Page 1 of 5 SCA Ai r Fr e s h Fl or al MATERI AL SAFETY DATA SHEET ACCORDING TO 91/155/EC (as amended 2001/58/EC) ISSUING DATE: November 2006 SECTI ON 1 - I DENTI FI CATI ON OF SUBSTANCE/ PREPARATI ON AND COMPANY/ UNDERTAKI NG Pr oduc t De t ai l s. Tr ade Name : Us e : SCA Air Fresh metered aerosols Fr agr anc e : Fl or al. Fragranced metered aerosol space sprays designed for use in proprietary automated dispensers. Pr oduc t Name : Tor k Pr e mi um Ai r f r e s he ne r Ae r os ol, Fl or al ( ar t nr 236052) Pr oduc t Cat e gor y: Airfreshener Suppl i e r : SCA Hygiene Products Adr e s s : 405 03 Göteborg Sweden Phone +46-(0)31-746 00 00 SECTI ON 2 - COMPOSI TI ON/ DATA ON COMPONENTS Che mi c al Char ac t e r i s at i on De s c r i pt i on: Mixture of organic solvents, perfume and propane/iso-butane (propellant) Dange r ous Compone nt s : De s i gnat i on CAS No. EC No. Symbol R- Phr as e s % Propan-2-ol 67-63-0 200-661-7 Xi, F 11-36-67 5 10 Ethanol 64-17-5 200-578-6 F 11 10 15 1,1,6,7-Tetramethyl-6-acetyldecalene 54464-57-2 259-174-3 N 51/53 < 1 Diphenyl ether 101-84-8 202-981-2 Xi, N 36/37/38-51/53 < 1 Amyl cinnamal 122-40-7 204-541-5 Xi, N 43-51/53 < 1 Eugenol 97-53-0 202-589-1 Xi 38-43 < 1 Phenylacetaldehyde 122-78-1 204-574-5 Xi 43 < 1 Addi t i onal i nf or mat i on For the wording of the listed risk phrases refer to section 16. SECTI ON 3 - HAZARDS I DENTI FI CATI ON Haz ar d De s i gnat i on: F+ Extremely flammable I nf or mat i on pe r t ai ni ng t o par t i c ul ar dange r s f or man and e nvi r onme nt : R12 Extremely flammable Cl as s i f i c at i on Sys t e m The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information furnished by supplier companies.
Page 2 of 5 SCA Ai r Fr e s h Fl or al SECTI ON 4 - FI RST AI D MEASURES Af t e r i nhal at i on Af t e r s ki n c ont ac t Af t e r e ye c ont ac t Supply fresh air, consult a doctor if symptoms develop. Remove soaked clothing and launder before reuse. Wash skin with water and soap. If symptoms develop or persist, consult a doctor. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. Af t e r s wal l owi ng Rinse mouth. DO NOT INDUCE VOMITING. Consult a doctor. SECTI ON 5 - FI RE FI GHTI NG MEASURES Sui t abl e Ext i ngui s hi ng Age nt s : For s af e t y r e as ons uns ui t abl e e xt i ngui s hi ng age nt s : Spe c i al haz ar ds c aus e d by t he mat e r i al, i t s pr oduc t s of c ombus t i on or f l ue gas e s : Water jet. CO 2, extinguishing powder or alcohol-resistant foam. In case of fire CO may be possible. Pr ot e c t i ve Equi pme nt : Wear protective clothing/equipment when fighting fires SECTI ON 6 - ACCI DENTAL RELEASE MEASURES Pe r s on- r e l at e d s af e t y pr e c aut i ons : Wear protective equipment. Keep unprotected persons away. Me as ur e s f or e nvi r onme nt al pr ot e c t i on: No special measures required. Me as ur e s f or c l e ani ng/ c ol l e c t i ng: Ensure adequate ventilation. Absorb liquid components with liquid binding material (sand, diatomite, acid binders, universal binders, sawdust). SECTI ON 7 - HANDLI NG AND STORAGE Handl i ng I nf or mat i on f or s af e handl i ng: Ensure good ventilation/exhaustion at the workplace. I nf or mat i on about pr ot e c t i on Keep ignition sources away - Do not smoke. agai ns t e xpl os i ons and f i r e s : Beware: Container is pressurised. Keep away from direct sun exposure and temperatures over 50 C. Do not open by force or throw into fire, even after use. Do not spray on flames or red-hot objects St or age Re qui r e me nt s t o be me t by Store in cool location s t or e r ooms and c ont ai ne r s : Observe official regulations on storing packagings with pressurised containers. I nf or mat i on about s t or age i n one c ommon s t or age f ac i l i t y: Do not store together with strong acids and strong oxidising agents. Fur t he r i nf or mat i on about s t or age c ondi t i ons : Protect from heat and direct sunlight.
Page 3 of 5 SCA Ai r Fr e s h Fl or al SECTI ON 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTI ON Addi t i onal i nf or mat i on about de s i gn of t e c hni c al s ys t e ms : No further data; see item 7. Compone nt s wi t h c r i t i c al val ue s The product does not contain any relevant quantities of t hat r e qui r e moni t or i ng at t he materials with critical values that have to be monitored at the wor kpl ac e : workplace. Addi t i onal i nf or mat i on: WEL - Values: EH40(2005) Ethanol OES 8hr TWA - 1000 ppm (1920 mg/m 3 ) Isopropanol OES 8hr TWA - 400 ppm (999 mg/m 3 ) 15min STEL 500 ppm (1250 mg/m 3 ) Propane Listed as an asphyxiant with no limit set Pe r s onal pr ot e c t i ve e qui pme nt Ge ne r al pr ot e c t i ve and hygi e ni c me as ur e s : Wash hands during breaks and at the end of the work. Br e at hi ng e qui pme nt : Pr ot e c t i on of hands : Not required, but ensure adequate ventilation when using the product. Not required when used as directed. Eye pr ot e c t i on: Not required when used as directed. SECTI ON 9 - PHYSI CAL AND CHEMI CAL PROPERTI ES For m: Col our : Sme l l : Aerosol According to Product specification. Perfume Val ue / Range Uni t Me t hod Change i n c ondi t i on Me l t i ng poi nt / Me l t i ng r ange : Not applicable, as aerosol Boi l i ng poi nt / Boi l i ng r ange : Not applicable, as aerosol Fl as h poi nt : Not applicable, as aerosol Se l f - f l ammabi l i t y: Dange r of e xpl os i on: Product is not self-igniting. Product is not explosive. However, formation of explosive air/steam mixtures is possible. Cr i t i c al val ue s f or e xpl os i on: Lowe r : 1.8 Vol % Uppe r : 19.0 Vol % Vapour pr e s s ur e : at 20 C 4.0 ± 0.5 bar De ns i t y: at 20 C 0.619-0.645 g/cm 3 Sol ubi l i t y i n/ Mi s c i bi l i t y wi t h Wat e r : Partly miscible
Page 4 of 5 SCA Ai r Fr e s h Fl or al SECTI ON 10 - STABI LI TY AND REACTI VI TY The r mal de c ompos i t i on/ c ondi t i ons t o be avoi de d: No decomposition if used according to instructions. Dange r ous r e ac t i ons : Mat e r i al s t o be avoi de d: No dangerous reactions known. Oxidising agents and strong acids. Dange r ous pr oduc t s of de c ompos i t i on: In case of fire CO may be possible. SECTI ON 11 - TOXI COLOGI CAL I NFORMATI ON Ac ut e t oxi c i t y: Pr i mar y i r r i t ant e f f e c t : On t he s ki n: Irritation may be possible. On t he e ye : Irritation may be possible. SECTI ON 12 - ECOLOGI CAL I NFORMATI ON Ge ne r al not e s : Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. SECTI ON 13 - DI SPOSAL CONSI DERATI ONS Pr oduc t : Re c omme ndat i on: Unc l e ane d pac kagi ngs : Re c omme ndat i on: Disposal must be made according to local regulations or via a licensed waste contractor. Disposal must be made according to local regulations or via a licensed waste contractor. SECTI ON 14 - TRANSPORT I NFORMATI ON Land t r ans por t ADR/ RI D and GGVS/ GGVE ( c r os s - bor de r / dome s t i c ) ADR/ RI D Cl as s : 2 UN Numbe r : 1950 Cor r e c t t e c hni c al name : Labe l : Re mar ks : Mar i t i me t r ans por t I MDG/ GGVSe a Aerosols (Flammable) Diamond shaped, framed UN 1950 AEROSOLS should be placed inside the diamond shaped label. Goods are classed as Limited Quantities and are therefore exempt from ADR regulations. Check local local legislation for domestic transport. I MDG/ GGVSe a Cl as s : 2 UN Numbe r : 1950 EMS Numbe r : F-D, S-U Mar i ne Pol l ut ant No Cor r e c t t e c hni c al name : Aerosols Re mar ks Limited Quantity AEROSOLS is required according to IMDG regulations Ai r t r ans por t I CAO- TI and I ATA- DGR I CAO/ I ATA Cl as s : 2.1 UN/ I D Numbe r : 1950 Cor r e c t Te c hni c al Name : Aerosols, flammable Re mar ks : Limited Quantity
Page 5 of 5 SCA Ai r Fr e s h Fl or al SECTI ON 15 - REGULATORY I NFORMATI ON De s i gnat i on ac c or di ng t o EC The product has been labelled in accordance with Gui de l i ne s : EC Directives/relevant national laws. For professional use only Code l e t t e r and haz ar d de s i gnat i on of pr oduc t : F+ Extremely flammable. Ri s k phr as e s : 12 Extremely flammable. Saf e t y phr as e s : 2 Keep out of reach of children. 16 Keep away from sources of ignition - No smoking. 23 Do not breathe spray. 51 Use only in well-ventilated areas. Nat i onal r e gul at i ons : Spe c i al de s i gnat i on of c e r t ai n pr e par at i ons : Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50 O C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Wat e r haz ar d c l as s : Water hazard class 1 (Self-assessment): slightly hazardous for water. SECTI ON 16 - OTHER I NFORMATI ON R- phr as e s us e d i n doc ume nt : R11 Highly flammable R12 Extremely flammable R36 Irritating to eyes R38 Irritating to skin R36/37/38 Irritating to eyes, respiratory system and skin R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment R67 Vapours may cause drowsiness and dizziness This data is based on our present knowledge. However, it shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. De par t me nt i s s ui ng dat a s pe c i f i c at i on s he e t : Technical Services Department. Cont ac t : Mr. K. Anderson Sour c e s : Raw material Safety Data sheets EH40/2005 Occupational Exposure limits (UK) Revision data: Rev 7 Rev. 4 - Compliance to CHIP 3 and the 2001/58/EC amendments to 91/155/ECC Rev. 5 - Changes to Section 2 Rev. 6 Changes to Sections 2, 15 and 16 Rev. 7 Changes to Section 14 Rev. 8 Changes to Section 8 & 16 (marked ) Print date: