Investigation of the flow in a flat bottom cyclone

Similar documents
LOCAL VELOCITY MEASUREMENTS AND COMPUTATIONAL FLUID DYNAMICS (CFD) SIMULATIONS OF SWIRLING FLOW IN A CYLINDRICAL CYCLONE SEPARATOR

Three-dimensional measurements in the baffle region of a turbulently stirred tank

Intensely swirling turbulent pipe flow downstream of an orifice: the influence of an outlet contraction

Temperature, Pressure and Velocity measurements on the Ranque-Hilsch Vortex Tube

LASER DOPPLER VELOCIMETRY AND CONFINED FLOWS

Evolution of the pdf of a high Schmidt number passive scalar in a plane wake

A comparative study on the hydrodynamics of liquid liquid hydrocyclonic separation

Flow measurements over a moving sandy bed

CHARACTRISTICS OF HYDROCYCLONE FLOWS. Mustafa A1 kayed

Numerical Study Of Flue Gas Flow In A Multi Cyclone Separator

Applied Fluid Mechanics

Applied Fluid Mechanics

PIV measurements of flow structures in a spray dryer

FIELD TEST OF WATER-STEAM SEPARATORS FOR THE DSG PROCESS

Flow Structure Investigations in a "Tornado" Combustor

Information on the Particle Dynamics Analysis (PDA) measurements

PIV measurements and convective heat transfer of an impinging air jet

Journal of Petroleum Science and Engineering

PDA Measurements of Single Point Injection in Cross-flow

SIMULTANEOUS VELOCITY AND CONCENTRATION MEASUREMENTS OF A TURBULENT JET MIXING FLOW

PARTICLE MOTION IN WATER-PARTICLE, GAS-PARTICLE AND GAS-DROPLET TWO-PHASE FLOWS

NUMERICAL SIMULATION OF THREE DIMENSIONAL GAS-PARTICLE FLOW IN A SPIRAL CYCLONE

Flow Characteristics around an Inclined Circular Cylinder with Fin

Computational Modelling and Analysis of the Flow and Performance in Hydrocyclones

CFD ANALYSIS FOR DESIGN OPTIMIZATION OF REVERSE FLOW TYPE CYCLONE SEPARATOR

Simultaneous Velocity and Concentration Measurements of a Turbulent Jet Mixing Flow

Numerical investigation of the flow in a swirl generator, using OpenFOAM

T H E U N I V E R S I T Y O F T U L S A THE GRADUATE SCHOOL DISPERSED TWO-PHASE SWIRLING FLOW CHARACTERIZATION FOR PREDICTING GAS CARRY-UNDER

MODULE 1 Mechanical Measurements

AN UNSTEADY AND TIME-AVERAGED STUDY OF A GROUND VORTEX FLOW

Cyclones. Vane Axial Cyclone 10/30/2013. EVE 402 Air Pollution Generation and Control. Chapter #5 Lectures (Part 4) A mechanical gas cleaning device

Flow analysis in centrifugal compressor vaneless diffusers

GA A22722 CENTRAL THOMSON SCATTERING UPGRADE ON DIII D

EFFECT OF PARTICLES DENSITY ON HOLDUP MASS AND HEAT TRANSFER RATE IN SOLID CYCLONE HEAT EXCHANGER

An Essential Requirement in CV Based Industrial Appliances.

Transactions on Engineering Sciences vol 9, 1996 WIT Press, ISSN

PARTICLE IMAGE VELOCIMETRY MEASUREMENTS IN AN AERATED STIRRED TANK

Evaluation and accuracy of the local velocity data measurements in an agitated vessel

Measurement of Dust Cloud Characteristics in Industrial Plants 1

CFD SIMULATION OF A SINGLE PHASE FLOW IN A PIPE SEPARATOR USING REYNOLDS STRESS METHOD

Experimental investigation of the draft tube inlet flow of a bulb turbine

White Paper FINAL REPORT AN EVALUATION OF THE HYDRODYNAMICS MECHANISMS WHICH DRIVE THE PERFORMANCE OF THE WESTFALL STATIC MIXER.

Experimental Investigation of the Velocity Distribution near the Swirl Generator of a Uniflow Cyclone for Performance Data Prediction

6. Laser Doppler Anemometry. Introduction to principles and applications

nozzle which is fitted to a pipe through which the liquid is flowing under pressure.

THE DETAILS OF THE TURBULENT FLOW FIELD IN THE VICINITY OF A RUSHTON TURBINE

An Experimental Investigation to Control the Flow Emerging From a Wide Angle Diffuser

A Comparative Study of Omega RSM and RNG k Model for the Numerical Simulation of a Hydrocyclone

Dynamic Effect of Discharge Flow of a Rushton Turbine Impeller on a Radial Baffle J. Kratěna, I. Fořt, O. Brůha

Basic Fluid Mechanics

A study of turbulence and cyclic variation levels in internal combustion engine cylinders

Fluid Flow Characteristics of a Swirl Jet Impinging on a Flat Plate

Chapter 24 Photonics Question 1 Question 2 Question 3 Question 4 Question 5

Boundary Layer Transition on the Suction Side of a Turbine Blade

Discharge measurements

INTERACTION OF AN AIR-BUBBLE DISPERSED PHASE WITH AN INITIALLY ISOTROPIC TURBULENT FLOW FIELD

Instrumentation. Dr. Hui Hu Dr. Rye Waldman. Department of Aerospace Engineering Iowa State University Ames, Iowa 50011, U.S.A

Laser Doppler Anemometry. Introduction to principles and applications

PASSIVE CONTROL ON JET MIXING FLOWS BY USING VORTEX GENERATORS

Manual Laser Doppler Anemometry Manual remote experiment Project e-xperimenteren+

Chapter Ray Optics and Optical Instrument

Laboratory exercise 1: Open channel flow measurement

PIV MEASUREMENTS AND CFD SIMULATION OF VISCOUS FLUID FLOW IN A STIRRED TANK AGITATED BY A RUSHTON TURBINE

EVALUATION OF FOUR TURBULENCE MODELS IN THE INTERACTION OF MULTI BURNERS SWIRLING FLOWS

Experimental and numerical analysis of eight different volutes with the same impeller in a squirrel-cage fan

2.2 The Turbulent Round Jet

Velocity and temperature measurements in a large-scale Rayleigh-Bénard experiment using LDA and micro thermistors

Experimental Study on the Non-reacting Flowfield of a Low Swirl Burner

Flow and heat transfer characteristics of tornado-like vortex flow

6. Laser Doppler Anemometry. Introduction to principles and applications

Detailed Outline, M E 320 Fluid Flow, Spring Semester 2015

3-Component-Doppler-Laser-Two-Focus Velocimetry Applied to a Transonic Centrifugal Compressor


ENGINEERING FLUID MECHANICS. CHAPTER 1 Properties of Fluids

Tenth International Symposium on Applications of Laser Techniques to Fluid Mechanics- July 2000, Lisbon, Portugal

Confined and Agitated Swirling Flows with Applications in Chemical Engineering

APPLICATION OF SHADOW DOPPLER VELOCIMETRY TO ARBITRARY-SHAPED DROPLET MEASUREMENT IN WATER SPRAY

MEASUREMENT OF LAMINAR VELOCITY PROFILES IN A PROTOTYPIC PWR FUEL ASSEMBLY. Sandia National Laboratories b. Nuclear Regulatory Commission

Effect of the Liquid Injection Angle on the Atomization of Liquid Jets in Subsonic Crossflows

A CFD Analysis on the Effect of Vortex Finder and

FLOW MEASUREMENT. INC 102 Fundamental of Instrumentation and Process Control 2/2560

Reynolds number effects in a turbulent pipe flow for low to moderate Re

NUMERICAL AND EXPERIMENTAL STUDIES OF LIQUID-LIQUID MIXING IN A KENICS STATIC MIXER

Studies on the Performance of Air Cyclone Separator for Removal of Particulate Matter

Paper ID ICLASS EFFECTS OF CAVITATION IN A NOZZLE ON LIQUID JET ATOMIZATION

ME332 FLUID MECHANICS LABORATORY (PART I)

A Review on Gas Solid Cyclone Separator Parametric Analysis Shah Nikhil 1

Visualization of flow pattern over or around immersed objects in open channel flow.

A Study of The Turbulent Flows in Sloping and Adversely Sloping Rectangular Culvert

ON THE ACCURACY OF SCALAR DISSIPATION MEASUREMENTS BY LASER RAYLEIGH SCATERING.

Comparison Between Flow Velocity Profiles In Conical and Cylindrical Hydrocyclones

ON THE CONDITIONS OF CLOGGING IN A HYDROCYCLONE. Dueck, Johann 1,2

LDV Measurements in the Endwall Region of an Annular Turbine Cascade Through an Aerodynamic Window

Robust and Miniaturized Interferometric Distance Sensor for In-Situ Turning Process Monitoring

Study of injection typology on turbulent homogeneous mixing in a natural gas swirl burner

The Effect of Endplates on Rectangular Jets of Different Aspect Ratios

Experimental Study of Near Wake Flow Behind a Rectangular Cylinder

PIV study for the analysis of planar jets in cross-flow at low Reynolds number

Chapter 4. Experimental Results - Statistics

INFLUENCE OF VAPOR FEED DESIGN ON THE FLOW DISTRIBUTION

Transcription:

Investigation of the flow in a flat bottom cyclone by B. Chiné (1) and F. Concha (2) (1) Catholic University of Concepción, Faculty of Engineering Campus San Andrés, Paicavi 000, Concepción, Chile E-mail: bchine@david.ucsc.cl (2) University of Concepción, Department of Metallurgical Engineering Edmundo Larenas 270, Concepción, Chile E-mail: fconcha@udec.cl ABSTRACT The main objective of this investigation was to determine the velocity profiles of a swirling flow in a flat bottom cyclone, a cylindrical vessel with central discharges used for classifying or separating particles in industrial processes. A two component laser Doppler velocimeter was used to measure the axial and the tangential component of velocity. A perspex model of a flat bottom cyclone 10,5 mm high and with a diameter of 102 mm was installed in an experimental rig under controlled water flow conditions. The velocity profiles were measured for two different overflow tube (vortex finder) diameters and three different values of pressure drop p in the cyclone. For each cyclone, three different values of both under flowrate through the apex tube and over flowrate through the vortex finder were thus originated, the Reynolds number Re varying in the range 1 x 4, 7 10 4 2, 80x10. Velocity data were measured on four symmetrical vertical halfplanes of aimuthal coordinates = 0º, 90º, 180º, 270º respectively. The experimental results have shown that the flow is approximately a forced vortex near the air core and a free vortex in the region between the radial coordinate of and the solid wall. The value of, M v, M, the maximum of the tangential velocity, v grows with p and it is virtually the same for changes in. The radial position of v, M varies lightly through the vessel and it moves radially outwards when the feed pressure increases. In the axial direction the velocity field gives two opposite axial flows separated by a cylindrical surface, where the axial velocity is ero. It has been observed that v, M, the maximum of the axial velocity, increases with p and decreases linearly with. The measurements obtained by laser Doppler velocimetry (LDV) have exhibited that both v and v present greater fluctuations near the solid wall and near the air-liquid interface. Then the turbulence is neither homogenous nor isotropic, since the RMS values of v are also greater than RMS values of v, except near the air core where they are of the same magnitude. Finally, we have observed that the velocity profiles are axisymmetric with exception of the region near the apex discharge and near the air core. The LDV data obtained varying the Re number have proved that the flow does not depend on feed pressure, since the flow changes only its magnitude, while the velocity and the turbulence profiles maintain a constant pattern. Again, when the experimental tests were developed varying the vortex finder diameter only a change in the magnitude of the flow was detected, yielding similar velocity and turbulence fields.

1. INTRODUCTION Since 1891, when Bretney patented the conical hydrocyclone, basically two cyclone shapes have been applied industrially, the conical and the cylindrical one. The conical cyclone is the most widespread dynamic classifier while the cylindrical classifier with central discharges or flat bottom cyclone is used in a lesser extent, although during the last years the use of the flat bottom cyclone in the mining and chemical industry has grown considerably. The general flow pattern inside a cyclone is a threedimensional swirling flow known as a Rankine s vortex, combination of a forced vortex and a free vortex. The flow is completed by an axial movement in two opposite directions, one towards the apex (underflow discharge) near the walls and one more towards the vortex finder (overflow discharge) near the centre of the vessel, where an air core forms. Some authors investigated this flow and reported their measurements using LDV for the conical cyclone, among others Hsieh and Rajamani (1991) and Fisher and Flack (1998) who measured velocity profiles in a hydrocyclone and an industrial cleaner respectively. The former authors gave a complete mapping of tangential v and axial v velocities in the hydrocyclone and calculated the radial velocity from the continuity equation. On the other hand Fisher and Flack (1998) made experimental measurements of radial velocity and confirmed the three-dimensional nature of the swirling flow. However only a few studies have been carried out to determine the flow pattern in cylindrical cyclones. Baranov et al. (1984), who using an electrodiffusion method measured the tangential velocity v, have studied a cylindrical cyclone with an upper central discharge and an under peripheral discharge. Being r the radial coordinate they showed that v modifies its radial profiles from the top, where is v k r, to the bottom of the cyclone where v describes a Rankine vortex. Using laser Doppler velocimetry Chiné et al. (1996) studied a similar cyclone and reported measurements of axial and tangential velocities. In their work they applied a back-pressure at the tangential under exit and, confirming the Baranov s results, showed also that the swirling flow depend on these pressure conditions. Then the axial velocity profile indicated the existence of less sharp transition region between the two main opposite flows, if compared to the conical cyclone profile. To properly evaluate numerical predictions, Hoekstra et al. (1998) studied the precessing vortex core (PVC) in a gas cyclone applying both LDV and PIV (Particle Image Velocimetry) techniques. By applying a simple model it was shown that the PVC has an important effect on the RMS values of velocity. Recently Chiné and Concha (1999) have compared flow patterns in conical and flat bottom cyclones showing that v is similar in both types of vessel while the axial velocity is different. In fact although there is the same profile made of two axial opposite flows, in the flat bottom cyclone v changes nearly linear with the axial coordinate. The slope of the v curve decreases with up to the bottom region where v is nearly ero, except in the area close to the air core where we find an upward flow. The following paragraphs describe the experimental work and present velocity data in a flat bottom cyclone measured by laser Doppler velocimetry, as a result of a research (Chiné, 1999) carried out to map the swirling flow in this vessel. 2. EXPERIMENTAL WORK 2.1 Cyclone and test rig A flat bottom cyclone model made with well-machined perspex material was used in the laser Doppler measurements. The cyclone has a diameter D of 102 mm and a total height H of 10,5 mm. The flow enters the cyclone through an involute inlet tube with a 16 mm x 4 mm rectangular crossing area. The cylindrical section of the cyclone is 01 mm deep while the short bottom conical section has a height of 9,5 mm and an included angle of 154º. The exit of the overflow is through a vortex finder with two different diameters D of 2 mm (cyclone 1) and 25 mm (cyclone 2). For both cyclones 1 and 2 the diameter O D of the apex underflow discharge is held invariable to 19 mm. U Water at room temperature (19 20 ºC) was fed to the model under controlled flow conditions. The fluid was pumped from a 0,665 m sump by using a 4 Hp pump and regulated by a set of valves. Feed pressure and flow rates were monitored with very accurate manometers and rotameters, as shown schematically in Fig. 1, while the discharged flows were measured by using a sharp crested weir mounted above the sump. To minimise the optical refraction of the laser beams at the curved cyclone walls, the model was immersed in a water-filled jacket. Finally, to generate tracer particles for the LDA measurements latex painting particles were added to the fluid. 2

overflow to the sump manometer feed probe transmitter laser rotameter traverse system power M BSA S IEEE-488 oscilloscope PC software underflow sump pump Fig. 1 The experimental rig. 2.2 Experimental Technique The velocity profiles inside the vessel were measured using a commercial laser Doppler velocimeter, which is shown in Fig. 1. The velocimeter was a Dantec two-component fibre-optic system with Burst Spectrum Analyers (BSA) and an automatic computer-controlled, three component traverse system. Coherent light with wavelength in the range 457 514,5 nm was directed to a transmitter box from a 00 mw Argon-ion laser, where frequency shifting to remove the direction ambiguity of the velocities and colour separation was performed. Green (514,5 nm) and blue (488 nm) light was then used to measure axial velocity and tangential velocity respectively. A Bragg cell split the light in two beams with a 40 MH frequency shift. These beams then passed through a dispersion prism which provided the two green an two blue light beams. The shifted and direct beams were led to an output aperture, where fibre manipulators were used to focus the beams into the fibre optic cables. Then a probe with a 160 mm focal length and a beam intersection angle of 0,26 rad caused the four beam to intersect. The same lens collected the scattered light coming back from the measurement volume, then the light was separated into green and blue components and directed to two photomultipliers. The Doppler signals were processed in two BSA with Fast Fourier Transform in order to extract the Doppler frequencies. The experimental data were transferred via an IEEE-488 interface to a computer for processing. During the measurements the

probe was moved using a highly accurate three component (x-y-) traverse system controlled by a computer via an RS-22 interface. As it was said before, the cyclone was immersed in a water filled jacket. This way, the change in the refractive index n, as well as the grade of refraction were lower as the light passed from the surrounding water ( n = 1,) to the perspex ( n = 1,49) than they would have been in absence of the jacket. The position of the laser beam intersection within the fluid was obtained by using an empirical relationship after measuring the real path of the light. This was achieved by moving the measurement volume between the opposite extreme locations at the inner side of the cyclone wall. Velocity data were measured on four symmetrical vertical positions chosen on the curved walls (aimuthal coordinates = 0º, 90º, 180º, 270º). Being r and the radial and axial coordinate respectively, the laser beams were focused on a median vertical r, halfplane crossing the model, one for each aimuthal coordinate. On the median vertical plane, seven vertical measurement levels were chosen giving a uniform measurement axial step equal to 40 mm, with exception of the last section, where the axial step was set to 0 mm. For a given coordinate, the first measurement point was placed near the wall of the cyclone and the last point was chosen in proximity of the air core. Radial steps r of 2,7 mm and 0,675 mm were applied. Finally, a sample of typically 1000 Doppler bursts was taken for each measurement point in all the experimental work.. RESULTS For both cyclones 1 and 2 the velocity profiles were measured at three feed pressure values p, which originated different values of under Q U and over Q O flowrate, through the apex tube and the vortex finder tube respectively. Table 1a and 1b give the operating conditions for cyclones 1 and 2 respectively. Table 1a: Operating conditions for cyclone 1. Pressure drop p ( psi) Inlet velocity V in) (m/s Cyclone 1: Flowrate Q D O = 2 mm, D U = 19 mm, D / D 1, 68 Over flowrate Q O Under flowrate Q U O U = Q Q U O Reynolds number Re Swirl number S 4 2,06 1,42x10-1,27x10-0,15x10-0,118 4 1, 77x10 4,1 6,5 2,75 1,89x10-1,76x10-0,1x10-0,074 4 2, 6x10 4,14 9,26 2,24x10-2,11x10-0,1x10-0,062 4 2, 80x10 4,2 Table 1b: Operating conditions for cyclone 2. Pressure drop p ( psi) Inlet velocity V in) (m/s Cyclone 2: Flowrate Q D O = 25 mm, D U = 19 mm, D / D 1, 2 Over flowrate Q O Under flowrate Q U O U = Q Q U O Reynolds number Re Swirl number S 4 1,60 1,10x10-0,7x10-0,7x10-0,507 4 1, 7 x10 4,14 6,5 2,15 1,48x10-1,10x10-0,8x10-0,46 4 1, 85 x10 4,00 9 2,57 1,77x10-1,5x10-0,42x10-0,11 4 2, 21x10 4,09 4

In Table 1a and 1b V in is the inlet velocity, Q is the feed flowrate, Re= V D / ν is the Reynolds number, 2 V= 4Q / π D is the mean velocity axial velocity in the cyclone, D is the cyclone diameter and ν is the water cinematic viscosity. To quantify the vortex intensity in the cyclone, the swirl number D 2 D 2 2 D 2 S = r v vdr r v dr 2 was used, where R W is the vortex finder external ratio. Numerical RW RW integration of S was made using an integration interval equal to the experimental measurement step. The values of v and v used in the computation are velocity data for = 65mm, measured above the vortex finder entry region. The final value of S is the mean of the values calculated for = 0º, 90º, 270º. The LDV measurements carried out on the four halfplanes = 0º, 90º, 180º, 270º have given axisymmetric velocity profiles with exception of the region near the apex discharge and the air core. Then we will analyse here only the velocity profiles for the halfplane = 90º. For the cyclone 1, fig. 2a and 2b give the experimental profiles for the axial v and tangential v velocity when p is equal to 4 and 9 psi respectively. In both cases the experimental results show that the flow is approximately a forced vortex near the air core and a free vortex in the region between the radial coordinate of v, M (the maximum of the tangential velocity) and the solid wall. Also there are two opposite axial currents separated by a cylindrical surface where the axial velocity is ero. The radial coordinate of v = 0 is constant along the cyclone down to the bottom. The slope of v curve decreases with and for = 295mm and, if we excluded the region near the air core, the axial velocity is practically ero. v In fig. a we plot, M, the maximum of the overflow axial velocity: it increases with p and decreases linearly with. Fig. b gives the values of v, M which grows with p and it is virtually the same for changes in. We observe that the radial coordinate of v, M varies lightly through the vessel and moves radially outwards when the feed pressure increases, as fig. 2 confirmed. The LDV data indicate (fig. c) that v, the maximum of the underflow axial velocity, increases with p and decreases with. In figs., m 4a, 4b and 4c the values of v, its RMS values and the intensity of turbulence are plotted for = 105mm and p = 4; 6, 5; 9 psi, while the tangential velocity data are given in figs. 5a, 5b and 5c. Both v and v present greater fluctuations near the solid wall and near the air liquid interface, then the turbulence is not homogenous, even though corrections would be made near the air core because of the precessing vortex core (Hoekstra et al. 1998). Finally it has been observed that the turbulence is not isotropic, since the RMS values of v are always greater than RMS values of v, except near the air core where they are of the same magnitude. The change of velocity with the variation of the vortex finder diameter (cyclone 2 ) is presented by means of fig. 6, where we give the LDV profiles obtained for p equal to 4 and 9 psi respectively. Although the reduction of the vortex finder diameter produces a larger flow towards the apex, the structure of the flow is the same, as it could be expected. Again the flow does not depend on feed pressure, since the flow changes only its magnitude, while the velocity and also the turbulence profiles maintain a constant pattern. 4. CONCLUSIONS Axial and tangential velocities and their RMS values have been measured in a flat bottom cyclone by laser Doppler velocimetry. The technique provided to be a useful tool in characterising the swirling flow in the cyclone. The results of the experimental work show that the inlet pressure affects only the magnitude of the velocities, but does not change the flow pattern. As in a conical cyclone, the tangential velocity describes a Rankine vortex while the axial velocity originates two opposite flows and furthermore it changes near linearly with the coordinate. For both components of velocity the turbulent fluctuations are greater near the wall and the air core, but the RMS values of the axial velocity are always bigger than the RMS of the tangential velocity. 5

6

7

8

9

10

ACKNOWLEDGEMENTS The authors acknowledge partial financial support of this work by the Fondef project D97-I2042, Chile. REFERENCES K.T. Hsieh and R.K Rajamani, Mathematical Model of the Hydrocyclone Based on Physics of Fluid Flow, AIChE Journal, 7(5), 1991, 75-746. M.J. Fisher and R.D. Flack, Laser Velocimetry Measurements in a Cyclone Separator, Proc. 9th International Symposium on Applications of Laser Techniques to Fluid Mechanics, 1-16 July 1998, Lisbon (Portugal), 8.1.1.-8.1.7. D. Baranov, A.M. Kutepov and I.G Ternovskii, Flow Rate Characteristics and Hydrodynamics of a Counterflow Cylindrical Hydrocyclone, Journal of Applied Chemistry - USSR (English trad.), 57(5), 1984, 1181-1184. B. Chiné, F. Concha and G. Ferrara, LDA Measurements of Axial and Tangential Velocity Components in a DMS Cylindrical Cyclone, Proc. 8th International Symposium on Applications of Laser Techniques to Fluid Mechanics, 8-11 July 1996, Lisbon (Portugal), 19.6.1.-19.6.6. A.J. Hoekstra, A.T. Israël, J.J. Derksen and H.E.A. Van den Akker, The Application of Laser Diagnostic to Cyclonic Flow with Vortex Precession, Proc. 9th International Symposium on Applications of Laser Techniques to Fluid Mechanics, 1-16 July 1998, Lisbon (Portugal), 4..1.-4..8. B. Chiné and F. Concha, Flow Patterns in Conical and Cylindrical Hydrocyclones, Journal of Separation and Purification Technology, accepted for publication (1999). B. Chiné, Experimental Study of the Swirling Flow in Hydrocyclones (in spanish), MSc. Thesis (1999), Department of Metallurgical Engineering, University of Concepción, Chile. 11