Radioactivity, Radioactive Dating, Band Theory of Solids, and Quantum Electronics Devices such as LEDs

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Physics 5K Lecture Friday May 11, 2012 Radioactivity, Radioactive Dating, Band Theory of Solids, and Quantum Electronics Devices such as LEDs Joel Primack Physics Department UCSC Friday, May 11, 12

Distant worlds may be wildly different from Earth, but there are things that must be true of them all, simply because of the nature of stardust. For example, on any planet where you find watery seas and land, there will be sandy beaches. This is because oxygen and silicon are two of the most abundant heavy atoms produced before a star explodes in a supernova. Free-floating in space, they combine with each other and the hydrogen that is everywhere, making H2O and SiO2 water and sand that travel together and become incorporated into new worlds. Friday, May 11, 12

Radioactivity Radioactivity was first discovered in 1896 by the French scientist Henri Becquerel. At first it seemed that the new radiation was similar to the then recently discovered X-rays. Further research by Becquerel, Marie Curie, Pierre Curie, Ernest Rutherford and others discovered that radioactivity was significantly more complicated. Different types of decay can occur, but Rutherford was the first to realize that they all are described by the same exponential formula. Rutherford also discovered the three main types of radioactivity: Alpha particles (helium nuclei) may be completely stopped by a sheet of paper. Beta particles (electrons or positrons) are stopped by a thin sheet of aluminum Gamma rays can only be reduced by much more substantial barriers, such as a very thick layer of lead. The genetic effects of radiation and the cancer risk were recognized much later. In 1927 Hermann Joseph Muller published research showing genetic effects, and in 1946 was awarded the Nobel prize for his findings. Friday, May 11, 12

Radioactive Decay (Review) Lifetime τand half-life T1/2 N(t)=N0 e t/ τ Note: e λt = e t/ τ implies that the lifetime τ= 1/λ. The relation between lifetime τand half-life T1/2 follows from e t/ τ = 2 t /T 1/2 Taking natural logs, t/τ= (t/t1/2) ln 2 so τ= T1/2 /ln 2 or T1/2 = τln 2 = 0.693 τ The figure is from Robert Eisberg and Robert Resnick, Quantum Physics of Atoms, Molecules, Solids, Nuclei, and Particles (Wiley, 1985). Friday, May 11, 12

Radioactive Dating Geologists quickly realized that the discovery of radioactivity upset the assumptions on which most calculations of the age of Earth were based. These calculations assumed that Earth and Sun had formed at some time in the past and had been steadily cooling since that time. Radioactivity provided a process that generated heat. Radioactivity, which had overthrown the old calculations, yielded a bonus by providing a basis for new calculations, in the form of radiometric dating. Late in 1904, Rutherford took the first step toward radiometric dating by suggesting that the alpha particles released by radioactive decay could be trapped in a rocky material as helium atoms. He dated a rock in his possession to an age of 40 million years by this technique. Ernest Rutherford in 1908. Barringer Crater, AZ, where the Canyon Diablo meteorite was found. Radiometric dating continues to be the predominant way scientists date geologic timescales. Techniques for radioactive dating have been tested and fine-tuned for the past 50+ years. Forty or so different dating techniques are utilized to date a wide variety of materials, and dates for the same sample using these techniques are in very close agreement on the age of the material. Today's accepted age of Earth of 4.54 billion years was determined by C.C. Patterson using uranium-lead isotope dating on several meteorites including the Canyon Diablo meteorite and published in 1956. It s been confirmed by a great deal of evidence since then. Friday, May 11, 12

238 U Decay Chain

232 Th Decay Chain

The Age of the Universe In the mid-1990s there was a crisis in cosmology, because the age of the old Globular Cluster stars in the Milky Way, then estimated to be 16±3 Gyr, was higher than the expansion age of the universe, which for a critical density (Ω m = 1) universe is 9±2 Gyr (with the Hubble parameter h=0.72±0.07). But when the data from the Hipparcos astrometric satellite became available in 1997, it showed that the distance to the Globular Clusters had been underestimated, which implied that their ages are 12±3 Gyr. Several lines of evidence now show that the universe does not have Ω m = 1 but rather Ω tot = Ω m + Ω Λ = 1.0 with Ω m 0.3, which gives an expansion age of about 14 Gyr. (Ω m means average density of matter in units of critical density.) Moreover, a new type of age measurement based on radioactive decay of Thorium-232 (half-life 14.1 Gyr) measured in a number of stars gives a completely independent age of 14±3 Gyr. A similar measurement, based on the first detection in a star of Uranium-238 (half-life 4.47 Gyr), gives 12.5±3 Gyr. All the recent measurements of the age of the universe are thus in excellent agreement. It is reassuring that three completely different clocks stellar evolution, expansion of the universe, and radioactive decay agree so well. Friday, May 11, 12

Band Theory of Solids (Review) ev If the Energy gap is larger than the energy of visible light (~3.2 ev), then the insulator will be transparent. Glass is an example. A very small percentage of impurity atoms in the glass can give it color by providing specific available energy levels which absorb certain colors of visible light. Another example: Ruby is aluminum oxide with a small amount (about 0.05%) of chromium, which gives it its characteristic red color by absorbing green and blue light. Friday, May 11, 12

Intrinsic semiconductor materials, pure to 1 part in 10 billion, are poor conductors. N-type semiconductor is doped with a pentavalent impurity to create free electrons. Such a material is conductive. The electron is the majority carrier. P-type semiconductor, doped with a trivalent impurity, has an abundance of free holes. These are positive charge carriers. The P-type material is conductive. The hole is the majority carrier. Text Semiconductor material may have specific impurities added at approximately 1 part per 10 million to increase the number of carriers. The addition of a desired impurity to a semiconductor is known as doping. Doping increases the conductivity of a semiconductor so that it is more comparable to a metal than an insulator. It is possible to increase the number of negative charge carriers within the semiconductor crystal lattice by doping with an electron donor like Phosphorus. Electron donors, also known as N-type dopants include elements from group VA of the periodic table: nitrogen, phosphorus, arsenic, and antimony. Nitrogen and phosphorus are N-type dopants for diamond. Phosphorus, arsenic, and antimony are used with silicon. Friday, May 11, 12

N-type and P-type Semicondutor Diode In Figure 2.29(a) the battery is arranged so that the negative terminal supplies electrons to the N-type material. These electrons diffuse toward the junction. The positive terminal removes electrons from the P-type semiconductor, creating holes that diffuse toward the junction. If the battery voltage is great enough to overcome the junction potential (0.6V in Si), the N-type electrons and P-holes combine annihilating each other. This frees up space within the lattice for more carriers to flow toward the junction. Thus, currents of N-type and P-type majority carriers flow toward the junction. The recombination at the junction allows a battery current to flow through the PN junction diode. Such a junction is said to be forward biased. Friday, May 11, 12 Figure 2.29: (a) Forward battery bias repells carriers toward junction, where recombination results in battery current. (b) Reverse battery bias attracts carriers toward battery terminals, away from junction. Depletion region thickness increases. No sustained battery current flows. If the battery polarity is reversed as in Figure 2.29 (b) majority carriers are attracted away from the junction toward the battery terminals. The positive battery terminal attracts N-type electrons majority carriers away from the junction. The negative terminal attracts P-type majority carriers, holes away from the junction. This increases the thickness of the nonconducting depletion region. There is no recombination of majority carriers; thus, no conduction. This arrangement of battery polarity is called reverse bias. Such a device is called a diode.

Light-emitting diode

Homework 2 Solutions

. ev Friday, May 11, 12

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