SHANGHAI JIAO TONG UNIVERSITY LECTURE

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Lecture 12 SHANGHAI JIAO TONG UNIVERSITY LECTURE 12 2015 Anthony J. Leggett Department of Physics University of Illinois at Urbana-Champaign, USA and Director, Center for Complex Physics Shanghai Jiao Tong University

Lecture 12 - Applications ELECTRICAL POWER GENERATION Total annual electricity production (10 12 kwh) Fraction dissipated in transmission Fraction from nonfossil sources US China World ~4 ~3 ~19 ~8% ~7% ~30% ~15% ~35%(+) (mostly (mostly (nuclear nuclear) hydro) +hydro) SJTU 12.1 With increased use of non-fossil sources, fraction of generated energy dissipated in transmission is likely to increase substantially over next few decades, unless

WHAT CONTROLS ELECTRICAL TRANSMISSION LOSSES? SJTU 12.2 For a given current, the loss is proportional to the resistance (R). The resistance is proportional to the distance over which power is transmitted, but for fixed distance depends on the material. R=V/I R depends on temperature (T):e.g., for Cu R T room temperature So no great gain by cooling power lines. But: R Superconductivity, R=0 T

EXPERIMENTAL FACT: For temperature below some critical temperature T c (which depends on the material ) and current below some critical current density J c (ditto), many materials including Al are superconductors, I.e., have zero (dc) * resistance. If we could use superconductors for long-distance power transmission, we would have ZERO TRANSISSION LOSS! Some other advantages of using superconductors for transmissional storage of electrical energy: Automatic quenching of runaway current High current density Lossless magnetic energy storage ALAS, ONE SLIGHT PROBLEM: SJTU 12.3 smaller transmission lines (e.g. underground) IN MOST MATERIALS, T c IS VERY LOW! e.g.al: superconductivity R Absolute zero (0 K, -273.15 C) T c (1.3K, -271.8 C) room temperature * Ac resistance is nonzero but extremely small at low (~50 Hz) frequencies

Superconductivity was discovered in 1911, and for the next 75 years was found to occur only under ~25 K (-248 o C). To get to such low temperature one must to cool material with liquid helium. So while it s practical to use superconductors for e.g., geophysical magnetometry, application to large scale power transmission out of the question (not enough helium in the world!) WHY IS T c SO LOW? BCS theory gives an explanation: T c ~T D F Dimensionless factor Characteristic ( Debye ) temperature of ionic lattice, typically~room temperature. In BCS theory, there are strong arguments that the factor F can never exceed ~0.1 T c always 30 K (-243 o C). AND YET SJTU 12.4

THE HIGH-TEMPERATURE (CUPRATE) SUPERCONDUCTORS Generic Pattern: SJTU 12.5 Coper oxide) planes charge reservoir layers example: BSCCO-2212 (Bi 2 Sr 2 CaCu 2 O 8 ) (T c =95K) SrO BiO BiO SrO Critical current is very high along planes ( ), much smaller perpendicular to planes ( ) In practice, critical current usually determined by motion of vortices, which always occur in a large magnetic field: vortex moves perpendicular to field and to current, and thereby produces voltage nonzero resistance. current Magnetic field Circulating current field Motion of vertex

APPLICATION OF HIGH-TEMPERATURE SUPERCONDUCTIVITY TO GRID: 2 MAJOR AVENUES OF RESEARCH 1.Using existing (cuprate) high-temperature superconductors SJTU 12.6 (BSCCO, YBCO(YBa 2 Cu 3 O 6+x ), ) Already practical for special purposes (e.g. transformers, current fault limiters, offshore wind power ). Also, pilot cables (up to ~1 km) already in operation. But, for large-scale power transmission, need (inter alia) - large reduction in manufacturing cost (currently >> Cu) - reduction in cost of refrigeration (50-77K) - most importantly: increase in J c (H,T) critical current magnetic field temperature Since the factor limiting electrical current is motion of vortices, most promising route to higher J c is to final better ways to pin vortices. (ex.:irradiate with fast ions so as to produce columnar defects) What microscopic conditions are best for pinning of vortices? A major challenge to current microscopic theory of superconductivity in cuprates!

2 nd major avenue of research: SJTU 12.7 2. By understanding superconductivity in cupraters, or otherwise, find better high-temperature superconductors (ideally: T c >room temperature, large J c (H,T)). Problem: we don t understand superconductivity in the cuprates! (in particular, why T c is so high). Recall: to form di-electronic molecules appear to need effective attractive between electrons. In BCS theory this can be provided by polarization of ionic lattice. (but then predicts T c 30K). Anyway, much evidence that in cuprates effect of ionic lattice is at best secondary. So, much get superconductivity out of Coulomb repulsion between electrons! This is a MAJOR challenge for theoretical condensed matter physics (~10 4 papers since 1986) If we can solve it, then we may know where to look for room temperature superconductivity in the haystack of possible compounds. (no. of possible 5-element compounds ~10 10 10 6 person-years of research!) My guess: look for Strongest possible repulsion Strongly layered (2D) structure weak inter-layer tunneling contact anomalous optical properties ( MIR peak )

Other (actual and potential) applications: SJTU 12.8 Superconducting levitation: (Condensation energy of YBCO at T = 0 0.5 MJ/m 3 : energy neccessary to levitate Tosanoumi 15 J. sumo wrestler main problem: "mobile" supply of liquid N2! again, room-temperature superconductivity would solve problem... Magnetometry: Recall that for dc SQUID I = I c0 cosπφ/φ 0 very accurate measurement of Φ, hence of B. applications: magnetoencephalography, geographical prospecting... Quantum computing: needs set of two-state systems ("qubits") such that one can prepare and manipulate quantum superpositions of form Ψ = a + b while minimizing effects of decoherence. Prima facie optimal candidates: microscopic systems well shielded from environment (nuclear spins, trapped single ions...) But...