Final Review #4 Experiments Statistical Mechanics, Kinetic Theory Ideal Gas Thermodynamics Heat Engines Relativity

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Final Review #4 Experiments Statistical Mechanics, Kinetic Theory Ideal Gas Thermodynamics Heat Engines Relativity 8.01t December 8, 2004

Review of 8.01T Experiments

Experiment 01: Introduction to DataStudio

Position of hand motion Where is the velocity zero? Where does the magnitude of the velocity reach its maximum?

Experiment 02: Projectile Motion

Reminder on projectile motion Horizontal motion (x) has no acceleration. Vertical motion (y) has acceleration g. Horizontal and vertical motion may be treated separately and the results combined to find, for example, the trajectory or path. Use the kinematic equations for x and y motion:

Experimental setup Coordinate system Impact point: Height: h Horizontal displacement: r Theta θ>0: upward Theta θ<0: downward With chosen coordinate system: Height: y=-h Horizontal displacement: x=r Solve above equation for g:

Experiment 03: Modeling Forces

Experimental setup Measuring the magnet gap h 2 - Measure heights h 1 and h 2 h1 with your ruler, and subtract them. (h 1 will be constant.) The two magnets stuck together weigh 6.0 pennies. The plastic coin holder weighs 4.0 pennies. Enter the gap (in mm) and the total weight (in pennies) into a table in DataStudio. The gap goes in the X (left) column of the table.

Exponential fit Carry out a user-defined fit of: Record A and C for part (a) and answer question about the characteristic length l over which the force drops by a factor 1/e

Semi-log plot and linear fit II

Experiment 04: Uniform Circular Motion

Goal Study a conical pendulum and measure the force required to produce a centripetal acceleration Extract from measurement of angular frequency and r m the spring constant k and pre-tension F 0 Understand how an instability in this system occurs at a critical frequency ω 0 and how to extract ω 0 from your measurements

Analysis of conical pendulum F s From my measurements of r m, ω: θ 88 Therefore: Ignore effect of gravitation!

Fitting Perform a User-Defined fit to: A/(1-x*x/(B*B))

Experiment 05A: Static equilibrium

Goal When a weight is suspended by two strings in the center as shown in the photograph below, the tension is given as follows: H θ x Mg Goal: Measure T for several values of θ using measurements of x, H (fixed), to verify the equation above! θ T T

Analyzing data Calculate sinθ from your vertical drop measurements (see write up). Plot force on y axis, sinθ on x axis. Fit y = A/x (User-defined fit) to your data.

Experiment 06: Work, Energy and the Harmonic Oscillator

Equipment setup Use the heavy spring on the force sensor. Put two 250g weights in the cart. Clip motion sensor to other end of track, and support it on a piece of 2x4.

Measurement Results Position vs. Time: Measure maximum heights either side of 2 nd bounce, calculate loss of potential energy, and friction force. Enter in table! Force vs. Time: Expand force peak around 2 nd bounce.

Finding Acceleration Up & Down Linear fit to find a up Linear fit to find a down

Experiment 07: Momentum and Collisions

Equipment setup Use the lighter spring on the force sensor. Clip the motion sensor to the end of the track. Level the track. Place Target cart at rest about 10cm from the spring. Place Incident cart about 16-20cm from motion sensor. Note: Velcro facing = inelastic and magnets facing = elastic. Roll incident cart just hard enough to come back to its starting point. Practice this first before you take your data! Make measurements with different weights of incident and target cart.

Graph 1 Two equal mass carts A and B collide. This is X A vs. time. 1. Along line AB? 2. At point B? 3. Along line BC? 4. At point C? 5. Along line CD? At approximately what time does cart B hit the spring?

Graph 2 Two equal mass carts A and B collide. This is V A vs. time. 1. Along line AB? 2. Along line BC? 3. Along line CD? 4. Along line DE? 5. Along line EF?

Graph 3 A cart of mass 0.25kg collides with a spring on the force sensor. Here is the force during the collision. The fit is to: A*sin(2π(x-C)/T) What does the area under the curve tell you? What can you learn from the parameter T?

Experiment 08: Physical Pendulum

Goals Investigate the oscillation of a real (physical) pendulum and compare to an ideal (point mass) pendulum. Angular frequency calculation: Practice calculating moments of inertia, using them, and solving the τ = I a equation of motion.

Understanding the graphs Position vs. time data from the motion sensor. What is happening: 1. Along the top plateaus marked by A? 2. At the downward peaks marked by B? How do you use this graph to find the period of oscillation of the pendulum?

Experiment 09: Angular momentum

Measure rotor I R Plot only the generator voltage for rest of experiment. Use a 55 gm weight to accelerate the rotor. Settings: Sensitivity: Low Sample rate 500 Hz. Delayed start: None Auto Stop: 4 seconds Start DataStudio and let the weight drop.

Understand graph output to measure I R Generator voltage while measuring I. What is happening: R 1. Along line A-B? 2. At point B? 3. Along line B-C? How do you use this graph to find I R?

Measure I R results Measure and record α up and α down. For your report, calculate I R :

Experiment 10: Energy transformation

Equipment setup Mechanical equivalent to heat: A motor applies a known friction torque τ f at a known ω to a plastic c = jar with a known mass of H 2 O. τ f ω ( ) mdt dt Electrical equivalent to heat: Apply voltage (2.5V) across a resistor (2.5Ohms) and use resulting electrical heat: Resistor is connected to right pair of posts. c = VI mdt dt ( ) Digital Volt Meter How can one double the temperature increase in both setups for a fixed amount of time?

REVIEW #4 Statistical Mechanics, Kinetic Theory Ideal Gas Thermodynamics Heat Engines Relativity

Statistical Mechanics and Thermodynamics Thermodynamics Old & Fundamental Understanding of Heat (I.e. Steam) Engines Part of Physics Einstein held inviolate Relevant to Energy Crisis of Today Statistical Mechanics is Modern Justification Based on mechanics: Energy, Work, Momentum Ideal Gas model gives observed thermodynamics Bridging Ideas Temperature (at Equilibrium) is Average Energy Equipartition - as simple/democratic as possible

Equation of State A condition that the system must obey Relationship among state variables Example: Perfect Gas Law Found in 18th Century Experimentally pv = NkT = nrt K is Boltzmann s Constant 1.38x10-23 J/K R is gas constant 8.315 J/mole/K

PV = n R T = N k T chemists vs physicists Mole View (more Chemical) = nrt R is gas constant 8.315 J/mole/K Molecular View (physicists) = NkT N is number of molecules in system K is Boltzmann s Constant 1.38x10-23 J/K

Ideal Gas Law Derivation: Assumptions Gas molecules are hard spheres without internal structure Molecules move randomly All collisions are elastic Collisions with the wall are elastic and instantaneous

Gas Properties N number of atoms in volume, m mass of molecule n m moles in volume M molar is atomic mass ( 12 C = 12) mass density ρ = m T = nm m molar m A = n N m V V V Avogadro s Number N A = 6.02 10 23 molecules mole 1

Pressure of a Gas: Microscopic to Macroscopic G Pressure gas, wall 1 2 P = pressure F = ρ v A 3 Root Mean Square Velocity v = rms 3P ρ Equipartition of Energy 1 2 3 mv ave Theorem 2 ( ) = 2 kt Ideal Gas Eq. Of State nmn A kt n mrt P = = V V

Degrees of Freedom in Motion Three types of degrees of freedom for molecule 1. Translational 2. Rotational 3. Vibrational Ideal gas Assumption: only 3 translational degrees of freedom are present for molecule with no internal structure

Equipartition of Energy: Kinetic Energy and Temperature Equipartition of Energy Theorem 1 (#degrees of freedom) 3 mv ( 2 ) ave = kt = kt 2 2 2 23 1 Boltzmann Constant k = 1.38 10 J K Average kinetic of gas molecule defines kinetic temperature

Heat If two bodies are in contact but initially have different temperatures, heat will transfer or flow between them if they are brought into contact. heat is the energy transferred, given the symbol Q.

Temperature and Equilibrium Temperature is Energy per Degree of Freedom Heat flows form hotter to colder object Until temperatures are equal Faster if better thermal contact Even flows at negligible t (for reversible process) The Unit of Temperature is the Kelvin Absolute zero (no energy) is at 0.0 K Ice melts at 273.15 Kelvin (0.0 C) Fahrenheit scale is arbitrary

State Variables of System State Variables - Definition Measurable Static Properties Fully Characterize System (if constituents known) e.g. Determine Internal Energy, compressibility Related by Equation of State State Variables: Measurable Static Properties Temperature - measure with thermometer Volume (size of container or of liquid in it) Pressure (use pressure gauge) Quantity: Mass or Moles or Number of Molecules Of each constituent or phase (e.g. water and ice)

Heat and Work are Processes Processes accompany/cause state changes Work along particular path to state B from A Heat added along path to B from A Processes are not state variables Processes change the state! But Eq. Of State generally obeyed

Thermodynamic Systems T,p,V,N measured Work W on world p=0 outside Heat Q The state variables are changed only in response to Q and W No other work or heat enters

Work p, V Work W on world Piston has Area A x Find Work if piston moves x: W = F x = pa x = p V In General : f W fi = i p(v,t ) dv

Variables in First Law Q is the Heat Added Could find from Temperature Gradient But need Heat Conductivity and Area Generally determine from First Law W is the Work done by system Equal to pdv U is the Internal Energy of system It is determined by state variables From equipartition, proportional to T

Internal Energy Based on Equipartition: -each coordinate of each particle 1/2 m <v x2 > = 1/2 m <v y2 >= 1/2 k B T 1/2 µ <v rel2 > = 1/2 k B T..molecule For an ideal monatomic gas: U(T)=3/2 N k T For an ideal diatomic molecular gas: U(T)=5/2 N k T (no vibration)

Thermodynamic cycles A thermodynamic cycle is any process that brings a system back to its original state. The cycle involves a path in state space over which various processes may act. A D B C Addition/Removal of heat and work 1.0 1.5 2.0 are typical processes. Often the objective is to get work from heat or vice versa, as in a heat engine or heat pump.

Heat Engines and Efficiency HEAT in at T 2 HEAT ENGINE WORK as Mechanical E HEAT Out at T 1 Energy Conserved Q(in at T 2 ) = W cycle + Q(out at T 1 ) W cycle Heat Engine Efficiency: ε = Q(in at T2 )

Reversibility of Cycle We showed that any leg of this cycle is reversible. Therefore, the entire cycle (heat engine) could operate in reverse In this case the total Work and the Heat flow will be reversed. 1.0 1.5 2.0 Operated in reverse it is a refrigerator that removes heat at the lower temperature A D T 1 T 2 B C Or a heat pump delivering heat at the temperature T 2

Why Carnot is Maximum Say a heat engine exceeded Carnot Limit W HEAT Q 2 ENGINE Q 1 W net W Q 1 HEAT PUMP Q 2 Q env Hook it to a perfect gas heat pump with the same T 1 Net Effect: Heat Q env becomes work W net

Second law of Thermodynamics No process shall have the only result that Heat is turned into Work or No process shall have the only result that Heat is transferred from cooler to hotter. The second law is the formal statement of the irreversibility of Nature on a classical scale: friction can irreversibly convert mechanical energy into heat; nothing can reverse this process.

Postulates of Relativity Relativity Postulate: All inertial frames are equivalent with respect to all the laws of physics. Speed of Light Postulate: The speed of light in empty space always has the same value c. This is really special case of Relativity Postulate since Maxwell s Eqn s predict speed of light.

Alternative Synchronization two identical clocks that are at rest in a reference frame at different spatial points will run at identical rates. a lamp at the origin emits a pulse of light at time. Every point in space has a clock that will begin running when the light pulse reaches it. Each clock has been pre-set to the time t = d/c where d is the distance from the clock to the origin and is the speed of light. When the light pulse reaches the clock, it begins to run at the same identical rate as all the other clocks. All the clocks are now synchronized (also according to Einstein s definition) Only good in that coordinate frame

The Relativity of Simultaneity Events that a synchronous in one reference frame are not synchronous in another reference frame Simultaneous flashes on the train aren t simultaneous To an observer at rest on ground

Causality If event A causes event B, it must be observed to occur before B in any and all reference frames. The time ordering cannot be reversed! If a light pulse from A reaches B before event B occurs, then all observers will observe that event A happened first. Such events have timelike separation Events that are not timelike are spacelike

Time Dilation Moving clocks run slow. Time interval t between two space-time events measured by muon clock in frame in which muon clock is moving dilates compared to same time as measured in frame in which muon clock is at rest t = γ t γ = 1/ (1 v 2 / c 2 )

Testing E=mc 2 (by weighing γ-rays) n + 32 S 33 S + γ 10 3 M( 32 S ) + M(n) M( 33 S ) = ( ) c 2 ( ) N A hc * λ m =? h c λ We measured 29 Si NIST measured λ s and 33 S ( ) + _ E/mc 2-1 = -2.5 3.3 X 10-7 Combined error X40 improvement of direct tests

If E = mc 2 Special Relativity results from the relativity postulate and observation of a limiting velocity, c. If E = mc 2 possibly: Yes, there is a preferred frame Michelson-Morley, Hughes-Drever look for anisotropy and place limits assuming CMB is preferred frame. (see M.P. Haugan and C.M. Will, Physics Today, May 1987) c doesn t equal c light Limited since high energy protons not radiating Cherenkov radiation Einstein s logic faulty Unlikely; it s been widely checked Our experiments are wrong We were very careful to check systematics BEFORE comparing with NIST New physics in our experiments There is no evidence from our experiment

Newtonian Mechanics Explain and predict phenomena ranging from scale of 100 s atoms to Intergalactic distances Theory built on Two Foundations 1. Principles of Dynamics embodied in the concept of Force Laws (based on experiments) and Newton s Three Laws of Motion 2. Conservation Laws: Momentum, Energy, and Angular Momentum

Constants and Fundamental Scales 1. Speed of Light 8 c = 2.99792458 10 m s -1 2. Universal Gravitational Constant G = 6.6726 10 3. Boltzmann s Constant 11 N m 2 kg -2 4. Planck s Constant 2 k = 1.3806503 10 23 kg m s -2 K -1 34 2 h = 6.626068 10 kg m s -1

Fundamental Scales: Planck Mass Mass dim 12 hc G = 2 (time) 3 ( mass )(length) (length / ) 3 12 = ( mass ) ( mass )(time) 2 34-1 -1 ) 2 hc 12 (6.626068 10 kg m 2 8 s )( 2.998 10 m s 1 11-2 ) G = (6.6726 10 N m 2 kg = 5.456 10 8 kg

Fundamental Scales: Planck Time Time hc dim = G 2 12 3 (mass)(length) (length / ) 3 12 (time ) (mass )(time ) 2 = (mass ) (time) dim G hc 12 12 G hg dim = 3 = dim = 5 (time) 3 c (mass) c G c hg 12 (6.626068 10 34 kg m 2 s -1 )(6.6726 10 11 N m 2 kg -2 ) = 5 c 8-1 5 (2.998 10 m s ) 12 = 1.35 10 43 s

Fundamental Scales: Planck Length Length dim G 2 3 hc 12 = ( mass )(length) (length / ) 3 (time ) (mass )(time ) 2 12 = (mass ) G (length) hg 12 dim = dim = length 2 3 c (mass) c hg 12 34-1 11-2 ) (6.626068 10 kg m 2 s )(6.6726 10 N m 2 kg = 3 c 8 (2.998 10 m s -1 3 ) 12 = 4.071 10 35 m

Fundamental Scales: Planck Temperature G hc 12 hg Temperature dim 3 = dim = (time ) 5 12 c G c dim[h / k ] = (energy)(time)/ -1 (energy) (temp ) = (time)(temp) 12 h G hc dim[ / k c 3 ] = (temp) G h G hc / k c 3 G 12 = 3.55499 10 32 K

Limits of Newtonian Mechanics Special Relativity: Rapidly moving objects when v/c 1 Quantum Mechanics: Atomic and Molecular Scales General Relativity: Non-Euclidian Structure of Universe Statistical Mechanics: Large Number of Particles Classical Chaos: Initial Conditions don t predict future Quantized Gravity: String Theory, Planck Length: