Numerical and Laboratory Study of Gas Flow through Unconventional Reservoir Rocks

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Numerical and Laboratory Study of Gas Flow through Unconventional Reservoir Rocks RPSEA Piceance Basin Tight Gas Research Review Xiaolong Yin, Assistant Professor Petroleum Engineering, Colorado School of Mines April 21 2011

Presentation Outline Challenges and our research activities Our RPSEA project and collaborators Preliminary results Goals and objectives

Background In very tight reservoir rocks, both measurement techniques and our understanding of the physics are being challenged Our group s research activities focus on pore-scale physics and flow using direct simulation and experiments Specifically, we investigate what makes unconventional rocks unconventional Surface interaction Non-continuum slippage Heterogeneity in pore structure and rock-fluid interactions

Our RPSEA Project RPSEA 09122-29 02/2011 02/2014 Use nanofluidic chips and single-molecule detection techniques to visualize fluid flow in nano-sized pores Combine core flooding test and SEM imaging to correlate fluid flow in tight rocks to pore structures Develop pore-scale numerical models to provide information that cannot be easily obtained from experiments, such as threedimensional motion of fluids Our Team Missouri University of Science & Technology B. Bai (core flooding), Y. Ma (single-molecule detection) Colorado School of Mines X. Yin (pore-scale models), K. Neeves (nanofluidic chips)

Traditional laboratory studies Pulse-decay permeability measurement Mercury porosimetry Linear core flooding Ultra-centrifuge PVT (CSM) These equipments allow us to study Porosity and permeability Storage capacity and transport Multiphase flows and formation damage A CMS-300 Pulse-Decay Permeameter

Non-traditional laboratory studies What makes flow in unconventional reservoir rocks unconventional? Surface interactions Non-continuum slippage Heterogeneity in surface properties Fractures and cracks In-situ stress This list is probably far from complete. Some of these effects can be studied using micro (right) and nanoscale (below) porous media analogs constructed on silicon / polymer chips Photo courtesy of Keith Neeves Chemical Engineering Colorado School of Mines

Permeability (Darcy) Preliminary results from micro-chip experiments 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 Experiment LB Simulation Air-water two phase flow test: Left: The geometry is initially saturated with water Below: Air is injected in the lower left corner forcing water out of the channels 1 2 3 4 5 Permeability comparison Data and photo provided by Keith Neeves and Melissa Wu, Chemical Engineering, Colorado School of Mines

Simulation of micro- and nano-scale flows Numerical tools have been and are being developed to study fluid flow with non-continuum effects in nano-sized pores Experimentally measured φ and k and pore structure Representative porous media geometry models Pore structure Relative permeability Effect of stress Adsorption / Desorption Direct numerical simulation models: Lattice-Boltzmann (for Navier-Stokes) DSMC (for non-continuum flows being developed)

Preliminary results from pore-scale modeling Porosity-permeability relation is the key to rock typing and understanding geomechanical effects on fluid flow ks 2 0.0030 0.0025 0.0020 0.0015 Homogeneous Geometry Heterogeneous Geometry Ideal, channelized geometry porositypermeability shows a strong correlation 0.0010 0.0005 0.0000 0.00 0.10 0.20 0.30 0.40 Porosity More realistic, heterogeneous geometry porosity-permeability shows large scattering

Preliminary results from pore-scale modeling A universal porosity-permeability correlation can be developed by recognizing that the large pores do not contribute to permeability ks 2 0.0030 Homogeneous Geometry 0.0025 Heterogeneous Geometry 0.0020 0.0015 0.0010 0.0005 0.0000 0.00 0.10 0.20 0.30 0.40 Conductive Porosity These data are from our scoping studies using 2D geometries 3D simulations and experiments are underway Such a correlation can be used to determine the geometry of pores from bulk measurement without resorting to image analysis

ka v 2 Simulation time -1 (s -1 ) Parallelized, 3D pore-scale simulator 0.025 10 1 0.02 10 0 Slope = 1 0.015 10-1 0.01 0.005 3D Representative Geometries 10-2 10-3 10 0 10 1 10 2 10 3 Number of Cores 0 0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 Porosity 3D Simulator Parallel Speedup 3D Porosity-Permeability Data

Goals and objectives Simulations with controlled geometries and assumed physics Increasing level of reality Micro- and nanofluidic experiments with controlled geometries and real physics The combined approach will significantly improve our understanding of fluid flow on nano-scale and unconventional reservoir dynamics Core-scale experiments with real geometries and real physics

Acknowledgements Collaborators Baojun Bai, Yinfa Ma (MUST) Keith Neeves (CSM, ChemE) Qinjun Kang (Los Alamos National Lab) Students Feng Xiao (PE) Lei Wang (PE) Melissa Wu (ChemE) Funding RPSEA

Simulated vs. measured permeability Simulation of flow through digital cores from CT-scan CT and experimental data from Imperial College Numerical simulations are done in CSM A1 BSS C1 F42A S1 S2 Porosity 42.9 19.6 23.3 33 14.1 24.6 Resolution 3.85 5.345 2.85 9.996 8.683 4.956 K (exp) 7,220 1,286 1,102 59,000 1,678 3,898 K (sim) 8,675 1,507 1,192 59,331 2,006 4,076 % error 20.2% 17.2% 8.1% 0.6% 19.6% 4.6%