LESSON PLAN FOR EVEN SEM SESSION 2017-18 NAME OF ASSISTANT PROFESSOR :MS.HIMANI MADAAN CLASS/SECTION : B.SC. II(SEC.-C) SUBJECT :CHEMISTRY UNIT/PART I DATE 1-1-18 DATE 2-1-18 DATE 5-1-18 DATE 6-1-18 DATE 8-1-18 DATE 9-1-18 DATE 12-1-18 DATE 13-1-18 DATE 15-1-18 DAY 10 DATE 16-1-18 1 DATE 19-1-18 Separation of a m ixture of primary, seco ndary and tertiary amines. Structural features affecting basicity o f am ines Preparation o f alkyl and aryl amines (reductio n o f nitro com pounds, nitriles, reductive aminatio n of aldehydic and ketonic com pounds Gabriel-phthalimide reactio n, Hofmann brom am ide reactio n electro philic arom atic substitutio n in aryl am ines, reactio ns o f am ines with nitro us acid Molecular vibrations, Hooke's law, selectio n rules 2 DATE 20-1-18 3 DATE 22-1-18 4 DATE 23-1-18 5 DATE 26-1-18 intensity and position of IR bands. SPORTS DAY 1
DAY 16 DATE 27-1-18 UNIT/PART II DATE 29-1-18 DATE 30-1-18 DATE 2-2-18 DATE 3-2-18 m easurem ent o f IR spectrum, fingerprint region characteristic abso rptions o f various functional groups interpretation o f IR spectra o f simple o rganic com pounds. DATE 5-2-18 DATE 6-2-18 DATE 9-2-18 DATE 10-2-18 DATE 12-2-18 0 DATE 13-2-18 1 DATE 16-2-18 2 DATE 17-2-18 3 DATE 19-2-18 4 DATE 20-2-18 5 DATE 23-2-18 ASSIGNMENT 1 Applications o f IR spectro sco py in structure elucidatio n o f sim ple o rganic com pounds Mechanism o f diazo tisation, structure o f benzene diazonium chloride Replacement o f diazo group by H, OH, F, Cl, Br, I, NO 2 and CN group UNIT/PART III DATE 24-2-18 reductio n of diazonium salts to hyrazines 2
DATE 26-2-18 DATE 27-2-18 DATE 2-3-18 DATE 3-3-18 DATE 5-3-18 DATE 6-3-18 DATE 9-3-18 DATE 10-3-18 DAY 10 DATE 12-3-18 1 DATE 13-3-18 2 DATE 16-3-18 3 DATE 17-3-18 4 DATE 19-3-18 5 DATE 20-3-18 DAY 16 DATE 23-3-18 DAY 17 DATE 24-3-18 coupling reactio n and its synthetic application ASSIGNMENT 2 Nomenclature and structure of the carbonyl group Synthesis of aldehydes and ketones with particular reference to the synthesis of aldehydes from acid chlorides advantage of oxidation of alcohols with chromium trioxide (Sarett reagent) pyridinium chlorochromate (PCC) and pyridinium dichromate UNIT/PART IV DATE 26-3-18 DATE 27-3-18 3
DATE 30-3-18 DATE 31-3-18 DATE 2-4-18 DATE 3-4-18 DATE 6-4-18 DATE 7-4-18 DATE 9-4-18 0 DATE 10-4-18 1 DATE 13-4-18 2 DATE 14-4-18 3 DATE 16-4-18 4 DATE 17-4-18 5 DATE 20-4-18 Comparison of reactivities of aldehydes and ketones and their physical properties Mechanism of nucleophilic additions to carbonyl group with particular emphasis on benzoin, aldol Perkin and Knoevenagel condensations. Wittig reaction. Mannich reactio n Condensation with ammonia and its derivatives Oxidation of aldehydes, Baeyer Villiger oxidation of ketones, Cannizzaro reaction. MPV, Clemmensen Wolff-Kishner, LiAlH 4 and NaBH 4 reductions NAME OF ASSISTANT PROFESSOR CLASS/SECTION SUBJECT :MS. HIMANI :B.SC.III(A) :ORGANIC CHEMISTRY UNIT/PART I Introduction to organosulfur:methods of DATE 1-1-18 formation,chem. Rxn. Of thiol andthioether Sulphonic acid DATE 2-1-18 DATE 5-1-18 Synthetic detergent DATE 8-1-18 Introduction of heterocyclic compounds 4
DATE 9-1-18 DATE 12-1-18 DATE 15-1-18 DAY 8 DATE 16-1-18 DATE 19-1-18 0 DATE 22-1-18 1 DATE 23-1-18 2 DATE 26-1-18 UNIT/PART II DATE 29-1-18 DATE 30-1-18 DATE 2-2-18 DATE 5-2-18 DATE 6-2-18 DATE 9-2-18 DATE 12-2-18 DATE 13-2-18 DATE 16-2-18 0 DATE 19-2-18 1 DATE 20-2-18 12 DATE 23-2-18 UNIT/PART III DATE 26-2-18 Methods of synthesis,chemical reaction of,mechanism of nucleophilic substitution in pyridine Comparision of basicity of pyridine,pyrolle and piperidine. SPORTS DAY Introduction to five and six membered heterocycles Preparation and reaction of indole and quinolone Skraup synthesis and bischler napieralski synthesis Introduction to ammino acids Preparation of ammino acids Structure of protein and classification of protein Peptide structure det. And classical peptide synthesis Structure of peptide and protein 5
DATE 27-2-18 DATE 2-3-18 DATE 5-3-18 DATE 6-3-18 DATE 9-3-18 DAY 7 DATE 12-3-18 DATE 13-3-18 DATE 16-3-18 0 DATE 19-3-18 1 DATE 20-3-18 DAY 12 DATE 23-3-18 UNIT/PART IV DATE 26-3-18 DATE 27-3-18 DATE 30-3-18 DATE 2-4-18 DATE 3-4-18 DATE 6-4-18 DATE 9-4-18 DATE 10-4-18 DATE 13-4-18 0 DATE 16-4-18 1 DATE 17-4-18 Synthesis of polymers:addition polymerisation Free radical polymerisation Polyester and polyammide Phenol formaldehyde resin Urea resin,epoxy resin and polyurathanes Chain growth polymerisation Vinyl polymerisation Synthesis of natural rubber Synthesis of synthetic rubber Organic synthesis via enolates,acidity of alpha hydrogen Alkylation of ethyl acetoacetate Synthesis of ethyl acetoacetate Claisen condensation Keto enol tautomeridm of ethyl acetoacetate Alkylation of diethyl malonate 6
2 DATE 20-4-18 NAME OF ASSISTANT PROFESSOR CLASS/SECTION SUBJECT UNIT/PART I DATE 1-1-18 DATE 3-1-18 DATE 4-1-18 DATE 8-1-18 DATE 10-1-18 0 DATE 11-1-18 3 DATE 15-1-18 5 DATE 17-1-18 6 DATE 18-1-18 1 DATE 24-1-18 2 DATE 25-1-18 UNIT/PART II DATE 29-1-18 DATE 31-1-18 DATE 1-2-18 DATE 5-2-18 DATE 7-2-18 0 DATE 8-2-18 3 DATE 12-2-18 : MS.HIMANI : M.SC.(FINAL) :ORGANIC CHEMISTRY General aspects of structure determination of terpenoids Structure elucidation of geraniol Synthesis of geraniol Structure elucidation of alpha-terpiniol Synthesis of alpha-terpiniol Structure elucidation of alpha-pinene 7
5 DATE 14-2-18 Day16 Date 15-2-18 9 SESSIONAL DATE 19-2-18 1 DATE 21-2-18 2 DATE 22-2-18 UNIT/PART III Synthesis of alpha-pinene DATE 26-2-18 DATE 28-2-18 DATE 1-3-18 Structure of camphor DATE 5-3-18 0 DATE 7-3-18 1 DATE 8-3-18 DAY 14 Synthesis of camphor DATE 12-3-18 6 DATE 14-3-18 7 DATE 15-3-18 0 DATE 19-3-18 Structure elucidation of squalene 2. DATE 21-3-18 3. DATE 22-3-18 UNIT/PART IV Synthesis of squalene DATE 26-3-18 DATE 28-3-18 DATE 29-3-18 Biogenetic isoprene rule 8
DATE 2-4-18 DATE 4-4-18 0 DATE 5-4-18 3 DATE 9-4-18 5 DATE 11-4-18 6 DATE 12-4-18 9 DATE 16-4-18 1 DATE 18-4-18 2 DATE 19-4-18 Biogenesis of terpinoids SESSIONAL 9