lecture, demonstrations, in-class problem-solving exercises, and a pre-lab seminar. Two three-hour laboratory sessions are scheduled on Tuesday and Wednesday evenings from 7:00 until 10:15 or until completed. Most labs take 2.5 to 3 hours to complete. Some labs last only one hour. No makeup labs are allowed unless arrangements are made ahead of time. Required Texts and Supplies Brown, Theodore L., LeMay et al. Chemistry: The Central Science. Textbook, 12 th edition. Prentice Hall. 2012. Rental $48.00 (new $240.25 used $180.25) General Chemistry Laboratory Manual. Manuscript, $4.75 Chemistry Laboratory Notebook. Hayden-McNeil, $14.95. Uvex Safety Goggles, $8.25. Optional Texts Student Study Guide, 12 th edition. Prentice Hall. 2012. New $77.00 Used $57.75 Student Solutions Manual, 12 th edition. Prentice Hall. 2012. New $80.75 Used 60.75 Course Description This course is a continuation of CHM 1006 (or the equivalent of a first-semester general chemistry course). Chem 1007 is the study of energy transfer in the direction, rate, and completion of chemical reactions. Other major topics are: Kinetic Theory of atoms and molecules in the gas phase, acid/base proton exchange, electronegativity values and their use in predicting reaction sites, the use of buffers in natural systems, electrochemistry, inorganic coordination chemistry, and nuclear chemistry. Laboratory methods include gravimetric, volumetric, titrometric, electroanalytic, and visible/infrared spectrometric analyses. Computer acquisition and graphing skills utilizing the Vernier software systems and the Ocean Optics UV/VIS Scanning Spectrophotometer interface are performed in many of the labs.
Assignment Schedule Date Day Topics to be Covered / Exams-Quizzes / Laboratory Exercises 14 June Wed Gases: Chapter 10 10.1: The Characteristics of Gases, pp.383-384, P 13 10.7: The Kinetic-Molecular Theory of Gases, pp. 402 405, P 77-85 (all odd) 10.2: Pressure, pp. 385-387, P 1,4,7,15,17,19,21,23,25 10.3: The Gas Laws, pp. 387-391, P 27 and 29 Experiment #1: Properties of Gases 15 June Thur 10.4: The Ideal-Gas Equation, pp.391-395, P 31 47 (all odd) 10.5: Further Applications, pp. 395-167-399, P 49-61 (all odd) 10.6: Gas Mixtures and Partial Pressures, pp. 399-402, P 63-75 (all odd) 20 June Tues 10.8: Molecular Effusion and Diffusion, pp. 405 409, P 87,89,91 10.9: Real Gases-Deviations from Ideal Behavior, pp. 409-413, P 93,95,97,99 Chemical Kinetics: Chapter 14 14.1: Factors That Affect Reaction Rate, pp. 558-559, P 1 and 17 14.2: Reaction Rates, pp. 559-563, P 3,19,21,23,25 Experiment #2: Determination of NA Using the Ideal Gas Law & Electrochemistry 21 June Wed Quiz 1: Ideal Gas Law and Stoichiometry (20 min) 14.3: Concentration and Rate Laws, pp. 563-569, P 27,29,31,33,35,37 14.4: The Change of Concentration With Time, pp. 569-575, P 39 to 51 (all odd) 14.5: Temperature and Rate, The Arrhenius Equation, pp. 575-581, P 53-67 (odd) Experiment #3: Measuring the Decay Constant of Ba-137m 22 June Thur 14.6: Reaction Mechanisms, pp. 581-588, P 12,16,69,70,71,72,73,75,77,79 14.7: Catalysis, pp. 589-595, P 81,83,85,87,89,91,,93,95 27 June Tues Chapter 21: Nuclear Chemistry 21.1 to 21.2: Radioactivity and Nuclear Stability, pp. 875-883, P 7-23 (odd) 21.3 to 21.4: First-Order Kinetics of Radioactive Decay, pp. 884-891, P 25-41 odd Experiment #4: Intro to UV-VIS Absorption Spectroscopy, Aspirin Analysis 28 June Wed Exam 1: Chapters 10, 14, and 21 (one hour) Chapter 15: Chemical Equilibria 15.1: The Concept of Equilibrium, pp. 611-613 15.2: The Equilibrium Constant, pp.614-618, P 13 and 15 Experiment #5: A Kinetic Study of the Crystal Violet Reaction with NaOH 29 June Thur 15.3: Understanding and Working with Different K s, pp. 619-622, P 17 25 (odd) 15.4: Heterogenous Equilibria, pp. 623-625, P 1,7,11,27,29,31 15.5: Calculating Equilibrium Constants, pp. 625-626, P 33,35,37,39,,41 04 July 05 July Tues Wed No Class 15.6: Applications of Equilibrium Constants, pp. 627-630, P 43 to 59 (all odd) 15.7: LeChâtelier s Principle, pp. 630-640, P 61,63,65,67 Chapter 16: Acid / Base Equilibria ` 16.1: Acids/Bases, A Brief Review, pp. 651-652, P 11 16.2: BrØnsted-Lowry Acids and Bases, pp. 652-658, P 1,13,15,17,19,21,23,25 Experiment: #6: Rate Determination and Activation Energy of the CV/OH Rxn 06 July Thur Quiz #2: An ICE Problem and LeChâtelier s Principle (20 min) 16.3: The Autoionization of Water, pp. 658-660, P 3, 27,29,31 16.4: The ph Scale, pp. 660-664, P 5,33,35,37,39
11 July Tues 16.5: Strong Acids and Bases, pp. 664-666, P 41,43,45,47 16.6: Weak Acids, pp. 666-675, P 49,51,53,55,57,59,61,63,65,67 16.7: Weak Bases, pp. 676-679, P 7,69,71,73,75 Experiment: #7: Chemical Equilibrium and LeChâtelier s Principle Exp #6: 12 July Wed 16.8: Relationship Between Ka and Kb, pp. 679-681, P 77 and 79 16.9: Acid-Base Properties of Salt Solutions, pp. 681-685, P 81,83,85 16.10: Acid-Behaviour and Chemical Structure, pp. 685-689, P 9,87,89,91,93 16.11: Lewis Acids and Bases, pp. 689-692, P 95,97,99 Experiment #8: The Titration Curve of a Monoprotic Acid 13 July Thur Exam #2: Chapters 15 and 16 (one hour) Chapter 17: Additional Aspects of Aqueous Equilibria 17.1: The Common Ion Effect, pp. 703-706, P 1,13,15,17 17.2: Buffered Solutions, pp. 707-713, P 4,19,21,23,25,27,29 18 July Tues 23.4: Nomenclature and Isomerism, pp. 979-985, P 6,35,37,39,41,43 17.3: Acid-Base Titrations, pp. 714-722, P 7,33,35,37,39,41,43,45,47 17.4: Solubility Equilibria, pp. 722-726, P 49,51,53,55,57,59 17.5: Factors That Affect Solubility, pp. 726-734, P 10,61,63,65 Exp #9: Synthesis of an Amminecopper(II) Complex 19 July Wed 17.6: Precipitation and Separation of Ions, pp. 734-739, P 67,69,71,73,75,77,79 Chapter 19: Chemical Thermodynamics 19.1: Spontanenous Processes, pp. 785-790, P 1,11,13,15,17,19,21 19.2: Entropy and the Second Law of Thermodynamics, pp. 790-793, P 23-29 odd Experiment #10: The Analysis of an Amminecopper(II) Complex 20 July Thur Quiz #3: Chapter 19 A Titration Problem (30 min) 19.3: Molecular Interpretation of Entropy, pp. 790-800, P 4,31,33,35,37,39,,41,43 19.4: Entropy Changes in Chemical Reactions, pp. 800-803, P 45,47,49,51,53 25 July Tues 19.5: Gibbs Free Energy, pp. 803-808, P 55,57,59,61 19.6: Free Energy and Temperature, pp. 809-810, P 63,65,67,69,71,73,75 19.7 Free Energy and the Equilibrium Constant, pp. 811-815, P 77,79,81,83,85 Experiment #11: The Solubility Product Constant of Potassium Bitartrate 26 July Wed Chapter 20: Electrochemistry 20.1: Oxidation States and Redox Reactions, pp. 827-829, P 1,13,15,17 20.2: Balancing Redox Reactions, pp. 830-834, P 19,21,23 20.3: Voltaic Cells, pp. 835-837, P 4,25,27 Experiment #13: Water Chemistry and River Testing - Outdoors 27 July Thur Exam #3: Chapter 17 (one hour) 20.4: Cell Potentials Under Standard Conditions, pp. 838-845, P 29-49 (all odd) 20.5: Free Energy and Redox Reactions, pp. 845-849, P 7,51,53,55,57,59 20.6: Cell EMF Under Non-Standard Conditions, pp. 849-854, P 9,61-71 (odd) 01 Aug Tues 20:5: Batteries and Fuel Cells, pp. 854-857, P 73,75,77,79,81 20.6 and 20.7: Corrosion and Electrolysis, pp. 857-863, P 83,85,87,89,91,93,95 Experiment #12: Electrochemistry and the Nernst Equation 02 Aug Wed Chapter 23: Transition Metals and Co-ordination Chemistry 23.2: Transition Metal Complexes, pp. 968-974, P 2,11,13,15,17,19 23.3: Common Ligands in Co-ordination Chemistry, pp. 974-979, P 4,27,29,31,33 03 Aug Thur Quiz #4: Ch 21 Voltaic Cells and the Nernst Equation (20 min) 23.5: Color and Magnetism, pp. 985-987, P 45 23.6: Crystal Field Theory, pp. 987-995, P 8,47,49,51,53,55,57,59,61,63 08 Aug Tues Finish Material and Final Exam Study Guide
09 Aug Wed Final Examination, 5:00 to 7:00 Grading Scale and Procedures 4 Quizzes @ 25 points each = 100 points 4 Problem Sets @ 20 points each = 80 points 2 Computer Assignments @ 20 points each = 40 points 3 Chapter Exams @ 100 points each = 300 points 11 Lab exercises @ 20 points each = 220 points Outdoor Water Quality Lab = 10 pts Final Examination @150 points = 150 points Total Points = 900 points Grade: 810-900 A; 720-809 B; 630-719 C; 540-629 D; 0-539...F Laboratory The American Chemical Society (ACS) Guidelines for Chemistry in Two-Year Programs, Spring 2009, American Chemical Society Committee on Education has set recommendations for the chemistry lab experience. IVCC is internally assessed according to these recommendations. To learn chemistry, students must directly manipulate chemicals, study their properties and reactions, and utilize laboratory equipment and modern laboratory instruments. Laboratory experiences include the following activities: anticipating, recognizing, and responding properly to potential hazards in laboratory procedures; keeping accurate and complete experimental records; performing accurate quantitative measurements; interpreting experimental results and drawing reasonable conclusions; analyzing data statistically, assessing the reliability of experimental results, and discussing the sources of systematic and random errors in experiments; communicating effectively through oral and written reports; synthesizing and characterizing inorganic compounds. Two lab sessions are scheduled per week. The first lab in a specified week must be completed on Tuesday or Wednesday and the second lab must be completed on Wednesday or Thursday. Laboratory exercises are due on Tuesday following the week the lab is assigned. Class Ethics: An Important Announcement You are encouraged to work together on Problem Set assignments. But note that any cheating on an exam, quiz, or lab will result in a grade of zero for that assignment. No texting, etc. (the etc. is broadly-based) is allowed during class.
Expected Student Outcomes Perform specific instructional objectives as listed for each chapter. Communicate effectively using proper scientific terminology through composing reports and laboratory writing. Calculation of kinetic, thermodynamic, ph, and free energy problems using scientific notation, SI units, and dimensional analysis and the ability to handle base10 and natural logarithms. Understand technological design in the use of scientific computing methods and tools. Attendance Policy Students are expected to attend all of the lectures and seminars. Please see me if you know of a conflict ahead of time. More than three unexcused absences may result in a withdrawal from the course by the instructor. Every attempt will be made to contact the student. The Last Day for student withdrawal from a Summer-D 8-week class is Tuesday, July 21 st. The student will not receive an F, but will receive a W (Withdraw) prior to and including this date. Note: Last day for a summer session D refund is Tuesday, June 16 th. Two items of interest to you: If you are a student with a documented cognitive learning, physical, or psychiatric disability (anxiety, depression, bipolar disorder, AD/HD, post-traumatic stress, and others) you may be eligible for academic support services such as extended test time, texts on disc, note-taking services, etc. If you are interested in learning if you can receive these academic support services, please contact either receiving academic support services, please contact Tina Hardy, tina_hardy@ivcc.edu, phone 224-0284, or stop by the Disability Services Office in C-211. Have a safe and rewarding summer. The class goes by quickly and a lot of work must be achieved in a short eight-week session. Best of Hard Work to you all!