APPENDIX A Monitoring Site Location Diagrams Appendix A contains 4 pages including cover Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A1 of A55
Mt Eden Site 4:65 Figure 1 Mt Eden, Auckland Site 4:65 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A2 of A55
Penrose Site 4:23 Penrose (ACI) Site 4:19 Figure 2 Penrose, Auckland Site 4:19 Site 4:23 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A3 of A55
St Albans Site 16:67 Figure 3 St Albans, Christchurch Site 16:67 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A4 of A55
APPENDIX B Graphed Results for SO 2 Appendix B contains 5 pages including cover Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A5 of A55
Penrose: 21 Sulphur dioxide (1 hour fixed averages) 35 3 Concentration (µg/m 3 ) 25 2 15 1 AAQG = 35µg/m 3 5 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A6 of A55
35 St Albans: 21 Sulphur dioxide (1 hour fixed averages) 3 Concentration (µg/m 3 ) 25 2 15 1 AAQG = 35µg/m 3 5 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A7 of A55
Penrose (ACI): 21 Sulphur dioxide (24 hour fixed averages) 12 1 Proposed AAQG = 12µg/m 3 Concentration (µg/m 3 ) 8 6 4 2 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A8 of A55
St Albans: 21 Sulphur dioxide (24 hour fixed averages) 12 1 Concentration (µg/m 3 ) 8 6 4 Proposed AAQG = 12µg/m 3 2 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A9 of A55
APPENDIX C Graphed Results for CO Appendix C contains 11 pages including cover Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A1 of A55
St Albans: 21 Carbon monoxide (1 hour fixed averages) 5 45 4 Concentration (mg/m 3 ) 35 3 25 2 15 1 Proposed AAQG = 3 mg/m 3 5 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A11 of A55
5 St Albans: Carbon monoxide (1 hour averages) (2) 4 Concentration (mg/m 3 ) 3 2 Air Quality Guideline 1 Jan- Feb- Mar- Apr- May- Jun- Jul- Aug- Sep- Oct- Nov- Dec- Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A12 of A55
5 St Albans: Carbon monoxide (1 hour averages) (1999) 4 Concentration (mg/m 3 ) 3 2 Air Quality Guideline 1 Jan-99 Feb-99 Mar-99 Apr-99 May-99 Jun-99 Jul-99 Aug-99 Sep-99 Oct-99 Nov-99 Dec-99 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A13 of A55
5 St Albans: Carbon monoxide (1 hour averages) (1998) 4 Concentration (mg/m 3 ) 3 2 Air Quality Guideline 1 Jan-98 Feb-98 Mar-98 Apr-98 May-98 Jun-98 Jul-98 Aug-98 Sep-98 Oct-98 Nov-98 Dec-98 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A14 of A55
5 St Albans: Carbon monoxide (1 hour averages) (1997) 4 Concentration (mg/m 3 ) 3 2 Air Quality Guideline 1 Jan-97 Feb-97 Mar-97 Apr-97 May-97 Jun-97 Jul-97 Aug-97 Sep-97 Oct-97 Nov-97 Dec-97 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A15 of A55
St Albans: 21 Carbon Monoxide (8 hour fixed averages) 2 15 Concentration (mg/m 3 ) 1 5 Proposed AAQG = 1 mg/m 3 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A16 of A55
3 St Albans: Carbon monoxide (8 hour moving averages) (2) 25 Concentration (mg/m 3 ) 2 15 1 Air Quality Guideline 5 Jan- Feb- Mar- Apr- May- Jun- Jul- Aug- Sep- Oct- Nov- Dec- Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A17 of A55
3 St Albans: Carbon monoxide (8 hour moving averages) (1999) 25 Concentration (mg/m 3 ) 2 15 1 Air Quality Guideline 5 Jan-99 Feb-99 Mar-99 Apr-99 May-99 Jun-99 Jul-99 Aug-99 Sep-99 Oct-99 Nov-99 Dec-99 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A18 of A55
3 St Albans: Carbon monoxide (8 hour moving averages) (1998) 25 Concentration (mg/m 3 ) 2 15 1 Air Quality Guideline 5 Jan-98 Feb-98 Mar-98 Apr-98 May-98 Jun-98 Jul-98 Aug-98 Sep-98 Oct-98 Nov-98 Dec-98 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A19 of A55
3 St Albans: Carbon monoxide (8 hour moving averages) (1997) 25 Concentration (mg/m 3 ) 2 15 1 Air Quality Guideline 5 Jan-97 Feb-97 Mar-97 Apr-97 May-97 Jun-97 Jul-97 Aug-97 Sep-97 Oct-97 Nov-97 Dec-97 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A2 of A55
APPENDIX D Graphed Results for NOx Appendix D contains22 pages including cover Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A21 of A55
Mt Eden: 21 Nitrogen dioxide (1 hour averages) 8 7 6 Concentration (µg/m 3 ) 5 4 3 Proposed 1 hour AAQG = 2 (µg/m 3 ) 2 1 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A22 of A55
2 Mt Eden: Nitrogen dioxide (1 hour averages) (2) 18 16 14 12 1 8 6 4 2 Jan- Feb- Apr- May- Jul- Sep- Oct- Dec- Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A23 of A55
Mt Eden: Nitrogen dioxide (1 hour averages) (1999) 2 18 Current 1 hour guideline = 3 µg/m 3 Proposed 1 hour guideline = 2 µg/m 3 16 14 12 1 8 6 4 2 Nov-98 Dec-98 Feb-99 Mar-99 May-99 Jul-99 Aug-99 Oct-99 Dec-99 Jan- Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A24 of A55
2 Mt Eden: Nitrogen dioxide (1 hour averages) (1998) 18 Current 1 hour guideline = 3 µg/m 3 Proposed1 hour guideline = 2 µg/m 3 16 14 Concentration (µg/m 3 ) 12 1 8 6 4 2 Jan-98 Feb-98 Mar-98 Apr-98 May-98 Jun-98 Jul-98 Aug-98 Sep-98 Oct-98 Nov-98 Dec-98 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A25 of A55
2 Mt Eden: Nitrogen dioxide (1 hour averages) (1997) 18 Current 1 hour guideline = 3 µg/m 3 Proposed1 hour guideline = 2 µg/m 3 16 14 12 1 8 6 4 2 Dec-96 Jan-97 Mar-97 Apr-97 Jun-97 Aug-97 Sep-97 Nov-97 Jan-98 Feb-98 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A26 of A55
Penrose: 21 Nitrogen dioxide (1 hour fixed averages) 8 7 6 Concentration (µg/m 3 ) 5 4 3 Proposed 1 hour AAQG = 2 (µg/m 3 ) 2 1 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A27 of A55
2 Penrose: Nitrogen dioxide (1 hour averages) (2) 18 Current 1 hour Air Quality Guideline = 3 µg/m 3 Proposed 1 hour Air Quality Guideline = 2 µg/m 3 16 14 Concentration (µg/m 3 ) 12 1 8 6 4 2 Jan- Feb- Mar- Apr- May- Jun- Jul- Aug- Sep- Oct- Nov- Dec- Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A28 of A55
Penrose: Nitrogen dioxide (1 hour averages) (1999) 2 18 Current 1 hour Air Quality Guideline = 3 µg/m 3 Proposed 1 hour Air Quality Guideline = 2 µg/m 3 16 14 Concentration (µg/m 3 ) 12 1 8 6 4 2 Jan-99 Feb-99 Mar-99 Apr-99 May-99 Jun-99 Jul-99 Aug-99 Sep-99 Oct-99 Nov-99 Dec-99 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A29 of A55
2 Penrose: Nitrogen dioxide (1 hour averages) (1998) 18 Current 1 hour Air Quality Guideline = 3 µg/m 3 Proposed 1 hour Air Quality Guideline = 2 µg/m 3 16 14 Concentration (µg/m 3 ) 12 1 8 6 4 2 Jan-98 Feb-98 Mar-98 Apr-98 May-98 Jun-98 Jul-98 Aug-98 Sep-98 Oct-98 Nov-98 Dec-98 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A3 of A55
Penrose: Nitrogen dioxide (1 hour averages) (1997) 2 18 Current 1 hour Air Quality Guideline = 3 µg/m 3 Proposed 1 hour Air Quality Guideline = 2 µg/m 3 16 14 12 1 8 6 4 2 Dec-96 Jan-97 Mar-97 Apr-97 Jun-97 Aug-97 Sep-97 Nov-97 Jan-98 Feb-98 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A31 of A55
St Albans: 21 Nitrogen dioxide (1 hour fixed averages) 8 7 6 Concentration (mg/m3) 5 4 3 2 Proposed 1 hour AAQG = 2 (µg/m 3 ) 1 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A32 of A55
2 St Albans: Nitrogen dioxide (1 hour averages) (2) 18 Current1 hour Air Quality Guideline = 3 µg/m 3 Proposed 1 hour Air Quality Guideline = 2 µg/m 3 16 14 Concentration (µg/m 3 ) 12 1 8 6 4 2 Jan- Feb- Mar- Apr- May- Jun- Jul- Aug- Sep- Oct- Nov- Dec- Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A33 of A55
St Albans: Nitrogen dioxide (1 hour averages) (1999) 2 18 Current1 hour Air Quality Guideline = 3 µg/m 3 Proposed 1 hour Air Quality Guideline = 2 µg/m 3 16 14 Concentration (µg/m 3 ) 12 1 8 6 4 2 Jan-99 Feb-99 Mar-99 Apr-99 May-99 Jun-99 Jul-99 Aug-99 Sep-99 Oct-99 Nov-99 Dec-99 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A34 of A55
St Albans: Nitrogen dioxide (1 hour averages) (1998) 2 18 Current1 hour Air Quality Guideline = 3 µg/m 3 Proposed 1 hour Air Quality Guideline = 2 µg/m 3 16 14 Concentration (µg/m 3 ) 12 1 8 6 4 2 Jan-98 Feb-98 Mar-98 Apr-98 May-98 Jun-98 Jul-98 Aug-98 Sep-98 Oct-98 Nov-98 Dec-98 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A35 of A55
St Albans: Nitrogen dioxide (1 hour averages) (1997) 2 18 Current1 hour Air Quality Guideline = 3 µg/m 3 Proposed 1 hour Air Quality Guideline = 2 µg/m 3 16 14 Concentration (µg/m 3 ) 12 1 8 6 4 2 Jan-97 Feb-97 Mar-97 Apr-97 May-97 Jun-97 Jul-97 Aug-97 Sep-97 Oct-97 Nov-97 Dec-97 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A36 of A55
Mt Eden: 21 Nitrogen dioxide (24 hour fixed averages) 3 25 Concentration (µg/m 3 ) 2 15 1 Proposed AAQ guideline = 1µg/m 3 5 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A37 of A55
2 Mt Eden: Nitrogen dioxide (24 hour averages) (1996-2) 18 24 hour guideline = 1 µg/m 3 16 14 12 1 8 6 4 2 Dec-96 Jul-97 Feb-98 Aug-98 Mar-99 Sep-99 Apr- Oct- Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A38 of A55
Penrose: 21 Nitrogen dioxide (24 hour fixed averages) 3 25 Concentration (mg/m 3 ) 2 15 1 Proposed AAQ guideline = 1µg/m 3 5 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A39 of A55
Penrose: Nitrogen dioxide (24 hour averages) (1996-2) 1 24 hour Air Quality Guideline = 1 µg/m 3 8 6 4 2 1996 1997 1998 1999 2 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A4 of A55
St Albans: 21 Nitrogen dioxide (24 hour fixed averages) 3 25 Concentration (µg/m 3 ) 2 15 1 Propsoed AAQ guideline = 1µg/m 3 5 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A41 of A55
St Albans: Nitrogen dioxide (24 hour averages) (1997-2) 1 24 hour Air Quality Guideline = 1 µg/m 3 8 Concentration (µg/m 3 ) 6 4 2 1997 1998 1999 2 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A42 of A55
APPENDIX E Quarterly Results for VOC Appendix E contains 4 pages including cover Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A43 of A55
VOC Results Apr May Jun Quarter Results (µg/m 3 ) Analyte LOD Chch 1 Chch 2 Mt Eden 1 Mt Eden 2 Penrose 1 Penrose 2 (µg/m 3 ) SQ5435 RB552 SN3298 SQ5337 SQ5214 SQ5378 Target VOCs ethanol ND ND ND ND ND ND acetone ND ND ND ND ND ND pentane 2.1 5 5 2 2 3 3 dichloromethane ND ND ND ND ND ND butan-2-one.4.4.6 <LOD <LOD 1 1 hexane.5 2 2 1 1 2 <LOD ethyl acetate ND ND ND ND ND ND trichloromethane ND ND ND ND ND ND 1,1,1-trichoroethane ND ND ND ND ND ND benzene.4 6 6 2 2 3 3 2-methylhexane.5 1 1 <LOD <LOD 1 1 2,3-dimethylpentane ND ND ND ND ND ND 3-methylhexane.5 1 1 1 1 1 1 heptane.5 1 1 <LOD <LOD 1 1 trichloroethene.5 <LOD <LOD <LOD <LOD <LOD.5 propyl acetate.5 <LOD <LOD <LOD <LOD 1 1 methylcyclohexane ND ND ND ND ND ND 4-methylpentan-2-one ND ND ND ND ND ND toluene.5 12 13 6 6 1 1 octane ND ND ND ND ND ND tetrachloroethene.5 1 1 1 1 <LOD <LOD butyl acetate ND ND ND ND ND ND ethylbenzene.5 2 2 1 1 1 2 m+p-xylene.5 8 8 4 4 6 6 o-xylene.5 2 3 1 1 2 2 nonane ND ND ND ND ND ND alpha pinene ND ND ND ND ND ND propylbenzene ND ND ND ND ND ND 1,3,5-.6 1 1 <LOD <LOD 1 1 trimethylbenzene beta pinene.6 1 1 <LOD <LOD <LOD <LOD decane ND ND ND ND ND ND 1,2,4-.6 3 3 1 1 2 2 trimethylbenzene limonene ND ND ND ND ND ND undecane ND ND ND ND ND ND dodecane ND ND ND ND ND ND tetradecane ND ND ND ND ND ND Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A44 of A55
VOC Results Jul-Aug-Sep Quarter Results (µg/m 3 ) Analyte LOD Chch 1 Chch 2 Mt Eden 1 Mt Eden 2 Penrose 1 Penrose 2 (µg/m 3 ) RB5562 RB5515 RH2118 RH234 RB5434 RB5386 Target VOCs ethanol ND ND ND ND ND ND Isopropyl alcohol ND ND ND ND ND ND acetone ND ND ND ND ND ND pentane 2.1 3.7 4.1 3. 3.2 4.3 4.5 dichloromethane 2. 2.7 2.5 <LOD <LOD <LOD <LOD butan-2-one ND ND ND ND ND ND hexane.5 3.6 3.2 1.3 1.4 1.6 1.6 ethyl acetate ND ND ND ND ND ND trichloromethane ND ND ND ND ND ND 1,1,1-trichoroethane ND ND ND ND ND ND benzene.4 7.4 6.8 2.4 2.4 2.6 2.6 2-methylhexane.5 1.1 1.1 <LOD <LOD.6.5 2,3-dimethylpentane ND ND ND ND ND ND 3-methylhexane.5 1.4 1.3 <LOD <LOD.6.6 heptane.5 2. 1.7 <LOD <LOD.5 <LOD trichloroethene.5.6.5 <LOD <LOD <LOD <LOD propyl acetate.5 <LOD <LOD <LOD <LOD 1.2 1.1 methylcyclohexane 2.6 4.8 3.5 <LOD <LOD <LOD <LOD 4-methylpentan-2-one ND ND ND ND ND ND toluene.5 17.2 15.3 6.1 6.1 7.5 7.5 octane ND ND ND ND ND ND tetrachloroethene.5.8.8 <LOD <LOD <LOD <LOD butyl acetate.5 <LOD <LOD <LOD <LOD.5.5 ethylbenzene.6 1.6 1.7.9.9 1.2 1.2 m+p-xylene.6 6.4 6.7 3.6 3.4 4.7 4.7 o-xylene.6 2.2 2.1 1.2 1.1 1.6 1.6 nonane ND ND ND ND ND ND alpha pinene ND ND ND ND ND ND propylbenzene ND ND ND ND ND ND 1,3,5-.6.7.8 <LOD <LOD.6.6 trimethylbenzene beta pinene ND ND ND ND ND ND decane ND ND ND ND ND ND 1,2,4-.6 2.2 2.3 1.3 1.2 1.7 1.7 trimethylbenzene limonene ND ND ND ND ND ND undecane ND ND ND ND ND ND dodecane ND ND ND ND ND ND tetradecane ND ND ND ND ND ND Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A45 of A55
VOC Results Oct-Nov-Dec Quarter Results (µg/m 3 ) Analyte LOD Chch 1 Chch 2 Mt Eden 1 Mt Eden 2 Penrose 1 Penrose 2 (µg/m 3 ) RF6584 RF651 RV728 RV867 RV566 RV1199 Target VOCs ethanol ND ND ND ND ND ND Isopropyl alcohol ND ND ND ND ND ND acetone 1.8 1.5 4.1 ND ND ND ND pentane ND ND ND ND ND ND dichloromethane 1.9 ND ND ND ND ND ND butan-2-one ND ND ND ND ND ND hexane.5 2.4 2.1.9 1.1.9.9 ethyl acetate ND ND ND ND ND ND trichloromethane ND ND ND ND ND ND 1,1,1-trichoroethane ND ND ND ND ND ND benzene.4 7.4 5.3 1.6 2. 2. 1.8 2-methylhexane.5.5.5 ND ND ND ND 2,3-dimethylpentane ND ND ND ND ND ND 3-methylhexane.5.8.5 ND ND ND ND heptane.5 1.6 1. ND ND ND ND trichloroethene ND ND ND ND ND ND propyl acetate ND ND ND ND ND ND methylcyclohexane 2.5 7.1 4.4 ND ND ND ND 4-methylpentan-2-one ND ND ND ND ND ND toluene.5 1.8 7.9 5.4 5.4 5.4 5.4 octane ND ND ND ND ND ND tetrachloroethene ND ND ND ND ND ND butyl acetate ND ND ND ND ND ND ethylbenzene.5.6.6.8.8 1. 1. m+p-xylene.5 1.1 1.1 1.8 1.6 1.8 1.8 o-xylene.5.8.8 1. 1. 1.3 1. nonane ND ND ND ND ND ND alpha pinene ND ND ND ND ND ND propylbenzene ND ND ND ND ND ND 1,3,5-trimethylbenzene ND ND ND ND ND ND beta pinene ND ND ND ND ND ND decane ND ND ND ND ND ND 1,2,4-.6.9.9.8.8 1.1 1.1 trimethylbenzene limonene ND ND ND ND ND ND undecane.7 ND ND ND ND 1. 1. dodecane.6 ND ND ND ND.6.9 tetradecane Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A46 of A55
APPENDIX F Laboratory Results Appendix F contains 7 pages including cover Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A47 of A55
Certificate of Analysis Client: Watercare Air Quality Group PO Box 5977 Mangere Bridge AUCKLAND 171 Attention: Johanna Symons Date Received: 17 July 21 Laboratory Reference: 1-297/1-7 Sample Type: Analysis: 3M Vapour Monitor Volatile Organic Compounds Method: The badge was desorbed with carbon disulphide. The extract was analysed by gas chromatography - mass spectrometry. Detection limits are given for target compounds used to validate the analysis. Non target compounds are identified by a mass spectral library search [Wiley Library (HP G135A)]. Full details of the methodology and precision are available on request. Results are reported in total micrograms (µg) of analyte on an as received basis and are not corrected for desorption efficiencies. M. D. Valentine A. R. Lister Trace Organics Laboratory Trace Organics Laboratory AgriQuality Environmental AgriQuality Environmental Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A48 of A55
VOC RESULTS Amounts are in total micrograms (µg) per badge Watercare Reference AQG A 3-1 AQG A 3-2 AQG A 3-3 AQG A 3-4 AQG A 3-5 AQG A 3-6 AQG A 3-7 Blank AgriQuality Lab. 1-1- 1-1- 1-1- 1-297/7 Reference 297/1 297/2 297/3 297/4 297/5 297/6 Target VOCs ethanol <2 <2 <2 <2 <2 <2 <2 acetone <1 <1 <1 <1 <1 <1 <1 pentane 23 24 11 11 15 15 <1 dichloromethane <1 <1 <1 <1 <1 <1 <1 butan-2-one 2 3 <2 <2 4 4 <2 hexane 1 1 6 5 8 <2 <2 ethyl acetate <2 <2 <2 <2 <2 <2 <2 trichloromethane <2 <2 <2 <2 <2 <2 <2 1,1,1-trichoroethane <2 <2 <2 <2 <2 <2 <2 benzene 27 28 11 11 14 14 <2 2-methylhexane 5 5 <2 <2 3 3 <2 2,3-dimethylpentane <2 <2 <2 <2 <2 <2 <2 3-methylhexane 5 5 2 2 3 3 <2 heptane 4 4 <2 <2 2 2 <2 trichloroethene <2 <2 <2 <2 <2 2 <2 propyl acetate <2 <2 <2 <2 5 5 <2 methylcyclohexane <2 <2 <2 <2 <2 <2 <2 4-methylpentan-2-one <2 <2 <2 <2 <2 <2 <2 toluene 51 53 27 25 4 41 <2 octane <2 <2 <2 <2 <2 <2 <2 tetrachloroethene 3 4 3 3 <2 <2 <2 butyl acetate <2 <2 <2 <2 <2 <2 <2 ethylbenzene 7 7 4 3 5 6 <2 m+p-xylene 28 28 13 13 21 22 <2 o-xylene 9 1 4 4 7 7 <2 nonane <2 <2 <2 <2 <2 <2 <2 alpha pinene <2 <2 <2 <2 <2 <2 <2 propylbenzene <2 <2 <2 <2 <2 <2 <2 1,3,5-trimethylbenzene 3 3 <2 <2 2 2 <2 beta pinene 2 2 <2 <2 <2 <2 <2 decane <2 <2 <2 <2 <2 <2 <2 1,2,4-trimethylbenzene 9 9 4 4 7 7 <2 limonene <2 <2 <2 <2 <2 <2 <2 undecane <2 <2 <2 <2 <2 <2 <2 dodecane <2 <2 <2 <2 <2 <2 <2 tetradecane <2 <2 <2 <2 <2 <2 <2 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A49 of A55
Certificate of Analysis Client: Watercare Services Limited PO Box 5977 Mangere Bridge AUCKLAND 171 Attention: Judy Warren Date Received: 15 October 21 Client Reference: Project AQG-A-3 Laboratory Reference: 1-4178/1-7 Sample Type: Analysis: 3M Vapour Monitor Volatile Organic Compounds Method: The badge was desorbed with carbon disulphide. The extract was analysed by gas chromatography - mass spectrometry. Detection limits are given for target compounds used to validate the analysis. Non target compounds are identified by a mass spectral library search [Wiley Library (HP G135A)]. Full details of the methodology and precision are available on request. Results are reported in total micrograms (µg) of analyte on an as received basis and are not corrected for desorption efficiencies. M. D. Valentine A. R. Lister UltraTrace Laboratory UltraTrace Laboratory AgriQuality Environmental AgriQuality Environmental Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A5 of A55
VOC RESULTS Amounts are in total micrograms (µg) per badge Watercare Reference MfE Chch MfE Chch MfE Penrose MfE Penrose MfE MtE MfE MtE MfEC RB5562 RB5515 RB5434 RB5386 RH211 8 RH23 4 Blank AgriQuality Lab. 1-1- 1-4178/3 1-4178/4 1-1- 1- Reference 4178/1* 4178/2* 4178/5 4178/6 4178/7 Target VOCs ethanol <2 <2 <2 <2 <2 <2 <2 isopropyl alcohol <1 <1 <1 <1 <1 <1 <1 acetone <1 <1 <1 <1 <1 <1 <1 pentane 18 2 2 21 14 15 <1 dichloromethane 14 13 <1 <1 <1 <1 <1 butan-2-one <1 <1 <1 <1 <1 <1 <1 hexane 16 14 7 7 6 6 <2 ethyl acetate <2 <2 <2 <2 <2 <2 <2 trichloromethane <2 <2 <2 <2 <2 <2 <2 1,1,1-trichoroethane <2 <2 <2 <2 <2 <2 <2 benzene 36 33 12 12 11 11 <2 2-methylhexane 5 4 2 2 <2 <2 <2 2,3-dimethylpentane <2 <2 <2 <2 <2 <2 <2 3-methylhexane 6 5 2 2 <2 <2 <2 heptane 8 7 2 <2 <2 <2 <2 trichloroethene 3 2 <2 <2 <2 <2 <2 propyl acetate < 2 <2 5 5 <2 <2 <2 methylcyclohexane 19 14 <2 <2 <2 <2 <2 4-methylpentan-2-one <2 <2 <2 <2 <2 <2 <2 toluene 74 66 31 31 25 25 <2 octane <2 <2 <2 <2 <2 <2 <2 tetrachloroethene 3 3 <2 <2 <2 <2 <2 butyl acetate <2 <2 2 2 <2 <2 <2 ethylbenzene 6 6 4 4 3 3 <2 m+p-xylene 24 25 17 17 13 12 <2 o-xylene 8 8 6 6 4 4 <2 nonane <2 <2 <2 <2 <2 <2 <2 alpha pinene <2 <2 <2 <2 <2 <2 <2 propylbenzene <2 <2 <2 <2 <2 <2 <2 1,3,5-trimethylbenzene 3 3 2 2 <2 <2 <2 beta pinene <2 <2 <2 <2 <2 <2 <2 decane <2 <2 <2 <2 <2 <2 <2 1,2,4-trimethylbenzene 8 8 6 6 4 4 <2 limonene <2 <2 <2 <2 <2 <2 <2 undecane <2 <2 <2 <2 <2 <2 <2 dodecane <2 <2 <2 <2 <2 <2 <2 tetradecane <2 <2 <2 <2 <2 <2 <2 < = less than the limit of detection * badges received without closure caps Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A51 of A55
Certificate of Analysis Client: Watercare Air Quality Group PO Box 5977 Mangere Bridge AUCKLAND 171 Attention: Judy Warren Date Received: 16 January 22 Laboratory Reference: 2-74/1-7 Sample Type: Analysis: 3M Vapour Monitor Volatile Organic Compounds Method: The badge was desorbed with carbon disulphide. The extract was analysed by gas chromatography - mass spectrometry. Detection limits are given for target compounds used to validate the analysis. Non target compounds are identified by a mass spectral library search [Wiley Library (HP G135A)]. Full details of the methodology and precision are available on request. Results are reported in total micrograms (µg) of analyte on an as received basis and are not corrected for desorption efficiencies. J. Fry M. Rogers UltraTrace Laboratory UltraTrace Laboratory AgriQuality Environmental AgriQuality Environmental Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A52 of A55
VOC RESULTS Amounts are in total micrograms (µg) per badge Watercare Reference MfE Chch MfE Chch MfE MtE MfE MtE MfE MfE MfEC Penrose Penrose RF6584 RF651# RV728 RV867 RV566 RV1199 Blank AgriQuality Lab. 2-74/1 2-74/2 2-74/5 2-74/6 2-74/3 2-74/4 2-74/7 Reference Target VOCs ethanol <2 <2 <2 <2 <2 <2 <2 isopropyl alcohol <1 <1 <1 <1 <1 <1 <1 acetone 56 22 <1 <1 <1 <1 <1 pentane <1 <1 <1 <1 <1 <1 <1 dichloromethane 27 18 <1 <1 <1 <1 <1 butan-2-one <1 <1 <1 <1 <1 <1 <1 hexane 1 9 4 5 4 4 <2 ethyl acetate <2 <2 <2 <2 <2 <2 <2 trichloromethane <2 <2 <2 <2 <2 <2 <2 1,1,1-trichoroethane <2 <2 <2 <2 <2 <2 <2 benzene 35 25 8 1 1 9 <2 2-methylhexane 2 2 <2 <2 <2 <2 <2 2,3-dimethylpentane <2 <2 <2 <2 <2 <2 <2 3-methylhexane 3 2 <2 <2 <2 <2 <2 heptane 6 4 <2 <2 <2 <2 <2 trichloroethene <2 <2 <2 <2 <2 <2 <2 propyl acetate <2 <2 <2 <2 3 3 <2 methylcyclohexane 27 17 <2 <2 <2 <2 <2 4-methylpentan-2-one <2 <2 <2 <2 <2 <2 <2 toluene 45 33 24 24 24 24 <2 octane <2 <2 <2 <2 <2 <2 <2 tetrachloroethene <2 <2 <2 <2 <2 <2 <2 butyl acetate <2 <2 <2 <2 <2 <2 <2 ethylbenzene 2 2 3 3 4 4 <2 m+p-xylene 4 4 7 6 7 7 <2 o-xylene 3 3 4 4 5 4 <2 nonane <2 <2 <2 <2 <2 <2 <2 alpha pinene <2 <2 <2 <2 <2 <2 <2 propylbenzene <2 <2 <2 <2 <2 <2 <2 1,3,5-trimethylbenzene <2 <2 <2 <2 <2 <2 <2 beta pinene <2 <2 <2 <2 <2 <2 <2 decane <2 <2 <2 <2 <2 2 <2 1,2,4-trimethylbenzene 3 3 3 3 4 4 <2 limonene <2 <2 <2 <2 <2 <2 <2 undecane <2 <2 <2 <2 3 3 <2 dodecane <2 <2 <2 <2 2 3 <2 tetradecane <2 <2 <2 <2 <2 <2 <2 < = less than the limit of detection ` Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A53 of A55
APPENDIX G Terms and Conditions for the Supply and Use of Environment Canterbury Information Appendix G contains 2 pages including cover Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A54 of A55
Terms and conditions for the supply and use of Environment Canterbury (promotional name for Canterbury Regional Council) information. Environment Canterbury Your regional council DESCRIPTION OF INFORMATION Information supplied to: JWarren (Judy) [jwarren@water.co.nz] Description of information to which these terms and conditions apply: Ten minute average PM 1 measured by TEOM@4 C at St Albans Coles Pl from March 1 to July 31, 21. For gaps of less than 6 hours interpolation has been used to fill gaps. Interpolated and non interpolated data are given. Daily averages from 9am are also included and the relationship with beta data defined and beta equivalent concentrations calculated. GENERAL TERMS AND CONDITIONS 1. Environment Canterbury owns the copyright on the information. 2. Environment Canterbury shall be acknowledged as the source of the information used in any reports, publications, media statements or other documents, or oral statements which include the information and are made available to third parties or the general public. 3. A copy of these terms and conditions shall accompany any of the attached information which is made available to third parties. 4. The user of the attached information agrees to indemnify Environment Canterbury for any losses sustained as a consequence of breach of any of these conditions. DISCLAIMER The attached information is supplied on the basis that it is accurate to the best of Environment Canterbury knowledge and belief and is based on the information currently held by Environment Canterbury. While Environment Canterbury has exercised all reasonable skill and care in controlling this information, Environment Canterbury accepts no liability in contract, tort or otherwise howsoever, for any loss, damage, injury or expense (whether direct, indirect or consequential) arising out of the provision of this information or its use by you. NOTE ON PROVISIONAL INFORMATION The attached information is provisional/audited (delete one) information. Provisional information has not yet been checked using the Council s Quality Assurance audit procedures. Provisional information may be subject to significant changes and are not citeable until reviewed and approved by Environment Canterbury. Information users are cautioned to consider carefully the nature of provisional information before using it for decisions that concern personal or public safety or the conduct of business that involves monetary or operational consequences. Prepared by: Teresa Aberkane Date: 8/8/1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A55 of A55