MINISTRY OF EDUCATION AND HUMAN RESOURCES, TERTIARY EDUCATION AND SCIENTIFIC RESEARCH MAURITIUS EXAMINATIONS SYNDICATE. CHEMISTRY OCTOBER hour

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MINISTRY OF EDUCATION AND HUMAN RESOURCES, TERTIARY EDUCATION AND SCIENTIFIC RESEARCH MAURITIUS EXAMINATIONS SYNDICATE NATIONAL ASSESSMENT AT FORM III NAME SCHOOL NAME CLASS/SECTION CHEMISTRY OCTOBER 2016 1 hour Students answer on the Question Paper. READ THE FOLLOWING INSTRUCTIONS CAREFULLY FIRST Write your name, the name of your school and your class/section in the spaces provided above. Write in dark blue or black ink. You may use a soft pencil for any diagrams, graphs or rough working. Any rough working should be done in this booklet. Do not use correction fluid. There are 7 questions in this paper. Check that this document consists of 10 printed pages and 2 blank pages. Any discrepancy in the document must be immediately notified to the responsible officer in your school. Answer all questions. The number of marks is given in brackets [ ] for each question or part question. The total of the marks for this paper is 50.

Question 1 - Multiple Choice (6 marks) For each item, there is only one correct answer. Draw a circle around the letter which shows the correct answer. (a) An example of an element which has a valency of 2 is A calcium. B sodium. C aluminium. D potassium. (b) Which one of the following is the correct formula for potassium bromide? A PBr B KBr C KB D POBr (c) Polluted air contains toxic gases. An example of a toxic gas is A N 2 B O 2 C CO 2 D NO 2 (d) A piece of blue litmus paper turns red when it is dipped in a solution. This solution could be A B C D aqueous ammonia. lemon juice. lime water. aqueous sodium hydroxide. 2

(e) The salt barium sulphate forms a suspension in water. Which one of the following methods cannot be used to separate it from water? A B C D Filtration Evaporation Decantation Chromatography (f) How is the process during which a solid changes into a liquid called? A B C D condensation freezing melting sublimation 3 Please turn over this page

Question 2 (7 marks) Elements are substances that are made up of only one type of atoms. Elements can be metallic or non-metallic. (a) Complete Table 1 by giving one example of a metallic element and one example of a non-metallic element as well as their symbols. Element Name Symbol Metallic Non-metallic Table 1 [2] (b) All metals are solids at room temperature except, which is a liquid. [1] (c) Carbon burns in air to form carbon dioxide. (i) What is the valency of carbon in carbon dioxide? Valency: [1] Write down the balanced chemical equation for the combustion of carbon in excess air. [2] (iii) The above reaction involves a chemical change. Give another example of a reaction in everyday life that leads to a chemical change and the creation of a new product. [1] 4

Question 3 (6 marks) (a) A list of separation methods is given below. Filtration Chromatography Sublimation Distillation Using a magnet Select one suitable method by which each of the following underlined substances can be separated from the mixture. Each method can be used only once. (i) Ammonium chloride from a mixture of calcium chloride and ammonium chloride. [1] Iron filings from a mixture of sand and iron filings. [1] (iii) Pure water from sea water. [1] (b) Separation techniques are widely used in our everyday life. Which technique can be used to obtain table salt from sea water in Mauritius? [1] (c) Water is one of the most important solvents used in everyday life. (i) Give one solid that readily dissolves in water. [1] Nail polish does not dissolve in water. Name a common solvent for nail polish. [1] 5 Please turn over this page

Question 4 (9 marks) Ammonium salts can be prepared in the laboratory by a method called titration. The procedure for preparing an ammonium salt is summarised below, using the set up in Figure 1. burette clamp acid A alkali B Instructions: 1. Fill the burette with acid A. 2. Measure 25 cm 3 of alkali B and place it in the conical flask. Add 2 drops of methyl orange indicator. 3. Slowly add acid A to the alkali B until the end point is reached. Figure 1 (a) Which measuring vessel is used to measure 25 cm 3 of alkali B accurately? [1] (b) Name acid A and alkali B which can be used in the titration above to prepare ammonium nitrate solution. Acid A: [1] Alkali B: [1] (c) Write down a balanced chemical equation for the reaction between acid A and alkali B. [2] (d) What type of reaction occurs during titration? [1] (e) Explain the purpose of the indicator in the reaction and the changes you would observe during the reaction. Purpose: Observation: [2] (f) Give one important use of ammonium salts. [1] 6

Question 5 (6 marks) (a) All the gases in Table 2 below are made up of molecules. Complete the table using (i) as example. Name of gas Formula Number of each type of atom present (i) Nitrogen N 2 2 Nitrogen atoms CO 2 (iii) Sulphur trioxide Table 2 [3] (b) Sulphur dioxide is a pollutant that is released in the air by chemical plants that burn sulphur. Sulphur dioxide can also be released in the air by natural events. (i) Name a natural source of sulphur dioxide. [1] Sulphur dioxide causes acid rain. Explain how acid rain is formed. [1] (iii) Give one way in which acid rain can affect the environment. [1] 7 Please turn over this page

Question 6 (10 marks) Copper metal can be extracted from a solution of copper (II) sulphate by the reaction between aqueous copper salt and zinc metal. Diagram 1 below shows the reaction process. (i) Add excess zinc powder Stir well solution W mixture of solids aqueous copper (II) sulphate filter solution W residue X filtrate add dilute sulphuric acid bubbles of gas solution Y solid Z filter solid Z solution Y Diagram 1 (a) Study the reaction process and answer the following questions: (i) Write a word equation for the reaction between zinc metal and copper (II) sulphate solution. [1] Write the balanced chemical equation for the reaction above. [2] 8

(b) (i) Name the type of reaction that occurs when zinc metal is added to copper (II) sulphate. Type of reaction: [1] Give another metal that can be used instead of zinc that will lead to a similar reaction. Another metal: [1] (c) (i) Give the name of the gas that is liberated when dilute sulphuric acid is added to Residue X. Gas: [1] How would you test for this gas in the laboratory? [1] (d) Give the name of (i) solid Z and its colour; solid Z: colour: solution Y: [3] 9 Please turn over this page

Question 7 (6 marks) The Earth s atmosphere is made up of a mixture of different gases. The pie chart in Figure 2 shows the percentage of different gases present in air. B: 20% 0.03% 0.97% A: 79% (a) Identify gases A and B. Figure 2: Composition of air A: B: [2] (b) The percentage of carbon dioxide in the atmosphere has increased in the last century and is a concern for the environment as it increases the greenhouse effect. (i) Give one possible explanation for the increase of carbon dioxide in the atmosphere. [1] Another term for the greenhouse effect is. [1] (iii) State how the above phenomenon affects our planet in general. [1] (iv) Give one consequence of the greenhouse effect on Mauritius. [1] 10

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