CO 2 Atlas Assessment of Geological Storage Potential

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CO 2 Atlas Assessment of Geological Storage Potential by M. Cloete 08/04/2010, Gaberone

Introduction The aim of a CO2 storage atlas is to identify the availability of geological sites that are both safe and practical for the storage of CO2 with a view of one day mitigating industrial greenhouse gas emissions Atlas are usually done on a country-wide or on a regional scale and include evaluation of all possible resources, e.g. deep saline formations, oil and gas reservoirs and unmineable coal seams. The deliverable should be a document illustrating the CO2 geological storage potential of the country or a region to inform decision makers and a broad as possible public audience of the nations storage potential. Make recommendations on the way forward regarding further exploration for CO 2 storage space, research and development of knowledge gaps. Theoretical global capacity (GtCO2) : DSF = 9500 (91%); DGR = 700 ( 6%); DOR = 120(1%); UMCS = 140 (1%)

Presentation Layout Project work plan Data availability Criteria for assessing storage suitability of sedimentary basins Screening Ranking Standards & data certainty of estimated CO 2 storage capacities

S.A. CO 2 GEOLOGICAL STORAGE ATLAS WORKPLAN (PHASE 1) Breakdown of Phase 1 into sub-phases Completion (weeks) 1.1 Document the stratigraphic, deep borehole and seismic data of all on- & offshore basins and rank them according to geological criteria 13 1.2 Document requisite information on physical and hydraulic properties of storage rocks, test methods and storage calculation formulae 21 1.3 Locate drill core of select stratigraphic boreholes, conduct fill-in petrographic and geotechnical tests 31 1.4 Delineate formations with best CO2 storage prospectivity and estimate storage capacities 41 1.5 Compile atlas brochure depicting the CO2 geological storage potential of basins in South Africa 56 1.6 Compile final technical report on Phase 1 with proposal whether to continue with Phase 2. 65 1.7 Editorial handling and printing of atlas & technical report 77

Data availability: extent of offshore seismic data and exploration wells (Petroleum Agency SA, 2007).

Criteria and classes for assessing the CO 2 storage suitability of sedimentary basins (modified after Bachu 2003, Gibson-Poole et al., 2006) Item Criterion 1 Tectonic setting Classes 1 2 3 4 5 Very Unstable eg Intermediate unstable eg synrift, eg foreland setting subduction intramontane arc margin 2 Basin size Very small <1,000 km 2 Small, 1,000 5,000 km 2 Medium 5,000-1,000 3 Basin depth Very shallow (< 300 m) 4 Reservoir-seal pairs Shallow (300 800 m) Mostly stable passive Stable, eg cratonic Large 5000 Very large 25,000 km 2 >50,000 km 2 Deep (>3,500 m) Intermediate 800 3500m Poor Intermediate Excellent 5 Fault intensity Extensive Moderate Limited

Comparative ranking of each basin for storage suitability based only on geological (i.e. no economic criteria - 9, 12, 14 and 15). Basin/area Geological Suitability Rank Outeniqua Basin 0,78 1 Northern Karoo 0,76 2 Orange Basin 0,75 3 Durban/Zululand Basin 0,73 4 Tshipse Basin 0,71 5 Katberg/Molteno-Indwe 0,69 6 Ellisras (Lephalale) 0,67 7 Springbok Flats Basin 0,67 8 Onshore Zululand Basin 0,67 9 Onshore Algoa Basin 0,65 10 Durban-Lebombo 0,62 11 Southern Karoo 0,60 12 Tuli Basin 0,56 13

Storage suitability of basins based on geological criteria, excluding the presence of coal and coal rank. Basin/area Suitability: Geol coal Rank Outeniqua Basin 0,91 1 Durban/Zululand Basin 0,84 2 Orange Basin 0,84 3 Onshore Zululand Basin 0,78 4 Onshore Algoa Basin 0,76 5 Northern Karoo 0,71 6 Katberg/Molteno-Indwe 0,71 7 Southern Karoo 0,69 8 Tshipse Basin 0,64 9 Durban-Lebombo 0,64 10 Springbok Flats Basin 0,60 11 Ellisras (Lephalale) 0,60 12 Tuli Basin 0,56 13

CO 2 Storage Capacity Estimation Formulae Deep saline aquifers: M CO2 = A h g φ tot ρ E (1) Coal beds M CO2 = A h g C ρ E (2) Oil and gas reservoirs M CO2 = A h n φ e (1-S w ) B ρ E (3) Symbols: M CO2 A h g φ tot ρ E C h n φ e S w B = Mass estimate of CO 2 storability = Geographical area of formation = Gross thickness of formation = Average porosity of formation = CO 2 density at storage pressure and temperature = Storage efficiency factor = Concentration of CO 2 standard volume per unit of coal volume = Net thickness of formation = Effective porosity of formation = Average water saturation within the storage volume = Formation volume factor (converts standard oil or gas volume to sub-surface volume)

Certainty of CO2 storage capacity Techno-Economic Resource-Reserve pyramid for CO2 storage capacity in geological media (CSLF, 2008). The pyramid shows the relationship between Theoretical, Effective, Practical and Matched capacities.

Subsurface Heterogene eity Complex subsurface, numerous structures at spacings of < 3 km, highly discontinuous formation properties at < 3 km spacing, typical of tectonically deformed areas Moderate heterogeneous subsurface, structure and anisotropy present but repetitive at 3 16 km spacing; possible to interpolate rock properties for up to 16 km Structural complications are infrequent and range of rock properties can be projected over areas > 16 km Confidence indicator 5 3 1 7 5 3 9 7 5 Borehole density avg. > 1 borehole/ 3 km 2 ; seismic survey spacing avg. > 1 line per 16 linear km Borehole density avg. > 1 borehole/ 23 km 2 ; seismic survey spacing avg. > 1 line per 80 linear km Borehole density avg. > 1 borehole/ 260 km 2 ; seismic survey spacing avg. > 1 line per 160 linear km Data Density

Conclusions Geological screening and ranking of the sedimentary basins provide an objective means for assessing which basins have the best storage potential. Data availability is very important as it allows for better storage estimates to be made, i.e. greater certainty of estimates and greater confidence. Atlases need to produce a storage potential estimate for the country or region which has been assessed Atlases need to make recommendations on knowledge gaps and provide a list of research projects that will address the most serious deficiencies Atlases need to advise decision makers on whether to proceed or not with the exploration for CO 2 storage space.

Thank you

Definitions for unmineable coal CSLF consider coal to be suitable for CO2 storage (i.e. unmineable) when at average geothermal gradients it occurs at a depth of no deeper than 800 m and upwards to where groundwater is protected by regulation (p19, Phase II Report). In the USA coal is not considered for CO2 storage if shallower 152 m. However, at intermediate depths (152-305m), only coal beds less than 1.1. m and greater than 0.52 m were considered as potential targets for CO2 storage.