Availability
Availability
Preparation via Insertion Grignard s Synthesis Generally Considered as a Radical Process
Schlenk Equilibrium Parasite Reactions Reversible Reaction in THF Substitution Reactions
Preparation via Permutation Towards the Most Stable Magnesium Species Relative Stabilities Relative Stabilities
TurboGrignard Reagent Preparation via Permutation Isopropylmagnesium chloride lithium chloride
Form C sp 3 to C sp 2 Preparation via Permutation - Increased functional group compatibility - Mild reaction conditions, including a convenient range of temperatures - Side reactions inhibited - Allows for preparation of functionalized heteroaryl organometallics - Large-scale production of Grignard reagents possible
Form C sp 3 to C sp 2 Preparation via Permutation
Form C sp 3 to C sp 2 Preparation via Permutation
Form C sp 3 to C sp 2 Preparation via Permutation
Form C sp 3 to C sp 2 Preparation via Permutation
Form C sp 3 to C sp 2 - Heteroaromatic Preparation via Permutation
Form C sp 3 to C sp 2 Alkenyl-Mg Preparation via Permutation
Form C sp 3 to C sp 2 Preparation via Permutation
In the Presence of an Acidic Proton Preparation via Permutation
In the Presence of an Acidic Proton Preparation via Permutation
In the Presence of an Acidic Proton Preparation via Permutation
In the Presence of an Acidic Proton Preparation via Permutation
In the Presence of an Acidic Proton Preparation via Permutation
Permutation of Sulfoxides
Permutation of Sulfoxides
Permutation of Sulfoxides
Permutation of Sulfoxides
Permutation of Sulfoxides
Exception of 2-Pyridinyl Sulfoxides
Exception of 2-Pyridinyl Sulfoxides Pentavalent Sulfur Species S. Oae et al. Tetrahedron Lett. 1984, 25, 69.
Exception of 2-Pyridinyl Sulfoxides
Case of Halogeno-cyclopropanes Configurationally Stable
Case of Halogeno-cyclopropanes
Preparation via Transmetallation Mechanism Will Not Be Discussed in Details «s-bond Metathesis» or «Substitution Mechanism»
Preparation via Transmetallation
Notation To Simplify Preparation via Transmetallation Grignard are easily prepare Transmetallation is not so commun to generate organomagnesium
From Lithium Enolates to Magnesium Enolates Preparation via Transmetallation Deprotonation with Grignard Reagents Uneasy Transmetallation Quite Easy Due to a Relatively Better Stability of Organomagnesium Species
From Lithium Enolates to Magnesium Enolates Preparation via Transmetallation
From Lithium Enolates to Magnesium Enolates Preparation via Transmetallation
From Lithium Enolates to Magnesium Enolates Preparation via Transmetallation
From Lithium Enolates to Magnesium Enolates Preparation via Transmetallation
From Lithium Enolates to Magnesium Enolates Preparation via Transmetallation
Preparation via Transmetallation 1,4-Additions towards Magnesium Enolates SPECIFIC EXAMPLES
Preparation via Transmetallation 1,4-Additions towards Magnesium Enolates SPECIFIC EXAMPLES
Preparation via Transmetallation 1,4-Additions towards Magnesium Enolates SPECIFIC EXAMPLES Aza-Michael Addition
Preparation via Transmetallation 1,4-Additions towards Magnesium Enolates SPECIFIC EXAMPLES Thio-Michael Addition
Reactivity of Organomagnesium Preparation via Transmetallation
Reactivity of Magnesium Enolates Preparation via Transmetallation
Other Reactivities Preparation via Transmetallation
Organozinc Reagents Preparation via Insertion - Smooth Reactivity Towards Electrophiles - Easily Prepared by Transmetallation - Can Be Used at Room Temperature - High Functional Group Tolerance
Organozinc Reagents Preparation via Insertion
Organozinc Reagents Preparation via Insertion
Organozinc Reagents Activation of Zn Preparation via Insertion Zn (0) + TMS-Cl (2-5 mol%) Zn (0) + dibromoethane (2-5 mol%) ZnCl2 + Li = Zn* (Rieke Zn) Zn (0) + LiCl (1 eq.)
Organozinc Reagents Activation of Zn Preparation via Insertion
Organozinc Reagents Activation of Zn Allylic Systems Preparation via Insertion
Organozinc Reagents Preparation via Insertion
Organozinc Reagents Preparation via Insertion
Organozinc Reagents Preparation via Insertion Insertion in Phosphates, Tosylates and Mesylates
Organozinc Reagents Preparation via Insertion Insertion in Phosphates, Tosylates and Mesylates
Organozinc Reagents High Functional Group Tolerance Preparation via Insertion
Organozinc Reagents From Lithium and Magnesium Preparation via Transmetallation
Organozinc Reagents From Lithium and Magnesium Preparation via Transmetallation
Organozinc Reagents From Boranes Preparation via Transmetallation
Organozinc Reagents From Boranes Preparation via Transmetallation
Organozinc Reagents From Boranes Preparation via Transmetallation
Organozinc Reagents From Boranes Preparation via Transmetallation
Organozinc Reagents From Boranes Preparation via Transmetallation
Organozinc Reagents From Boranes Preparation via Transmetallation
Organozinc Reagents From Zirconium Preparation via Transmetallation
Organozinc Reagents Alkyl and Aryl Zinc Species Reactivity of Zinc Species
Organozinc Reagents Allylzinc Species Reactivity of Zinc Species
Organozinc Reagents Allylzinc Species Reactivity of Zinc Species Stereocontrolled by Zimmermann-Traxler
Organozinc Reagents Zinc Carbenoids Reactivity of Zinc Species Guy Emschwiller, 1929 (Zn insertion) «Zinc Iodide Exchange»
Organozinc Reagents Zinc Carbenoids More Reactive Species Reactivity of Zinc Species Shi Carbenoid Charette Carbenoid
Organozinc Reagents Zinc Carbenoid Reactivity of Zinc Species
Organozinc Reagents Zinc Carbenoid in Homologations Reactivity of Zinc Species
Organozinc Reagents Zinc Carbenoid in Homologations Reactivity of Zinc Species I. Marek et al. J. Am. Chem. Soc. 2010, 132, 5588 I. Marek et al. Org. Lett. 2011, 13, 3604
Organozinc Reagents Zinc Carbenoid in Homologations Reactivity of Zinc Species I. Marek et al. Nature Chem. 2009, 1, 128 I. Marek et al. Chem. Commun. 2006, 1683
Organoalane Derivatives Preparation via Transmetallation - Special Reactivity - Highly Sensitive
Organomanganese Reagents Preparation via Transmetallation - Special Reactivity