Technical Information Stamolys CAHA Total Hardness Analyzer Compact photometric analysis system for total hardness measurement in drinking water systems Application Total hardness monitoring in reverse osmosis systems inlets Total hardness monitoring after ion exchange systems Monitoring of precipitant addition in drinking water treatment plants Your benefits Direct reaction in photometer at constant temperature Fast response time due to low system volume and short distances Low reagent requirement Low sample requirement Two selectable measuring ranges User-friendly interface Sample stream monitoring and plain text error menu Measured value storage using integrated data logger Automatic self-cleaning Automatic calibration With two channel version: measurement sequences programmable Two housing versions and an open version available TIC/0/en/0.0 0
Function and system design Measuring principle After sample conditioning, the analyzer sample pump conveys a part of the filtrate to a mixing vessel. The reagent pump adds reagent at a specific ratio. As a result of the reaction, the sample turns a characteristic colour. The photometer determines the sample s absorption of an emitted light at a specific wavelength (s. Fig., Pos. ). The wavelength is parameter specific. The absorption intensity is proportional to the concentration of the specified parameter in the sample (Pos. ). Additionally, the absorption of a reference light is determined to receive a genuine measuring result. The reference signal is subtracted from the measuring signal to prevent any effects due to turbidity, contamination and ageing of the LEDs. The temperature in the photometer is controlled thermostatically so that the reaction is reproducible and takes place within a short period of time. Reference LED Emitter LED Sample Reference detector Measuring detector Photometric principle C0-CA0XXx--08-00-xx-00.eps Photometric determination Interferences Complexometric method for total hardness determination By adding MgEDTA to the sample, calcium is equivalently replaced by magnesium. At ph 0 calcium, magnesium and eriochrome black T form a ruby dye. The absorption is determined at a wavelength of nm (HA-A) resp. 880 nm (HA-B). The absorption intensity is proportional to the total hardness in the sample. The reference wavelength is 0 nm (HA-A) resp. 0 nm (HA-B). No interferences up to the given concentration: Concentration [mg/l] Ion.00 Fe +.0 Fe + 0. Cu + 0. Cr + 0.0 Mn + 0.0 Zn + Endress+Hauser
Sample conditioning Micro/ultrafiltration (Stamoclean CAT0, optional) A membrane filter element is suspended directly into the wastewater basin or channel. A hose pump is located in a pump box on the basin rim.the pump creates a vacuum between the membrane and the carrier plate of the filter element. This vacuum makes the filtrate pass through the filter membrane. Suspended materials, particles, algae and bacteria are collected on the surface of the membrane. Due to alternating pumping and pause, intervals of more than one month are achieved between cleaning cycles. Parallel connection of two or four filter elements increases the sampling quantity up to approx. l/h. The hose pump pressure transports the sample to a collecting vessel near the analyzer over a distance of 0 m. For distances up to 00 m the sample is transported to the collecting vessel by means of compressed air. The analyzers suck the needed sample volume from the collecting vessel. Membrane filtration (Stamoclean CAT, optional) A sample flow of 0.8 to.8 m /h is continuously conducted through the micro filter via a pressure pipe. A part of the sample passes the filter membrane and is then conveyed to the measuring device as filtrate. Sampling is based on the cross flow filtration principle. The PTFE filter membrane separates particles with sizes > 0. µm from the filtrate. These particles are collected in front of the membrane and are washed away with the sample flow. The medium is conducted in a meander-like channel through the filter element. This results in a constantly high flow rate. The high flow rate generates the self cleaning effect. Therefore, mechanical drives for the generation of a flow at the filter surface are not necessary. Backwash filter (Stamoclean CAT, optional) A sample flow of to. m /h is permanently conveyed through the backwash filter by means of a sampling pump or a pressure pipe. The filtrate passes through the wedge wire sieve and is then transported to the measuring device. Clogging is minimised by the tangential flow of the wedge wire sieve. Automatic backwashing results in a filter operating time of several weeks. The automatic backwashing and a small compressor guarantee low-maintenance and low-energy operation. Customer specific solution Before analysis, the sample has to be conditioned and to be transported to an external or to the delivered collecting vessel. Measuring system A complete measuring system comprises: An analyzer A sample conditioning system (optionally): Micro filtration / ultra filtration Stamoclean CAT0 or Stamoclean CAT Backwash filter Stamoclean CAT Customer specific solution Collecting vessel (see product structure) Micro / ultra filtration 8 9 Hose pump box Hose pump Control unit Collecting unit (optional) Collecting vessel Overflow Analyzer Aeration basin Membrane filter 9 8 Measuring system with Stamoclean CAT0 C0-CAXXx--08-00-xx-00.eps Endress+Hauser
8 9 8 9 Stamoclean CAT Inlet Sample pump or hydraulic main Filtrate line Collecting vessel Overflow Analyzer Analyzer sample line Outlet Measuring system with Stamoclean CAT C0-CAXXx--08-00-xx-00.eps Backwash filter StamoClean CAT Compressor or compressed air Sample pump or hydraulic main Sample outlet Collecting vessel Overflow Analyzer Measuring system with StamoClean CAT C0-CA0XXx--08-00-xx-00.eps Input Measured variable Measuring ranges Wavelength Reference wavelength CaCO [mg/l, fh, dh, mmol/l, ppm] 0.... 0 mg/l CaCO (HA-A) 0.8... 80 mg/l CaCO (HA-B) nm (HA-A) 880 nm (HA-B) 0 nm (HA-A) 0 nm (HA-B) Endress+Hauser
Output Output signal Signal on alarm Load Data interface Data logger Load capacity 0/... 0 ma Contacts: limit contacts (per channel), system alarm contact optional: end of measurement (with two channel version display of channel no. available) max. 00 Ω RS C 0 data pairs per channel with date, time and measured value 00 data pairs with date, time and measured value for calibration factor determination (diagnostic tool) 0 V / V AC max. A, 0 V DC max. A Power supply Electrical connection 0V fx Photometer +V Photometer -V Photometer MP MP Analog Out Kanal Kanal Schirm/ BK 0/-0mA Channel Screen Channel F M 0. A F M 0. A Schirm COM GN 0V BK 8 0 8 Screen Schirm Schirm keine Probe NC 80 V 0 - V 9 Screen Screen BN YE I + No sample n.b. NO OR 9 V 9 WH + V WH Reserve 8 I - 0 n.c. n.b. Mess n.b. COM BK 8 V 8 YE fx 9 n.c. Meas n.c. n.b. n.b. NC RD V BU 0 +V I + 0 8 n.c. n.c. NO YE 0V BN GY 9 Status GN 0V I - 9 0V SCHRITTMOTOR STEP MOTOR LECKF. LEAK S. ALARM ALARM OPTION STÖRUNG ERROR ALARM ALARM RELAIS / Relay: max. Last / load: A bei / at /0V AC, A bei / at 0V DC Klemmen führen auch bei ausgeschaltetem Gerät Spannung!!! Terminals voltage to ground even when the unit is switched off!!! L AC Motor T 0.A F NETZ MAINS N L PE AC MOTOR Elektronik Electronics T 0.A F L N PE Connection sticker CA C0-CAxxxx-0-08-00-a-00.eps Supply voltage Power consumption Current consumption Fuses V AC / 0 V AC ±0%, 0/0 Hz approx. 0 VA approx. 0. A at 0 V approx. 0. A at V x time-lag 0. A for electronics x medium time-lag 0. A for photometer x time-lag 0. A for motors Endress+Hauser
Performance characteristics Time between two measurements Maximum measured error Measuring interval Reaction time Sample requirement Reagent requirement Calibration interval Rinse interval t mes = reaction time + rinse time + waiting time + rinse again time + filling time + sampling time + reagent refusal time (min. waiting time = 0 min) % of measuring range end (HA-A) % of measuring range end (HA-B) t mes to 0 min minutes 0 ml (0.00 US.gal.) per measurement x 0. ml (0.000 US.gal).0 l (0. US.gal) per reagent per 90 days (HA-A) resp. per days (HA-B) with a 0 minute measuring interval 0 to h 0 to h Rinse time selectable from 0 to 00 s (standard = 80 s) Rinse again time Filling time Sampling time Reagent refusal time Maintenance interval Servicing requirement 0 s s (HA-A) 0 s (HA-B) t sampling = 80 s t refusal = 0 s (HA-A) t refusal = 0 s (HA-B) months (typical) minutes per week (typical) Environment Ambient temperature... 0 C (... 0 F), avoid strong fluctuations Humidity below the condensation limit, installation in usual, clean rooms outdoor installation only possible with protective devices (customer supplied) Ingress protection IP Endress+Hauser
Process Sample temperature to 0 C ( to 0 F) Sample flow rate min. ml (0.00 US.gal.) per min Consistence of the sample low solid content (< 0 ppm) Sample inlet pressureless Sample ph value > ph (not buffered) Mechanical construction Design, dimensions Analyzer /0. Detail A 0/.8 8/. /. /0.9 Ø /.0 0/. 0/.99 /0.9 0/9.8 0/.0 9/0. /0.9 0/. 0/. 00/.9 00/.8 0/. /9. A Ø /.0 /.8 /.8 /0. /.0 /.9 9/.9 Ø /0.8 8/.0 /.8 Ø /.0 Ø /0.8 80/.8 8/. 0/. 0/8. /. mm / inch C0-CAxxx-0-08-00-en-00.eps Stainless steel version Endress+Hauser
RS 0/. Stamolys CAHA 8/. 0/9.8 0/.0 0/. 0/.99 Ø /.0 0/. 0/. 00/.9 -/ 0.8-0. (M ) 00/.8 0/. /9. /.8 /.0 /.9 9/.9 Ø /0.8 8/.0 /.8 Ø /.0 Ø / 0.8 8/. /.8 Ø /.0 Ø /0. 0/. /. /8. 00/9.9 0/. Ø /.0 mm / inch GFK version C0-CAxxx-0-08-00-en-00.eps 8/ /.8 9/0. 9/. /. /.89 Ø/0. 9/. /.80 9/0. Open version (without housing) 8/0. mm/inch C0-CAxxx-0-08-00-en-00.eps 8 Endress+Hauser
Collecting vessel 8 Collecting vessel at analyzer (optional) Ventilation Sample inlet from sampling Collecting vessel Electrical connections Analyzer sample inlet C0-CAxxx--08-00-xx-00.eps Collecting vessel dimensions * variable, freely adjustable dimensions Sampling for analyzer Analyzer outlet 8 Sample overflow C0-CAxxx-0-08-0-en-00.eps Weight GFK housing Stainless steel housing Without housing approx. 8 kg (. lb) approx. kg (.8 lb) approx. kg (0. lb) Material Housing: Front windows: Endless hose: Pump hose: Valves: Stainless steel.0 (AISI 0) or GFK Plexiglass C-Flex, Norprene Tygon, Viton Tygon Sample line connection One channel version Collecting vessel (at analyzer, with or without level measurement) Connection hose ID. mm (0.") Customer collecting vessel Connection hose ID. mm (0.0") Max. distance from collecting vessel to analyzer m (.8 ft) Max. height difference from collecting vessel to analyzer 0. m (. ft) Two channel version Depending on the ordered version, one or two collecting vessels (with or without level measurement) are included in the scope of delivery. Level measurement is only possible for one channel. Only one collecting vessel can be mounted at the housing. The second is to be placed nearby the analyzer. Sample outlet Connection Hose ID mm (0.") Max. length of closed loop: m (.8 ft) Open outlet downgrade installed No combination of several devices to a closed-loop system Min. volume per measurement 0 ml Endress+Hauser 9
Human Interface Display and operating elements M CE E K RS ENDRESS+HAUSER STAMOLYS CA CA display and operating elements LED (measured value) LC display (measured value and status) Serial interface RS Operating keys and control LEDs C0-CAxxx-9-08-00-xx-00.eps Ordering information Product structure Measuring range A Measuring range 0.... 0 mg/l CaCO B Measuring range 0.8... 80 mg/l CaCO Y Special version acc. to customer s specification Sample transfer Sample transfer from one measuring point (one-channel version) Sample transfer from two measuring points (two-channel version) Power supply 0 Power supply 0 V AC / 0 Hz Power supply V AC / 0 Hz Collecting vessel for up to analyzers A Without collecting vessel B With collecting vessel without level measurement C With collecting vessel with level measurement (one-channel version only) D With two collecting vessels without level measurement (two-channel version) Housing version Without housing With GFK housing With stainless steel.0 (AISI 0) housing Communication A 0/... 0 ma, RS Additional equipment Quality certificate Quality certificate + set of inactive reagents HA-A Quality certificate + three sets of inactive reagents HA-A Quality certificate + set of inactive reagents HA-B Quality certificate + three sets of inactive reagents HA-B CA HA - complete order code 0 Endress+Hauser
Scope of delivery! Note! The scope of delivery comprises: an analyzer with mains plug a cleaning injector a tin of silicone spray a Norprene hose, length. m (8. ft), ID. mm (0.0") a Grifflex hose, length.0 m (. ft), ID 9 mm (0.") a C-flex hose, length. m (8. ft), ID. mm (0.") two hose fittings of each size:. mm x. mm (0.0" x 0.0"). mm x. mm (0.0" x 0.") two T-hose fittings of each size:. mm x. mm x. mm (0.0" x 0.0" x 0.0"). mm x. mm x. mm (0." x 0." x 0.") an interference suppressor for the current output edge covers a quality certificate Operating Instructions (English). Please, order reagents separately with analyzer version CA XX-XXXXXX. With all other versions, inactive reagents are included in the scope of delivery. You have to mix the reagents before using them. Please, read the mixing instructions attached to the reagents. Certificates and approvals approval Declaration of conformity The product meets the legal requirements of the harmonised European standards. Endress+Hauser confirms compliance with the standards by affixing the symbol. Test reports Quality certificate Depending on the order code, you receive a quality certificate. With the certificate the manufacturer confirms compliance with all technical regulations and the successful individual testing of your product. Accessories Reagents and standard solutions Cleaner for hoses Collecting vessel Reagent set, l active reagents HA-A+HA-A each; order no. CAY8-V0AAE Reagent set, l inactive reagents HA-A+HA-A each; order no. CAY8-V0AAH Reagent set, l active reagents HA-B+HA-B each; order no. CAY9-V0AAE Reagent set, l inactive reagents HA-B+HA-B each; order no. CAY9-V0AAH Standard solution mg/l CaCO ; order no. CAY0-V0C0AAE Standard solution 0 mg/l CaCO ; order no. CAY0-V0C0AAE Standard solution 0 mg/l CaCO ; order no. CAY0-V0C0AAE Standard solution 0 mg/l CaCO ; order no. CAY0-V0C0AAE Standard solution 80 mg/l CaCO ; order no. CAY0-V0C88AAE Cleaning agent, alkaline, 00 ml; order no. CAY-V0AAE Cleaning agent, acidic, 00 ml; order no. CAY-V0AAE for sampling from pressurised systems results in an unpressurised continuous sample stream Collecting vessel without level measurement; order no. 088 Collecting vessel with level measurement (conductive); order no. 089 Endress+Hauser
Maintenance kit Maintenance kit CAV 0: set pump hoses yellow/blue set pump hoses black/black set hose connectors per hose set order no. CAV 0-C Interference suppressor for control, power and signal lines order no. 800 Silicon spray order no. 0 Valve set, pieces, for two-channel version order no. Upgrade kit for upgrading from one-channel to two-channel version order no. 0 Documentation Technical Information Stamoclean CAT0, TI 8C/0/en (order no. 089) Technical Information Stamoclean CAT, TI 9C/0/en (order no. 088) Technical Information Stamoclean CAT, TI 8C/0/en (order no. 899) International Head Quarters Endress+Hauser GmbH+Co. KG Instruments International Colmarer Str. 9 Weil am Rhein Deutschland Tel. +9 9 0 Fax +9 9 www.endress.com info@ii.endress.com TIC/0/en/0.0 0 Printed in Germany / FM+SGML.0 / DT