First Quarter 2016 Report Sudbury, Ontario Submitted to: Vale Canada Limited Submitted by: Amec Foster Wheeler Environment & Infrastructure 131 Fielding Road Lively, Ontario P3Y 1L7 9 Amec Foster Wheeler Project number: TY156006
9 Amec Foster Wheeler Project Number: TY156006 Vale Canada Limited General Engineering Building Copper Cliff, Ontario P0M 1N0 Re: First Quarter 2016 Report Particulate Monitoring Power Street, Union Street, Venice Street, Norite Street, Copper Cliff Creek, Delki Dozzi, Spruce Street, and Dynamic Earth Sampling Stations Copper Cliff, Ontario Amec Foster Wheeler Environment & Infrastructure is pleased to submit the first quarter (Q1) 2016 report to Vale Canada Limited (Vale). The report presents Total Suspended Particulate (TSP) and Inhalable Particulate (PM 10) matter and metals concentration results obtained from particulate samples collected at the Power Street, Union Street, Venice Street, Norite Street, Copper Cliff Creek, Delki Dozzi, Spruce Street, and Dynamic Earth sampling stations. Please contact Pamela Koski at your convenience, if you have any questions about the report. Sincerely, Amec Foster Wheeler Environment & Infrastructure, a Division of Amec Foster Wheeler Americas Limited Pamela Koski, MSc. Environmental Scientist Steve Lamming PhD EP Principal, Air Quality Amec Foster Wheeler Environment & Infrastructure 131 Fielding Road Lively, Ontario, CANADA P3Y 1L7 Phone 705.682.2632 Fax 705.682.2260 www.amecfw.com
Table of Contents Section Page 1.0 SAMPLING PROGRAM OVERVIEW... 1 2.0 SAMPLING RESULTS... 1 3.0 FLOW CALIBRATION CHECKS AND AUDITS... 3 4.0 CLOSURE... 4 LIST OF TABLES Table 1: Summary of Data Recovery... 1 Table 2: Summary Statistics for TSP and PM 10Concentrations... 2 LIST OF APPENDECES Appendix A Appendix B Appendix C Sampling Results Hivol flow calibration Certificate Ministry of the Environment and Climate Change Audit Reports Amec Foster Wheeler Project No.: TY156006 Page ii
1.0 SAMPLING PROGRAM OVERVIEW Vale Canada Limited s (Vale) TSP Hi-Vol ambient air monitoring stations operate on a 3-day sampling schedule. This includes the Dynamic Earth, Norite Street, Venice Street, Copper Cliff Creek, Union Street, Spruce Street, Delki Dozzi and Power Street stations. All filters are subsequently analyzed for metal content. The PM 10 Hi-Vol ambient air monitors are co-located at Dynamic Earth, Norite Street, Venice Street, Copper Cliff Creek and Union Street stations. These monitors operate on a 6-day sampling schedule. Similarly, all filters are analyzed for metal content. The metal list for both size fractions comprise arsenic, cadmium, chromium, cobalt, copper, iron, lead, manganese, nickel, selenium, vanadium and zinc. The analysis also includes sulphur. Each sample consists of a 24-hour (midnight to midnight) period that operates concurrent to the National Air Pollution Surveillance (NAPS) schedule. 2.0 SAMPLING RESULTS The results of the samples at each of the eight (8) monitoring sites are presented in the following section. Table 1 outlines the data recovery efficiencies of each site (all monitors combined). Table 1: Summary of Data Recovery Station Total Number of Samples Total Number of Valid Samples Percentage of Valid Samples Dynamic Earth 47 45 96 Norite Street 47 46 98 Venice Street 47 45 96 Copper Cliff Creek 47 47 100 Union Street 47 45 96 Spruce Street 31 30 97 Delki Dozzi 31 30 97 Power Street 31 30 97 Total 328 318 97 Amec Foster Wheeler Project No.: TY156006 Page 1
During this quarter, a total of 318 valid samples were collected from a possible total of 328 samples. Therefore, a total of 10 samples were invalid. Eight (8) samples were lost due to flows which fell outside the valid range; one (1) at Power Street, two (2) at Venice Street, one (1) at Norite Street, one (1) at Delki Dozzi, one (1) at Spruce Street and two (2) at Dynamic Earth. Two (2) samples were lost due to motor failure at Union Street. The overall sample recovery for the quarter was 97%. The invalid sample flow rates were due to issues with either the mass flow controllers and/or the brushless motors during operation. If the units were unable to stabilize, the suspect flow controllers and/or motors were either replaced (or repaired) or the flow controller was readjusted to the required flow rate. Measured TSP results were compared to their applicable Schedule 3 Standards under O.Reg. 419/05 or guidelines, as noted in MOE document PIBS #6569e, titled Summary of Standards and Guidelines to support Ontario Regulation 419: Air Pollution Local Air Quality (including Schedule 6 of O. Reg. 419 on Upper Risk Thresholds). The PM 10 size fraction was compared to the Ambient Air Quality Criteria (AAQC). Table 2 outlines the statistics for the collected samples from each site and particulate size fraction. A full summary of the Q1 results (from all samples) is provided in Appendix A of the report. Table 2: Summary Statistics for TSP and PM 10 Concentrations Station Geometric Arithmetic % Data Number of Maximum Mean Mean Limit Recovery Values in (µg/m 3 ) (µg/m 3 ) (µg/m 3 ) (µg/m 3 ) (%) Exceedance Power Street Union Street TSP 13 23 132 120 97 1 (TSP) TSP 8 10 25 120 94 0 PM 10 5 9 30 50 100 0 Venice Street TSP 10 13 35 120 94 0 PM 10 4 5 15 50 100 0 Norite Street Copper Cliff Creek TSP 5 8 29 120 97 0 PM 10 5 7 19 50 100 0 TSP 8 13 62 120 100 0 PM 10 7 10 36 50 100 0 Amec Foster Wheeler Project No.: TY156006 Page 2
Station Geometric Arithmetic % Data Number of Maximum Mean Mean Limit Recovery Values in (µg/m 3 ) (µg/m 3 ) (µg/m 3 ) (µg/m 3 ) (%) Exceedance Delki Dozzi Spruce Street Dynamic Earth TSP 8 11 54 120 97 0 TSP 9 13 49 120 97 0 TSP 16 23 122 120 97 1 (TSP) PM 10 11 15 60 50 94 1 (PM10) There were two (2) exceedances of the Schedule 3 Standard for TSP. These exceedances took place on 4 January 2016, at the Power Street sampling station and on 18 February 2016, at the Dynamic Earth sampling station. In addition, there was one (1) exceedance of the interim 24-hour Ambient Air Quality Criterion (AAQC) for PM 10. This exceedance took place on 18 February 2016, at the Dynamic Earth Sampling station. Evidence suggests that the road sand/salt was a contributing factor to the high level of PM concentrations found at these specific sampling stations, during these sampling dates. There were no other exceedances of the Schedule 3 Standards, Section 20 Guidelines, and Schedule 6 Upper Risk Thresholds (URTs) listed in O.Reg.419/05. There were also no other exceedances of the interim 24-hour AAQC for PM 10. Please note that all iron (total) results have been conservatively expressed as ferric oxide, since it is difficult to determine the amount of iron that has been oxidized. Iron is not present as metallic iron but a small portion of the metallic iron is assumed to be oxidized. Therefore, the iron results are conservatively compared to the Fe 2O 3 Schedule 3 standard for information purposes only. 3.0 FLOW CALIBRATION CHECKS AND AUDITS Amec Foster Wheeler staff performed a flow calibration check on the air samplers on 3 March 2016, using a BGI direct reading hivol electronic flow calibrator. The calibrator was received from the manufacturer certified to an overall accuracy of 0.60%. A copy of the calibration certificate is provided in Appendix B. All samplers were found to operate within acceptable tolerances at the time of the calibration. The Ontario Ministry of the Environment and Climate Change (MOECC) performed a flow check audit on September 28 th, 2015. All samplers, except for the Power Street TSP, Union street PM 10, Norite Street TSP and Dynamic Earth PM 10 samplers, were found to operate within acceptable tolerances. A data correction was done on the data collected at the failed sites between our flow calibration in September 2015 and the MOECC audit. These sampling dates included September 24 th and September 27 th 2016. The MOECC audit reports are provided in Appendix C. Amec Foster Wheeler Project No.: TY156006 Page 3
4.0 CLOSURE We trust that the information presented in this report meets your requirements. Should you have any questions, or concerns, please do not hesitate to contact the undersigned. Sincerely, Amec Foster Wheeler Environment & Infrastructure, a Division of Amec Foster Wheeler Americas Limited Pamela Koski M.Sc. Environmental Scientist Steve Lamming PhD EP Principal, Air Quality Amec Foster Wheeler Project No.: TY156006 Page 4
APPENDIX A SAMPLING RESULTS Amec Foster Wheeler Project No.: TY156006
All non detectable results were reported as 1/2 the detection limit Cells in RED indicate an exceedance Power Street Monitoring Results for TSP and Metals (results expressed in µg/m 3 ) TSP As Cd Cr Co Cu Fe(Fe2O3) Pb Mn Ni Se S V Zn SO4 Sch. 3/Guideline (µg/m3) 120 0.3 0.025 1.5 0.1 50 25 0.5 2.5 2.0 10-2.0 120 - January 1, 2016 6 0.002 0.001 0.005 0.001 0.009 0.107 0.001 0.002 0.010 0.003 0.520 0.002 0.011 1.560 January 4, 2016 132 0.004 0.001 0.013 0.015 0.322 4.440 0.010 0.034 0.242 0.003 1.020 0.002 0.036 3.060 January 7, 2016 11 0.002 0.001 0.007 0.001 0.015 0.281 0.003 0.005 0.010 0.003 0.540 0.002 0.018 1.620 January 10, 2016 11 0.002 0.001 0.006 0.001 0.028 0.302 0.003 0.002 0.018 0.003 0.150 0.002 0.013 0.450 January 13, 2016 8 0.002 0.001 0.003 0.003 0.054 0.798 0.005 0.013 0.035 0.003 0.150 0.002 0.029 3.540 January 16, 2016 2 0.002 0.001 0.006 0.001 0.020 0.139 0.001 0.011 0.003 0.165 0.150 0.002 0.009 0.450 January 19, 2016 8 0.002 0.001 0.007 0.001 0.021 0.352 0.007 0.020 0.003 0.165 0.150 0.002 0.012 0.450 January 22, 2016 19 0.002 0.001 0.023 0.002 0.053 0.505 0.005 0.026 0.003 0.380 0.380 0.002 0.015 1.140 January 25, 2016 17 0.002 0.001 0.021 0.001 0.015 0.231 0.004 0.007 0.003 1.380 1.380 0.002 0.021 4.140 January 28, 2016 8 0.002 0.001 0.014 0.003 0.046 0.166 0.002 0.072 0.003 0.600 0.600 0.002 0.012 1.800 January 31, 2016 5 0.002 0.001 0.014 0.001 0.018 0.087 0.001 0.012 0.003 0.360 0.360 0.002 0.012 1.080 February 3, 2016 8 0.002 0.001 0.016 0.002 0.030 0.447 0.002 0.004 0.019 0.003 0.510 0.002 0.027 1.530 February 6, 2016 6 0.002 0.001 0.012 0.001 0.015 0.134 0.001 0.002 0.020 0.003 0.490 0.002 0.010 1.470 February 9, 2016 11 0.002 0.001 0.006 0.001 0.049 0.277 0.005 0.002 0.032 0.003 0.470 0.002 0.010 1.410 February 12, 2016 10 0.002 0.001 0.005 0.001 0.020 0.201 0.001 0.003 0.013 0.003 0.155 0.002 0.019 0.465 February 15, 2016 3 0.002 0.002 0.007 0.001 0.011 0.089 0.001 0.001 0.007 0.003 0.370 0.002 0.009 1.110 February 18, 2016 Invalid Flow February 21, 2016 13 0.002 0.001 0.007 0.001 0.025 0.329 0.001 0.003 0.015 0.003 0.150 0.002 0.008 0.450 February 24, 2016 94 0.009 0.002 0.013 0.008 0.419 2.593 0.019 0.025 0.208 0.003 1.420 0.002 0.088 4.260 February 27, 2016 8 0.002 0.001 0.043 0.001 0.040 0.143 0.005 0.003 0.016 0.003 0.580 0.002 0.011 1.740 March 1, 2016 9 0.002 0.001 0.047 0.001 0.031 0.278 0.006 0.002 0.023 0.003 0.400 0.002 0.013 1.200 March 4, 2016 25 0.002 0.001 0.022 0.004 0.106 0.747 0.007 0.007 0.114 0.003 0.700 0.002 0.017 2.100 March 7, 2016 22 0.002 0.001 0.057 0.001 0.046 0.688 0.008 0.006 0.027 0.003 1.320 0.002 0.025 3.960 March 10, 2016 10 0.005 0.001 0.005 0.002 0.087 0.654 0.006 0.004 0.066 0.003 0.340 0.002 0.013 1.020 March 13, 2016 61 0.007 0.001 0.007 0.012 0.415 2.797 0.014 0.018 0.129 0.003 0.660 0.002 0.023 1.980 March 16, 2016 18 0.002 0.001 0.003 0.003 0.067 0.711 0.002 0.005 0.024 0.003 0.150 0.002 0.011 0.450 March 19, 2016 82 0.005 0.001 0.008 0.009 0.346 4.574 0.013 0.026 0.167 0.007 0.790 0.002 0.042 2.370 March 22, 2016 32 0.009 0.001 0.004 0.010 0.255 1.540 0.042 0.009 0.207 0.003 0.430 0.002 0.017 1.290 March 25, 2016 19 0.002 0.001 0.021 0.002 0.048 0.622 0.003 0.005 0.030 0.003 0.500 0.002 0.013 1.500 March 28, 2016 24 0.002 0.001 0.022 0.003 0.070 1.589 0.004 0.010 0.076 0.003 0.700 0.002 0.021 2.100 March 31, 2016 7 0.008 0.001 0.020 0.002 0.093 0.495 0.018 0.002 0.063 0.003 0.500 0.002 0.014 1.500 Guideline - Point of Impingement Gui (1) Ferric oxide values are presented for informational purposes only; ferric oxide was calculated from elemental iron (total Fe) assuming the Fe to be oxidized * O. Reg.419/05 schedule 3, 24-hour standard; note that the URT (under schedule 6) for cadmium and its compounds is 0.025 µg/m3 and Nickel is 2 µg/m3 A "-" in the Fe(Fe2O3) indicates there was a ND for Fe for that sample and thus a value for Fe(Fe2O3) can not be calculated. Standard * 120 n/a 0.025 n/a n/a 50 25 0.5 n/a 3 n/a n/a 2 120 n/a No. > Sch. 3 value * 1 n/a 0 n/a n/a 0 0 n/a n/a 0 n/a n/a 0 0 n/a Guideline n/a 0.3 n/a 1.5 0.1 n/a n/a n/a 2.5 n/a 10 n/a n/a n/a n/a No. > guideline n/a 0 n/a 0 0 n/a n/a n/a 0 n/a 0 n/a n/a n/a n/a Geometric mean 13.5 0.002 0.001 0.011 0.002 0.048 0.457 0.004 0.007 0.023 0.008 0.430 0.002 0.016 1.382 Arithmetic mean 22.9 0.003 0.001 0.015 0.003 0.092 0.877 0.007 0.011 0.053 0.104 0.535 0.002 0.019 1.707 Max. concentration 132.0 0.009 0.002 0.057 0.015 0.419 4.574 0.042 0.072 0.242 1.380 1.420 0.002 0.088 4.260 Min. concentration 1.5 0.002 0.001 0.003 0.001 0.009 0.087 0.001 0.001 0.003 0.003 0.150 0.002 0.008 0.450 No. of valid samples 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 No. samples < mdl 1 23 28 0 10 0 2 0 0 3 6 30 0 0 Detection limit 3.0 0.0036 0.0012 0.0032 0.0012 0.0012-0.0018 0.0006 0.0018 0.0060 0.2800 0.0060 0.0033 - Half detection limit 1.5 0.0018 0.0006 0.0016 0.0006 0.0006-0.0009 0.0003 0.0009 0.0030 0.1400 0.0030 0.0017 - % < detection limit 3 77 93 0 33 0-7 0 0 10 20 100 0 - % valid data 97 97 97 97 97 97 97 97 97 97 97 97 97 97 97 Amec Foster Wheeler Project No.: TY156006 Page 6
All non detectable results were reported as 1/2 the detection limit Cells in RED indicate an exceedance Union Street Monitoring Results for TSP and Metals (results expressed in µg/m 3 ) TSP As Cd Cr Co Cu Fe(Fe2O3) Pb Mn Ni Se S V Zn SO4 Sch. 3/Guideline (µg/m3) 120 0.3 0.025 1.5 0.1 50 25 0.5 2.5 2.0 10-2.0 120 - January 1, 2016 5 0.002 0.001 0.004 0.001 0.009 0.113 0.001 0.002 0.007 0.003 0.580 0.002 0.008 1.740 January 4, 2016 19 0.002 0.001 0.008 0.002 0.054 0.417 0.004 0.005 0.046 0.003 0.480 0.002 0.010 1.440 January 7, 2016 12 0.002 0.001 0.007 0.001 0.014 0.267 0.005 0.005 0.011 0.003 0.590 0.002 0.018 1.770 January 10, 2016 7 0.004 0.001 0.006 0.002 0.072 0.326 0.007 0.002 0.070 0.012 0.600 0.002 0.023 1.800 January 13, 2016 4 0.013 0.001 0.007 0.002 0.096 0.238 0.011 0.002 0.045 0.007 0.440 0.002 0.010 1.320 January 16, 2016 2 0.002 0.001 0.006 0.001 0.043 0.092 0.002 0.001 0.008 0.003 0.150 0.002 0.002 0.450 January 19, 2016 2 0.002 0.001 0.006 0.001 0.006 0.061 0.004 0.001 0.003 0.003 0.150 0.002 0.002 0.450 January 22, 2016 5 0.002 0.001 0.019 0.001 0.025 0.162 0.001 0.001 0.016 0.003 0.150 0.002 0.002 0.450 January 25, 2016 12 0.005 0.001 0.019 0.001 0.042 0.168 0.006 0.002 0.019 0.014 1.280 1.280 0.002 3.840 January 28, 2016 5 0.002 0.001 0.011 0.001 0.042 0.146 0.005 0.002 0.036 0.003 0.470 0.470 0.002 1.410 January 31, 2016 4 0.002 0.001 0.013 0.002 0.029 0.069 0.004 0.001 0.027 0.003 0.450 0.450 0.002 1.350 February 3, 2016 8 0.015 0.002 0.015 0.006 0.364 0.894 0.037 0.002 0.136 0.021 1.170 0.002 0.023 3.510 February 6, 2016 6 0.002 0.001 0.011 0.001 0.043 0.142 0.001 0.002 0.026 0.003 0.460 0.002 0.008 1.380 February 9, 2016 6 0.002 0.001 0.007 0.003 0.137 0.474 0.008 0.002 0.119 0.003 0.690 0.002 0.014 2.070 February 12, 2016 5 0.002 0.001 0.007 0.001 0.030 0.200 0.002 0.003 0.022 0.003 0.420 0.002 0.009 1.260 February 15, 2016 7 0.002 0.001 0.013 0.001 0.094 0.158 0.004 0.002 0.040 0.003 0.610 0.002 0.010 1.830 February 18, 2016 25 0.002 0.001 0.015 0.005 0.089 0.635 0.015 0.007 0.083 0.003 0.550 0.002 0.011 1.650 February 21, 2016 6 0.002 0.001 0.007 0.001 0.019 0.192 0.001 0.002 0.011 0.003 0.330 0.002 0.005 0.990 February 24, 2016 February 27, 2016 March 1, 2016 10 0.002 0.001 0.051 0.001 0.074 0.293 0.005 0.002 0.037 0.003 0.520 0.002 0.014 1.560 March 4, 2016 11 0.002 0.001 0.023 0.002 0.027 0.310 0.004 0.005 0.028 0.003 0.520 0.002 0.012 1.560 March 7, 2016 13 0.002 0.001 0.049 0.004 0.065 0.438 0.010 0.004 0.077 0.003 1.180 0.002 0.015 3.540 March 10, 2016 4 0.002 0.001 0.011 0.001 0.035 0.212 0.001 0.003 0.045 0.003 0.150 0.002 0.015 0.450 March 13, 2016 19 0.031 0.001 0.014 0.009 0.594 1.667 0.034 0.007 0.259 0.026 1.380 0.002 0.021 4.140 March 16, 2016 20 0.060 0.001 0.007 0.010 0.812 2.098 0.061 0.006 0.273 0.046 2.360 0.002 0.031 7.080 March 19, 2016 21 0.004 0.001 0.007 0.004 0.251 1.712 0.006 0.008 0.112 0.003 0.420 0.002 0.013 1.260 March 22, 2016 19 0.007 0.001 0.005 0.008 0.204 1.232 0.035 0.007 0.166 0.003 0.390 0.002 0.009 1.170 March 25, 2016 8 0.002 0.001 0.023 0.002 0.106 0.558 0.004 0.003 0.045 0.003 0.530 0.002 0.011 1.590 March 28, 2016 14 0.002 0.001 0.023 0.002 0.070 1.113 0.003 0.006 0.036 0.003 0.790 0.002 0.011 2.370 March 31, 2016 8 0.007 0.001 0.027 0.006 0.136 0.937 0.017 0.003 0.168 0.003 0.750 0.002 0.016 2.250 Guideline - Point of Impingement Guideline as per O.Reg.419/05 (1) Ferric oxide values are presented for informational purposes only; ferric oxide was calculated from elemental iron (total Fe) assuming the Fe to be oxidized * O. Reg.419/05 schedule 3, 24-hour standard; note that the URT (under schedule 6) for cadmium and its compounds is 0.025 µg/m3 and Nickel is 2 µg/m3 A "-" in the Fe(Fe2O3) indicates there was a ND for Fe for that sample and thus a value for Fe(Fe2O3) can not be calculated. Equipment failure Equipment failure Standard * 120 n/a 0.025 n/a n/a 50 25 0.5 n/a 3 n/a n/a 2 120 n/a No. > Sch. 3 value * 0 n/a 0 n/a n/a 0 0 n/a n/a 0 n/a n/a 0 0 n/a Guideline n/a 0.3 n/a 1.5 0.1 n/a n/a n/a 2.5 n/a 10 n/a n/a n/a n/a No. > guideline n/a 0 n/a 0 0 n/a n/a n/a 0 n/a 0 n/a n/a n/a n/a Geometric mean 7.8 0.003 0.001 0.011 0.002 0.063 0.332 0.005 0.003 0.040 0.004 0.519 0.003 0.008 1.557 Arithmetic mean 9.8 0.006 0.001 0.014 0.003 0.123 0.528 0.010 0.003 0.068 0.007 0.640 0.077 0.011 1.920 Max. concentration 25.2 0.060 0.002 0.051 0.010 0.812 2.098 0.061 0.008 0.273 0.046 2.360 1.280 0.031 7.080 Min. concentration 1.5 0.002 0.001 0.004 0.001 0.006 0.061 0.001 0.001 0.003 0.003 0.150 0.002 0.002 0.450 No. of valid samples 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 No. samples < mdl 2 3 23 0 9 0 4 0 0 5 4 26 0 0 Detection limit 3.0 0.0036 0.0012 0.0032 0.0012 0.0012-0.0018 0.0006 0.0018 0.0060 0.2800 0.0031 0.0033 - Half detection limit 1.5 0.0018 0.0006 0.0016 0.0006 0.0006-0.0009 0.0003 0.0009 0.0030 0.1400 0.0016 0.0017 - % < detection limit 7 10 79 0 31 0-14 0 0 17 14 90 0 - % valid data 94 94 94 94 94 94 94 94 94 94 94 94 94 94 94 Amec Foster Wheeler Project No.: TY156006 Page 7
All non detectable results were reported as 1/2 the detection limit Cells in RED indicate an exceedance Union Street Monitoring Results for PM10 and Metals (results expressed in µg/m 3 ) PM10 As Cd Cr Co Cu Fe(Fe 2 O 3 ) Pb Mn Ni Se S V Zn SO4 AAQC (µg/m 3 ) 50 - - - - - - - - - - - - - - January 1, 2016 2 0.002 0.001 0.002 0.001 0.007 0.081 0.001 0.002 0.005 0.003 0.550 0.002 0.007 1.650 January 7, 2016 7 0.002 0.001 0.007 0.001 0.007 0.155 0.004 0.003 0.003 0.003 0.510 0.002 0.014 1.530 January 13, 2016 2 0.013 0.001 0.007 0.001 0.048 0.114 0.010 0.001 0.024 0.006 0.380 0.002 0.007 1.140 January 19, 2016 2 0.002 0.001 0.005 0.001 0.002 0.028 0.003 0.001 0.002 0.003 0.150 0.165 0.002 0.450 January 25, 2016 10 0.004 0.001 0.020 0.001 0.018 0.080 0.005 0.002 0.005 0.011 0.960 0.960 0.002 2.880 January 31, 2016 4 0.002 0.001 0.011 0.001 0.012 0.028 0.003 0.000 0.010 0.003 0.150 0.165 0.002 0.450 February 6, 2016 24 0.002 0.001 0.013 0.001 0.010 0.103 0.001 0.001 0.013 0.003 0.420 0.002 0.004 1.260 February 12, 2016 25 0.002 0.001 0.005 0.001 0.008 0.083 0.001 0.002 0.007 0.003 0.33 0.002 0.005 0.990 February 18, 2016 12 0.002 0.001 0.015 0.003 0.048 0.326 0.010 0.004 0.048 0.003 0.380 0.002 0.008 1.140 February 24, 2016 30 0.006 0.002 0.027 0.008 0.632 0.946 0.013 0.009 0.383 0.003 0.910 0.002 0.041 2.730 March 1, 2016 3 0.002 0.001 0.055 0.001 0.027 0.195 0.003 0.002 0.022 0.003 0.410 0.002 0.005 1.230 March 7, 2016 5 0.002 0.001 0.052 0.001 0.023 0.117 0.007 0.001 0.026 0.003 0.770 0.002 0.008 2.310 March 13, 2016 5 0.020 0.001 0.007 0.003 0.243 0.756 0.021 0.002 0.110 0.017 0.830 0.002 0.010 2.490 March 19, 2016 6 0.002 0.001 0.004 0.001 0.065 0.565 0.003 0.003 0.037 0.003 0.150 0.002 0.006 0.450 March 25, 2016 3 0.002 0.001 0.022 0.001 0.031 0.248 0.001 0.002 0.017 0.003 0.150 0.002 0.006 0.450 March 31, 2016 2 0.002 0.001 0.018 0.001 0.016 0.132 0.006 0.001 0.015 0.003 0.155 0.002 0.006 0.465 AAQC 50 - - - - - - - - - - - - - - No. > AAQC 0 - - - - - - - - - - - - - - Geometric mean 5.3 0.003 0.001 0.011 0.001 0.023 0.152 0.004 0.002 0.017 0.004 0.365 0.004 0.006 1.096 Arithmetic mean 8.7 0.004 0.001 0.017 0.001 0.075 0.247 0.006 0.002 0.045 0.005 0.450 0.082 0.008 1.351 Max. concentration 29.9 0.020 0.002 0.055 0.008 0.632 0.946 0.021 0.009 0.383 0.017 0.960 0.960 0.041 2.880 Min. concentration 1.5 0.002 0.001 0.002 0.001 0.002 0.028 0.001 0.000 0.002 0.003 0.150 0.002 0.002 0.450 No. of valid samples 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 No. samples < mdl 4 12 15 1 13 0 1 0 0 13 1 12 1 0 Detection limit 3.0 0.0036 0.0012 0.0032 0.0012 0.0012-0.0018 0.0006 0.0018 0.0060 0.2800 0.0030 0.0033 - Half detection limit 1.5 0.0018 0.0006 0.0016 0.0006 0.0006-0.0009 0.0003 0.0009 0.0030 0.1400 0.0015 0.0017 - % < detection limit 25 75 94 6 81 0-6 0 0 81 6 75 6 - % valid data 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 Notes: (1) Ferric oxide values are presented for informational purposes only; ferric oxide was calculated from elemental iron (total Fe) assuming the Fe to be oxidized Amec Foster Wheeler Project No.: TY156006 Page 8
All non detectable results were reported as 1/2 the detection limit Cells in RED indicate an exceedance Venice Street Monitoring Results for TSP and Metals (results expressed in µg/m 3 ) TSP As Cd Cr Co Cu Fe(Fe 2 O 3 ) Pb Mn Ni Se S V Zn SO4 Sch. 3/Guideline (µg/m 3 ) 120 0.3 0.025 1.5 0.1 50 25 0.5 2.5 3.0 10-2.0 120 - January 1, 2016 3 0.002 0.001 0.003 0.001 0.006 0.105 0.001 0.002 0.005 0.003 0.600 0.003 0.007 1.800 January 4, 2016 26 0.002 0.001 0.013 0.006 0.148 0.842 0.007 0.008 0.219 0.003 0.800 0.003 0.015 2.400 January 7, 2016 13 0.002 0.001 0.007 0.001 0.026 0.324 0.005 0.005 0.027 0.003 0.660 0.003 0.019 1.980 January 10, 2016 5 0.002 0.001 0.007 0.001 0.050 0.300 0.006 0.002 0.038 0.003 0.380 0.003 0.021 1.140 January 13, 2016 13 0.031 0.001 0.010 0.022 0.534 1.279 0.032 0.008 0.468 0.015 1.120 0.003 0.025 3.360 January 16, 2016 2 0.002 0.001 0.005 0.001 0.038 0.107 0.001 0.001 0.011 0.003 0.150 0.003 0.002 0.450 January 19, 2016 24 0.002 0.001 0.005 0.001 0.008 0.062 0.001 0.001 0.005 0.003 0.150 0.003 0.002 0.450 January 22, 2016 25 0.002 0.001 0.020 0.001 0.059 0.201 0.001 0.002 0.035 0.003 0.150 0.003 0.002 0.450 January 25, 2016 23 0.002 0.001 0.004 0.016 0.268 1.002 0.016 0.007 0.300 0.006 1.540 1.540 0.002 4.620 January 28, 2016 8 0.002 0.001 0.013 0.002 0.045 0.241 0.005 0.002 0.039 0.003 0.500 0.500 0.002 1.500 January 31, 2016 3 0.002 0.001 0.012 0.001 0.012 0.055 0.003 0.001 0.012 0.003 0.390 0.390 0.002 1.170 February 3, 2016 4 0.002 0.001 0.012 0.003 0.062 0.459 0.005 0.002 0.056 0.003 0.440 0.003 0.013 1.320 February 6, 2016 8 0.002 0.001 0.013 0.001 0.026 0.134 0.003 0.002 0.016 0.003 0.550 0.003 0.012 1.650 February 9, 2016 6 0.002 0.001 0.007 0.002 0.073 0.286 0.003 0.001 0.084 0.003 0.460 0.003 0.010 1.380 February 12, 2016 5 0.002 0.001 0.006 0.001 0.077 0.183 0.001 0.002 0.072 0.003 0.440 0.003 0.010 1.320 February 15, 2016 30 0.002 0.001 0.014 0.015 0.588 1.131 0.048 0.005 0.375 0.026 4.280 0.003 0.029 12.840 February 18, 2016 February 21, 2016 11 0.002 0.001 0.011 0.002 0.130 0.593 Invalid Flow 0.003 0.006 0.069 0.003 0.540 0.003 0.036 1.620 February 24, 2016 35 0.005 0.001 0.024 0.009 0.514 1.030 0.011 0.008 0.361 0.003 0.850 0.003 0.057 2.550 February 27, 2016 8 0.002 0.001 0.059 0.002 0.066 0.229 0.003 0.003 0.065 0.003 0.670 0.003 0.017 2.010 March 1, 2016 March 4, 2016 11 0.002 0.001 0.023 0.002 0.035 0.289 Invalid Flow 0.005 0.005 0.030 0.003 0.530 0.003 0.010 1.590 March 7, 2016 12 0.002 0.001 0.005 0.003 0.058 0.427 0.007 0.005 0.056 0.003 1.140 0.003 0.019 3.420 March 10, 2016 4 0.002 0.001 0.026 0.003 0.081 0.280 0.001 0.003 0.130 0.003 0.150 0.003 0.020 0.450 March 13, 2016 14 0.004 0.001 0.011 0.009 0.268 1.576 0.007 0.006 0.264 0.003 0.660 0.003 0.014 1.980 March 16, 2016 15 0.010 0.001 0.005 0.005 0.277 1.162 0.016 0.005 0.146 0.003 1.030 0.003 0.017 3.090 March 19, 2016 20 0.005 0.001 0.014 0.008 0.408 1.506 0.005 0.007 0.239 0.003 0.450 0.003 0.017 1.350 March 22, 2016 23 0.007 0.001 0.009 0.010 0.277 1.452 0.034 0.009 0.229 0.003 0.450 0.003 0.015 1.350 March 25, 2016 20 0.007 0.001 0.036 0.012 0.813 2.022 0.010 0.007 0.277 0.003 0.750 0.003 0.035 2.250 March 28, 2016 14 0.002 0.001 0.023 0.002 0.062 0.607 0.003 0.004 0.051 0.003 0.590 0.003 0.011 1.770 March 31, 2016 9 0.005 0.001 0.031 0.006 0.123 1.119 0.013 0.003 0.200 0.003 0.680 0.003 0.018 2.040 Guideline - Point of Impingement Guideline as per O.Reg.419/05 (1) Ferric oxide values are presented for informational purposes only; ferric oxide was calculated from elemental iron (total Fe) assuming the Fe to be oxidized * O. Reg.419/05 schedule 3, 24-hour standard; note that the URT (under schedule 6) for cadmium and its compounds is 0.025 µg/m3 and Nickel is 2 µg/m3 A "-" in the Fe(Fe2O3) indicates there was a ND for Fe for that sample and thus a value for Fe(Fe2O3) can not be calculated. Standard * 120 n/a 0.025 n/a n/a 50 25 0.5 n/a 3 n/a n/a 2 120 n/a No. > Sch. 3 value * 0 n/a 0 n/a n/a 0 0 n/a n/a 0 n/a n/a 0 0 n/a Guideline n/a 0.3 n/a 1.5 0.1 n/a n/a n/a 2.5 n/a 10 n/a n/a n/a n/a No. > guideline n/a 0 n/a 0 0 n/a n/a n/a 0 n/a 0 n/a n/a n/a n/a Geometric mean 10.4 0.003 0.001 0.011 0.003 0.089 0.427 0.005 0.003 0.071 0.004 0.552 0.005 0.011 1.656 Arithmetic mean 13.5 0.004 0.001 0.015 0.005 0.177 0.655 0.009 0.004 0.134 0.004 0.728 0.086 0.016 2.183 Max. concentration 35.4 0.031 0.001 0.059 0.022 0.813 2.022 0.048 0.009 0.468 0.026 4.280 1.540 0.057 12.840 Min. concentration 1.6 0.002 0.001 0.003 0.001 0.006 0.055 0.001 0.001 0.005 0.003 0.150 0.003 0.002 0.450 No. of valid samples 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 No. samples < mdl 0 19 25 0 5 0 6 0 0 26 4 26 6 0 Detection limit 3.0 0.0036 0.0012 0.0032 0.0012 0.0012-0.0018 0.0006 0.0018 0.0060 0.2800 0.0060 0.0033 - Half detection limit 1.5 0.0018 0.0006 0.0016 0.0006 0.0006-0.0009 0.0003 0.0009 0.0030 0.1400 0.0030 0.0017 - % < detection limit 0 66 86 0 17 0-21 0 0 90 14 90 21 - % valid data 94 94 94 94 94 94 94 94 94 94 94 94 94 94 94 Amec Foster Wheeler Project No.: TY156006
All non detectable results were reported as 1/2 the detection limit Cells in RED indicate an exceedance Venice Street Monitoring Results for PM10 and Metals (results expressed in µg/m 3 ) PM10 As Cd Cr Co Cu Fe(Fe 2 O 3 ) Pb Mn Ni Se S V Zn SO4 AAQC (µg/m 3 ) 50 - - - - - - - - - - - - - - January 1, 2016 1.5 0.002 0.001 0.003 0.001 0.003 0.047 0.001 0.001 0.002 0.003 0.390 0.003 0.005 1.170 January 7, 2016 5.5 0.002 0.001 0.007 0.001 0.007 0.124 0.004 0.003 0.003 0.003 0.510 0.003 0.012 1.530 January 13, 2016 4.6 0.022 0.001 0.007 0.007 0.177 0.465 0.017 0.003 0.161 0.011 0.720 0.003 0.011 2.160 January 19, 2016 1.5 0.002 0.001 0.006 0.001 0.004 0.150 0.001 0.000 0.001 0.003 0.150 0.170 0.002 0.450 January 25, 2016 5.0 0.002 0.001 0.002 0.001 0.014 0.071 0.005 0.001 0.005 0.003 0.790 0.790 0.002 2.370 January 31, 2016 1.5 0.002 0.001 0.012 0.001 0.006 0.150 0.002 0.001 0.007 0.003 0.330 0.330 0.002 0.990 February 6, 2016 1.5 0.002 0.001 0.013 0.001 0.005 0.150 0.001 0.001 0.005 0.003 0.150 0.002 0.002 0.450 February 12, 2016 1.5 0.002 0.001 0.006 0.001 0.019 0.109 0.001 0.002 0.017 0.003 0.150 0.003 0.007 0.450 February 18, 2016 11.8 0.002 0.001 0.016 0.003 0.055 0.374 0.006 0.005 0.051 0.003 0.410 0.003 0.078 1.230 February 24, 2016 15.3 0.002 0.001 0.021 0.008 0.297 0.970 0.007 0.006 0.314 0.003 0.770 0.003 0.027 2.310 March 1, 2016 4.8 0.002 0.001 0.056 0.001 0.040 0.285 0.003 0.002 0.036 0.003 0.480 0.003 0.011 1.440 March 7, 2016 6.4 0.002 0.001 0.004 0.002 0.028 0.170 0.006 0.002 0.033 0.003 0.680 0.003 0.018 2.040 March 13, 2016 3.6 0.002 0.001 0.007 0.003 0.077 0.552 0.003 0.003 0.075 0.003 0.330 0.003 0.008 0.990 March 19, 2016 5.3 0.002 0.001 0.007 0.003 0.099 0.603 0.002 0.003 0.087 0.003 0.015 0.003 0.009 0.045 March 25, 2016 6.3 0.002 0.001 0.022 0.002 0.092 0.508 0.003 0.003 0.059 0.003 0.430 0.003 0.016 1.290 March 31, 2016 4.0 0.006 0.001 0.025 0.001 0.050 0.348 0.013 0.002 0.049 0.003 0.450 0.003 0.012 1.350 AAQC 50 - - - - - - - - - - - - - - No. > AAQC 0 - - - - - - - - - - - - - - Geometric mean 3.9 0.002 0.001 0.009 0.001 0.027 0.233 0.003 0.002 0.020 0.003 0.321 0.007 0.008 0.962 Arithmetic mean 5.0 0.003 0.001 0.013 0.002 0.061 0.317 0.005 0.002 0.056 0.004 0.422 0.083 0.014 1.267 Max. concentration 15.3 0.022 0.001 0.056 0.008 0.297 0.970 0.017 0.006 0.314 0.011 0.790 0.790 0.078 2.370 Min. concentration 1.5 0.002 0.001 0.002 0.001 0.003 0.047 0.001 0.000 0.001 0.003 0.015 0.002 0.002 0.045 No. of valid samples 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 No. samples < mdl 5 14 16 0 7 0 4 1 1 0 3 0 4 0 Detection limit 3.0 0.0036 0.0012 0.0032 0.0012 0.0012-0.0018 0.0006 0.0018 0.0060 0.2800 0.0060 0.0033 - Half detection limit 1.5 0.0018 0.0006 0.0016 0.0006 0.0006-0.0009 0.0003 0.0009 0.0030 0.1400 0.0030 0.0017 - % < detection limit 31 88 100 0 44 0-25 6 6 0 19 0 25 - % valid data 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 Notes: (1) Ferric oxide values are presented for informational purposes only; ferric oxide was calculated from elemental iron (total Fe) assuming the Fe to be oxidized Amec Foster Wheeler Project No.: TY156006
All non detectable results were reported as 1/2 the detection limit Cells in RED indicate an exceedance Norite Street Monitoring Results for TSP and Metals (results expressed in µg/m 3 ) TSP As Cd Cr Co Cu Fe(Fe 2 O 3 ) Pb Mn Ni Se S V Zn SO4 Sch. 3/Guideline (µg/m 3 ) 120 0.3 0.025 1.5 0.1 50 25 0.5 2.5 3.0 10-2.0 120 - January 1, 2016 2 0.002 0.001 0.002 0.001 0.006 0.089 0.001 0.002 0.006 0.003 0.570 0.002 0.007 1.710 January 4, 2016 15 0.002 0.001 0.007 0.001 0.043 0.447 0.003 0.006 0.039 0.003 0.480 0.002 0.011 1.440 January 7, 2016 9 0.002 0.001 0.007 0.001 0.009 0.221 0.002 0.004 0.007 0.003 0.470 0.002 0.018 1.410 January 10, 2016 4 0.002 0.001 0.007 0.001 0.023 0.219 0.003 0.002 0.022 0.003 0.155 0.002 0.023 0.465 January 13, 2016 2 0.002 0.001 0.006 0.001 0.052 0.157 0.004 0.002 0.029 0.003 0.350 0.002 0.007 1.050 January 16, 2016 2 0.002 0.001 0.007 0.001 0.016 0.075 0.002 0.001 0.008 0.003 0.160 0.160 0.002 0.480 January 19, 2016 2 0.002 0.001 0.007 0.001 0.009 0.084 0.001 0.001 0.007 0.003 0.155 0.155 0.002 0.465 January 22, 2016 3 0.002 0.001 0.024 0.001 0.013 0.124 0.001 0.002 0.007 0.003 0.155 0.155 0.002 0.465 January 25, 2016 8 0.002 0.001 0.004 0.001 0.009 0.145 0.002 0.003 0.006 0.003 1.110 1.110 0.002 3.330 January 28, 2016 2 0.002 0.001 0.015 0.002 0.028 0.108 0.005 0.001 0.043 0.003 0.490 0.490 0.002 1.470 January 31, 2016 2 0.002 0.001 0.013 0.001 0.010 0.050 0.002 0.001 0.012 0.003 0.155 0.155 0.002 0.465 February 3, 2016 4 0.010 0.001 0.013 0.002 0.158 0.338 0.019 0.002 0.046 0.023 0.460 0.002 0.012 1.380 February 6, 2016 5 0.002 0.001 0.012 0.001 0.022 0.082 0.001 0.002 0.016 0.003 0.420 0.002 0.016 1.260 February 9, 2016 5 0.005 0.001 0.008 0.001 0.085 0.167 0.015 0.002 0.046 0.003 0.730 0.002 0.020 2.190 February 12, 2016 2 0.002 0.001 0.005 0.001 0.008 0.080 0.001 0.002 0.006 0.003 0.155 0.002 0.006 0.465 February 15, 2016 7 0.002 0.001 0.012 0.001 0.008 0.092 0.001 0.003 0.006 0.003 0.470 0.002 0.009 1.410 February 18, 2016 21 0.002 0.001 0.016 0.003 0.061 0.560 0.009 0.007 0.053 0.003 0.380 0.002 0.012 1.140 February 21, 2016 5 0.002 0.001 0.006 0.001 0.007 0.113 0.001 0.001 0.005 0.003 0.155 0.002 0.005 0.465 February 24, 2016 19 0.002 0.001 0.054 0.003 0.222 0.481 0.017 0.005 0.111 0.003 0.690 0.002 0.027 2.070 February 27, 2016 4 0.002 0.001 0.053 0.001 0.019 0.091 0.001 0.002 0.014 0.003 0.490 0.002 0.009 1.470 March 1, 2016 6 0.002 0.001 0.050 0.001 0.032 0.234 0.004 0.002 0.023 0.003 0.400 0.002 0.009 1.200 March 4, 2016 10 0.002 0.001 0.021 0.001 0.017 0.259 0.002 0.004 0.018 0.003 0.440 0.002 0.008 1.320 March 7, 2016 11 0.005 0.001 0.004 0.002 0.129 0.312 0.016 0.003 0.042 0.003 1.230 0.002 0.022 3.690 March 10, 2016 2 0.002 0.001 0.004 0.001 0.011 0.130 0.001 0.001 0.012 0.003 0.155 0.002 0.006 0.465 March 13, 2016 18 0.015 0.001 0.007 0.003 0.232 0.866 0.016 0.005 0.102 0.008 0.660 0.002 0.010 1.980 March 16, 2016 12 0.054 0.001 0.004 0.003 0.278 0.788 0.044 0.003 0.117 0.035 0.930 0.002 0.019 2.790 March 19, 2016 29 0.002 0.001 0.006 0.004 0.137 2.211 0.004 0.011 0.079 0.003 0.350 0.002 0.015 1.050 March 22, 2016 17 0.006 0.001 0.004 0.007 0.123 1.225 0.028 0.007 0.151 0.003 0.330 0.002 0.011 0.990 March 25, 2016 6 0.002 0.001 0.020 0.001 0.034 0.274 0.001 0.003 0.016 0.003 0.360 0.002 0.009 1.080 March 28, 2016 8 0.002 0.001 0.021 0.001 0.018 0.404 0.001 0.002 0.008 0.003 0.470 0.002 0.006 1.410 March 31, 2016 Invalid Flow Guideline - Point of Impingement Guideline as per O.Reg.419/05 (1) Ferric oxide values are presented for informational purposes only; ferric oxide was calculated from elemental iron (total Fe) assuming the Fe to be oxidized * O. Reg.419/05 schedule 3, 24-hour standard; note that the URT (under schedule 6) for cadmium and its compounds is 0.025 µg/m3 and Nickel is 2 µg/m3 A "-" in the Fe(Fe2O3) indicates there was a ND for Fe for that sample and thus a value for Fe(Fe2O3) can not be calculated. Standard * 120 n/a 0.025 n/a n/a 50 25 0.5 n/a 3 n/a n/a 2 120 n/a No. > Sch. 3 value * 0 n/a 0 n/a n/a 0 0 n/a n/a 0 n/a n/a 0 0 n/a Guideline n/a 0.3 n/a 1.5 0.1 n/a n/a n/a 2.5 n/a 10 n/a n/a n/a n/a No. > guideline n/a 0 n/a 0 0 n/a n/a n/a 0 n/a 0 n/a n/a n/a n/a Geometric mean 5.4 0.003 0.001 0.010 0.001 0.030 0.215 0.003 0.002 0.020 0.004 0.376 0.005 0.008 1.129 Arithmetic mean 7.9 0.005 0.001 0.014 0.001 0.061 0.348 0.007 0.003 0.035 0.005 0.451 0.076 0.010 1.353 Max. concentration 29.0 0.054 0.001 0.054 0.007 0.278 2.211 0.044 0.011 0.151 0.035 1.230 1.110 0.027 3.690 Min. concentration 1.5 0.002 0.001 0.002 0.001 0.006 0.050 0.001 0.001 0.005 0.003 0.155 0.002 0.002 0.465 No. of valid samples 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 No. samples < mdl 3 24 30 0 10 0 4 0 0 27 8 30 6 0 Detection limit 3.0 0.0036 0.0012 0.0032 0.0012 0.0012-0.0018 0.0006 0.0018 0.0060 0.2800 0.0060 0.0033 - Half detection limit 1.5 0.0018 0.0006 0.0016 0.0006 0.0006-0.0009 0.0003 0.0009 0.0030 0.1400 0.0030 0.0017 - % < detection limit 10 80 100 0 33 0-13 0 0 90 27 100 20 - % valid data 97 97 97 97 97 97 97 97 97 97 97 97 97 97 97 Amec Foster Wheeler Project No.: TY156006
All non detectable results were reported as 1/2 the detection limit Cells in RED indicate an exceedance Norite Street Monitoring Results for PM10 and Metals (results expressed in µg/m 3 ) PM10 As Cd Cr Co Cu Fe(Fe 2 O 3 ) Pb Mn Ni Se S V Zn SO4 AAQC (µg/m 3 ) 50 - - - - - - - - - - - - - - January 1, 2016 2 0.002 0.001 0.002 0.001 0.004 0.049 0.001 0.001 0.002 0.003 0.470 0.003 0.007 1.410 January 7, 2016 8 0.002 0.001 0.006 0.001 0.005 0.158 0.003 0.004 0.002 0.003 0.610 0.003 0.017 1.830 January 13, 2016 2 0.002 0.001 0.006 0.001 0.018 0.070 0.004 0.001 0.008 0.003 0.150 0.003 0.004 0.450 January 19, 2016 2 0.002 0.001 0.007 0.001 0.005 0.061 0.001 0.002 0.003 0.003 0.160 0.003 0.002 0.480 January 25, 2016 10 0.002 0.001 0.014 0.001 0.004 0.098 0.002 0.002 0.001 0.003 1.100 1.100 0.002 3.300 January 31, 2016 2 0.002 0.001 0.012 0.001 0.007 0.015 0.003 0.001 0.007 0.003 0.330 0.330 0.002 0.990 February 6, 2016 4 0.002 0.001 0.013 0.001 0.006 0.063 0.001 0.002 0.008 0.003 0.500 0.003 0.007 1.500 February 12, 2016 4 0.002 0.002 0.007 0.001 0.016 0.191 0.001 0.003 0.016 0.003 0.370 0.003 0.009 1.110 February 18, 2016 16 0.002 0.001 0.007 0.004 0.063 0.603 0.008 0.006 0.076 0.003 0.450 0.003 0.010 1.350 February 24, 2016 19 0.004 0.001 0.062 0.005 0.218 0.825 0.020 0.007 0.155 0.003 0.950 0.003 0.026 2.850 March 1, 2016 6 0.002 0.001 0.051 0.001 0.022 0.236 0.004 0.003 0.018 0.003 0.510 0.003 0.007 1.530 March 7, 2016 10 0.004 0.001 0.002 0.001 0.072 0.172 0.013 0.002 0.029 0.003 1.120 0.003 0.014 3.360 March 13, 2016 9 0.002 0.001 0.005 0.002 0.176 0.531 0.019 0.003 0.058 0.010 0.740 0.003 0.009 2.220 March 19, 2016 14 0.002 0.001 0.004 0.002 0.070 1.147 0.003 0.006 0.039 0.003 0.310 0.003 0.009 0.930 March 25, 2016 6 0.002 0.001 0.023 0.001 0.019 0.263 0.002 0.003 0.011 0.003 0.460 0.003 0.007 1.380 March 31, 2016 4 0.008 0.002 0.020 0.002 0.079 0.425 0.021 0.001 0.049 0.003 0.670 0.003 0.016 2.010 AAQC 50 - - - - - - - - - - - - - - No. > AAQC 0 - - - - - - - - - - - - - - Geometric mean 5.3 0.002 0.001 0.009 0.001 0.021 0.175 0.004 0.003 0.013 0.003 0.480 0.006 0.007 1.440 Arithmetic mean 7.2 0.002 0.001 0.015 0.001 0.049 0.307 0.007 0.003 0.030 0.003 0.556 0.092 0.009 1.669 Max. concentration 18.6 0.008 0.002 0.062 0.005 0.218 1.147 0.021 0.007 0.155 0.010 1.120 1.100 0.026 3.360 Min. concentration 1.5 0.002 0.001 0.002 0.001 0.004 0.015 0.001 0.001 0.001 0.003 0.150 0.003 0.002 0.450 No. of valid samples 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 No. samples < mdl 3 12 14 1 6 0 4 0 0 15 1 14 3 0 Detection limit 3.0 0.0036 0.0012 0.0032 0.0012 0.0012-0.0018 0.0006 0.0018 0.0060 0.2800 0.0060 0.0033 - Half detection limit 1.5 0.0018 0.0006 0.0016 0.0006 0.0006-0.0009 0.0003 0.0009 0.0030 0.1400 0.0030 0.0017 - % < detection limit 19 75 88 6 38 0-25 0 0 94 6 88 19 - % valid data 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 Notes: (1) Ferric oxide values are presented for informational purposes only; ferric oxide was calculated from elemental iron (total Fe) assuming the Fe to be oxidized Amec Foster Wheeler Project No.: TY156006
All non detectable results were reported as 1/2 the detection limit Cells in RED indicate an exceedance Copper Cliff Creek Monitoring Results for TSP and Metals (results expressed in µg/m 3 ) TSP As Cd Cr Co Cu Fe(Fe 2 O 3 ) Pb Mn Ni Se S V Zn SO4 Sch. 3/Guideline (µg/m 3 ) 120 0.3 0.025 1.5 0.1 50 25 0.5 2.5 3.0 10-2.0 120 - January 1, 2016 2 0.002 0.001 0.002 0.001 0.005 0.077 0.001 0.002 0.005 0.003 0.410 0.003 0.007 1.230 January 4, 2016 52 0.002 0.001 0.009 0.004 0.146 1.012 0.006 0.008 0.168 0.003 1.020 0.003 0.014 3.060 January 7, 2016 13 0.002 0.001 0.007 0.001 0.021 0.326 0.003 0.005 0.028 0.003 0.610 0.003 0.016 1.830 January 10, 2016 3 0.002 0.001 0.006 0.001 0.050 0.148 0.006 0.001 0.020 0.003 0.330 0.003 0.015 0.990 January 13, 2016 3 0.002 0.001 0.006 0.001 0.036 0.145 0.003 0.001 0.018 0.003 0.150 0.003 0.007 0.450 January 16, 2016 2 0.002 0.001 0.006 0.001 0.046 0.145 0.003 0.001 0.018 0.003 0.440 0.440 0.002 1.320 January 19, 2016 2 0.002 0.001 0.007 0.001 0.013 0.139 0.001 0.002 0.014 0.003 0.160 0.003 0.002 0.480 January 22, 2016 4 0.004 0.001 0.022 0.001 0.091 0.238 0.010 0.002 0.029 0.003 0.400 0.400 0.002 1.200 January 25, 2016 11 0.002 0.001 0.014 0.001 0.016 0.207 0.002 0.003 0.011 0.003 0.950 0.950 0.002 2.850 January 28, 2016 4 0.002 0.001 0.013 0.001 0.021 0.132 0.002 0.001 0.023 0.003 0.420 0.420 0.002 1.260 January 31, 2016 4 0.002 0.001 0.012 0.001 0.010 0.062 0.005 0.002 0.006 0.003 0.155 0.155 0.002 0.465 February 3, 2016 3 0.002 0.001 0.016 0.003 0.022 0.517 0.003 0.003 0.031 0.003 0.330 0.003 0.012 0.990 February 6, 2016 4 0.002 0.001 0.012 0.001 0.014 0.083 0.002 0.002 0.013 0.003 0.430 0.003 0.005 1.290 February 9, 2016 4 0.004 0.001 0.007 0.003 0.178 0.326 0.027 0.002 0.146 0.003 0.780 0.003 0.019 2.340 February 12, 2016 4 0.002 0.001 0.007 0.001 0.021 0.171 0.002 0.004 0.031 0.003 0.370 0.003 0.008 1.110 February 15, 2016 9 0.002 0.001 0.014 0.001 0.012 0.124 0.001 0.005 0.007 0.003 0.520 0.003 0.010 1.560 February 18, 2016 19 0.002 0.001 0.007 0.006 0.084 0.490 0.013 0.006 0.091 0.003 0.410 0.003 0.012 1.230 February 21, 2016 5 0.002 0.001 0.007 0.001 0.027 0.145 0.001 0.001 0.013 0.003 0.155 0.003 0.005 0.465 February 24, 2016 38 0.016 0.001 0.049 0.007 0.529 1.216 0.019 0.010 0.257 0.011 1.090 0.003 0.030 3.270 February 27, 2016 7 0.008 0.001 0.047 0.010 0.140 0.148 0.020 0.002 0.119 0.003 0.690 0.003 0.008 2.070 March 1, 2016 9 0.005 0.001 0.051 0.001 0.079 0.350 0.025 0.003 0.060 0.003 0.620 0.003 0.019 1.860 March 4, 2016 17 0.002 0.001 0.025 0.001 0.024 0.469 0.003 0.007 0.018 0.003 0.700 0.003 0.019 2.100 March 7, 2016 12 0.007 0.001 0.004 0.005 0.088 0.425 0.012 0.004 0.087 0.008 1.040 0.003 0.016 3.120 March 10, 2016 6 0.030 0.001 0.009 0.002 0.336 0.310 0.022 0.002 0.069 0.039 0.650 0.003 0.013 1.950 March 13, 2016 43 0.011 0.001 0.007 0.008 0.370 2.155 0.012 0.013 0.209 0.013 0.690 0.003 0.020 2.070 March 16, 2016 22 0.002 0.001 0.004 0.003 0.098 1.145 0.002 0.007 0.097 0.003 0.155 0.003 0.014 0.465 March 19, 2016 62 0.008 0.001 0.009 0.007 0.412 2.986 0.018 0.021 0.185 0.003 0.590 0.003 0.036 1.770 March 22, 2016 18 0.008 0.001 0.024 0.007 0.177 1.310 0.030 0.008 0.142 0.003 0.450 0.003 0.014 1.350 March 25, 2016 18 0.002 0.001 0.018 0.003 0.140 0.898 0.006 0.004 0.096 0.003 0.530 0.003 0.012 1.590 March 28, 2016 14 0.002 0.001 0.021 0.002 0.111 0.607 0.008 0.004 0.069 0.003 0.760 0.003 0.011 2.280 March 31, 2016 6 0.012 0.001 0.018 0.002 0.149 0.353 0.020 0.002 0.051 0.010 0.600 0.003 0.016 1.800 Guideline - Point of Impingement Guideline as per O.Reg.419/05 (1) Ferric oxide values are presented for informational purposes only; ferric oxide was calculated from elemental iron (total Fe) assuming the Fe to be oxidized * O. Reg.419/05 schedule 3, 24-hour standard; note that the URT (under schedule 6) for cadmium and its compounds is 0.025 µg/m3 and Nickel is 2 µg/m3 A "-" in the Fe(Fe2O3) indicates there was a ND for Fe for that sample and thus a value for Fe(Fe2O3) can not be calculated. Standard * 120 n/a 0.025 n/a n/a 50 25 0.5 n/a 3 n/a n/a 2 120 n/a No. > Sch. 3 value * 0 n/a 0 n/a n/a 0 0 n/a n/a 0 n/a n/a 0 0 n/a Guideline n/a 0.3 n/a 1.5 0.1 n/a n/a n/a 2.5 n/a 10 n/a n/a n/a n/a No. > guideline n/a 0 n/a 0 0 n/a n/a n/a 0 n/a 0 n/a n/a n/a n/a Geometric mean 8.0 0.003 0.001 0.011 0.002 0.058 0.324 0.005 0.003 0.040 0.004 0.464 0.007 0.009 1.391 Arithmetic mean 13.4 0.005 0.001 0.015 0.003 0.112 0.544 0.009 0.004 0.069 0.005 0.536 0.079 0.012 1.607 Max. concentration 61.8 0.030 0.001 0.051 0.010 0.529 2.986 0.030 0.021 0.257 0.039 1.090 0.950 0.036 3.270 Min. concentration 1.5 0.002 0.001 0.002 0.001 0.005 0.062 0.001 0.001 0.005 0.003 0.150 0.003 0.002 0.450 No. of valid samples 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 No. samples < mdl 2 20 25 1 10 0 1 0 0 26 5 26 6 0 Detection limit 3.0 0.0036 0.0012 0.0032 0.0012 0.0012-0.0018 0.0006 0.0018 0.0060 0.2800 0.0060 0.0033 - Half detection limit 1.5 0.0018 0.0006 0.0016 0.0006 0.0006-0.0009 0.0003 0.0009 0.0030 0.1400 0.0030 0.0017 - % < detection limit 6 65 81 3 32 0-3 0 0 84 16 84 19 - % valid data 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 Amec Foster Wheeler Project No.: TY156006
All non detectable results were reported as 1/2 the detection limit Cells in RED indicate an exceedance Copper Cliff Creek Monitoring Results for PM10 and Metals (results expressed in µg/m 3 ) PM10 As Cd Cr Co Cu Fe(Fe 2 O 3 ) Pb Mn Ni Se S V Zn SO4 AAQC (µg/m 3 ) 50 - - - - - - - - - - - - - - January 1, 2016 3 0.002 0.001 0.002 0.001 0.005 0.055 0.001 0.002 0.003 0.003 0.500 0.003 0.006 1.500 January 7, 2016 9 0.002 0.001 0.006 0.001 0.008 0.204 0.003 0.003 0.003 0.003 0.590 0.003 0.016 1.770 January 13, 2016 2 0.002 0.001 0.006 0.001 0.019 0.096 0.003 0.002 0.009 0.003 0.320 0.003 0.006 0.960 January 19, 2016 2 0.002 0.001 0.005 0.001 0.003 0.053 0.001 0.002 0.002 0.003 0.140 0.003 0.002 0.420 January 25, 2016 9 0.002 0.001 0.016 0.001 0.007 0.129 0.002 0.003 0.001 0.003 1.180 1.180 0.002 3.540 January 31, 2016 3 0.002 0.001 0.013 0.001 0.009 0.058 0.005 0.001 0.005 0.003 0.350 0.350 0.002 1.050 February 6, 2016 4 0.002 0.001 0.007 0.001 0.011 0.094 0.002 0.002 0.011 0.003 0.530 0.003 0.006 1.590 February 12, 2016 5 0.002 0.001 0.008 0.001 0.025 0.274 0.002 0.005 0.028 0.003 0.460 0.003 0.007 1.380 February 18, 2016 11 0.002 0.001 0.007 0.004 0.059 0.252 0.012 0.003 0.059 0.003 0.380 0.003 0.009 1.140 February 24, 2016 28 0.018 0.001 0.048 0.005 0.354 1.034 0.023 0.009 0.173 0.013 1.280 0.003 0.023 3.840 March 1, 2016 9 0.005 0.001 0.049 0.001 0.061 0.327 0.027 0.003 0.046 0.012 0.790 0.003 0.011 2.370 March 7, 2016 7 0.005 0.001 0.003 0.002 0.045 0.187 0.009 0.002 0.036 0.007 0.810 0.003 0.010 2.430 March 13, 2016 22 0.011 0.001 0.005 0.005 0.235 1.372 0.012 0.009 0.134 0.015 0.760 0.003 0.011 2.280 March 19, 2016 36 0.007 0.002 0.007 0.005 0.281 2.419 0.019 0.017 0.134 0.003 0.710 0.003 0.030 2.130 March 25, 2016 9 0.002 0.001 0.022 0.001 0.046 0.393 0.006 0.004 0.024 0.003 0.590 0.003 0.008 1.770 March 31, 2016 6 0.016 0.002 0.019 0.001 0.109 0.261 0.026 0.001 0.033 0.013 0.690 0.003 0.020 2.070 AAQC 50 - - - - - - - - - - - - - - No. > AAQC 0 - - - - - - - - - - - - - - Geometric mean 7.0 0.003 0.001 0.009 0.001 0.031 0.230 0.006 0.003 0.017 0.005 0.559 0.006 0.008 1.677 Arithmetic mean 10.3 0.005 0.001 0.014 0.002 0.080 0.451 0.009 0.004 0.044 0.006 0.630 0.098 0.010 1.890 Max. concentration 35.8 0.018 0.002 0.049 0.005 0.354 2.419 0.027 0.017 0.173 0.015 1.280 1.180 0.030 3.840 Min. concentration 1.5 0.002 0.001 0.002 0.001 0.003 0.053 0.001 0.001 0.001 0.003 0.140 0.003 0.002 0.420 No. of valid samples 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 No. samples < mdl 3 10 14 1 11 0 1 0 1 11 4 14 0 0 Detection limit 3.0 0.0036 0.0012 0.0032 0.0012 0.0012-0.0018 0.0006 0.0018 0.0060 0.2800 0.0060 0.0033 - Half detection limit 1.5 0.0018 0.0006 0.0016 0.0006 0.0006-0.0009 0.0003 0.0009 0.0030 0.1400 0.0030 0.0017 - % < detection limit 19 63 88 6 69 0-6 0 6 69 25 88 0 - % valid data 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 Notes: (1) Ferric oxide values are presented for informational purposes only; ferric oxide was calculated from elemental iron (total Fe) assuming the Fe to be oxidized Amec Foster Wheeler Project No.: TY156006
All non detectable results were reported as 1/2 the detection limit Cells in RED indicate an exceedance Delki Dozzi Monitoring Results for TSP and Metals (results expressed in µg/m 3 ) TSP As Cd Cr Co Cu Fe(Fe 2 O 3 ) Pb Mn Ni Se S V Zn SO4 Sch. 3/Guideline (µg/m 3 ) 120 0.3 0.025 1.5 0.1 50 25 0.5 2.5 3.0 10-2.0 120 - January 1, 2016 4 0.002 0.001 0.002 0.001 0.040 0.212 0.006 0.002 0.036 0.003 0.660 0.003 0.008 1.980 January 4, 2016 Invalid Flow January 7, 2016 10 0.002 0.001 0.007 0.001 0.008 0.255 0.003 0.004 0.006 0.003 0.640 0.003 0.019 1.920 January 10, 2016 4 0.002 0.001 0.006 0.001 0.017 0.166 0.004 0.001 0.011 0.003 0.140 0.003 0.011 0.420 January 13, 2016 3 0.002 0.001 0.005 0.001 0.019 0.111 0.002 0.001 0.005 0.003 0.145 0.003 0.006 0.435 January 16, 2016 4 0.002 0.001 0.005 0.001 0.012 0.133 0.002 0.001 0.003 0.003 0.145 0.003 0.002 0.435 January 19, 2016 5 0.002 0.001 0.008 0.001 0.038 0.293 0.005 0.004 0.016 0.003 0.170 0.003 0.002 0.510 January 22, 2016 6 0.002 0.001 0.019 0.001 0.009 0.158 0.001 0.002 0.005 0.003 0.150 0.003 0.002 0.450 January 25, 2016 13 0.002 0.001 0.014 0.001 0.010 0.160 0.003 0.003 0.001 0.003 1.270 1.270 0.002 3.810 January 28, 2016 8 0.002 0.001 0.014 0.001 0.021 0.186 0.002 0.002 0.008 0.003 0.520 0.520 0.002 1.560 January 31, 2016 6 0.002 0.001 0.013 0.001 0.027 0.073 0.009 0.001 0.026 0.003 0.380 0.380 0.002 1.140 February 3, 2016 4 0.002 0.001 0.013 0.001 0.011 0.186 0.003 0.001 0.007 0.003 0.150 0.003 0.007 0.450 February 6, 2016 6 0.002 0.001 0.006 0.003 0.073 0.128 0.023 0.002 0.087 0.003 0.630 0.003 0.008 1.890 February 9, 2016 5 0.002 0.001 0.007 0.001 0.008 0.110 0.001 0.002 0.004 0.003 0.150 0.003 0.011 0.450 February 12, 2016 7 0.002 0.001 0.006 0.001 0.014 0.201 0.001 0.003 0.012 0.003 0.330 0.003 0.009 0.990 February 15, 2016 6 0.002 0.001 0.013 0.001 0.007 0.079 0.001 0.001 0.004 0.003 0.450 0.003 0.008 1.350 February 18, 2016 54 0.002 0.002 0.009 0.002 0.050 1.363 0.005 0.015 0.020 0.003 0.640 0.003 0.039 1.920 February 21, 2016 6 0.002 0.001 0.007 0.001 0.009 0.110 0.001 0.001 0.005 0.003 0.155 0.003 0.006 0.465 February 24, 2016 27 0.002 0.001 0.056 0.001 0.027 0.724 0.007 0.008 0.011 0.003 0.520 0.003 0.067 1.560 February 27, 2016 8 0.002 0.001 0.045 0.004 0.049 0.104 0.009 0.003 0.052 0.003 0.490 0.003 0.009 1.470 March 1, 2016 7 0.002 0.001 0.046 0.001 0.017 0.151 0.001 0.002 0.005 0.003 0.170 0.003 0.034 0.510 March 4, 2016 13 0.002 0.001 0.022 0.003 0.054 0.535 0.010 0.004 0.047 0.003 0.520 0.003 0.015 1.560 March 7, 2016 15 0.002 0.001 0.002 0.001 0.015 0.340 0.003 0.003 0.008 0.003 0.930 0.003 0.014 2.790 March 10, 2016 4 0.002 0.001 0.002 0.001 0.005 0.127 0.001 0.001 0.001 0.003 0.150 0.003 0.010 0.450 March 13, 2016 19 0.002 0.001 0.004 0.001 0.010 0.951 0.001 0.007 0.008 0.003 0.150 0.003 0.009 0.450 March 16, 2016 6 0.002 0.001 0.002 0.001 0.012 0.234 0.001 0.002 0.001 0.003 0.150 0.003 0.016 0.450 March 19, 2016 31 0.002 0.001 0.004 0.001 0.017 1.314 0.002 0.010 0.006 0.003 0.150 0.003 0.016 0.450 March 22, 2016 35 0.012 0.001 0.023 0.015 0.465 4.895 0.015 0.011 0.139 0.003 0.510 0.003 0.030 1.530 March 25, 2016 10 0.002 0.001 0.021 0.001 0.018 0.265 0.003 0.002 0.005 0.003 0.400 0.003 0.015 1.200 March 28, 2016 9 0.002 0.001 0.020 0.001 0.013 0.293 0.002 0.002 0.004 0.003 0.590 0.003 0.011 1.770 March 31, 2016 4 0.002 0.001 0.017 0.001 0.007 0.155 0.002 0.001 0.002 0.003 0.145 0.003 0.009 0.435 Guideline - Point of Impingement Guideline as per O.Reg.419/05 (1) Ferric oxide values are presented for informational purposes only; ferric oxide was calculated from elemental iron (total Fe) assuming the Fe to be oxidized * O. Reg.419/05 schedule 3, 24-hour standard; note that the URT (under schedule 6) for cadmium and its compounds is 0.025 µg/m3 and Nickel is 2 µg/m3 A "-" in the Fe(Fe2O3) indicates there was a ND for Fe for that sample and thus a value for Fe(Fe2O3) can not be calculated. Standard * 120 n/a 0.025 n/a n/a 50 25 0.5 n/a 3 n/a n/a 2 120 n/a No. > Sch. 3 value * 0 n/a 0 n/a n/a 0 0 n/a n/a 0 n/a n/a 0 0 n/a Guideline n/a 0.3 n/a 1.5 0.1 n/a n/a n/a 2.5 n/a 10 n/a n/a n/a n/a No. > guideline n/a 0 n/a 0 0 n/a n/a n/a 0 n/a 0 n/a n/a n/a n/a Geometric mean 8.0 0.002 0.001 0.009 0.001 0.018 0.243 0.003 0.002 0.008 0.003 0.304 0.005 0.009 0.912 Arithmetic mean 11.1 0.002 0.001 0.014 0.001 0.036 0.467 0.004 0.003 0.018 0.003 0.387 0.075 0.013 1.160 Max. concentration 54.4 0.012 0.002 0.056 0.015 0.465 4.895 0.023 0.015 0.139 0.003 1.270 1.270 0.067 3.810 Min. concentration 2.9 0.002 0.001 0.002 0.001 0.005 0.073 0.001 0.001 0.001 0.003 0.140 0.003 0.002 0.420 No. of valid samples 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 No. samples < mdl 0 29 29 4 22 0 7 0 3 30 11 27 6 0 Detection limit 3.0 0.0036 0.0012 0.0032 0.0012 0.0012-0.0018 0.0006 0.0018 0.0060 0.2800 0.0060 0.0033 - Half detection limit 1.5 0.0018 0.0006 0.0016 0.0006 0.0006-0.0009 0.0003 0.0009 0.0030 0.1400 0.0030 0.0017 - % < detection limit 0 97 97 13 73 0-23 0 10 100 37 90 20 - % valid data 97 97 97 97 97 97 97 97 97 97 97 97 97 97 97 Amec Foster Wheeler Project No.: TY156006