Unit 4: The Nature of Matter

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16

16 Table of Contents Unit 4: The Nature of Matter Chapter 16: Solids, Liquids, and Gases 16.1: Kinetic Theory 16.2: Properties and Fluids 16.3: Behavior of Gases

16.1 Kinetic Theory Kinetic Theory kinetic theory is an explanation of how particles in matter behave.

16.1 Kinetic Theory Kinetic Theory All matter is composed of small particles (atoms, molecules) These particles are in constant, random motion.

16.1 Kinetic Theory Thermal Energy and the Kinetic Theory Thermal energy- The total energy of a material s particles High Temp = High Thermal energy particles move faster Low Temp = Low Thermal Energy particles move slowly

16.1 Kinetic Theory Average Kinetic Energy In science, temperature means the average kinetic energy of particles in the substance, or how fast the particles are moving. On average, molecules of frozen water at 0 C will move slower than molecules of water at 100 C.

16.1 Kinetic Theory Average Kinetic Energy Water molecules at 0 C have lower average kinetic energy than the molecules at 100 C. Molecules will have kinetic energy at all temperatures, including absolute zero.

16.1 Solid State Kinetic Theory The particles closely packed together. Have a fixed shape and volume Particles still vibrate

16.1 Liquid State Kinetic Theory What happens to a solid when thermal energy or heat is added to it? The particles vibrate faster until they have enough energy to overcome the attractive forces liquid Have fixed volume not fixed shape!

16.1 Liquid State Kinetic Theory melting point - Temp at which a solid begins to liquefy. A.K.A. - Heat of fusion

16.1 Liquid Flow Kinetic Theory Particles in a liquid have more kinetic energy than particles in a solid.

16.1 Liquid Flow This extra kinetic energy allows particles to partially overcome the attractions to other particles. Kinetic Theory

16.1 Liquid Flow Kinetic Theory Thus, the particles can slide past each other, allowing liquids to flow and take the shape of their container.

16.1 Liquid Flow Kinetic Theory However, the particles in a liquid have not completely overcome the attractive forces between them This causes the particles to cling together, giving liquids a definite volume.

16.1 Gas State Kinetic Theory Gas particles have enough kinetic energy to overcome the attractions between them. Do not have a fixed volume or shape. Therefore, they can spread far apart or contract to fill the container that they are in.

16.1 Gas State Kinetic Theory Some particles are moving faster and have more kinetic energy than others. The particles that are moving fast enough can escape the attractive forces of other particles and enter the gas state. Click image to view movie

16.1 Gas State Kinetic Theory Vaporization- particles are moving fast enough to escape the attractive forces evaporation and boiling.

16.1 Gas State Kinetic Theory Boiling point - Temperature at which the liquid starts to boil. A.K.A. - Heat of vaporization Click image to view movie

16.1 Gas State Kinetic Theory Pressure of the vapor in the liquid is equal to the external pressure acting on the surface of the liquid.

16.1 Kinetic Theory Gases Fill Their Container Diffusion - Spreading of particles throughout a given volume until they are uniformly distributed.

16.1 Kinetic Theory Thermal Expansion The kinetic theory also explains other characteristics of matter in the world around you. Have you noticed the seams in a concrete driveway or sidewalk? These separation lines are called expansion joints.

16.1 Kinetic Theory Thermal Expansion When concrete absorbs heat, it expands. Then when it cols, it contracts. If expansion joints are not used, the concrete will crack when the temperature changes.

16.1 Kinetic Theory Expansion of Matter Particles move faster and separate as the temperature rises. This separation of particles results in an expansion of the entire object, known as thermal expansion. Thermal expansion Increase or decrease in the size of a substance when the temperature is increased or decreased.

16.1 Kinetic Theory Expansion of Matter Increase Temp Increased particle movement Increase in sizes Decrease Temp Decrease particle movement Decrease in size Examples: Solid? Liquid? Gas?

16.1 Kinetic Theory Expansion in Liquids A common example of expansion in liquids occurs in thermometers. The addition of energy causes the particles of the liquid in the thermometer to move faster.

16.1 Kinetic Theory Expansion in Gases Hot-air balloons are able to rise due to thermal expansion of air. The air in the balloon is heated, causing the distance between the particles in the air to increase.

16.1 Kinetic Theory Expansion in Gases As the hot-air balloon expands, and becomes less dense causing the balloon to rise

16.1 Section Check Question 1 What are the three assumptions of the kinetic theory?

16.1 Section Check Answer The three assumptions are that all mater is composed of small particles, these particles are in constant random motion, and these particles are colliding with each other and with the walls of their containers.

16.1 Section Check Question 2 What is the difference between thermal energy and temperature?

16.1 Section Check Answer Thermal energy is the total amount of kinetic and potential energy of a materials particles; temperature is a measure of the average kinetic energy of a material s particles.

16.1 Section Check Question 3 The temperature at which a solid begins to liquefy is called its. A. boiling point B. heat of fusion C. heat of vaporization D. melting point

16.1 Section Check Answer The answer is D. The heat of fusion is the amount of energy required; melting point is a temperature.

16.2 Properties of Fluids How do ships float? Despite their weight ships are able to float.

16.2 Properties of Fluids How do ships float? Buoyancy is the ability of a fluid a liquid or a gas to exert an upward force on an object immersed in it. If the buoyant force is less than the object s weight, the object will sink.

16.2 Properties of Fluids Archimedes Principle Archimedes Principle buoyant force on an object is equal to the weight of the fluid displaced by the object.

16.2 Density Properties of Fluids An object will float if its density is less than the density of the fluid it is placed in.

16.2 Density Properties of Fluids

16.2 Properties of Fluids Pascal s Principle Pressure is force exerted per unit area. Pascal s Principle- pressure applied to a fluid is transmitted throughout the fluid. Examples:

16.2 Properties of Fluids Pascal s Principle

16.2 Properties of Fluids Applying the Principle

16.2 Properties of Fluids Bernoulli s Principle Bernoulli s principle- as the velocity of a fluid increases, the pressure exerted by the fluid decreases. Examples

16.2 Properties of Fluids Bernoulli s Principle The velocity of the air you blew over the top surface of the paper is greater than that of the quiet air below it.

16.2 Properties of Fluids Bernoulli s Principle

16.3 Fluid Flow Properties of Fluids Viscosity- The resistance to flow by a fluid is called.

16.2 Fluid Flow Properties of Fluids flowing particles are pulling the other particles, causing them to flow High viscosity= Low Flow, Thick Low viscosity= High flow, Thin

16.2 Section Check Question 1 If the buoyant force on an object in a fluid is less than the object s weight, the object will. A. be propelled forward B. expand C. float D. sink

16.2 Section Check Answer The answer is D. Buoyancy is the ability of a fluid to exert an upward force on an object immersed in it.

16.2 Section Check Question 2 Why can a steel ship float in water if a steel block with the same mass sinks?

16.2 Section Check Answer The reason the steel ship can float is because its mass takes up a larger volume, so its density is less than that of the steel block, and less than the density of water.

16.2 Section Check Question 3 According to Pascal s principle, applied to a fluid is transmitted throughout the fluid. A. density B. pressure C. temperature D. volume

16.2 Section Check Answer The answer is B. Pressure is a force exerted per unit area. Pressure applied to a fluid is transmitted throughout the fluid

16.3 Pressure is the amount of force exerted per unit of area, or P = F/A. Pressure Behavior of Gases They remain inflated because of collisions the air particles have with the walls of their container.

16.3 Pressure Behavior of Gases Pascal Unit of Pressure (Pa) 1 Pascal = 1 Newton per square meter or 1 N/m 2

16.3 Pressure Behavior of Gases At sea level, atmospheric pressure is 101.3 kpa. At Earth s surface, the atmosphere exerts a force of about 101,300 N on every square meter about the weight of a large truck.

16.3 Boyle s Law Behavior of Gases Boyle s law- Decrease size of container Increases Pressure Increase size of container Decrease Pressure ***Temperature must remain constant***

16.3 Boyle s Law Behavior of Gases

16.3 Behavior of Gases Boyle s Law in Action P 1 V 1 = P 2 V 2. P- pressure in container V- volume in container

16.3 Behavior of Gases The Pressure-Temperature Relationship Temp vs. Pressure

16.3 Charles s Law Behavior of Gases Charles s law- Volume of a gas increases with increasing temperature, as long as pressure does not change

16.3 Charles s Law Behavior of Gases

16.3 Behavior of Gases Using Charles s Law V 1 /T 1 = V 2 /T 2 V- Volume of gas T- Temperature of gas The pressure must be the same Temperature in Kelvin (add 273 to C )

16.3 Section Check Question 1 Compare Boyle s law to Charles law.

16.3 Section Check Answer Boyle s law relates the pressure of a gas to its volume at constant temperature. As volume increases, the pressure decreases; the reverse is also true. Charles law relates the volume of a gas to its temperature at a constant pressure. As the temperature of a gas increases, its volume also increases.

16.3 Section Check Question 2 What would be the resulting volume of a 3.0-L balloon at 25.0º C that was placed in a container of ice water at 4.0º C, if pressure is constant? A. 2.8 L B. 3.0 L C. 4.8 L D. 5.0 L

16.3 Section Check Answer The answer is A. Use the formula that relates volume to temperature given in Kelvin, V 1 /T 1 = V 2 /T 2. In this case, V 1 = 3.0 L, T 1 = 25.0º C + 273 = 298º K, T 2 = 4.0º C + 273 = 277º K. Solving for V 2 gives 2.8 L.

16.3 Section Check Question 3 The SI unit of pressure is the, which is N/m 2 A. coulomb B. tesla C. Watt D. pascal

16.3 Section Check Answer The answer is D. The SI unit of pressure is the Pascal; pressures are often given in kilopascals.

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