Barbara Johnson, PE Associate - PDF Free Download

Q'/jt Golder Associates September 29, 2017 Project No.:023-6105.017 Metropolitan Council Environmental Services Industrial Waste Division 390 Robert St. N. St. Paul, MN 55101 Attention: Ms. Ashley Corbeille RE: AUGUST 2017 SAMPLING RESULTS SMR INDUSTRIAL DISCHARGE PERMIT NUMBER 2289 SOUTHEAST PUMP AND TREAT SYSTEM CANADIAN PACIFIC SHOREHAM FACILITY Dear Ms. Corbeille: On behalf of Canadian Pacific, enclosed is the August 2017 Sampling Results Self-Monitoring Report for the site located at 28th & Central Avenue NE, Minneapolis MN. In accordance with the Metropolitan Council Environmental Services (MCES) Industrial Discharge Permit Number 2289, effective October 1, 2016 (MCES permit), this submittal documents the quality of water discharged from the groundwater pump and treat system owned by Canadian Pacific. Required information for the discharge is provided as follows: Attachment A - Sampling Results - SMR. Attachment 8 - Analytical data from for the August 2017 monthly sam piing event. Attachment C - Field Instrument ph Calibration Records Analytical results from the August 2017 sampling event 1 showed that the treated discharge water was in compliance with the MCES permit discharge limitations during this reporting period. If you have any questions or comments, please do not hesitate to contact Barbara Johnson at (651) 697-9737. Thank you for your assistance in this matter. Very truly yours, GOLDER ASSOCIATES INC. 41flp Alan Phillips Project Geologist /~~Oµ)U Barbara Johnson, PE Associate Cc: Ms. Aimee Zack, CP Ms. Claire Mackler, Golder 1 Note that sample point SP-01 is identified as sample SE EFFLUENT in the analytical results from August 2017 (Attachmen_t_B Golder Associates Inc. 1751 West County Rd. B, Ste. 105 Roseville, MN USA 55113 Tel: (651) 697-9737 Fax: (651) 697-9737 www.golder.com Golder Associates: Operations in Africa, Asia, Australasia, Europe, North America and South America

Attachment A SAMPLING RESULTS SELF-MONITORING REPORT

Metropolitan Council Environmental Services Industrial Waste & Pollution Prevention Section 390 North Robert Street St. Paul, Minnesota 55101-1805 For MCES Use Only Permit No: Staff: Received: 0 L 45 E SAMPLING RESULTS - SMR for Standard and Special Discharge Permits Please complete Page 2 of this form for each monitoring point with sampling requirements in Attachment A of the Permit. 1. Permittee Name: Canadian Pacific Railway Permit No: 2289 ------ 2. Facility Address: 28th Ave NE & Central Ave NE, Minneapolis, MN 55418 3. Reporting Period: Year: 20_1_7 Choose applicable period below: Quarterly Reporter: Jan-Mar D Apr-Jun [!] Jul-Sep D Oct-Dec Semi-Annual Reporter: Jan-Jun D Jul-Dec Annual Reporter: D Jan-Dec D No discharge/no sampling this period. If checked, proceed to section 9 below and do not complete page 2. 4. Proper Sampling: Were all samples collected and composited according to permit requirements? [!]Yes D No If No, add explanation below: 5. Proper Analysis: Were all analyses conducted per permit requirements? [!] Yes D No If No, add explanation below: 6. Representative Discha~: Are the an~ical results representative of the wastewater discharged during this monitoring event? l.!j Yes LJ No If No, add explanation below: 7. Compliance Status: Compare the analytical results with the corresponding discharge limits in your Permit. Do any analytical results exceed the corresponding discharge limit(s) in your Permit? D Yes E] No If Yes, add explanation below: When did you become aware of the exceedance(s)? 8. General comments regarding submission: 9. Certification Statement: "I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to ensure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties under law for submitting false information, including the possibility of fine and imprisonment for known violations." Name (print): Barbara Johnson, PE Title: Authorized Representative for Canadian Pacific Signature: Date: Email: bsjohnson@golder.com Phone: 651-697-9737 Report form help sheet Page 1of2 SMR-SR-2016

Sample Results: Submit one result sheet for each sampling day per monitoring point. Enter daily values for each sampling event from one monitoring point, in accordance with requirements in the Industrial Discharge Permit (Section B). Daily and long-term values shall be compared to Discharge Limitations in Permit Section A.1 for compliance determinations. Attach all laboratory data sheets and supporting calculations. Monitoring Point: _s_p_-_0_1 -----------------Description: Effluent discharge line Sample Start Date & Time: 8/15/17 20:00 Sample End Date & Time: _8_11_5_11_1_2_0_:0_0 Discharge volume through monitoring point on sampling day: 1,248 (estimated) gallons Sample collected by: D Permittee EJ Other, name: Golder Associates Inc. Method of collection: 0 Manual D Automatic Sample composited by: D Permittee D Other, name: ------------- Composite method: N_A Substance Analytical Sample Laboratory Result Unit Detection Limits Analysis Method Sample Method Result Container Type Name ph 7.27 S.U. 0-14 4500-H+ Grab-Single Other Field Measurement Total Suspended Solids NS Grab - Single NA Chemical Oxygen Demand NS Grab - Single NA 1, 1-Dichloroethane 0.0655 mg/i 0.00024 EPA 8260 Grab - Single Vial - 40ml clear 1, 1-Dichloroethene 0.0199 mg/i 0.00041 EPA 8260 Grab - Single Vial - 40ml clear cis-1,2-dichloroethene 0.0378 mg/i 0.00026 EPA 8260 Grab - Single Vial - 40ml clear trans-1,2-dichloroethene 0.00043J mg/i 0.00026 EPA 8260 Grab - Single Vial - 40ml clear Tetrachloroethene 0.201 mg/i 0.00050 EPA 8260 Grab - Single Vial - 40ml clear 1, 1, 1-Trichloroethane 0.0951 mg/i 0.00050 EPA 8260 Grab - Single Vial - 40ml clear Trichloroethene 0.0132 mg/i 0.00033 EPA8260 Grab - Single Vial - 40ml clear Page 2of2 SMR-SR-2016

Attachment B ANALYTICAL DATA FROM PACE ANALYTICAL SERVICES, LLC August 2017

#=CL# LIMS USE: FR - ALISON ZOLL LIMS OBJECT ID: 40155143 August 21, 2017 Alison Zoll Golder Associates Inc. 744 Broad Street 25th Floor Newark, NJ 07102 RE: Pace Project No.: 40155143 Dear Alison Zoll: Enclosed are the analytical results for sample(s) received by the laboratory on August 17, 2017. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Laurie Woelfel laurie.woelfel@pacelabs.com Project Manager Enclosures Page 1 of 17

#=CP# CERTIFICATIONS Pace Project No.: 40155143 Green Bay Certification IDs 1241 Bellevue Street, Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky UST Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 New York Certification #: 12064 North Dakota Certification #: R-150 Virginia VELAP ID: 460263 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 Wisconsin Certification #: 405132750 Wisconsin DATCP Certification #: 105-444 USDA Soil Permit #: P330-16-00157 Federal Fish & Wildlife Permit #: LE51774A-0 Page 2 of 17

#=SS# SAMPLE SUMMARY Pace Project No.: 40155143 Lab ID Sample ID Matrix Date Collected Date Received 40155143001 081517-2000-200 Water 08/15/17 20:00 08/17/17 08:45 40155143002 SE EFFLUENT Water 08/15/17 20:00 08/17/17 08:45 Page 3 of 17

#=SA# SAMPLE ANALYTE COUNT Pace Project No.: 40155143 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 40155143001 081517-2000-200 EPA 8260 MDS 71 PASI-G 40155143002 SE EFFLUENT EPA 8260 MDS 71 PASI-G Page 4 of 17

#=AR# ANALYTICAL RESULTS Pace Project No.: 40155143 Sample: 081517-2000-200 Lab ID: 40155143001 Collected: 08/15/17 20:00 Received: 08/17/17 08:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Analytical Method: EPA 8260 Acetone <3.0 ug/l 20.0 3.0 1 08/18/17 12:02 67-64-1 Allyl chloride <2.2 ug/l 5.0 2.2 1 08/18/17 12:02 107-05-1 Benzene <0.50 ug/l 1.0 0.50 1 08/18/17 12:02 71-43-2 Bromobenzene <0.23 ug/l 1.0 0.23 1 08/18/17 12:02 108-86-1 Bromochloromethane <0.34 ug/l 1.0 0.34 1 08/18/17 12:02 74-97-5 Bromodichloromethane <0.50 ug/l 1.0 0.50 1 08/18/17 12:02 75-27-4 Bromoform <0.50 ug/l 1.0 0.50 1 08/18/17 12:02 75-25-2 Bromomethane <2.4 ug/l 5.0 2.4 1 08/18/17 12:02 74-83-9 2-Butanone (MEK) <3.0 ug/l 20.0 3.0 1 08/18/17 12:02 78-93-3 n-butylbenzene <0.50 ug/l 1.0 0.50 1 08/18/17 12:02 104-51-8 sec-butylbenzene <2.2 ug/l 5.0 2.2 1 08/18/17 12:02 135-98-8 tert-butylbenzene <0.18 ug/l 1.0 0.18 1 08/18/17 12:02 98-06-6 Carbon tetrachloride <0.50 ug/l 1.0 0.50 1 08/18/17 12:02 56-23-5 Chlorobenzene <0.50 ug/l 1.0 0.50 1 08/18/17 12:02 108-90-7 Chloroethane <0.37 ug/l 1.0 0.37 1 08/18/17 12:02 75-00-3 Chloroform <2.5 ug/l 5.0 2.5 1 08/18/17 12:02 67-66-3 Chloromethane <0.50 ug/l 1.0 0.50 1 08/18/17 12:02 74-87-3 2-Chlorotoluene <0.50 ug/l 1.0 0.50 1 08/18/17 12:02 95-49-8 4-Chlorotoluene <0.21 ug/l 1.0 0.21 1 08/18/17 12:02 106-43-4 1,2-Dibromo-3-chloropropane <2.2 ug/l 5.0 2.2 1 08/18/17 12:02 96-12-8 Dibromochloromethane <0.50 ug/l 1.0 0.50 1 08/18/17 12:02 124-48-1 1,2-Dibromoethane (EDB) <0.18 ug/l 1.0 0.18 1 08/18/17 12:02 106-93-4 Dibromomethane <0.43 ug/l 1.0 0.43 1 08/18/17 12:02 74-95-3 1,2-Dichlorobenzene <0.50 ug/l 1.0 0.50 1 08/18/17 12:02 95-50-1 1,3-Dichlorobenzene <0.50 ug/l 1.0 0.50 1 08/18/17 12:02 541-73-1 1,4-Dichlorobenzene <0.50 ug/l 1.0 0.50 1 08/18/17 12:02 106-46-7 Dichlorodifluoromethane <0.22 ug/l 1.0 0.22 1 08/18/17 12:02 75-71-8 1,1-Dichloroethane <0.24 ug/l 1.0 0.24 1 08/18/17 12:02 75-34-3 1,2-Dichloroethane <0.17 ug/l 1.0 0.17 1 08/18/17 12:02 107-06-2 1,1-Dichloroethene <0.41 ug/l 1.0 0.41 1 08/18/17 12:02 75-35-4 cis-1,2-dichloroethene <0.26 ug/l 1.0 0.26 1 08/18/17 12:02 156-59-2 trans-1,2-dichloroethene <0.26 ug/l 1.0 0.26 1 08/18/17 12:02 156-60-5 Dichlorofluoromethane <0.21 ug/l 1.0 0.21 1 08/18/17 12:02 75-43-4 1,2-Dichloropropane <0.23 ug/l 1.0 0.23 1 08/18/17 12:02 78-87-5 1,3-Dichloropropane <0.50 ug/l 1.0 0.50 1 08/18/17 12:02 142-28-9 2,2-Dichloropropane <0.48 ug/l 1.0 0.48 1 08/18/17 12:02 594-20-7 1,1-Dichloropropene <0.44 ug/l 1.0 0.44 1 08/18/17 12:02 563-58-6 cis-1,3-dichloropropene <0.50 ug/l 1.0 0.50 1 08/18/17 12:02 10061-01-5 trans-1,3-dichloropropene <0.23 ug/l 1.0 0.23 1 08/18/17 12:02 10061-02-6 Diethyl ether (Ethyl ether) <2.2 ug/l 5.0 2.2 1 08/18/17 12:02 60-29-7 Ethylbenzene <0.50 ug/l 1.0 0.50 1 08/18/17 12:02 100-41-4 Hexachloro-1,3-butadiene <2.1 ug/l 5.0 2.1 1 08/18/17 12:02 87-68-3 Isopropylbenzene (Cumene) <0.14 ug/l 1.0 0.14 1 08/18/17 12:02 98-82-8 p-isopropyltoluene <0.50 ug/l 1.0 0.50 1 08/18/17 12:02 99-87-6 Methylene Chloride <0.23 ug/l 1.0 0.23 1 08/18/17 12:02 75-09-2 4-Methyl-2-pentanone (MIBK) <2.1 ug/l 5.0 2.1 1 08/18/17 12:02 108-10-1 Date: 08/21/2017 05:02 PM Page 5 of 17

#=AR# ANALYTICAL RESULTS Pace Project No.: 40155143 Sample: SE EFFLUENT Lab ID: 40155143002 Collected: 08/15/17 20:00 Received: 08/17/17 08:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Analytical Method: EPA 8260 Acetone <3.0 ug/l 20.0 3.0 1 08/18/17 15:17 67-64-1 Allyl chloride <2.2 ug/l 5.0 2.2 1 08/18/17 15:17 107-05-1 Benzene <0.50 ug/l 1.0 0.50 1 08/18/17 15:17 71-43-2 Bromobenzene <0.23 ug/l 1.0 0.23 1 08/18/17 15:17 108-86-1 Bromochloromethane <0.34 ug/l 1.0 0.34 1 08/18/17 15:17 74-97-5 Bromodichloromethane <0.50 ug/l 1.0 0.50 1 08/18/17 15:17 75-27-4 Bromoform <0.50 ug/l 1.0 0.50 1 08/18/17 15:17 75-25-2 Bromomethane <2.4 ug/l 5.0 2.4 1 08/18/17 15:17 74-83-9 2-Butanone (MEK) <3.0 ug/l 20.0 3.0 1 08/18/17 15:17 78-93-3 n-butylbenzene <0.50 ug/l 1.0 0.50 1 08/18/17 15:17 104-51-8 sec-butylbenzene <2.2 ug/l 5.0 2.2 1 08/18/17 15:17 135-98-8 tert-butylbenzene <0.18 ug/l 1.0 0.18 1 08/18/17 15:17 98-06-6 Carbon tetrachloride <0.50 ug/l 1.0 0.50 1 08/18/17 15:17 56-23-5 Chlorobenzene <0.50 ug/l 1.0 0.50 1 08/18/17 15:17 108-90-7 Chloroethane <0.37 ug/l 1.0 0.37 1 08/18/17 15:17 75-00-3 Chloroform <2.5 ug/l 5.0 2.5 1 08/18/17 15:17 67-66-3 Chloromethane <0.50 ug/l 1.0 0.50 1 08/18/17 15:17 74-87-3 2-Chlorotoluene <0.50 ug/l 1.0 0.50 1 08/18/17 15:17 95-49-8 4-Chlorotoluene <0.21 ug/l 1.0 0.21 1 08/18/17 15:17 106-43-4 1,2-Dibromo-3-chloropropane <2.2 ug/l 5.0 2.2 1 08/18/17 15:17 96-12-8 Dibromochloromethane <0.50 ug/l 1.0 0.50 1 08/18/17 15:17 124-48-1 1,2-Dibromoethane (EDB) <0.18 ug/l 1.0 0.18 1 08/18/17 15:17 106-93-4 Dibromomethane <0.43 ug/l 1.0 0.43 1 08/18/17 15:17 74-95-3 1,2-Dichlorobenzene <0.50 ug/l 1.0 0.50 1 08/18/17 15:17 95-50-1 1,3-Dichlorobenzene <0.50 ug/l 1.0 0.50 1 08/18/17 15:17 541-73-1 1,4-Dichlorobenzene <0.50 ug/l 1.0 0.50 1 08/18/17 15:17 106-46-7 Dichlorodifluoromethane <0.22 ug/l 1.0 0.22 1 08/18/17 15:17 75-71-8 1,1-Dichloroethane 65.5 ug/l 1.0 0.24 1 08/18/17 15:17 75-34-3 1,2-Dichloroethane <0.17 ug/l 1.0 0.17 1 08/18/17 15:17 107-06-2 1,1-Dichloroethene 19.9 ug/l 1.0 0.41 1 08/18/17 15:17 75-35-4 cis-1,2-dichloroethene 37.8 ug/l 1.0 0.26 1 08/18/17 15:17 156-59-2 trans-1,2-dichloroethene 0.43J ug/l 1.0 0.26 1 08/18/17 15:17 156-60-5 Dichlorofluoromethane <0.21 ug/l 1.0 0.21 1 08/18/17 15:17 75-43-4 1,2-Dichloropropane <0.23 ug/l 1.0 0.23 1 08/18/17 15:17 78-87-5 1,3-Dichloropropane <0.50 ug/l 1.0 0.50 1 08/18/17 15:17 142-28-9 2,2-Dichloropropane <0.48 ug/l 1.0 0.48 1 08/18/17 15:17 594-20-7 1,1-Dichloropropene <0.44 ug/l 1.0 0.44 1 08/18/17 15:17 563-58-6 cis-1,3-dichloropropene <0.50 ug/l 1.0 0.50 1 08/18/17 15:17 10061-01-5 trans-1,3-dichloropropene <0.23 ug/l 1.0 0.23 1 08/18/17 15:17 10061-02-6 Diethyl ether (Ethyl ether) <2.2 ug/l 5.0 2.2 1 08/18/17 15:17 60-29-7 Ethylbenzene <0.50 ug/l 1.0 0.50 1 08/18/17 15:17 100-41-4 Hexachloro-1,3-butadiene <2.1 ug/l 5.0 2.1 1 08/18/17 15:17 87-68-3 Isopropylbenzene (Cumene) <0.14 ug/l 1.0 0.14 1 08/18/17 15:17 98-82-8 p-isopropyltoluene <0.50 ug/l 1.0 0.50 1 08/18/17 15:17 99-87-6 Methylene Chloride <0.23 ug/l 1.0 0.23 1 08/18/17 15:17 75-09-2 4-Methyl-2-pentanone (MIBK) <2.1 ug/l 5.0 2.1 1 08/18/17 15:17 108-10-1 Date: 08/21/2017 05:02 PM Page 7 of 17

#=QC# QUALITY CONTROL DATA Pace Project No.: 40155143 QC Batch: QC Batch Method: 264995 EPA 8260 Associated Lab Samples: 40155143001, 40155143002 Analysis Method: Analysis Description: EPA 8260 8260 MSV METHOD BLANK: 1558903 Associated Lab Samples: 40155143001, 40155143002 Parameter Units Blank Result Matrix: Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/l <0.18 1.0 0.18 08/18/17 10:13 1,1,1-Trichloroethane ug/l <0.50 1.0 0.50 08/18/17 10:13 1,1,2,2-Tetrachloroethane ug/l <0.25 1.0 0.25 08/18/17 10:13 1,1,2-Trichloroethane ug/l <0.20 1.0 0.20 08/18/17 10:13 1,1,2-Trichlorotrifluoroethane ug/l <0.81 5.0 0.81 08/18/17 10:13 1,1-Dichloroethane ug/l <0.24 1.0 0.24 08/18/17 10:13 1,1-Dichloroethene ug/l <0.41 1.0 0.41 08/18/17 10:13 1,1-Dichloropropene ug/l <0.44 1.0 0.44 08/18/17 10:13 1,2,3-Trichlorobenzene ug/l <2.1 5.0 2.1 08/18/17 10:13 1,2,3-Trichloropropane ug/l <0.50 1.0 0.50 08/18/17 10:13 1,2,4-Trichlorobenzene ug/l <2.2 5.0 2.2 08/18/17 10:13 1,2,4-Trimethylbenzene ug/l <0.50 1.0 0.50 08/18/17 10:13 1,2-Dibromo-3-chloropropane ug/l <2.2 5.0 2.2 08/18/17 10:13 1,2-Dibromoethane (EDB) ug/l <0.18 1.0 0.18 08/18/17 10:13 1,2-Dichlorobenzene ug/l <0.50 1.0 0.50 08/18/17 10:13 1,2-Dichloroethane ug/l <0.17 1.0 0.17 08/18/17 10:13 1,2-Dichloropropane ug/l <0.23 1.0 0.23 08/18/17 10:13 1,3,5-Trimethylbenzene ug/l <0.50 1.0 0.50 08/18/17 10:13 1,3-Dichlorobenzene ug/l <0.50 1.0 0.50 08/18/17 10:13 1,3-Dichloropropane ug/l <0.50 1.0 0.50 08/18/17 10:13 1,4-Dichlorobenzene ug/l <0.50 1.0 0.50 08/18/17 10:13 2,2-Dichloropropane ug/l <0.48 1.0 0.48 08/18/17 10:13 2-Butanone (MEK) ug/l <3.0 20.0 3.0 08/18/17 10:13 2-Chlorotoluene ug/l <0.50 1.0 0.50 08/18/17 10:13 4-Chlorotoluene ug/l <0.21 1.0 0.21 08/18/17 10:13 4-Methyl-2-pentanone (MIBK) ug/l <2.1 5.0 2.1 08/18/17 10:13 Acetone ug/l <3.0 20.0 3.0 08/18/17 10:13 Allyl chloride ug/l <2.2 5.0 2.2 08/18/17 10:13 Benzene ug/l <0.50 1.0 0.50 08/18/17 10:13 Bromobenzene ug/l <0.23 1.0 0.23 08/18/17 10:13 Bromochloromethane ug/l <0.34 1.0 0.34 08/18/17 10:13 Bromodichloromethane ug/l <0.50 1.0 0.50 08/18/17 10:13 Bromoform ug/l <0.50 1.0 0.50 08/18/17 10:13 Bromomethane ug/l <2.4 5.0 2.4 08/18/17 10:13 Carbon tetrachloride ug/l <0.50 1.0 0.50 08/18/17 10:13 Chlorobenzene ug/l <0.50 1.0 0.50 08/18/17 10:13 Chloroethane ug/l <0.37 1.0 0.37 08/18/17 10:13 Chloroform ug/l <2.5 5.0 2.5 08/18/17 10:13 Chloromethane ug/l <0.50 1.0 0.50 08/18/17 10:13 cis-1,2-dichloroethene ug/l <0.26 1.0 0.26 08/18/17 10:13 cis-1,3-dichloropropene ug/l <0.50 1.0 0.50 08/18/17 10:13 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 08/21/2017 05:02 PM Page 9 of 17

#=QC# QUALITY CONTROL DATA Pace Project No.: 40155143 METHOD BLANK: 1558903 Associated Lab Samples: 40155143001, 40155143002 Parameter Units Blank Result Matrix: Water Reporting Limit MDL Analyzed Dibromochloromethane ug/l <0.50 1.0 0.50 08/18/17 10:13 Dibromomethane ug/l <0.43 1.0 0.43 08/18/17 10:13 Dichlorodifluoromethane ug/l <0.22 1.0 0.22 08/18/17 10:13 Dichlorofluoromethane ug/l <0.21 1.0 0.21 08/18/17 10:13 Diethyl ether (Ethyl ether) ug/l <2.2 5.0 2.2 08/18/17 10:13 Ethylbenzene ug/l <0.50 1.0 0.50 08/18/17 10:13 Hexachloro-1,3-butadiene ug/l <2.1 5.0 2.1 08/18/17 10:13 Isopropylbenzene (Cumene) ug/l <0.14 1.0 0.14 08/18/17 10:13 m&p-xylene ug/l <1.0 2.0 1.0 08/18/17 10:13 Methyl-tert-butyl ether ug/l <0.17 1.0 0.17 08/18/17 10:13 Methylene Chloride ug/l <0.23 1.0 0.23 08/18/17 10:13 n-butylbenzene ug/l <0.50 1.0 0.50 08/18/17 10:13 n-propylbenzene ug/l <0.50 1.0 0.50 08/18/17 10:13 Naphthalene ug/l <2.5 5.0 2.5 08/18/17 10:13 o-xylene ug/l <0.50 1.0 0.50 08/18/17 10:13 p-isopropyltoluene ug/l <0.50 1.0 0.50 08/18/17 10:13 sec-butylbenzene ug/l <2.2 5.0 2.2 08/18/17 10:13 Styrene ug/l <0.50 1.0 0.50 08/18/17 10:13 tert-butylbenzene ug/l <0.18 1.0 0.18 08/18/17 10:13 Tetrachloroethene ug/l <0.50 1.0 0.50 08/18/17 10:13 Tetrahydrofuran ug/l <2.0 5.0 2.0 08/18/17 10:13 Toluene ug/l <0.50 1.0 0.50 08/18/17 10:13 trans-1,2-dichloroethene ug/l <0.26 1.0 0.26 08/18/17 10:13 trans-1,3-dichloropropene ug/l <0.23 1.0 0.23 08/18/17 10:13 Trichloroethene ug/l <0.33 1.0 0.33 08/18/17 10:13 Trichlorofluoromethane ug/l <0.18 1.0 0.18 08/18/17 10:13 Vinyl chloride ug/l <0.18 1.0 0.18 08/18/17 10:13 4-Bromofluorobenzene (S) % 87 61-130 08/18/17 10:13 Dibromofluoromethane (S) % 114 67-130 08/18/17 10:13 Toluene-d8 (S) % 96 70-130 08/18/17 10:13 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1558904 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1-Trichloroethane ug/l 50 50.5 101 70-130 1,1,2,2-Tetrachloroethane ug/l 50 52.8 106 70-130 1,1,2-Trichloroethane ug/l 50 54.3 109 70-130 1,1,2-Trichlorotrifluoroethane ug/l 50 51.1 102 50-150 1,1-Dichloroethane ug/l 50 51.6 103 71-132 1,1-Dichloroethene ug/l 50 47.0 94 75-130 1,2,4-Trichlorobenzene ug/l 50 45.5 91 70-130 1,2-Dibromo-3-chloropropane ug/l 50 50.0 100 63-123 1,2-Dibromoethane (EDB) ug/l 50 53.6 107 70-130 1,2-Dichlorobenzene ug/l 50 52.1 104 70-130 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 08/21/2017 05:02 PM Page 10 of 17

#=QC# QUALITY CONTROL DATA Pace Project No.: 40155143 LABORATORY CONTROL SAMPLE: Parameter 1558904 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,2-Dichloroethane ug/l 50 49.1 98 70-131 1,2-Dichloropropane ug/l 50 56.4 113 80-120 1,3-Dichlorobenzene ug/l 50 53.0 106 70-130 1,4-Dichlorobenzene ug/l 50 50.8 102 70-130 Benzene ug/l 50 52.1 104 73-145 Bromodichloromethane ug/l 50 53.9 108 70-130 Bromoform ug/l 50 51.8 104 67-130 Bromomethane ug/l 50 30.8 62 26-128 Carbon tetrachloride ug/l 50 55.9 112 70-133 Chlorobenzene ug/l 50 53.2 106 70-130 Chloroethane ug/l 50 48.0 96 58-120 Chloroform ug/l 50 53.5 107 80-121 Chloromethane ug/l 50 33.1 66 40-127 cis-1,2-dichloroethene ug/l 50 52.7 105 70-130 cis-1,3-dichloropropene ug/l 50 50.1 100 70-130 Dibromochloromethane ug/l 50 50.4 101 70-130 Dichlorodifluoromethane ug/l 50 34.1 68 20-135 Ethylbenzene ug/l 50 53.9 108 87-129 Isopropylbenzene (Cumene) ug/l 50 55.1 110 70-130 m&p-xylene ug/l 100 110 110 70-130 Methyl-tert-butyl ether ug/l 50 42.9 86 66-143 Methylene Chloride ug/l 50 48.8 98 70-130 o-xylene ug/l 50 55.7 111 70-130 Styrene ug/l 50 53.2 106 70-130 Tetrachloroethene ug/l 50 47.1 94 70-130 Toluene ug/l 50 53.5 107 82-130 trans-1,2-dichloroethene ug/l 50 48.3 97 75-132 trans-1,3-dichloropropene ug/l 50 50.5 101 70-130 Trichloroethene ug/l 50 55.6 111 70-130 Trichlorofluoromethane ug/l 50 45.8 92 76-133 Vinyl chloride ug/l 50 42.0 84 57-136 4-Bromofluorobenzene (S) % 101 61-130 Dibromofluoromethane (S) % 100 67-130 Toluene-d8 (S) % 99 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1559932 MS 40155121003 Spike Parameter Units Result Conc. MSD Spike Conc. 1559933 MS Result MSD Result MS % Rec MSD % Rec Max % Rec Limits RPD RPD 1,1,1-Trichloroethane ug/l 1.8 50 50 49.7 53.3 96 103 70-134 7 20 1,1,2,2-Tetrachloroethane ug/l <0.25 50 50 51.1 54.7 102 109 70-130 7 20 1,1,2-Trichloroethane ug/l <0.20 50 50 54.1 53.4 108 107 70-130 1 20 1,1,2-Trichlorotrifluoroethane ug/l <0.81 50 50 46.6 50.6 93 101 50-150 8 20 1,1-Dichloroethane ug/l 0.87J 50 50 58.4 56.4 115 111 71-133 3 20 1,1-Dichloroethene ug/l <0.41 50 50 44.6 47.4 89 95 75-136 6 20 Qual Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 08/21/2017 05:02 PM Page 11 of 17

#=QC# QUALITY CONTROL DATA Pace Project No.: 40155143 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1559932 MS 40155121003 Spike Parameter Units Result Conc. MSD Spike Conc. 1559933 MS Result MSD Result MS % Rec MSD % Rec Max % Rec Limits RPD RPD 1,2,4-Trichlorobenzene ug/l <2.2 50 50 47.9 48.3 96 97 70-130 1 20 1,2-Dibromo-3- ug/l <2.2 50 50 46.1 48.8 92 98 63-123 6 20 chloropropane 1,2-Dibromoethane (EDB) ug/l <0.18 50 50 53.8 53.6 108 107 70-130 0 20 1,2-Dichlorobenzene ug/l <0.50 50 50 50.9 53.3 102 107 70-130 5 20 1,2-Dichloroethane ug/l <0.17 50 50 47.9 48.8 96 98 70-131 2 20 1,2-Dichloropropane ug/l <0.23 50 50 59.4 58.2 119 116 80-120 2 20 1,3-Dichlorobenzene ug/l <0.50 50 50 52.9 54.1 106 108 70-130 2 20 1,4-Dichlorobenzene ug/l <0.50 50 50 51.0 51.9 102 104 70-130 2 20 Benzene ug/l <0.50 50 50 52.2 54.8 104 110 73-145 5 20 Bromodichloromethane ug/l <0.50 50 50 52.7 54.3 105 109 70-130 3 20 Bromoform ug/l <0.50 50 50 51.0 52.6 102 105 67-130 3 20 Bromomethane ug/l <2.4 50 50 33.5 37.0 67 74 26-129 10 20 Carbon tetrachloride ug/l <0.50 50 50 52.3 56.8 105 114 70-134 8 20 Chlorobenzene ug/l 1.2 50 50 53.9 53.8 105 105 70-130 0 20 Chloroethane ug/l <0.37 50 50 44.7 46.9 89 94 58-120 5 20 Chloroform ug/l <2.5 50 50 51.0 53.9 102 108 80-121 6 20 Chloromethane ug/l <0.50 50 50 31.0 31.3 62 63 40-128 1 20 cis-1,2-dichloroethene ug/l 2.4 50 50 53.4 53.0 102 101 70-130 1 20 cis-1,3-dichloropropene ug/l <0.50 50 50 52.1 53.9 104 108 70-130 4 20 Dibromochloromethane ug/l <0.50 50 50 48.9 50.5 98 101 70-130 3 20 Dichlorodifluoromethane ug/l <0.22 50 50 31.2 32.8 62 66 20-146 5 20 Ethylbenzene ug/l <0.50 50 50 52.5 53.8 105 108 87-129 2 20 Isopropylbenzene (Cumene) ug/l <0.14 50 50 53.5 55.1 107 110 70-130 3 20 m&p-xylene ug/l <1.0 100 100 109 111 109 111 70-130 1 20 Methyl-tert-butyl ether ug/l <0.17 50 50 55.4 58.2 111 116 66-143 5 20 Methylene Chloride ug/l <0.23 50 50 51.5 53.1 103 106 70-130 3 20 o-xylene ug/l <0.50 50 50 55.0 55.1 110 110 70-130 0 20 Styrene ug/l <0.50 50 50 53.0 52.8 106 106 70-130 0 20 Tetrachloroethene ug/l <0.50 50 50 46.5 48.6 93 97 70-130 5 20 Toluene ug/l <0.50 50 50 53.0 54.1 106 108 82-131 2 20 trans-1,2-dichloroethene ug/l <0.26 50 50 52.3 54.7 105 109 75-135 5 20 trans-1,3-dichloropropene ug/l <0.23 50 50 54.2 52.8 108 106 70-130 3 20 Trichloroethene ug/l <0.33 50 50 53.7 55.4 107 111 70-130 3 20 Trichlorofluoromethane ug/l <0.18 50 50 43.2 45.2 86 90 76-150 5 20 Vinyl chloride ug/l <0.18 50 50 38.2 39.8 76 80 56-143 4 20 4-Bromofluorobenzene (S) % 101 101 61-130 Dibromofluoromethane (S) % 103 104 67-130 Toluene-d8 (S) % 98 98 70-130 Qual Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 08/21/2017 05:02 PM Page 12 of 17

#=QL# QUALIFIERS Pace Project No.: 40155143 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-G Pace Analytical Services - Green Bay Date: 08/21/2017 05:02 PM Page 13 of 17

#=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: 40155143 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 40155143001 081517-2000-200 EPA 8260 264995 40155143002 SE EFFLUENT EPA 8260 264995 Date: 08/21/2017 05:02 PM Page 14 of 17

Company Name: Branch/Location: Project Contact: Phone: Project Number: Project Name: Project State: Sampled By (Print): Sampled By (Sign): PO#: Data Package Options (billable) 0 EPA Level Ill 0 EPA Level IV PACE LAB# (Please Print Clearly) MS/MSD O On your sample (billable) 0 NOT needed on your sample CLIENT FIELD ID ~l-/ (;fl) Regulatory Program: A=Air B =Biota C =Charcoal O=Oil S=Soil DATE l'.10 l <9 SI 51 7-2..<Wl!.9 - t.oi <.9 i /15/17 i/l"f/17 00~ 5 Efflqe'4 f- ff UPPER MIDWEST REGION MN: 612-607-1700 WI: 920-469-2436 d" eana.lytical I CHAIN Qf CUST Y M lltocom.«www.pecelabs.com v - - - *Preservation Codes A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH H=Sodium Bisulfate Solution FILTERED? (YES/NO) PRESERVATION (CODE)* Matrix Codes W=Water OW = Drinking Water GW = Ground Water SW = Surface Water!=Sodium Thiosulfate J=Other Quote#: I Mall To Company: Mail To Address: Invoice To Contact: Invoice To Company: Invoice To Address: Invoice To Phone: CLIENT COMMENTS of Page 15 of 17 I LAB COMMENTS Profile# We>r/..:. Rush Turnaround Time Requested - Prelims (Rush TAT subject to approval/surcharge) Date Needed: Transmit Prelim Rush Results by (complete what you want): Email#1: Emall#2: ITelephone: I IRelinquished By: Fax: Samples on HOU> are subject to special pricing and release of llablllty Relinquished By: Date/Time: Received By: Date/Time: PACE Project No. ~ l1ot fst'-(j l(v5 C Sample Receipt ph OK I Adjusted Custody Seal Prefse~t I Not Present 1Wct I Not Intact C019a(27 Jun2006)

I Minneapolis Cooler T.ransler Chee!( List Document Number: e-mn-c-214-rev O< Page 1 of 1 Issuing Authority Pace Minnesota Quality Office Client ltr~ulls~ rr Ch <elk l~st v{olf)f\;f) Destination Lab Received with Custody Seal Custody Seal Intact Yes Temp Read Corrected Temp Correction Factor Samples on cooling process has begu:i Rush/Short Hold Containers Intact No a Re Iced P Blank Included Shipped By/Date ~No E?/!b(f7' Notes Page 16 of 17

Courier: Fed Ex Client r Pace Other: Sample Condition Upon Receipt \~A-M...,'-'. ~"'"""'6 Project#:... o...- Tracking#: -------...1-'-""'i:...o:~~+.--...:A,.-------- 40155143 Custody Seal on Cooler/Box Present:~es no Seals intact: no Custody Seal on Samples Present: r yes no Seals intact: no Packing Material: Bubble Wrap ~Bubble Bags None Other. - Green Bay WI 1241 Bellevue Street, Suite 9 WOl.40155143 ll 11 ll \II Ill \I II Ill Ill Thermometer Used ;)/t.., S 3 Type of Ice: ~ Blue Dry None ~ Samples on ice, cooling process has begun Cooler Temperature Uncorr: ~ S /Corr: 'Lf. '\ Biological Tissue is Frozen: yes >. Temp Blank Present: Yes no no Temp should be above freezing to 6 C. Biota Samples may be received at $ 0 c. Chain of Custody Present: 'afes ONo ON/A 1. Chain of Custody Filled Out: ~es ONo ON/A 2. Chain of Custody Relinquished: ~es ONo ON/A 3. Sampler Name & Signature on COG: ~es ONo ON/A 4. Samples Arrived within Hold Time: )ib-es ONo ON/A 5. Comments: - VOA Samples frozen upon receipt 0Yes ONo Date/Time: Short Hold Time Analysis (<72hr): 0Yes 'BNo ON/A 6. Rush Turn Around Time Requested: 0Yes ~o ON/A 7. Sufficient Volume: ~s ONo ON/A 8. Correct Containers Used: ~es ONo ON/A 9. -Pace Containers Used: )i;jves ONo ON/A t--7 Perso~~ng contents: Date: Initials: J.f/Zq -Pace IR Containers Used: 0Yes ONo ~/A Containers Intact: ~es ONo ON/A 10. Filtered volume received for Dissolved tests 0Yes ONo ~ 11. Sample Labels match COG: 0Yes 'liia:no ON/A 12.'5P01- )v:,..{5 ~.,/t ba<. r~41 -Includes date/time/id/analysis Matrix: iv.j!l..j/11.ff7 All containers needing preservation have been checked. 0Yes ONo 'ntnta HN03 H2S04 NaOH NaOH +ZnAct (Non-Compliance noted in 13.) 13. ------- ------------------------------ All containers needing preservation are found to be in compliance with EPA recommendation. 0Yes ONo ~/A (HN03, H2S04 $2; NaOH+ZnAct ;::9, NaOH ~12) e~?tio;;; ~ ~iif~~ roc: roi.toh,- --- --- --~- -- --- -- Initial when I Lab Std #ID of lua1e1 O&G, WIDR, Phenolics, OTHER: es 0No completed preservative Time: Headspace in VOA Vials ( >6mm): 0Yes ~o ON/A 14. Trip Blank Present: ~es ONo ON/A 15. Trip Blank Custody Seals Present s i ~@es ONo ON/A Pace Trip Blank Lot# (if purchased): Client Notification/ Resolution: Person Contacted: Date/Time: Comments/ Resolution: ----------------- If checked, see attached form for additional comments D ---------------------------------------------------------------- Project Manager Review: F-GB-C-031-Rev.04 (12Dec2016) SCUR.xls Pace Analytical Services LLC. - Green Bay WI Date:?\_,_..,...,\...,q... Page 17 of 17

Attachment C FIELD INSTRUMENT ph CALIBRATION RECORDS

FIELD ENVIRONMENTAi. INSTRUMENTS, INC. www.fleldenvlron,mental.com 301 Elru$hton.i:av-en... e Suite A PiHsburgh PA 1522"1 BOo--393-4009 Toll Free (4'12) 436-2600 Loe.al (4"12) 436-2616 Fax YSI 556 MPS Calibration Certificate Cal Standard Pll7@25c Cal Standard PH4@25c Cal Standard PH 10@25c Lot# Expiration Pre-Cal Reading Post-Cal Reading G006-14 I --- -- r 3/30/2019 7.01 7.00 ph m V value -23.8 Lot# Expiration Pre-Cal Reading Post-Cal Reading 0053-13 3/14/2019 3.88 4.00 phmvvalue 149.1 Lot # Expiration ~70443 0! 5/fo/2019 Pre-Cal Reading Post-Cal 9.::-J Reading 9.90 ph mvvalue -190.9 j Acceptable Range (6.86 to 7.14) (0 mv +/- 50mV) Acceptable Range (3.92 to 4.08) (141.2m V to l 56.2m V) Acceptable Range (9.80 to I 0.20) (-188.8mV to -203.8mV) Cal Standard Conductivity Lot# L G006-15 Expiration Pre-Cal Reading Post-Cal Reading 1.409 Gain 0.981 I 111112019 T 1.417 [ Acceptable Range (1.338 to 1.479) (0.9 to 1.10) Check Standard ORP Temp Reading Acceptable Range --2-0-.8--..---.---23-7-.5-=------.1 ( +/- 2.0m V) mv Offset 1 33.53 (0 +/- 100) Dissolved Oxygen % Saturation m IL r 100.0 I 8.89 Acceptable Range Gain 0.8 (.7 to 1.4) Model SIN Barcode Cable Order# 556-4 MPS """ 14C101881 U75230X U74830X 347036 New DO Membrane --- 0 Yes @ No 1 DO cap Color 0 Black@ BlueO Yellow Calibrated By l Al Marshall J Date of Calibration '8114/2017 l *Solutions provided by LabChem ( 412-826-5230) All calibrations performed by FEI conform to manufacturer's specifications. Please report any issues within 24 hours of receiving equipment.. All calibration solutions used are traceable to NIST. Additional documentation is available upon request.