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Geology / Monitoring Drilling and Logging Operations at Ketzin Injection facility Drilling Hydraulic testing ti

Motivated Colleagues Core Logging Device

Core Control 18.5 9% 100 50% 1% 5% 13% 83 41% Ktzi 200 Ktzi 201 Ktzi 202 39% caprock (Weser Fm.) mudstone (Stuttgart Fm.) sandstone/siltstone (Stuttgart Fm.) 42% coal, coaly mudstone (Stuttgart Fm.) total of 201.5 m of cores mudstone (Grabfeld Fm.) Coring Geological Profile Norden et al. 2007

Characterized Rock Types Caprock (Weser and Arnstadt Fm.): Playa-type mudstones (210 m thick) Couplets of mudstone (0.05 1.5 m thick) and dolomite beds (0.01 and 0.5 m thick) Couplets stacked in groups of two to seven Basin wide uniformity Reservoir rock (Stuttgart Fm.): Sandstones consist of varying amounts of quartz, feldspar, and rock fragments (graywacke) Fine to medium-grained, well sorted, and weakly cemented by silicates / clay / anhydrite Monitoring Smart Casing

Smart Casing Concept Sensors placed behind the well casing Fully cemented in the annular space between casing and rock formation Special protector systems help to avoid damaging g the fiber optic cables and sensors This concept has a number of advantages: 1. High data quality due to small distance between the sensors and the target (injected CO 2 ) 2. Same coupling conditions in all repeat measurements (time-lapse measurements) 3. High repetition rate Permanent Downhole Monitoring Temperature Distributed Temperature Sensing (DTS) Pressure (+ Temperature) Fibre optic sensor Resistivity it Vertical Electrical Resistivity Array (VERA) Micro seismicity Triple Axis Accelerometer (TAA)

Smart Casing Installation Fibre Optic Pressure Sensor Slug test in Ktzi 201 (550 m depth ) Sensor limits: p = 137 MPa, T = 150 C Remote operation (distance > 10 km) No down hole electronics required High structural integration Reliability in hostile (HT/HP) environments Point wise or distributed monitoring Schmidt-Hattenberger et al. 2007

Krüger et al. 2007 DTS and Heater Cables Energy meter Fiber-optic DTS Electric generator or grid power Temperature Depth Line Source Heater Henninges et al. 2007

Gas Membrane Sensor data aquisition unit gas sampling quadrupole mass spectrometer (H 2, He, CH 4, N 2, 02, Ar, CO 2, 2 Kr ) Argon with formation gas pressurized Argon borehole pure Argon gas flow control unit fluid level formation gas formation gas phase separating membrane pressure & temperature sensor Non-Permanent Monitoring 3D seismics: sources and receivers placed at surface low resolution but reservoir coverage sensitive to low CO 2 (up to 10 %) low repetition rate due to costs (maximum once per year) Cross hole seismics and surface to borehole seismics: sources and receivers placed in boreholes (x-hole) source at surface, receivers moving in boreholes (VSP) source at surface (moving), receivers in boreholes (MSP) higher resolution than 3D seismics may interfere with other measurements in well cross-hole tomography and caprock integrity

Geochemistry Baseline - Geochemistry Nauen Havelländi ische Rinne meteorolgical station carbon dioxide surface soil flux determination mulitsensor in groundwater well methane determination (in 2 meter deep wells) graben structure 600m isobaths of the Schilfsandstein 800m Fa alkensee Ora ranienburge er Rinne rim of subsurface channels Zimmer 2007

Mud Gas Monitoring while Drilling mud gas extraction gas analysis in field laboratory from degasser gas pump eparator tank s gas pipeline water trap massspectrometer H 2, He, CH 4, N 2, O 2, Ar, CO2 gas chromatograph CH 4, C2H 6, C3H 8, C 4H 10 sampling bottle gas meter data collection exhaust haker screen shak mud pump possum belly cuttings mud tank Zimmer et al. 2007 Mud Gas Monitoring while Drilling With this method complete depth profiles of relevant gases gained Gas rich zones and fluid bearing inflow horizons are indicated by higher gas concentrations in the mud gas!boreholes in Ketzin: No zone with higher gas concentration detected Drilled formations generally poor in gas

Gas Discharged from Cores Fluid Monitoring Set Up to waste line switch over valve pump control unit water meter bypass water meter gas meter water trap water-gas separator quadrupole mass spectrometer (H 2, He, CH 4, N 2, Ar, CO, O ) 2 2 gas sampling unit exhaust draw down level multi parameter tool (ph, T, electrical conductivity) pressure gauge down hole pump (approx. 130m) waste line Zimmer et al. 2007

Fluid Sampling Set-up at Ketzin Stimulation N 2 -Lift

Removing Safety Valve Particle Sampling Specialist for on site analytic (Dargel, RWE Dea)! Fluid looks already clean after 1 h lifting (5m 3 )! Stop of lifting after production of 50m 3??? Microfiltration (1.2 "m)

Successful Measure 16.3 g/l REM, XRD: Fe + S 0.2 g/l 2.7 g/l Fines < 1 mg/l # stop of lifting after production of 100 m 3 water Modelling

t Geological (Static) Model 1. Pre-drilling reservoir model for general simulation of injection and distribution Nearest well information 5 km away Old core material crumbled, little petrophysics Fluvial sequence, general channel direction assumed to be known 2. Updated and refined model after information from 3 new wells has been included Frykman et al. 2007 Heterogeneity HORIZO NTAL HETEROGENEITY LOW MODERATE HIG H LOW Layercake VERTIC CAL HETERO OGENEITY MEDIUM HIG GH Jigsaw! La byrinth Flow unit W ell spacing Tyler and Finley RJ 1991

Probabilistic Reservoir Simulation Area of channel/sting facies CO 2 SINK drill site FLUVSIM area (10km x 9km x 80m) Bore hole data with channel and non-channel facies Vertical proportion curve, account for vertical trends Channel parameters (orientation, number, thickness, width) Areal variations given as areal proportion map Frykman et al. 2007 Permeability to Numerical Model

Flow of CO 2 in the Reservoir Kopp 2007 Modelling of CO 2 Injection One example of a scenario of gas Assumptions: 3 channels ~ 500 m Darcy, Mud flow facies ~ 0,1 m Darcy The CO 2 -Storage Team 2006

CO 2 migration / temperature effects Results of simplified numerical model: Bielinski et al. 2008 Media Coverage > 1000 articles and around 40 TV-stories

Conclusions Project start: 1 st April 2004 Permissions (> 20) applied for and collected Successful completion of 3 wells (1 IW, 2 OW) Delay around 1 year (only) Injector stimulated Baseline measurements completed Outlook CO 2 Injection in Spring 2008

Wissenschaftspark (scientific park) Albert-Einstein - Telegrafenberg Thank you for your attention References Beutler G, Hauschke N, Nitsch E (1999) Faziesentwicklung des Keupers im Germanischen Becken, in Hauschke N and Wilde V (eds eds.) Trias, eine ganz andere Welt: München, Verlag Dr. Friedrich Pfeil, p. 129 173 173 Bielinski A, Kopp A, Schütt H, Class H (2008) Monitoring of CO2 plumes during storage in geological formations using temperature signals: numerical investigation. International Journal of Greenhouse Gas Control (accepted for publication) Förster A, Norden B, Zinck-Jørgenson ørgenson, Frykman P, Kulenkampff J, Spangenberg E, Erzinger J, Zimmer M, Kopp J, Borm G, Juhlin C, Cosma C-G, Hurter S (2006) Baseline characterization of the CO2SINK geological storage site at Ketzin, Germany. Environmental Geosciences 13(3): 145-161 161 Frykman P, Zink-Jørgensen K, Bech N (2007) Geostatistical modelling for decisions in a CO2 storage experimental site. The Universities Forum on Reservoir Description and Simulation (UFORDS). 2-6 September, 2007. Scarborough, England. Heriot-Watt University, Edinburgh. Abstract volume, 1 p Tyler N, Finley RJ (1991) Architectural controls on the recovery of hydrocarbons from sandstone reservoirs. In: A.D. Miall and N. Tyler (Editors), The three-dimensional facies architecture t of terrigenous clastic sediments and its implications for hydrocarbon discovery and recovery. Concepts in Sedimentology and Paleontology. SEPM (Society for Sedimentary Geology), Tulsa, OK, United States, pp. 1-5