Improved Oil Recovery in the Cypress Using an Unconventional Approach

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Improved Oil Recovery in the Cypress Using an Unconventional Approach Nathan D. Webb IOGA Annual Convention March 2, 2017

2 Acknowledgments Project Co-PIs Scott Frailey Hannes Leetaru Geology Nathan Webb Zohreh Askari John Grube Kalin Howell Yaghoob Lasemi Geocellular modeling and well log analysis Nate Grigsby Reservoir Simulation Roland Okwen Fang Yang Research herein was supported by the US Department of Energy contract number DE-FE0024431 Through a university grant program, IHS Petra, Geovariences Isatis, and Landmark Software was used for the geologic, geocellular, and reservoir modeling, respectively

3 Presentation Outline Background: Cypress Sandstone and ROZs Geologic Characterization Well Log Analysis & Preliminary Reservoir Simulation Results Summary

4 Cypress Sandstone Cypress Sandstone presents nco 2 -EOR and storage opportunity NE-SW trending fairway of incised valley fill sandstone deposits though the central Illinois Basin Cypress Provinces & Production Figure modified from Nelson et al. 2002 Cypress Stratigraphic Model eroded thick sandstone fairway Figure modified from Nelson et al 2002 Figure modified from Webb and Grube 2014; no scale implied

5 Valley Fill Cypress Ss Reservoirs Thin Oil Reservoirs Residual and mobile oil above brine Difficult to produce economically due to water coning and management Nonconventional EOR Bypassed oil in the conventional reservoir Potential for underlying Residual Oil Zone (ROZ) MPZ

Depth (feet) 6 What is an ROZ? Result of Mother Nature s Waterflood Brownfield: Has MPZ Greenfield: No MPZ Same characteristics as swept portions of a mature waterflood Permian Basin examples 15% to 35% S o 10% to 20% can be recovered by CO 2 -EOR Scale and saturations could be quite different in the Illinois Basin Ideal water saturation profile Water Saturation 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1 2550 2560 2570 2580 MPZ Producing OWC 2590 2600 2610 ROZ 2620 2630 2640 Ultimate OWC 2650 2660 2670 2680 2690 2700 2710 2720 100% Sw 100% Sw OWC POWC Water Saturation

Modified from Lewan et al. 2002 7 How does an ROZ Form? ROZs form through successive oil migration in the subsurface Steuber et al 1993 Secondary migration from mature source driven by buoyancy and hydrodynamic flow followed catchments emplaced in the Cypress Ss over much of the basin

8 How do we identify an ROZ? Geophysical logs Well log analysis of existing logs New cased hole pulsed neutron logs (Planned for 2017) Cores Testing for oil saturation in existing cores Evidence of petroleum trapped in mineral cements Quantifying oil saturation in fresh core (Planned for 2017) Mapping Evidence of tilted oil-water contacts that may reflects tectonic or hydrodynamic changes Geochemistry Evidence of biodegraded oils (Planned for 2017) Decrease in API Gravity and n-alkanes Sterane and hopane biomarkers absent

Geologic Characterization 9

10 Geologic Characterization Oil field studies Noble Field Kenner West Field Loudon Field Dale Field Regional studies Core Outcrop

Case Studies: Noble and Kenner West Fields Oil fields with documented production from the thick Cypress Sandstone Abundant core and log data available for detailed characterization 11

Cumulative Production (Million Bbls oil) Yearly Production (Million Bbls oil) Cumulative Production (Million Bbls oil) Annual Production (100,000 Bbls oil) Case Studies: Noble and Kenner West Fields 50 Noble Field Production 5 2.5 Kenner West Field Production 400 45 4.5 350 40 35 4 3.5 2 300 30 3 1.5 250 25 2.5 200 20 2 1 150 15 1.5 10 1 5 0.5 0 0 1935 1955 1975 1995 2015 Year Comingled Cumulative Cypress Cumulative Comingled Yearly Cypress Yearly Cypress Production = 24 MMBO OOIP = 95 to 110 MMBO Recovery Efficiency = ~25% 100 0.5 50 0 0 1940 1960 1980 2000 Year Comingled Cumulative Cypress Cumulative Cumulative Yearly Cypress Yearly Cypress Production = 1.3 MMBO OOIP = 7.8 to 10 MMBO Recovery Efficiency = ~15% 12

Noble Correlations Example Noble Field Cross Section Correlated nearly 1,000 logs to map geometry of thick Cypress Sandstone Stacked sandstone bodies Lower sheet sandstone extends out of field Upper sandstone bodies change facies laterally 13

14 Noble Maps Cypress net sandstone isopach map OWC structure map Up to 170 ft thick sandstone intersects Clay City Anticline Tilted OWC with down dip oil saturation to the SW; Paleo-OWC related calcite cement? MPZ up to 55 ft thick; 110 ft closure Oil reservoir isopach map

15 Kenner West Correlations Similar to Noble Field, but better developed upper Cypress Ss lenses

Kenner West Maps Cypress net sandstone isopach map Base of Barlow Ls structure map 1 mile-wide N-S sandstone trend intersects small dome forming structural-stratigraphic trap Sandstone up to 100 ft thick; MPZ up to 35 ft thick; 40 ft closure OWC tilts slightly to the southeast Oil reservoir isopach map 16

Comparison with Xenia East Field No thick Cypress Ss oil production from Xenia East, 4 mi south of KW Xu and Huff 1995 Structural closure plays a role in oil emplacement, but so does geology of the Cypress Are there areas where thick Cypress Ss is oil productive when there are upper Cypress Ss lenses? Cypress shales are leaky seals? 17

18 Core Study How do we interpret the geology and understand the geologic controls on reservoir properties? Rocks! Noble Field Whole core of upper 30-40 ft in two wells Chips/partial core from a handful of old wells Kenner West Field No cores, but lots of core analysis data Cypress Outcrops Kenner West Noble

19 Samples and Core Samples can reveal general lithology and texture and provide material to test for oil saturation Cores allow detailed sedimentological study but are usually limited to the MPZ

Sedimentology 121592606400 Montgomery B-34 Flaser/wavy-bedded vf Ss Ripple-bedded vf-f Ss Cross-bedded f-m Ss Decreasing depositional energy 20

21 Integrating Core/Outcrop Studies? Can we build on core studies by leveraging outcrops to better understand internal reservoir architecture of the Cypress?

17 Tripp #1 Core Drilled Sept 2016 in Union Co., IL Southern end of valley fill Cypress fairway 259 ft TD 160 ft Cypress Fm 100 ft thick Ss Near I-57 roadcut and Cypress Creek outcrops

Tripp #1 Properties 19 10.00% 15.00% 20.00% 86.2 87.8 89.4 91.4 93.4 95 96.2 98.1 99.6 101.3 103 105.3 107.3 109.3 111.6 115.1 117.3 119.4 121.9 123.6 125.6 127.2 129 135 137 140.3 143.2 145.4 147.7 150.9 152.7 154.6 156 157.9 159.5 161.6 163.3 165.6 167.5 169.5 171.2 174.6 176.7 178.9 180.5 183 184.9 Porosity 0 200 400 600 86.2 87.8 89.4 91.4 93.4 95 96.2 98.1 99.6 101.3 103 105.3 107.3 109.3 111.6 115.1 117.3 119.4 121.9 123.6 125.6 127.2 129 135 137 140.3 143.2 145.4 147.7 150.9 152.7 154.6 156 157.9 159.5 161.6 163.3 165.6 167.5 169.5 171.2 174.6 176.7 178.9 180.5 183 184.9 Permeability (md)

19 Relating Core to Outcrop Multistory fluvial channels Channels likely form flow units within a reservoir Stacked sandstone channels are not a continuous genetic body Grain size increase, basal lags, and juxtaposing lithofacies

25 Parallels to Basin Interior Cypress Creek Tripp 1 Dale Oil Field Similar sedimentology to oilfield cores Dominantly vf-f cross bedded and ripple bedded sandstone with coarser sand in channel bases Channel bases hard or impossible to identify on well logs, but permeability is likely a better proxy Next: Correlation with existing core in Loudon Field and an upcoming core from Noble Field

26 Controls on Porosity/Permeability Depositional environment and diagenetic history control reservoir properties Field Loudon Noble Porosity and permeability vary amongst fields in the Illinois Basin Kenner West Dale Minor variations in depositional environment? Different diagenetic histories in different areas of the basin? Location Eastern Fayette County Western Richland County Southwestern Clay County Southern Hamilton County Depth to Typical porosity, Typical permeability, Cypress, ft (m) % md (μm 2 ) 1,600 (487.7) 19.2 80.9 (0.080) 2,600 (792.5) 18.0 482.0 (0.476) 2,600 (792.5) 18.0 106.0 (0.105) 2,900 (883.9) 13.5 62.5 (0.062)

27 Controls on Porosity/Permeability Analyzed XRD results for bulk and clay mineralogy Related mineralogical composition to facies and porosity / permeability

28 Controls on Porosity/Permeability Hybrid pore system of primary intergranular and secondary porosity from dissolution of grains and cements Long, well-connected pores contribute to the exceedingly high permeability observed in Noble Field

29 Reservoir Architecture Compartmentalization despite being relatively homogeneous Grain size variation relating to channel stacking Minor thin shale interbeds and heterolithic intervals within the sandstone body Some can be laterally extensive Calcite cements Some concurrent with and others unrelated to OWC

20 Depositional Environments Interpreted the Cypress Sandstone at Noble Field as part of an incised valley fill system (LST-TST) Erosional base, multistory sandstone, overall fining upward (f-vf) Becomes estuarine at the top (lower energy, more clays, lower reservoir quality) Distinct environment from Cypress Ss tidal shoals Wright and Marriott 1993 Dalrymple and Choi 2007

31 Depositional Environments 121592606400 Montgomery B-34 Summary of major facies and attributes for Carboniferous valley-fill sequence Archer et al 1994

32 Analogue: Bartlesville Ss Braided fluvial lower sheet sandstone Meandering fluvial middle sandstone Tidal-estuarine upper facies Ye and Kerr 2000

16 Summary of Characterization Multistory valley fill Cypress Sandstone dominated by high energy deposits with good reservoir properties Depositional and diagenetic controls on porosity and permeability Sandstone texture and sedimentary structures very similar across the basin Diagenetic factors may be responsible for regional variation in porosity and permeability Combination of structural and stratigraphic controls on oil trapping; tilted OWCs a clue for ROZs Through DOE investment in ROZ and CO 2 -EOR and research, we learn a lot about geology and reservoir properties of the Cypress Sandstone

34 Well Log Analysis & Preliminary Reservoir Simulation Results

Depth (feet) Depth (feet) Well Log Analysis Ideal ROZ saturation curve Analyses applied to detect ROZ Water Saturation 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1 2550 2560 2570 MPZ 2580 2590 2600 2610 ROZ 2620 2630 2640 2650 2660 100% Sw 2670 100% Sw 2680 OWC 2690 POWC 2700 2710 Water Saturation 2720 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1 2550 2560 2570 2580 2590 2600 2610 2620 2630 2640 2650 2660 2670 2680 2690 2700 2710 2720 Possible ROZ 100% Sw OWC POWC Rwa MHI BVW Rw MPZ Movable Hydrocarbon Index, Bulk Volume Water, Water Resistivity 35

Depth (ft) 36 Example from Kenner West Field Curves 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 1.4 1.5 2550 2560 2570 2580 2590 2600 2610 2620 2630 Water Saturation Water Saturation MHI Rw Rwa BVW Quantity Main Pay Zone (MPZ) 6 ft thick 40% oil saturation 0.5 feet of oil σ 1 S w φ Residual Oil Zone (ROZ) 48 Feet 10 25% oil saturation 1.8 feet of oil σ 1 S w φ 2640

37 Kenner West saturation model MPZ Thin MPZ at the top of the Cypress Ss OOIP 7.8 MMBO MPZ + ROZ Much thicker underlying ROZ OOIP 19.7 MMBO 10% 20% 30% 40% 50% 60% S o

Daily production (stb/d) Np (MSTB) 38 Kenner West Reservoir Simulations: History Match Compare simulation results to historical production Increase confidence in geologic and geocellular models and distribution of oil and water within the formation 800 700 Daily oil production rates Field data Simulation 1200 Cumulative oil production 600 1000 500 800 400 600 300 200 400 100 0 1946 1951 1956 1961 1966 1971 1976 1981 1986 1991 1996 2001 2006 Year Primary Waterflood Primary Waterflood 200 Field data Simulation 0 1946 1951 1956 1961 1966 1971 1976 1981 1986 1991 1996 2001 2006 Year

39 Kenner West Reservoir Simulations Time 1: Before EOR Starts CO 2 Saturation After Primary/waterflood Water coning/inefficient recovery of MPZ Permeability Distribution Oil Saturation

40 Kenner West Reservoir Simulations Time 2: EOR Starts CO 2 Saturation Perforations: From base of ROZ to top of MPZ Permeability Distribution Oil Saturation

41 Kenner West Reservoir Simulations Time 1: Before EOR Starts CO 2 Saturation Buoyancy and solubility of CO 2 sweep ROZ and MPZ Permeability Distribution Oil Saturation

42 Kenner West Reservoir Simulations Time 4: 8 Years of EOR CO 2 Saturation Permeability Distribution Oil Saturation

Np (MSTB) Qo (STB/D) Kenner West Reservoir Simulations: Future Projections Testing various injection scenarios EOR produces additional oil over waterflood in the MPZ and MPZ+ROZ 9.8% of MPZ OOIP produced via EOR 5.6% of MPZ+ROZ OOIP produced via EOR Cumulative Oil Production Oil Production rates 3450 3200 2950 10000 MPZ MPZ + ROZ WF Baseline 2700 1000 2450 2200 1950 100 1700 1450 1200 MPZ MPZ + ROZ WF Baseline 0 1000 2000 3000 4000 5000 6000 7000 8000 10 0 1000 2000 3000 4000 5000 6000 7000 8000 Days Days 43

44 Summary of Log Analysis and Simulation Log analyses also indicate possible ROZs below MPZ Still need physical evidence of ROZ resource Planned core through entire thickness of the Cypress in Noble Field Planned cased hole logs through entire thickness of the Cypress in Noble Field Reservoir simulations show potential for increasing oil production from the MPZ and new production from the ROZ

45 Project Outcomes Quantification of the potential ROZ resource within the Cypress Sandstone Better understanding of how to develop valley fill Cypress Sandstone reservoirs DOE investment may yield identification of ROZ resource and has allowed us to advance our geological understanding of the Cypress Ss New outcrop studies and cores (one near outcrop, one in Noble Field) Sampling/testing of numerous shale units for TOC content and biomarkers Sampling/testing of oils from the Cypress Ss for biomarkers and linking to source rock

Nathan D. Webb ASSISTANT PETROLEUM GEOLOGIST ndwebb2@illinois.edu 615 E. Peabody Dr. Champaign, IL 61820-6918 +1 217 244 2426 http://isgs.illinois.edu/research/erd/nco2eor