SECARB Phase III ANTHROPOGENIC TEST: Risk Management through Detailed Geologic Characterization and Modeling

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SECARB Phase III ANTHROPOGENIC TEST: Risk Management through Detailed Geologic Characterization and Modeling Prepared by: David Riestenberg, George Koperna, and Vello Kuuskraa, Advanced Resources International, Inc., Arlington, VA SECARB Stakeholders Briefing March 9-10, 2011 Atlanta, GA 1

Acknowledgement This presentation is based upon work supported by the Department of Energy National Energy Technology Laboratory under DE-FC26-05NT42590 and was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof. 2

How Do We Address Storage Risks (prior to drilling a well)? 1. Storage permanence Select a site with 4-way geologic closure (i.e. structural trap) Multiple confining units and secondary storage compartments 2. Adequate reservoir injectivity and storage capacity Conduct detailed reservoir characterization using existing log and core data Reservoir simulation 3. Existing wellbore leakage risk Survey of existing deep penetrations in the project area Working relationship with existing well operator(s) 4. New wellbore leakage risk Construct project wells to underground injection control (UIC) Class I nonhazardous standards 3

Structural Contour Map of the Top of the Rodessa Formation 1. Storage Permanence A Plant Barry A Regional data and studies show that the Citronelle Dome is: A subtle open fold Limbs dipping less than 1 degree Four-way structural closure Sources: Pashin et al., 2008; Cottingham, 1988; Esposito and others, 2008 Anthro Test Site Cross Section from Plant Barry to Citronelle Dome Test Site Modified from: Pashin et al., 2008 Source: Esposito et al., 2008 4

1. Storage Permanence (Cont.) Southeast Alabama Saline Reservoirs and Seals The Anthropogenic Test s CO 2 Storage Site Target reservoir is the Lower Cretaceous Paluxy Fm (at 9,400 ). 1,100 foot interval of stacked sandstones and shales. Numerous reservoir seals and confining units (at least 5). No evidence of faulting or fracturing, based on reinterpretation of existing 2D seismic lines. Confining Zone Injection Zone 5

Log Depth (ft) 9400 Citronelle SE Unit # D-9-7 Top of Paluxy ( 2. Injectivity and Capacity 9500 9600 ( Upper Paluxy ( Sand Layer 9620 Establishing Reservoir Properties for Paluxy Saline Formation 9700 9800 9900 10000 10100 ( ( ( Middle Paluxy ( ( Sand Layer 10060 Sand continuity mapping to determine open or closed sand intervals. Detailed analysis of over 80 well logs for porosity and depositional style. Regional core data for porosity and permeability. 10200 10300 10400 (- (- Lower (- Paluxy 340 net feet of sand at injector Average porosity of 19% Average permeability of 90 md 10500 Top of (- Mooringsport 6

2. Injectivity and Capacity (Cont.) Reservoir Simulation Modeling the CO 2 Plume Understanding CO 2 Flow and Optimizing Storage Capacity X-Sectional View of CO 2 Plume CO2 Injection Well CO2 Saturation (v/v) 3D View of CO 2 Plume CO2 Injection Well j The information from detailed reservoir characterization was used to model and optimize the CO 2 plume: Areal extent of CO 2 will be limited (~1,000 ft) by injection into multiple sand layers. Low dip results in a near-circular plume and little post CO 2 injection up-dip migration. 7

3. Existing Wellbore Leakage Risk Catalog of data for wells within estimated plume area (Area of Review) Oil field operator maintains active MIT program for the field Ran cement bond logs on selected wells in the injection area (highlighted with red circles) Adequate cement bonds observed across injection interval and confining unit in all wells Average top of cement depth is at a depth of 6,800 ft (>2,000 ft above top of confining unit). Proposed new injection well location Area of Review 8

4. New wellbore leakage risk: Design for new Project Wells Completion Well Diagram Using accepted UIC well construction standards (Class I nonhazardous) to construct all wells Surface casing run to below base of USDW and cemented to surface Long string casing to TD Cemented into surface casing Injection through tubing and packer Monitoring well-head and down-hole pressure throughout injection period COMPLETION DETAIL 1. 16 Conductor Pipe set at 60. 2. 10-3/4 Surface Casing @ 2,500, set in 13 1/2 hole; 45.5 lb/ft J-55 STC; Cemented to surface. 3. 7 Protection Casing @ 11,800, set in 9-7/8 hole; 26.0 lb/ft L-80 LTC; Cemented to surface (2 stage). 4. 2-7/8 Injection Tubing @ 9,300 ; 6.5 lb/ft L-80 EUE 8rd. 5. Annular Fluid: 8.4 lb/gal inhibited fresh water. 6. Injection Packer @ 9,300 ; 7 x 2 7/8 Ni-plated full-bore lockset packer 7. Perforations: 9,400 to 10,500. 8. Cast Iron Bridge Plug and Cement Cap at Ferry Lake 9. Total Depth @ 11,800. 1 2 3 4 5 6 7 8 9 9

How Does Drilling a Characterization Well Further Address These Risks? 1. Storage Permanence confirm properties of the confining units with core and log data 2. Adequate reservoir injectivity and storage capacity confirm properties of the confining units with core, log and fluid data 3. Existing wellbore leakage update reservoir simulation using new characterization data to reassess the project AoR 4. New wellbore leakage risk Well construction requirements 10

Anthropogenic Test Characterization Well (D-9-8 8 #2) At the end of December 2010, we began drilling the Anthropogenic Test characterization well Well drilled to 11,800 TD (spud to TD) in 30 days and under budget. Well was cased and cemented in January 2011. Whole and sidewall cores, geophysical well logs Well will be used as an observation/monitoring well 11

Above-Zone Monitoring Confining Zone Top Paluxy Data Collection at D-9-8#2D Recovered extensive Paluxy Formation whole core (98 feet in two intervals) 62 Whole core plugs tested Recovered a total of 45 percussion sidewall cores from: Overlying confining units, Overlying saline reservoirs Paluxy Formation Ran full set of well logs (quad combo, array gamma, MRI, mineralogy, dipole sonic, etc.). Base Paluxy 12

D-9-8#2 Sidewall Core Data Sidewall cores can be used to acquire reasonable porosity values for sandstone intervals and confirm lithology for shales. Unreliable for permeability. Above-Zone Monitoring Sand Properties Sample Depth (ft) Porosity (%) Lithology Above-Zone Monitoring 9,120 9,160 23.5 21.0 SS, fine-grained SS, fine-grained 9,170 21.8 SS, fine-grained 9,180 23.4 SS, fine-grained Confining Zone Lithology Confining Zone Top Paluxy 9,318 ft Siltstone-Shale 9,210 ft Shale 13

Top of Paluxy 9,40 ft Core #1 Paluxy Whole Core 10,440 ft Core #2 9,450 ft Cored Top and Basal Paluxy Sands: Fluvial System: sand and shale sequence in both upper and lower core Fining upward units suggest channel fill Sandy intervals are typically between ~ 2-10 ft Sharp base of medium- coarse grained sand grading upward to finer sand and then shale. Prior to this project no core of the Paluxy Formation had been collected regionally Top of Mooringsport 10,450 ft 14

9,390 ft Paluxy Core #1 9350 9400 9450 9500 9,420 ft 9,400 ft Notable Features: Heavily burrowed Rip-up clay pebbles Root zones Trough cross beds Multiple soil horizons Upper sands in Core # 1 were oxidized (red color) Lower sands are not oxidized 9550 9,430 ft 15

Porosity and Permeability Ranges, Core #1 9350 Porosity Range: 6-18% Permeability Range: 1 50 md Porosity Average: 13 % Permeability Average: 8 md 9400 9450 Porosity Range: 6-23% Permeability Range: 1 3,800 md Porosity Average: 18% Permeability Average: 440 md 9500 9550 Porosity Range: 8-22% Permeability Range: 1 1,900 md Porosity Average: 18% Permeability Average: 500 md 16

Confirming Storage Capacity (Thickness) SP Induction Upper Paluxy Sands Calculated sand thickness using new log data. New results suggest Paluxy reservoir thickness of: 278.5 ft of 50% clean sand Sand thickness estimates made using old logs (310 ft) appear to be acceptable However there were notable individual exceptions Note: thickness values are in feet 17

Confirming Storage Capacity (Thickness) Previous slide showed comparison of vintage and new logs for the Upper Paluxy The basal Paluxy sandstone (one of our whole core targets) appears to be of lower quality (thickness and vertical continuity) than the old log would indicate D-9-8#1 Vintage Spontaneous Potential D-9-8#2 Well Log 10,400 ft 60+ feet 10,500 ft 20 to 40 feet? 18

Confirming Storage Capacity (Porosity) 9380 Porosity (%) 0 5 10 15 20 25 3 0 9,300 Porosity (%) 0 10 20 30 9390 Log Depth (ft) 9400 9410 9420 9,400 9,500 Whole Core #1 9430 9440 9450 Porosity Curve Whole Core Data Log Depth (ft) 9,600 9,700 Porosity log data and core data were used to develop a Paluxy sandstone porosity curve Averaged porosity of the Paluxy Formation sandstones using this approach is 18.9 % This estimate compares quite well with the prior sandstone estimate of 19% 9,800 9,900 10,000 Porosity Curve Whole Core Data 19

Confirming Reservoir Injectivity (Permeability) Core tests demonstrated exceptional reservoir permeability Core permeability, Kliq, md Core Porosity and Permeability Relationship 10,000 1,000 100 10 1 Horizontal Perm Vertical Perm y = 0.0124e 0.5289x R 2 = 0.7369 y = 0.0002e 0.715x R 2 = 0.8934 10.0 12.5 15.0 17.5 20.0 22.5 25.0 Core porosity, % Phi (%) 24 22 20 18 16 14 12 10 Hz Perm (md) 4,040 1,400 490 170 60 20 7 2 Vt Perm (md) 5,670 1,360 320 80 20 4 1 0 20

Updating the Geocellular Model 3D View of CO 2 Plume End of Injection Original Model Updated Model Model plume extent was 1,000 ft j radius in original model CO2 Saturation (v/v) New model now shows plume extent nearly 1,700 ft Due to higher permeability in upper Paluxy sandstones Necessitates updated Area of Review MVA plan appears to be adequate Next step incorporate permeability variation within each sandstone how does that affect the plume behavior? 21

Monitoring within and Beyond the Updated AoR D-4-13 and/or D-4-14 In-zone montoring Above-zone monitoring Fluid sampling Proposed Injector Injection Surveys Downhole Pressure New Characterization Well Neutron logging MBM (in-zone pressure, fluid sampling, seismic, temp) UPDATED AOR Proposed Inj/Obs Well Neutron logging Crosswell seismic (source) D-9-11 Neutron Logging 22

Conclusions (1) Site characterization using existing geologic and well data defined project risks to an acceptable level to move forward with characterization well drilling 1. Storage permanence Geologic closure, no faults or major fracture zones. Confining units and seals. 2. Adequate reservoir injectivity and storage capacity Reservoir thickness, porosity and permeability appeared to be adequate to accept CO 2 volume. Stacked sand/shale package appears to confine plume extent. 3. Existing wellbore leakage risk Condition of deep penetrations in UPDATED project area appear to be adequate to prevent CO 2 leakage. 4. New wellbore leakage risk Wells constructed to UIC Class I standards. 23

Conclusions (2) Data from the new characterization well further addresses these risks 1. Storage permanence Promising confining unit characteristics. Establish mechanical properties (work ongoing) 2. Adequate reservoir injectivity and storage capacity Reservoir thickness, porosity and permeability as good or better than preliminary estimates. More than adequate to accept CO 2 volume. Stacked sand/shale package still appears to confine plume extent. 3. Existing wellbore leakage risk Condition of deep penetrations in the updated project area appear to be adequate to prevent CO 2 leakage. 4. New wellbore leakage risk First project well drilled to UIC Class I standards. 24