ICP Test Report Certification Packet Company name : Littelfuse, Inc. Product Series: Mini PCB Holder 153 series Product #: 01530008Z_01530007Z Issue Date: November 12, 2012 It is hereby certified by Littelfuse, Inc. that there is neither RoHS (EU Directive 2002/95/EC, 2011/65/EU)-restricted substance nor such use, for materials to be used for unit parts, for packing/packaging materials, and for additives and the like in the manufacturing processes. In addition, it is hereby reported to you that the parts and sub-materials, the materials to be used for unit parts, the packing/packaging materials, and the additives and the like in the manufacturing processes, are all composed of the following components. Issued by: <Global EHS Coordinator> (1) Parts, sub-materials and unit parts This document covers the 01530008Z series RoHS-Compliant series products manufactured by Littelfuse, Inc. < Raw Materials Used Please see Table 1 (2) The ICP data on all measurable substances Remarks: Please see appropriate pages as identifed in Table 1 1 Decemeber 01, 2005 Littelfuse, Inc. Page 1
Table 1: List of Raw Materials covered by this report Total Parts Raw Material Part Number Raw Material Description Page(s) 1 883-057/ 883-058 Terminal 3-7 2 153007-4/ 153007-3 Body Half 8-16 2
Test Report Number : TWNC00260675 Applicant: Littelfuse, S.A. de C.V. Date : Jun 18, 2012 Blvd. Fausto Z. Martinez #1800 Col. Magisterio Seccion 38 C.P. 26070 Piedra Negras, Coahuila, Mexico Sample Description: One (1) group of submitted samples said to be : Part Description : VERT. HOLDER CL Part Number : 883-057 Date Sample Received : Jun 04, 2012 Date Test Started : Jun 05, 2012 : As requested by the applicant, for details please refer to attached pages. Authorized By: On Behalf Of Intertek Testing Services Taiwan Limited K. Y. Liang Director This report shall not be reproduced except in full, without the written approval of the laboratory. Page 1 of 5
Number : TWNC00260675 (Ⅰ) Test Result Summary : Test Item Result (ppm) (1) (2) Heavy Metal Cadmium (Cd) content Lead (Pb) content 236 Mercury (Hg) content Chromium VI (Cr 6+ ) content (mg/kg with 50cm 2 ) Negative (< 0.02) Negative (< 0.02) Remarks: ppm = Parts per million based on weight of tested sample = mg/kg = Not detected < = Less than mg/kg with 50cm 2 = milligram per kilogram with 50 square centimetre Negative = A negative test result indicated positive observation was not found at the time of Test. Tested Components (1) Coppery Metal Base Material (2) Silvery Plating Layer Responsibility of Chemist : Irene Chiou / Kevin Liu / Cathy Chen Date Sample Received : Jun 04, 2012 Test Period : Jun 05, 2012 To Jun 18, 2012 (Ⅱ) RoHS Requirement: Restricted Substances Cadmium (Cd) Content Lead (Pb) Content Mercury (Hg) Content Chromium VI (Cr 6+ ) Content Limits 0.01% (100ppm) 0.1% (1000ppm) 0.1% (1000ppm) 0.1% (1000ppm) The above limits were quoted from 2002/95/EC and amendment 2005/618/EC for homogeneous material. Page 2 of 5
Number : TWNC00260675 (Ⅲ) Test Method: Test Item Test Method Reporting Limit 1.0:2008 in clause 8/9/10, by Cadmium (Cd) microwave digestion until the tested content samples are totally dissolved and 2 ppm determined by ICP-OES. 1.0:2008 in clause 8/9/10, by Lead (Pb) content microwave digestion until the tested 2 ppm samples are totally dissolved and Mercury (Hg) content Chromium VI (Cr 6+ ) content determined by ICP-OES. 1.0:2008 in clause 7, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES. 1.0:2008 in annex B, by boiling water extraction and determined by UV-Vis Spectrophotometer. Remark: Reporting limit = Quantitation limit of analyte in sample 2 ppm 0.02 mg/kg with 50cm 2 Page 3 of 5
(Ⅳ) Measurement Flowchart: Test for Cd/Pb/Hg/Chromium (VI) Reference Standard:IEC 62321 edition 1.0:2008 Sample preparation Number : TWNC00260675 Take sample and immerse into Aqua Regia, start to strip plating layer Stop the stripping procedure upon color change completely Take the Aqua solution as plating component and stripped body as substrate component Cd/Pb/Hg Metal Cr 6+ Polymers / electronics For different material, digest the sample with appropriate acid *1 Confirm the tested samples are totally dissolved By spot test Get 50cm 2 sample Negative *2 Weigh sample and add alkaline solution Definite temp. extraction Make up with deionized water By boiling water extraction Cool and filter the extract Analyzed by ICP-OES Make up with deionized water and add diphenyl-carbazide solution Analyzed by UV-VIS Remarks: *1: List of Appropriate Acid: Material Acid Added for Digestion Polymers HNO 3, HCl,HF,H 2 O 2, H 3 BO 3 Metals HNO 3, HCl,HF Electronics HNO 3, HCl,H 2 O 2, HBF 4 *2: If the result of spot test is positive, Chromium VI would be determined as detected. End of Report Page 4 of 5
Number : TWNC00260675 Photo Page 5 of 5
Test Report Number : TWNC00260676 Applicant: Littelfuse, S.A. de C.V. Date : Jun 12, 2012 Blvd. Fausto Z. Martinez #1800 Col. Magisterio Seccion 38 C.P. 26070 Piedra Negras, Coahuila, Mexico Sample Description: One (1) group of submitted samples said to be : Part Description : HORIZ BODY HALF Part Number : 153007-4 Date Sample Received : Jun 04, 2012 Date Test Started : Jun 06, 2012 : As requested by the applicant, for details please refer to attached pages. Authorized By: On Behalf Of Intertek Testing Services Taiwan Limited K. Y. Liang Director This report shall not be reproduced except in full, without the written approval of the laboratory. Page 1 of 9
Z Number : TWNC00260676 (Ⅰ) Test Result Summary : Test Item Result (ppm) Black Plastic Heavy Metal Cadmium (Cd) content Lead (Pb) content Mercury (Hg) content Chromium VI (Cr 6+ ) content Polybrominated Biphenyls (PBBs) Monobrominated Biphenyls (MonoBB) Dibrominated Biphenyls (DiBB) Tribrominated Biphenyls (TriBB) Tetrabrominated Biphenyls (TetraBB) Pentabrominated Biphenyls (PentaBB) Hexabrominated Biphenyls (HexaBB) Heptabrominated Biphenyls (HeptaBB) Octabrominated Biphenyls (OctaBB) Nonabrominated Biphenyls (NonaBB) Decabrominated Biphenyl (DecaBB) Polybrominated Diphenyl Ethers (PBDEs) Monobrominated Diphenyl Ethers (MonoBDE) Dibrominated Diphenyl Ethers (DiBDE) Tribrominated Diphenyl Ethers (TriBDE) Tetrabrominated Diphenyl Ethers (TetraBDE) Pentabrominated Diphenyl Ethers (PentaBDE) Hexabrominated Diphenyl Ethers (HexaBDE) Heptabrominated Diphenyl Ethers (HeptaBDE) Octabrominated Diphenyl Ethers (OctaBDE) Nonabrominated Diphenyl Ethers (NonaBDE) Decabrominated Diphenyl Ether (DecaBDE) Halogen Content Fluorine (F) 946 Chlorine (Cl) 96 Bromine (Br) 21737 Iodine (I) Page 2 of 9
Z Number : TWNC00260676 (Ⅰ) Test Result Summary : Test Item Phthalates Di(2-ethylhexyl) Phthalate (DEHP) Dibutyl Phthalate (DBP) Benzyl Butyl Phthalate (BBP) Others Hexabromocyclododecane (HBCDD) Result (ppm) Black Plastic Remarks: ppm = Parts per million based on weight of tested sample = mg/kg = Not detected Responsibility of Chemist : Irene Chiou / Kevin Liu / Cathy Chen Date Sample Received : Jun 04, 2012 Test Period : Jun 06, 2012 To Jun 11, 2012 (Ⅱ) RoHS Requirement: Restricted Substances Cadmium (Cd) Content Lead (Pb) Content Mercury (Hg) Content Chromium VI (Cr 6+ ) Content Polybrominated Biphenyls (PBBs) Polybrominated Diphenyl Ehters (PBDEs) Limits 0.01% (100ppm) 0.1% (1000ppm) 0.1% (1000ppm) 0.1% (1000ppm) 0.1% (1000ppm) 0.1% (1000ppm) The above limits were quoted from 2002/95/EC and amendment 2005/618/EC for homogeneous material. Page 3 of 9
Number : TWNC00260676 (Ⅲ) Test Method: Test Item Test Method Reporting Limit Cadmium (Cd) content 1.0:2008 in clause 8/9/10, by microwave digestion until the tested samples are totally 2 ppm dissolved and determined by ICP- OES. Lead (Pb) content 1.0:2008 in clause 8/9/10, by microwave digestion until the tested samples are totally 2 ppm dissolved and determined by ICP- OES. Mercury (Hg) content 1.0:2008 in clause 7, by microwave digestion until the tested samples are totally dissolved and 2 ppm Chromium VI (Cr 6+ ) content Polybrominated Biphenyls (PBBs) Polybrominated Diphenyl Ethers (PBDEs) Halogen Content Phthalates Hexabromocyclododecane (HBCDD) determined by ICP-OES. 1.0:2008 in annex C, by alkaline digestion and determined by UV-Vis spectrophotometer. 1.0:2008 in annex A, by solvent extraction and determined by GC-MS and further HPLC-DAD confirmation when necessary. 1.0:2008 in annex A, by solvent extraction and determined by GC-MS and further HPLC-DAD confirmation when necessary. With reference to EN 14582:2007 by calorimetric bomb with oxygen and determined by Ion Chromatograph. With reference to EN 14372: 2004, by solvent extraction and determined by GC-MS. With reference to USEPA 3540C, by solvent extraction and determined by GC-MSD. Remark: Reporting limit = Quantitation limit of analyte in sample 1 ppm 5 ppm 5 ppm 50 ppm 50 ppm 10 ppm Page 4 of 9
Number : TWNC00260676 (Ⅳ) Measurement Flowchart: Test for Cd/Pb/Hg/Chromium (VI)/PBBS/PBDES Contents Reference Standard: IEC 62321 edition 1.0:2008 For metal part Sample preparation For non-metal part Take sample and immerse into Aqua Regia, start to strip plating layer Stop the stripping procedure upon color change completely Take the Aqua solution as plating component and stripped body as substrate component Cd/Pb/Hg Metal Cr 6+ Polymers / electronics PBBs/PBDEs For different material, digest the sample with appropriate acid *1 Confirm the tested samples are totally dissolved By spot test Get 50cm 2 sample Negative *2 Weigh sample and add alkaline solution Definite temp. extraction Weigh sample and add organic solvent By Soxhlet extraction or Solvent extraction Make up with deionized water By boiling water extraction Cool and filter the extract Concentrate the extract and make up with organic solvent Analyzed by ICP-OES Analyzed by GC-MSD Make up with deionized water and add diphenylcarbazide solution Analyzed by UV-VIS Remarks: *1: List of Appropriate Acid: Material Acid Added for Digestion Polymers HNO 3, HCl,HF,H 2 O 2, H 3 BO 3 Metals HNO 3, HCl,HF Electronics HNO 3, HCl,H 2 O 2, HBF 4 *2: If the result of spot test is positive, Chromium VI would be determined as detected. Page 5 of 9
Number : TWNC00260676 (Ⅳ) Measurement Flowchart: Test for Halogen Content Reference Standard:EN 14582 Sampling/grinding or cutting Add absorbent in a combustion flask & place weighed sample in equipment Fill oxygen into calorimetric bomb Ignite then leave the bomb at room temperature Transfer the absorbent into a volumetric flask Make up with deionized water Analyzed by ion chromatography Page 6 of 9
Number : TWNC00260676 (Ⅳ) Measurement Flowchart: Test For Phthalates Contents Reference Method: EN 14372: 2004 Sampling/grinding or cutting Weigh sample and add organic solvent By solvent extraction Concentrate the extract and make up with organic solvent Analyzed by GC-MSD Page 7 of 9
Number : TWNC00260676 (Ⅳ) Measurement Flowchart: Test For Hexabromocyclododecane (HBCDD) Reference Standard:USEPA 3540C Sampling/grinding or cutting Weigh sample and add organic solvent By soxhlet extraction Concentrate the extract and make up with organic solvent Analyzed by GC-MSD End of Report Page 8 of 9
Number : TWNC00260676 Photo Page 9 of 9