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Welcome to Phys 774: Principles of Spectroscopy Fall 2007 Instructor: Andrei Sirenko Associate Professor at the Dept. of Physics, NJIT http://web.njit.edu/~sirenko 476 Tiernan Office hours: After the classes on We. s or by appointment 973-596-5342 Class Schedule: Wednesday 11:30am - 12:55pm FMH 106 Friday 1:00pm - 2:25pm FMH 203 Lecture 2 Andrei Sirenko, NJIT 1 Lecture 2 Andrei Sirenko, NJIT 2 Spectrum of Electromagnetic Radiation and Light How can we produce EM waves? Lecture 2 Andrei Sirenko, NJIT 3 Lecture 2 Andrei Sirenko, NJIT 4

How can we analyze EM waves? Position Wavelength Resolution How can we analyze EM waves? Resolution depends on d number of groves per mm Prism vs. Grating Lecture 2 Andrei Sirenko, NJIT 5 Lecture 2 Andrei Sirenko, NJIT 6 How can we analyze EM waves? Energy Dispersive Principle http://www4.nau.edu/microanalysis/microprobe/course%20overview.html How can we analyze EM waves? Interferometry Principle Lecture 2 Andrei Sirenko, NJIT 7 Lecture 2 Andrei Sirenko, NJIT 8

Light and Atoms Light and Atoms Lecture 2 Andrei Sirenko, NJIT 9 Lecture 2 Andrei Sirenko, NJIT 10 Light and Atoms Light and Atoms Lecture 2 Andrei Sirenko, NJIT 11 Lecture 2 Andrei Sirenko, NJIT 12

Light and Atoms Light and Atoms: Photoelectric Effect Lecture 2 Andrei Sirenko, NJIT 13 Lecture 2 Andrei Sirenko, NJIT 14 Light and Atoms: Photoelectric Effect Wave-Particle Duality Lecture 2 Andrei Sirenko, NJIT 15 Lecture 2 Andrei Sirenko, NJIT 16

Wave-Particle Duality The interaction of radiation with matter Lecture 2 Andrei Sirenko, NJIT 17 Lecture 2 Andrei Sirenko, NJIT 18 The interaction of radiation with matter Application of Lasers Laser Dreams TELECOMMUNICATION Lecture 2 Andrei Sirenko, NJIT 19 Lecture 2 Andrei Sirenko, NJIT 20

Types of Lasers The laser medium can be a solid, gas, liquid or semiconductor. Solid-state lasers have lasing material distributed in a solid matrix (such as the ruby or neodymium:yttrium-aluminum garnet "YAG" lasers). The neodymium-yag laser emits infrared light at 1064 nanometers (nm). Gas lasers (helium and helium-neon, HeNe, are the most common gas lasers) have a primary output of visible red light. CO2 lasers emit energy in the far-infrared, and are used for cutting hard materials. Excimer lasers (the name is derived from the terms excited and dimers) use reactive gases, such as chlorine and fluorine, mixed with inert gases such as argon, krypton or xenon. When electrically stimulated, a pseudo molecule (dimer) is produced. When lased, the dimer produces light in the ultraviolet range. Dye lasers use complex organic dyes, such as rhodamine 6G, in liquid solution or suspension as lasing media. They are tunable over a broad range of wavelengths. Semiconductor lasers, sometimes called diode lasers, are not solid-state lasers. These electronic devices are generally very small and use low power. They may be built into larger arrays, such as the writing source in some laser printers or CD players. Regular Light Laser Light What is the difference? Properties of laser radiation: Monochromatic Coherent Directional Stimulated emission and gain And more: Ring lasers, Disk lasers, Free electron lasers, Lecture 2 Andrei Sirenko, NJIT 21 Lecture 2 Andrei Sirenko, NJIT 22 Laser Wavelength Regular Light Like rain Properties of laser radiation: Monochromatic Coherent Directional Stimulated emission and gain Laser Light Lecture 2 Andrei Sirenko, NJIT 23 Lecture 2 Andrei Sirenko, NJIT 24

Regular Light COHERENCE: Like rain Regular Light COHERENCE: Laser Light Laser Light go! go! Lecture 2 Andrei Sirenko, NJIT 25 Lecture 2 Andrei Sirenko, NJIT 26 Visible Lasers: Red Laser Orange Laser Yellow Laser Green Laser Blue Laser Typical Laser Wavelengths: Laser Type Argon fluoride (UV) Krypton fluoride (UV) Xenon chloride (UV) Nitrogen (UV) Argon (blue) Argon (green) Helium neon (green) Helium neon (red) Rhodamine 6G dye (tunable) Wavelength (nm) 193 248 308 337 488 514 543 633 570-650 Indigo Laser Violet Laser Anything else? Lecture 2 Andrei Sirenko, NJIT 27 Ruby (CrAlO 3 ) (red) Nd:Yag (NIR) 1064 Carbon dioxide (FIR) 10600 Lecture 2 Andrei Sirenko, NJIT 28 694

MEMS OXC-- 2N Mirror Design Optical Transmission System I/O Fibers Laser Transmitter(s) Optical Fiber Amp Amplifier Amp Detector Receiver(s) Reflector MEMS 2-axis Tilt Mirrors Imaging Lenses Beam scanning during connection setup. 30-100 miles Lecture 2 Andrei Up to Sirenko, 10,000 NJIT miles 29 2N MEMS mirrors in an NxN single-mode fiber optical crossconnect. Lecture 2 Andrei Sirenko, NJIT 30 Principles of Laser Radiation Principles of 3-level laser operation Lecture 2 Andrei Sirenko, NJIT 31 Lecture 2 Andrei Sirenko, NJIT 32

Principles of the Solid State Laser operation Semiconductor Lasers Lecture 2 Andrei Sirenko, NJIT 33 Lecture 2 Andrei Sirenko, NJIT 34 Three level energy diagram of the He-Ne laser transition Fundamentals of Laser Operation If the atom is in the excited state, it may decay into the ground state by the process of spontaneous emission: E 2 E 1 = hν the rate of which stimulated emission, where ρ(ν) is the radiation density of photons : 2S electron impact interatomic collision 1S 3S 1E-7 sec Laser transition 632 nm 1E-8 sec 2P The laser process in a HeNe laser starts with collision of electrons from the electrical discharge with the helium atoms in the gas. This excites helium from the ground state to the long-lived, metastable excited states. Collision of the excited helium atoms with the ground-state neon atoms results in transfer of energy to the neon atoms. This is due to a coincidence of energy levels between the helium and neon atoms. This process is given by the reaction equation: He* + Ne He + Ne* + E Stimulated emission cross section Optical amplification where g 1 and g 2 are the degeneracies of energy levels 1 and 2, respectively General gain equation Saturation intensity: 1S diffusion to wall Helium Neon Lecture 2 Andrei Sirenko, NJIT 35 Gain: Large signal: Lecture 2 Andrei Sirenko, NJIT Saleh, Bahaa E. A. and Teich, Malvin Carl (1991). Fundamentals of Photonics. 36 New York: John Wiley & Sons. ISBN 0-471-83965-5. The intensity of the stimulated emission [W/m 2 ]

Examples of transverse Gaussian laser modes Examples of longitudinal laser modes Lecture 2 Andrei Sirenko, NJIT 37 Lecture 2 Andrei Sirenko, NJIT 38