Physics 262/266. George Mason University. Prof. Paul So

Similar documents
CHAPTER 13 Temperature and Kinetic Theory. Units

What determines how matter behaves? Thermodynamics.

General Chemistry II, Unit I: Study Guide (part I)

Thermodynamics and Equilibrium

Chapters 29 and 35 Thermochemistry and Chemical Thermodynamics

AP CHEMISTRY CHAPTER 6 NOTES THERMOCHEMISTRY

Thermodynamics Partial Outline of Topics

Study Guide Physics Pre-Comp 2013

Chapter 17: Thermodynamics: Spontaneous and Nonspontaneous Reactions and Processes

Chapter 11: Atmosphere

o o IMPORTANT REMINDERS Reports will be graded largely on their ability to clearly communicate results and important conclusions.

CHEM 103 Calorimetry and Hess s Law

Physics 231 Lecture 31

CHEM 116 Electrochemistry at Non-Standard Conditions, and Intro to Thermodynamics

Chapter Outline 4/28/2014. P-V Work. P-V Work. Isolated, Closed and Open Systems. Exothermic and Endothermic Processes. E = q + w

GOAL... ability to predict

Phy 212: General Physics II 1 Chapter 18 Worksheet 3/20/2008

Unit 14 Thermochemistry Notes

Thermochemistry. Thermochemistry

Equilibrium of Stress

Natural Sciences I. lecture 7: Heat & Temperature. The Kinetic Molecular Theory

Part One: Heat Changes and Thermochemistry. This aspect of Thermodynamics was dealt with in Chapter 6. (Review)

Edexcel GCSE Physics

Heat is energy and is measured in joules (J) or kilojoules (kj). The symbol for heat is H.

CHEM-443, Fall 2013, Section 010 Midterm 2 November 4, 2013

Matter Content from State Frameworks and Other State Documents

Recitation 06. n total = P total V/RT = (0.425 atm * 10.5 L) / ( L atm mol -1 K -1 * 338 K) = mol

Study Group Report: Plate-fin Heat Exchangers: AEA Technology

BASD HIGH SCHOOL FORMAL LAB REPORT

Spontaneous Processes, Entropy and the Second Law of Thermodynamics

Chapter 23 Electromagnetic Waves Lecture 14

Surface and Contact Stress

22.54 Neutron Interactions and Applications (Spring 2004) Chapter 11 (3/11/04) Neutron Diffusion

Types of Energy COMMON MISCONCEPTIONS CHEMICAL REACTIONS INVOLVE ENERGY

Unit 11 Solutions- Guided Notes. What are alloys? What is the difference between heterogeneous and homogeneous mixtures?

Electric Current and Resistance

Compressibility Effects

I. Analytical Potential and Field of a Uniform Rod. V E d. The definition of electric potential difference is

Thermodynamics: Gas Laws

Lecture 4. The First Law of Thermodynamics

NGSS High School Physics Domain Model

Fall 2013 Physics 172 Recitation 3 Momentum and Springs

Lecture 13: Electrochemical Equilibria

Lecture 17: Free Energy of Multi-phase Solutions at Equilibrium

Chapter One. Matter and Energy - Chemistry the study of matter and its changes the "central science" Natural Laws

Instructions: Show all work for complete credit. Work in symbols first, plugging in numbers and performing calculations last. / 26.

Module 4: General Formulation of Electric Circuit Theory

ChE 471: LECTURE 4 Fall 2003

Suggested reading: Lackmann (2011), Sections

Entropy, Free Energy, and Equilibrium

(1.1) V which contains charges. If a charge density ρ, is defined as the limit of the ratio of the charge contained. 0, and if a force density f

Chem 115 POGIL Worksheet - Week 8 Thermochemistry (Continued), Electromagnetic Radiation, and Line Spectra

Lecture 12: Chemical reaction equilibria

ALE 21. Gibbs Free Energy. At what temperature does the spontaneity of a reaction change?

Copyright Paul Tobin 63

Chemistry 20 Lesson 11 Electronegativity, Polarity and Shapes

Honors Physics Final Review Summary

General Chemistry II, Unit II: Study Guide (part 1)

Lecture 5: Equilibrium and Oscillations

Entropy. Chapter The Clausius Inequality and Entropy

Thermodynamics EAS 204 Spring 2004 Class Month Day Chapter Topic Reading Due 1 January 12 M Introduction 2 14 W Chapter 1 Concepts Chapter 1 19 M MLK

GAUSS' LAW E. A. surface

CHEM Thermodynamics. Change in Gibbs Free Energy, G. Review. Gibbs Free Energy, G. Review

Chapter 17 Free Energy and Thermodynamics

MODULE FOUR. This module addresses functions. SC Academic Elementary Algebra Standards:

Q1. A string of length L is fixed at both ends. Which one of the following is NOT a possible wavelength for standing waves on this string?

Revisiting the Mysterious Mpemba Effect

4F-5 : Performance of an Ideal Gas Cycle 10 pts

First Semester 6 th Grade Exam Review

Course/ Subject: Chemistry I Grade: Teacher: Hill Oberto Month: September/October (6-8 weeks)

Research Questions: Proposed Data Collection. Questions and Concerns

Phys102 Final-061 Zero Version Coordinator: Nasser Wednesday, January 24, 2007 Page: 1

NAME TEMPERATURE AND HUMIDITY. I. Introduction

Chapter 10. Thermal Physics

Solution to HW14 Fall-2002

, which yields. where z1. and z2

11. DUAL NATURE OF RADIATION AND MATTER

Chem 163 Section: Team Number: ALE 24. Voltaic Cells and Standard Cell Potentials. (Reference: 21.2 and 21.3 Silberberg 5 th edition)

Chemistry 1. Worksheet 4. Temperature in Chemistry. 1 MathTutorDVD.com

Semester 2 AP Chemistry Unit 12

Q1. A) 48 m/s B) 17 m/s C) 22 m/s D) 66 m/s E) 53 m/s. Ans: = 84.0 Q2.

Chemistry/ Biotechnology Reference Sheets

Name AP CHEM / / Chapter 1 Chemical Foundations

February 28, 2013 COMMENTS ON DIFFUSION, DIFFUSIVITY AND DERIVATION OF HYPERBOLIC EQUATIONS DESCRIBING THE DIFFUSION PHENOMENA

/ / Chemistry. Chapter 1 Chemical Foundations

Computational modeling techniques

Process Engineering Thermodynamics E (4 sp) Exam

PHYS 219 Spring semester Lecture 02: Coulomb s Law how point charges interact. Ron Reifenberger Birck Nanotechnology Center Purdue University

Downloaded from

Find this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.

TOPPER SAMPLE PAPER 2 Class XII- Physics

FIELD QUALITY IN ACCELERATOR MAGNETS

A.P. CHEMISTRY. SOLUTIONS AND ACID BASE CHEMISTRY. p 1

Examples: Everything in the universe is made up of matter. How atoms are form the. Solids Liquids Gases. The a substance has, If a substance has

Chapter 9. Preview. Objectives Defining Temperature. Thermal Equilibrium. Thermal Expansion Measuring Temperature. Section 1 Temperature and

CHAPTER PRACTICE PROBLEMS CHEMISTRY

Chapters 16 Temperature and Heat

Calculating the optimum pressure and temperature for vacancy minimization from theory; Niobium is an example. Jozsef Garai

( ) kt. Solution. From kinetic theory (visualized in Figure 1Q9-1), 1 2 rms = 2. = 1368 m/s

More Tutorial at

Transcription:

Physics 262/266 Gerge Masn University Prf. Paul S

PHYS 262/266 Annuncements WELCOME TO A NEW SEMESTER! Curse Website - http://cmplex.gmu.edu/www-phys/phys262 - http://cmplex.gmu.edu/www-phys/phys266 Recitatins - Officially starts next week - 5 sectins: ALL n Tuesday (12:30a, 1:30p, 2:30p, 3:30p, & 4:30p) - Prfs Niklic, Satija, and Yigit Hmewrk/Mastering Physics - 1 st HW due next Friday (February 2nd) 11:59p - Curse ID: MPSO95033

Curse Inf First 5 weeks: Thermdynamics vl.1 (PHYS 262 & 266) Mid 5 weeks: Optics vl. 2 (PHYS 262) Last 5 weeks: Mdern Physics vl. 3 (PHYS 262) Relativity Quantum Mechanics

Chapter 17: Temperature & Heat Tpics fr Disscusin thermmeters and temperature scales abslute zer and the Kelvin scale meaning f thermal equilibrium thermal expansin meaning f heat calrimetry calculatins mechanisms f heat transfer

Descriptin f Physical Systems micrscpic prperties f atms/mlecules that make up the system nt directly assciated with sense perceptins macrscpic bulk prperties f the system directly assciated with sense perceptins

Descriptin f Physical Systems variables: micrscpic xvapke,,,,, PE,... Thery: Classical/Quantum Mechanics Newtn s Eqs, Maxwell s Eqs, Schrdinger s Eq (later) variables: macrscpic TPVUS,,,,,... Thery: Thermdynamics 0 th Law f Therm. 1 st Law f Therm. 2 nd Law f Therm. Statistical Mechanics (e.g. Kinetic Thery)

Temperature (T) Cmmn usage: a measure f ht & cld Physics definitin: average KE f mlecules (mre n this next chapter) Physical changes assciated with T: Mst materials expand when heated Pressure f gas (in a clsed cntainer) with T Electrical resistance changes with T Materials radiate at different at different T State f matter change with T Ice water steam

Measuring Temperature/Thermmeter A small amunt f liquid will typically increase in vlume as temperatures rise. Mercury was chsen early n because it s dense; a small vlume can recrd a large temperature range. The pressure f a fixed vlume f gas will rise if temperature rises.

Measuring Temperature/Thermmeter Anther cmmnly used measuring device relies n the differential expansin f a bimetal strip. D bimetal strip D infrared sensr

Temperature Scales Celsius ( C) & Fahrenheit ( F) are traditinally defined with tw readily reprducible reference states: (new) 5 TC TF 32 9 9 TF TC 32 5 Freezing pint & Biling pint f water at 1 atm.

Temperature Scales Celsius ( C) & Fahrenheit ( F) are traditinally defined with tw readily reprducible reference states: (new) 5 TC TF 32 9 9 TF TC 32 5 Freezing pint & Biling pint f water at 1 atm.

Abslute Zer and the Kelvin Scale (K) A Gas Thermmeter with sufficiently diluted gas (~Ideal Gas)

Abslute Zer and the Kelvin Scale (K) Imprtant Experimental Observatins: 1. P vs. T relatinship is linear fr all dilute gases. 2. All curves extraplate t a single zer pint with zer pressure. These imply There exists a unique abslute zer reference pint and ne can define an abslute temperature scale with it. At this abslute zer pint, Kelvin T Scale (K) TC 273.15 C T K T C 273.15

Thermal Equilibrium Observatin: When tw bjects at different T are brught tgether, they will eventually reach the same temperature and the system reaches an equilibrium state when n further physical changes ccur in the system. e.g. warm sda cans in a cler filled with ice

Thermal Equilibrium Additinal cncepts Heat (mre n this later): the transfer f energy between bjects with different T. Thermal Cntact: tw bjects are in thermal cntact if heat can transfer between them (nt necessary in physical cntact). Thermal equilibrium: the situatin in which tw bjects in thermal cntact cease t exchange energy by the prcess f heat.

The 0 th Law f Thermdynamics N heat flw between A-C and B-C. N heat flw between A-B. Nte: this transitive prperty is nt true fr all physical prcess, e.g. tw pieces f irn with a magnet but the 0 th Law have been shwn t be true experimentally.

Thermal Expansin (linear) Objects such as these railrad tracks will thermal expand when T increases. The size f the change will depend n the material. L L T 0 L L L L (1 T ) 0 0 T T T 0 is the cefficient f linear expansin

Thermal Expansin (vlume) Mlecules can be visualized as spheres cnnected by springs. At a given temperature, these mlecules vibrate accrding t the spring ptential energy. Because f the asymmetry f this ptential energy, the mlecules average separatin tends t increase with T. One can apprx. this vlume expansin by: V V T 0 is the cefficient f vlume expansin

Cefficients f Expansin Ntes: 1. These relatins are apprximately linear in a given range f T nly. & ~ cnstant in T range f interest. 3. Mst substances have & but sme are nt, e.g. water. Typically, 3

Linear and Vlume Expansin Rates V WHL Each f the linear dimensins expands accrding t the Linear Thermal Expansin equatin given previusly. W W W T, H H H T, L L L T (assuming material t be istrpic same in all directins) V ( W W T)( H H T )( L L T) 0 V V 3 V W H L W H TL W TH L W H L T T (nly terms up t T)