Preparation of Polyethylene/Montmorillonite (MMT) Nanocomposites Through in situ Polymerization Using a Montmorillonite-Supported Nickel Diimine Yiyoung Choi, Sang Young A. Shin, João B.P. Soares
1. Introduction Properties & Applications of Polyolefin/Layered Silicate Nanocomposites Polymer/layered silicate nanocomposites provide the better performance characteristics when compared to virgin polymer or conventional composites. Recently, the success on polymer/layered silicate nanocomposites has extended into making high performance polyolefin olefin nanocomposites. Polyolefin/Layered Silicate Nanocomposites have Improved Mechanical strength Auto parts Improved Thermal Stability Application Cf.) Tortuous paths Improved Gas-barrier Properties Film
1. Introduction Structure of Layered Silicates- Montmorillonite Montmorillonite (MMT) has been used as the main material for polymer/layered silicate nanocomposite due to its remarkable intercalation ability. MMT is consisted of stacks of each silica/alumina phase and gallery. For preparation of polymer/mmt nanocomposite, single layer of MMT is exfoliated and dispersed into polymer matrix. To make it easy dispersion, hydrophilic MMT are converted to the ones with organophilic surface.
1. Introduction Several Techniques for Polymer/Layered Silicate Nanocomposites Technique of PLS Preparation Method 1 Method 2 Method 3 In-situ Polymerization Melt Compounding Solution Blending Polyolefin/Layered ed Silicates (MMT) Nanocomposites Method 1. Easier intercalation of monomer but it needs understanding of polymerization catalyst and process. Method 2. Simple but organic modifier of MMT is decomposed by harsh condition, it leads agglomerization of MMT. Method 3. Impossible method due to poor solubility of polyolefin.
1.Introduction Polyethylene/MMT Nanocomposites Using In-situ Polymerization 1) 3 types of montmorillonite (MMT) were used, and modified with trimethyl aluminum. 2) Nickel diimine catalyst was intercalated in the MMT galleries. 3) Formation of polyethylene inside the galleries leads to the exfoliation of the MMT. Exfoliation of MMT by Ethylene polymerization MMT Intercalation of Used MMTs (1)Cloisite Na (2)Cloisite 30B (3)Cloisite 93A Growing polymer chain Na C C OH T N C C OH C C H N HT HT T, tallow (~65% C 18, ~30% C 16, ~5% C 14 )
2. Experimental Materials All operations were performed under nitrogen (99.999%, Praxair) using standard Schlenk techniques or inside Glove-box. General Solvents (Toluene, Hexane, Methylene dichloride, etc ) Purchased from VWR and purified with activated alumina and 3A/4A mixed molecular sieves. Synthesis of Nickel Diimine Purchased from Aldrich or Acros and used without purification MMTs (Cloisite Na, Cloisite 30B and Cloisite 93A) for s Supporting Purchased from Southern Clay Products and used after drying under vacuum at 60 o C overnight. In situ polymerization Ethylene (99.9%, Praxair) was purified with R3-11 copper catalyst, activated alumina and 3A/4A mixed molecular sieves
2. Experimental Nanocomposite Characterization Differential Scanning Calorimetry (DSC, Q2000, TA Instruments) Thermal Gravimetric Analysis (TGA, Q500, TA Instruments) X-ray Diffractometer (XRD, D8-Focus, Bruker) Scanning Electron microscope (SEM, LEO 1530 FE-SEM) Transition Electron microscope (TEM, CM12, Philips)
Synthesis of Nickel Diimine with Functional Group Toluene 2 H 2 N NH 2 H N N H 2 SO 2 N NH 2 4 O O CH 2 Cl 2 H 2 N N N NH 2 NiBr 2 (DME) H 2 N N N NH 2 Ni Br Br bis(4-amino-2,3,5,6-tetramethylimino)acenaphtene nickel(ii) dibromide P. P. Pflugl, M. Brookhart, Macromolecules 2002, 35, 6074
Synthesis of MMT-Supported Nickel Diimine -1) C30B 1) Cloisite 30B was reacted with TMA for the organic modification and reactive groups generation. 2) Amine functionalized nickel diimine catalysts were supported onto Cloisite 30B gallery through chemical bonding. C T N C C OH C C OH MMT (Cloisite 30B) TGA analysis 260 o C TMA 390 o C Nickel Diimine C C O T N C C C O XRD patterns Al Al Cloisite 30B-Supported Nickel Diimine (C30B) 4.9 o (18.0 A) 360 o C 4.1 o (21.6 A) ity Relative Intensi 7.6 o (11.6 A) Cloisite 30B C30B 2 3 4 5 6 7 8 9 10 2 Theta
Synthesis of MMT-Supported Nickel Diimine - 2) C93A 1) Nickel diimine catalyst was physisorbed onto Cloisite 93A surface or gallery. C TH NH TH TGA analysis TMA Nickel Diimine Complex TH XRD patterns C NH TH MMT (Cloisite 93A) Cloisite 93A-Supported Nickel Diimine (C93A) 360 o C 400 o C ty Relative Intensi Cloisite 93A C93A 2 3 4 5 6 7 8 9 10 2 Theta
Synthesis of MMT-Supported Nickel Diimine - 3) CNa 1) Nickel diimine catalyst could be physisorbed onto Cloisite Na surface or gallery. TMA Na Nickel Diimine MMT (Cloisite Na) MMT-Supported Nickel Diimine (CNa) TGA analysis XRD patterns tensity Na Cloisite Na Relative In CNa 2 3 4 5 6 7 8 9 10 2 Theta
In Situ Polymerization 1) MMT layers are exfoliated by growth of polyethylene, and it means nano size layers are distributed into polyethylene matrix. Intercalation of Ethylene Polymerizatoin Exfoliated MMT into PE matrix (Slurry batch reactor, Hexane solvent, Continuously ethylene feeding, EASC activator or no activator)
In Situ Polymerization Results - 1) Activity Profiles 1) MMT supported catalysts systems show very stable activity profile. 2) A series of PE/MMT nanocomposites with different MMT fractions were prepared by varying the polymerization time. t Activity it Profiles (C30B vs. Unsupported ) t) thylene Flow [ml/min] 200 - Condition: 60 o C, Ethylene 50 psi, no activator 150 100 - C30B - Unsupported MMT 14.3% EMMT 50 8.3% MMT 3.8% 0 0 50 100 150 200 Time (min)
In Situ Polymerization Results- 1) Activity 1) C30B shows the highest yield. 2) C30B comparable catalyst activity in the absence of EASC activator, but CNa and C93A had not catalyst activity without EASC activator. Activity EASC activator No activator Structure of C30B H 2 N T N O O Al Al N C C Ni C C N N H Al Al Aluminoxane linkage could function as activator for C30B O O N T - Condition: 60 o C, Ethylene 50 psi,
In Situ Polymerization Results- 2) Crystallinity & Melting Temperature of Nanocomposites C30B without activator made nanocomposite with the highest T m and crystallinity. Crystallinity Low steric hindrance causes higher short chain branched PE High steric hindrance causes fewer short chain branched PE Melting Temperature - Polymerization Conditions: 60 o C, Ethylene 20 psi, EASC activator or no activator
In Situ Polymerization Results- 3) Decomposition Temperature of PE/C30B T d of nanocomposites with C30B were similar with reference homogeneous PE resin (473.4 o C). Good dispersion of the MMT layers in the polymer matrix, resulting in enhanced thermal stability of the nanocomposites. De erivative Weig ght (%) PE/C30B 473.6 2.5 o C 2.0 15 1.5 1.0 0.5 PE(83)/C30B(17) nanocomposite PE(93)/C30B(7)composite 0.0 200 250 300 350 400 450 500 Temperature ( o C) - Polymerization Conditions: 60 o C, Ethylene 50 psi, no activator
In Situ Polymerization Results- 3) Decomposition Temperature of PE/C93A and CNa 1) T d of nanocomposites using CNa and C93A were lower than that of the reference homogeneous PE resin (473.4 o C) 2) As MMT contents increase, T d of nanocomposites decreases. 3) MMT and/or alkyl modifier accelerate the degradation of PE. Derivative Weig ght (%) 2.5 2.0 15 1.5 1.0 0.5 PE/CNa PE(87)/CNa(13) nanoomposite PE(95)/CNa (5) nanocomposite ht (%) De erivative Weig 25 2.5 2.0 1.5 1.0 0.5 PE/C93A PE(88)/C93A(12) nanocomposite PE(95)/C93A(5) nanocomposite 0.0 0.0 200 250 300 350 400 450 500 200 250 300 350 400 450 500 Temperature ( o C) Temperature ( o C) - Polymerization Conditions: 60 o C, Ethylene 50 psi, EASC activator
In Situ Polymerization Results- 4) XRD Patterns of PE/C30B As increased polymerization time (lower C30B contents), the MMT layers were exfoliated. tensity 15.0 A Relative In PE/C30B PE(77)/C30B(23) nanocomposite 15.2 A PE(93)/C30B(7) nanocomposite 2 3 4 5 6 7 8 9 10 2 Theta - Polymerization Conditions: 60 o C, Ethylene 20 psi, EASC activator
In Situ Polymerization Results- 4) XRD Patterns of PE/CNa and C93A As increased polymerization time (lower MMT content), the MMT layers were not fully exfoliated. nsity Relative Inte PE/CNa 15.0 A PE(87)/CNa(13) nanocomposite 19.6 A PE(94)/CNa(6) nanocomposite nsity Relative Inte PE/C93A PE(87)/C93A(13) nanocomposite PE(94)/C93A(6) nanocomposite 2 3 4 5 6 7 8 9 10 2 3 4 5 6 7 8 9 10 2 Theta 2 Theta - Polymerization Conditions: 60 o C, Ethylene 20 psi, EASC activator
In Situ Polymerization Results- 5) SEM Micrographs of Supported C30B shows irregular particles in the 2-3 μm width. The edge of the C30B particles are curly, indicating that MMT layers have been intercalated and exfoliated by diffusion of the reactants from their edges to their centers during supporting process. C30B 1 μm 0.3 μm
3. Results and Discussion In Situ Polymerization Results - 5) SEM Micrographs of Nanocomposites 20 00.5 0 53 μm 0.3 μm R 200 μm TEM IP PE/C30B 10 Free-flowing nanocomposite particles were obtained without reactor fouling. The MMT layers y appear pp as stacks connected byy polymer p y strips p and fibrils of different lengths g and width. 21
3. Results and Discussion In Situ Polymerization Results- 5) TEM Micrographs of Nanocomposites 3 as dark regions. The MMT layers are oriented perpendicularly to the slicing plane, showing very good exfoliation. Several layers of MMT appear to be completely exfoliated and seem to flow with the ppolymer. y 2. 10 1 1. The MMT layers are oriented in planes that are parallel to the slicing plane, appearing 20 3. 2 50 nm 2 IP 1 R 200 nm 50 nm 3 50 nm 22
- Particle Fragmentation Mechanism 1. Large MMT particles are broken into several smaller particles. 2. The MMT layers are exfoliated by growing polymer. 3. Nanophase distribution of MMT layers on the polymer matrix. Step 1 Step 2 Step 3
4. Conclusion 1. PE/MMT nanocomposites were prepared by in situ polymerization with a functionalized nickel diimine catalyst on Cloisite Na and two organically modified MMTs, Cloisite 93A and Cloisite 30B. 2. The particle intercalation and exfoliation was initiated by the insertion of the nickel diimine catalyst into TMA-modified MMT galleries, and continued even further during the polymerization by the formation of polymer chains within the clay galleries. 3. C30B made nanocomposites with better thermal properties than those made with CNa and C93A. 4. C30B was active for ethylene polymerization even in the absence of the EASC activator. 5. SEM and TEM micrographs confirmed the formation of a nanophase of MMT layers distributed ib t d in the polymer matrix. Yiyoung Choi, Sang Young A. Shin, João B.P. Soares, Macromol. Chem. Phys. 2010, 211,1026 Thank you!