ZION OIL & GAS, INC. (NASDAQ SYMBOL: ZN) DEDICATED TO EXPLORING FOR OIL & GAS, ONSHORE ISRAEL

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ZION OIL & GAS, INC. (NASDAQ SYMBOL: ZN) Fall 2014 DEDICATED TO EXPLORING FOR OIL & GAS, ONSHORE ISRAEL Israel is known as the land flowing with milk and honey but not necessarily flowing with oil and gas. In fact, Israel s former Prime Minister Golda Meir is said to have complained that Moses could have picked somewhere other than the one spot in the Middle East that has no oil as a Jewish homeland. Indeed, there has been a seismic shift in thinking in the last few years. In 2009 and 2010, world-class natural gas discoveries were announced, approximately 50-80 miles west of Haifa, offshore Israel. Noble Energy s Tamar and Leviathan discoveries have since been followed up by additional large natural gas finds. Immediately after the announcement, Israel s Minister of Infrastructure said, We are witnessing a historic moment in Israel s energy market... we are talking about the biggest find in Israel s history. The Leviathan discovery is the largest discovery in Noble Energy s history. To date, total discovered gross mean resources in the Levant Basin (offshore) are now estimated to be approximately 40 trillion cubic feet of natural gas. Noble Energy recently stated that significant exploration potential remains on the Company s acreage position in the Eastern Mediterranean, with approximately 3 billion barrels of gross unrisked oil potential in the deep Mesozoic play in both Cyprus and Israel In April 2010, the United States Geological Survey (USGS) issued a report on the Levant Basin and indicated that there are still massive undiscovered amounts of oil and gas in the Levant Basin. Zion s petroleum exploration areas fall completely within the Levant Basin. Following, you will find a copy of the USGS report. The USGS estimates a mean of 1.7 billion barrels of recoverable oil and 122 trillion cubic feet of recoverable gas in the Levant Basin.

Three of the seven references cited in the USGS report were co-authored by Zion Oil & Gas Board member (and co-chairman of Zion s Technical Advisory Group) Dr. Yehezkel Druckman. Dr. Druckman is also a former Petroleum Commissioner of Israel. We are very excited about and 100% focused on our new Megiddo-Jezreel License. In December 2013, Israel s Petroleum Commissioner officially granted us the exclusive right to explore in an area of approximately 99,000 acres between the ancient city of Megiddo and the Jordan River. This new license has a primary term through December 2016 but we hope to drill our next deep well, the Megiddo - Jezreel #1, in 2015. Zion Oil and Gas, Inc. was founded in 2000 and is publicly traded on the NASDAQ Global Market (Stock Symbol: ZN). Since our founding, we have worked diligently to assemble an experienced and professional team using petroleum industry bestpractice techniques in order to discover oil and gas onshore Israel. We are optimistic that the day draws near when we will achieve exploration success and our many years of hard work will bear fruit for our stockholders and for Israel. For further information please visit our website: www.zionoil.com Your support is vital to Zion s work in Israel. In your good pleasure, make Zion prosper... Psalm 51:18 FORWARD LOOKING STATEMENTS: Statements in this communication that are not historical fact, including statements regarding Zion s planned operations, plans to achieve certain milestones, the existence of commercially productive oil and natural gas reserves, and plans for future drilling, are forward-looking statements as defined in the Safe Harbor provisions of the Private Securities Litigation Reform Act of 1995. These forward-looking statements are based on assumptions that are subject to significant known and unknown risks, uncertainties and other unpredictable factors, many of which are described in Zion s periodic reports filed with the SEC and are beyond Zion s control. These risks could cause Zion s actual performance to differ materially from the results predicted by these forwardlooking statements. Zion can give no assurance that the expectations reflected in these statements will prove to be correct and assumes no responsibility to update these statements.

World Petroleum Resources Project Assessment of Undiscovered Oil and Gas Resources of the Levant Basin Province, Eastern Mediterranean Introduction As part of a program aimed at estimating the recoverable oil and gas resources of priority basins around the world, the U.S. Geological Survey (USGS) estimated the undiscovered oil and gas resources of the Levant Basin Province. The Levant Basin Province encompasses approximately 83,000 square kilometers (km 2 ) of the eastern Mediterranean area (fig. 1). The area is bounded to the east by the Levant Transform Zone, to the north by the Tartus Fault (Roberts and Peace, 2007), to the northwest by the Eratosthenes Seamount, to the west and southwest by the Nile Delta Cone Province boundary, and to the south by the limit of compressional structures in the Sinai. This assessment was based on published geologic information and on commercial data from oil and gas wells, fields, and field production. The USGS approach is to define petroleum systems and geologic assessment units and to assess the potential for undiscovered oil and gas resources in each of the three assessment units defined for this study Plio-Pleistocene, Levant Sub-Salt, and Levant Margin. 36 N 35 N 34 N 33 N 32 N 31 N 30 N 29 N 30 E TURKEY ITALY LIBYA 31 E Mediterranean Sea GREECE Mediterranean Sea EXPLANATION Gas fields Oil fields EGYPT 0 50 100 KILOMETERS TURKEY 0 50 100 MILES Red Sea 32 E SAUDI ARABIA EGYPT Red Sea Figure 1. Location of the three assessment units (AU) in the Levant Basin Province in the Eastern Mediterranean. The boundaries of the Levant Sub-Salt AU and the Plio-Pleistocene AU are coincident. 33 E CYPRUS Eratosthenes Seamount Nile Delta Cone 34 E 35 E Levant Sub-Salt Assessment Unit Plio-Pleistocene Assessment Unit A Tartus Fault ISRAEL A Levant Transform 36 E LEBANON Zone JORDAN SYRIA Levant Margin Assessment Unit Limit of compressional structures U.S. Department of the Interior U.S. Geological Survey Printed on recycled paper Fact Sheet 2010 3014 March 2010

Composite Petroleum System and Assessment Units Resource Summary A A Levant Basin Levant Margin NW SE Sea level Plio-Pleistocene Assessment Unit 2 F M Horizon Two-Way Time (seconds) 4 6 E D C B Levant Sub-Salt AU N Horizon Levant Margin Assessment Unit Jordan rift valley Levant Transform zone 8 A Basement 10 0 50 KILOMETERS 0 100 MILES Figure 2. Geologic cross section of the southern part of the Levant Basin Province illustrating the definition of the three assessment units (AU) in this study. The areas of the Levant Sub-Salt AU and the Plio-Pleistocene AU are coincident, and neither AU overlaps with the Levant Margin AU. Dashed line separates Cenozoic (above) from pre-cenozoic rocks. Messinian-age salt (between the M and N seismic horizons) is shown in green. Location of schematic section (A-A ) shown in figure 1. A, Permian to Aalenian age; B, Bajocian to Turonian age; C, Senonian to Early Oligocene age; D, Oligocene to Late Miocene Age; E, Late Miocene (Messinian) age; F, Plio-Pleistocene age rocks. Modified from Gardosh and Druckman (2006) and Cartwright and Jackson (2008).

Eocene nearshore marine sandstones and limestones, Wadi Degla, northern Egypt. Table 1. Levant Basin Province assessment results. Total Petroleum Systems (TPS) and Assessment Units (AU) Largest Total undiscovered resources Field type expected mean Oil (MMBO) Gas (BCFG) NGL (MMBNGL) field size F95 F50 F5 Mean F95 F50 F5 Mean F95 F50 F5 Mean Levant Basin Province, Mesozoic-Cenozoic Composite TPS

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